CN111205752A - UV-cured powder flame-retardant coating containing cage-structure flame retardant and preparation method thereof - Google Patents
UV-cured powder flame-retardant coating containing cage-structure flame retardant and preparation method thereof Download PDFInfo
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- CN111205752A CN111205752A CN202010111173.6A CN202010111173A CN111205752A CN 111205752 A CN111205752 A CN 111205752A CN 202010111173 A CN202010111173 A CN 202010111173A CN 111205752 A CN111205752 A CN 111205752A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention relates to a UV curing powder flame retardant coating containing a cage-like structure flame retardant and a preparation method thereof, and is characterized in that: weighing 5-20% of a flame-retardant system, 70-85% of UV (ultraviolet) light curing resin, 0-10% of titanium dioxide, 2-5% of a photoinitiator and 1-3% of an auxiliary agent, and then adding the materials into a premixer to mix for 3-5min at 300-600rpm to obtain a mixture; and then putting the mixture into an extruder for extrusion, wherein the temperature of the extruder is 70-110 ℃, and then cooling, tabletting, crushing, grinding, and finally sieving and grading to obtain the UV curing powder flame-retardant coating containing the cage-structure flame retardant. Its advantage does: the flame-retardant system is simple, the flame retardant containing a cage-like structure is used, the formula is simplified, and the flame-retardant performance of the flame-retardant coating is improved.
Description
Technical Field
The invention relates to the technical field of flame retardant coatings, in particular to a UV curing powder flame retardant coating containing a cage-shaped flame retardant and a preparation method thereof.
Background
The fire disaster is one of the multiple disasters in the world at present, and the flame-retardant coating is coated on the surface of the flammable base material, so that the combustion performance of the surface of the base material can be changed, the fire disaster is prevented from rapidly spreading, the escape or rescue time is prolonged, and the danger and property loss caused by the fire disaster are reduced. The UV flame-retardant coating is a UV coating with a flame-retardant function, and is a newly developed flame-retardant coating variety. The invention discloses a Chinese patent application with the publication number of CN103525272A and the name of 'a flame-retardant UV photocureable coating and a preparation method thereof', wherein a flame-retardant system such as tetrabutyl phosphorus chloride, hexabromocyclododecane and the like is added into the coating, so that the coating has good flame-retardant performance. The invention discloses a Chinese patent application with the publication number of CN103788843A and the name of 'high-gloss flame-retardant UV photocureable coating and a preparation method thereof', and the coating obtains good flame-retardant performance by mixing sodium phytate, carbon nano tubes and oligosaccharide. The invention discloses a dust-proof antibacterial fireproof UV photocureable coating and a preparation method thereof, and the dust-proof antibacterial fireproof UV photocureable coating is disclosed in the Chinese invention patent application with the publication number of CN103805034A, wherein nano chitin and aluminum hydroxide are added, so that the coating is stable in dispersion and not easy to settle, the fireproof performance is improved, and the dust-proof antibacterial fireproof UV photocureable coating has excellent water resistance and antibacterial effect, is safe and environment-friendly. The Chinese patent application with the publication number of CN104087152A and the name of 'a flame-retardant UV photocureable coating' has the advantages of high curing rate, environmental protection, high safety, low use cost and the like by adding an aluminum compound and sodium sulfate. The invention discloses a Chinese patent with publication number CN104312423A and name 'a UV curing flame retardant coating', which takes ammonium polyphosphate, ammonium phosphate, urea phosphate, ammonium pyrophosphate or ammonium dihydrogen phosphate, pentaerythritol, tripentaerythritol, mannitol, xylitol, caramel, cellulose and derivatives thereof or dipentaerythritol as a flame retardant system to obtain the UV coating with excellent flame retardant property. The invention discloses a Chinese patent application with the publication number of CN105585942A and the name of 'a UV-cured transparent flame-retardant coating', which takes phosphorus-modified bisphenol epoxy acrylic resin and phosphorus-modified novolac epoxy acrylic resin as film-forming substances, and improves the flame-retardant effect of a coating. The invention discloses a Chinese patent application with the publication number of CN106118331A and the name of 'a fireproof and deformation-preventing environment-friendly UV coating and a preparation method thereof', and the safe and environment-friendly UV flame-retardant coating is prepared by adopting inorganic flame-retardant systems such as coconut shell activated carbon, sericite, alumina, quartz sand and the like. The invention discloses a Chinese patent application with the publication number of CN107652875A and the name of 'UV fire-retardant coating and a preparation method thereof', which takes flame-retardant modified fluorine-containing hyperbranched polyurethane-epoxy acrylate resin copolymer (phosphorus) as an additive, and greatly improves the flame-retardant property of the coating.
In the prior art listed above, the halogen-containing flame retardant has a good flame retardant effect, but is not environment-friendly, and the phosphorus-nitrogen flame retardant system has poor water resistance, and the development of a novel flame retardant system is one of the research hotspots in the field of flame retardant coatings.
Disclosure of Invention
The invention aims to provide a UV curing powder flame-retardant coating containing a cage-shaped flame retardant and a preparation method thereof.
In order to achieve the aim, the UV curing powder flame retardant coating containing the cage-shaped flame retardant is realized by the following steps of, by mass, 5-20% of a flame retardant system containing the cage-shaped flame retardant, 70-85% of UV light curing resin, 0-10% of titanium dioxide, 2-5% of a photoinitiator and 1-3% of an auxiliary agent.
In the technical scheme, the UV-curable powder flame-retardant coating containing the cage-structure flame retardant according to claim 1 is characterized in that the flame-retardant system can be independently used with the cage-structure flame retardant, or can be formed by compounding ammonium polyphosphate, melamine polyphosphate, piperazine pyrophosphate or aluminum hypophosphite with the cage-structure flame retardant, wherein the mass ratio of the ammonium polyphosphate, the melamine polyphosphate, the piperazine pyrophosphate or the aluminum hypophosphite to the cage-structure flame retardant is 5:1-1: 5; wherein:
the structural formula of the flame retardant containing the cage-like structure is as follows:
in the formula: y is NH or O; x is phenyl, phenoxy, phenylamino and one of phenyl with substituent or phenoxy or phenylamino; r is a straight chain or branched chain alkyl containing 1-18 carbon atoms, and one of a p-phenyl group, a m-phenyl group or an o-phenyl group;
the ammonium polyphosphate is high-polymerization degree crystal II type ammonium polyphosphate, and the polymerization degree n is more than or equal to 1500;
the polymerization degree n of the polyphosphoric acid melamine is more than or equal to 1000.
In the technical scheme, the UV light-cured resin is one or more of acrylic resin, epoxy resin, polyurethane resin, polyester resin and vinyl ether resin.
In the technical scheme, the photoinitiator is one or more of 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl phenyl propyl ketone, 2,4, 6-trimethyl benzoyl diphenyl phosphorus oxide and α -dimethyl- α -phenyl acetophenone.
In the technical scheme, the auxiliary agent comprises one or more of a leveling agent and a degassing agent.
In the technical scheme, the preparation process of the UV curing powder flame retardant coating containing the cage-like structure flame retardant is characterized by comprising the following steps of: weighing 5-20% of a flame-retardant system, 70-85% of UV (ultraviolet) light curing resin, 0-10% of titanium dioxide, 2-5% of a photoinitiator and 1-3% of an auxiliary agent, and then adding the materials into a premixer to mix for 3-5min at 300-600rpm to obtain a mixture; and then putting the mixture into an extruder for extrusion, wherein the temperature of the extruder is 70-110 ℃, and then cooling, tabletting, crushing, grinding, and finally sieving and grading to obtain the UV curing powder flame-retardant coating containing the cage-structure flame retardant.
Compared with the prior art, the invention has the advantages that: the flame-retardant system is simple, the flame retardant containing a cage-like structure is used, the formula is simplified, and the flame-retardant performance of the flame-retardant coating is improved.
Detailed Description
The following further describes the embodiments of the present invention. It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
Example one
The UV curing powder flame-retardant coating containing the cage-structure flame retardant is prepared by accurately weighing 640g of polyester resin, 60g of TGIC, 100g of ammonium polyphosphate (APP), 50g of cage-structure flame retardant (FR 1), 100g of rutile titanium dioxide, 30g of 1-hydroxycyclohexyl phenyl ketone, 10g of degasifier and 10g of flatting agent, adding the weighed materials into a premixer, mixing at 600rpm for 3min to obtain a mixture, then putting the mixture into an extruder for extrusion, controlling the temperature of an area I of the extruder to be 70 ℃ and the temperature of an area II of the extruder to be 90 ℃, cooling, tabletting, crushing, grinding, and finally sieving and grading to obtain the UV curing powder flame-retardant coating containing the cage-structure flame retardant. The oxygen index of the coating prepared by the coating is 28.0%.
Example two
The UV curing powder flame-retardant coating containing the cage-structure flame retardant is prepared by accurately weighing 350g of acrylic resin, 350g of polyester resin, 75g of melamine polyphosphate (MPP), 25g of cage-structure flame retardant (FR 2), 100g of anatase titanium dioxide, 40g of 2-hydroxy-2-methyl propiophenone, 10g of degassing agent and 20g of leveling agent, adding the above materials into a premixing machine, mixing for 4min at 450rpm to obtain a mixture, then putting the mixture into an extruding machine for extrusion, controlling the temperature of an area I of the extruding machine to be 75 ℃ and the temperature of an area II of the extruding machine to be 90 ℃, then cooling, tabletting, crushing, grinding, and finally sieving and grading to obtain the UV curing powder flame-retardant coating containing the cage-structure flame retardant. The oxygen index of the coating prepared by the coating is 24.0 percent.
EXAMPLE III
Firstly, accurately weighing 650g of acrylic resin, 150g of epoxy resin, 120g of piperazine pyrophosphate (PPAP), 80g of cage-structure flame retardant (FR 3), 50g of rutile titanium dioxide, 35g of 2,4, 6-trimethylbenzoyl diphenyl phosphorus oxide, 10g of degasifier and 15g of flatting agent, adding the weighed materials into a premixer, mixing for 5min at 300rpm to obtain a mixture, then putting the mixture into an extruder, extruding the mixture, cooling the mixture in an area I of the extruder at 80 ℃, and the temperature in an area II of the extruder at 110 ℃, tabletting, crushing, grinding, and finally sieving and grading to obtain the UV-cured powder flame retardant coating containing the cage-structure flame retardant. The oxygen index of the coating prepared by the coating is 28.5%.
Example four
The UV curing powder flame-retardant coating containing the cage-structure flame retardant is prepared by accurately weighing 510g of polyester resin, 340g of epoxy resin, 80g of aluminum hypophosphite, 20g of cage-structure flame retardant (FR 4), 50g of anatase titanium dioxide, 20g of α -dimethyl- α -phenyl acetophenone, 10g of degassing agent and 15g of leveling agent, adding the components into a premixing machine, mixing for 4.5min at 500rpm to obtain a mixture, then putting the mixture into an extruding machine for extrusion, controlling the temperature of an area I of the extruding machine to be 70 ℃, controlling the temperature of an area II of the extruding machine to be 95 ℃, cooling, tabletting, crushing, grinding, and finally sieving and grading to obtain the UV curing powder flame-retardant coating containing the cage-structure flame retardant, wherein the oxygen index of the coating prepared by the coating is 26.5%.
EXAMPLE five
The UV curing powder flame-retardant coating containing the cage-structure flame retardant is prepared by accurately weighing 480g of acrylic resin, 350g of vinyl ether resin, 150g of ammonium polyphosphate (APP), 30g of cage-structure flame retardant (FR 5), 20g of 2-hydroxy-2-methyl propiophenone, 10g of degassing agent and 15g of flatting agent, adding the weighed materials into a premixer, mixing for 3min at 500rpm to obtain a mixture, then putting the mixture into an extruder, extruding the mixture, wherein the temperature of the area I of the extruder is 80 ℃, the temperature of the area II of the extruder is 90 ℃, cooling, tabletting, crushing and grinding, and finally sieving and grading to obtain the UV curing powder flame-retardant coating containing the cage-structure flame retardant. The oxygen index of the coating prepared by the coating is 25.5%.
（FR5）
EXAMPLE six
The UV curing powder flame-retardant coating containing the cage-structure flame retardant is prepared by accurately weighing 420g of acrylic resin, 280g of polyurethane resin, 100g of melamine polyphosphate (MPP), 75g of cage-structure flame retardant (FR 6), 50g of rutile titanium dioxide, 30g of 2,4, 6-trimethylbenzoyl diphenyl phosphorus oxide and 15g of degassing agent, adding the weighed materials into a premixer, mixing at 550rpm for 5min to obtain a mixture, then putting the mixture into an extruder, extruding, cooling at 85 ℃ in the area I of the extruder and at 95 ℃ in the area II of the extruder, tabletting, crushing, grinding, and finally sieving and grading to obtain the UV curing powder flame-retardant coating containing the cage-structure flame retardant. The oxygen index of the coating prepared by the coating is 27.5%.
EXAMPLE seven
The UV curing powder flame-retardant coating containing the cage-structure flame retardant is prepared by accurately weighing 550g of acrylic resin, 200g of amino resin, 200g of cage-structure flame retardant (FR 5), 30g of 1-hydroxycyclohexyl benzophenone, 10g of degassing agent and 10g of leveling agent, adding the acrylic resin, the amino resin, the 200g of cage-structure flame retardant, the 1-hydroxycyclohexyl benzophenone, the degassing agent and the leveling agent into a premixer, mixing for 5min at 300rpm to obtain a mixture, then putting the mixture into an extruder, extruding, tabletting, crushing and grinding at 80 ℃ in the I area of the extruder and 90 ℃ in the II area of the extruder, and finally sieving and grading to obtain the UV curing powder flame-retardant coating containing the cage-structure flame retardant. The oxygen index of the coating prepared by the coating is 26.0 percent.
Example eight
The UV curing powder flame-retardant coating containing the cage-structure flame retardant is prepared by accurately weighing 300g of acrylic resin, 100g of epoxy resin, 200g of cage-structure flame retardant (FR 6), 100g of rutile titanium dioxide, 30g of 2,4, 6-trimethylbenzoyl diphenyl phosphorus oxide, 10g of degasifier and 20g of flatting agent, adding the weighed materials into a premixer, mixing for 5min at 300rpm to obtain a mixture, then putting the mixture into an extruder, extruding the mixture at 80 ℃ in the I area of the extruder and 110 ℃ in the II area of the extruder, cooling, tabletting, crushing and grinding, and finally sieving and grading to obtain the UV curing powder flame-retardant coating containing the cage-structure flame retardant. The oxygen index of the coating prepared by the coating is 28.5%.
Because the flame-retardant system containing the cage-shaped flame retardant is added, the service performance of the product is improved; no flame-retardant system is added in the comparative example below, and the service performance of the product is poor.
Comparative example
Accurately weighing 250g of polyester resin, 250g of acrylic resin, 200g of rutile titanium dioxide, 30g of 2-hydroxy-2-methyl propiophenone, 10g of defoaming agent, 10g of leveling agent and 10g of leveling aid, adding the above materials into a pre-mixer, and mixing for 5min to obtain a mixture, wherein the rotating speed of the pre-mixer is 300 rpm; and then putting the mixture into an extruder for extrusion, cooling, tabletting, crushing, grinding, and finally sieving and grading to obtain the intumescent powder flame retardant coating, wherein the temperature of the first zone of the extruder is 85 ℃, and the temperature of the second zone of the extruder is 95 ℃. The coating produced with this paint had an oxygen index of 21%.
The flame retardant performance of the UV curing powder flame retardant coating containing the cage-structure flame retardant prepared in the first to eighth examples and the flame retardant performance of the common polyester powder coating prepared in the comparative example are in accordance with the standard GB/T2406.2-2009.
The embodiments of the present invention have been described in detail, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in the embodiments without departing from the principles and spirit of the invention, and these embodiments are within the scope of the invention.
Claims (6)
1. The UV curing powder flame-retardant coating containing the cage-shaped flame retardant is characterized by comprising 5-20% of a flame-retardant system containing the cage-shaped flame retardant, 70-85% of UV light-cured resin, 0-10% of titanium dioxide, 2-5% of a photoinitiator and 1-3% of an auxiliary agent in percentage by mass.
2. The UV-curable powder flame-retardant coating containing the cage-structure flame retardant according to claim 1, wherein the flame-retardant system can use the cage-structure flame retardant alone, or can use ammonium polyphosphate, melamine polyphosphate, piperazine pyrophosphate or aluminum hypophosphite to be compounded with the cage-structure flame retardant, and the mass ratio of the ammonium polyphosphate, melamine polyphosphate, piperazine pyrophosphate or aluminum hypophosphite to the cage-structure flame retardant is 5:1-1: 5; wherein:
the structural formula of the flame retardant containing the cage-like structure is as follows:
in the formula: y is NH or O; x is phenyl, phenoxy, phenylamino and one of phenyl with substituent or phenoxy or phenylamino; r is a straight chain or branched chain alkyl containing 1-18 carbon atoms, and one of a p-phenyl group, a m-phenyl group or an o-phenyl group;
the ammonium polyphosphate is high-polymerization degree crystal II type ammonium polyphosphate, and the polymerization degree n is more than or equal to 1500;
the polymerization degree n of the polyphosphoric acid melamine is more than or equal to 1000.
3. The UV-curable powder flame-retardant coating material containing a cage-like structure flame retardant according to claim 1, wherein the UV-curable resin is one or more of an acrylic resin, an epoxy resin, a polyurethane resin, a polyester resin and a vinyl ether resin.
4. The UV-curable powder flame-retardant coating material containing a cage-structured flame retardant according to claim 1, wherein the photoinitiator is one or more selected from 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl phenyl propyl ketone, 2,4, 6-trimethyl benzoyl diphenyl phosphorus oxide, and α -dimethyl- α -phenyl acetophenone.
5. The UV flame retardant coating material containing cage structure flame retardant according to claim 1, wherein the auxiliary agent comprises one or more of a leveling agent and a degassing agent.
6. The method for preparing a UV-curable powder flame-retardant coating material containing a cage-structured flame retardant according to claim 1, characterized by comprising the steps of: weighing 5-20% of a flame-retardant system, 70-85% of UV (ultraviolet) light curing resin, 0-10% of titanium dioxide, 2-5% of a photoinitiator and 1-3% of an auxiliary agent, and then adding the materials into a premixer to mix for 3-5min at 300-600rpm to obtain a mixture; and then putting the mixture into an extruder for extrusion, wherein the temperature of the extruder is 70-110 ℃, and then cooling, tabletting, crushing, grinding, and finally sieving and grading to obtain the UV curing powder flame-retardant coating containing the cage-structure flame retardant.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114058210A (en) * | 2021-12-21 | 2022-02-18 | 安徽省高泰新材料有限公司 | Water-based photo-curing ink composition, and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101857805A (en) * | 2010-05-13 | 2010-10-13 | 中国地质大学（武汉） | P-N type flame retardant and synthesis method thereof |
| CN103113619A (en) * | 2013-02-05 | 2013-05-22 | 东华大学 | Triazine ring containing caged organic phosphate flame retardant and preparation method thereof |
| CN107118347A (en) * | 2017-05-31 | 2017-09-01 | 顺德职业技术学院 | " Trinity " expansion type flame retardant and its synthetic method |
| CN110283486A (en) * | 2019-07-12 | 2019-09-27 | 顺德职业技术学院 | Novel UV curing powder anti-flaming dope and preparation method thereof |
-
2020
- 2020-02-24 CN CN202010111173.6A patent/CN111205752A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101857805A (en) * | 2010-05-13 | 2010-10-13 | 中国地质大学（武汉） | P-N type flame retardant and synthesis method thereof |
| CN103113619A (en) * | 2013-02-05 | 2013-05-22 | 东华大学 | Triazine ring containing caged organic phosphate flame retardant and preparation method thereof |
| CN107118347A (en) * | 2017-05-31 | 2017-09-01 | 顺德职业技术学院 | " Trinity " expansion type flame retardant and its synthetic method |
| CN110283486A (en) * | 2019-07-12 | 2019-09-27 | 顺德职业技术学院 | Novel UV curing powder anti-flaming dope and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114058210A (en) * | 2021-12-21 | 2022-02-18 | 安徽省高泰新材料有限公司 | Water-based photo-curing ink composition, and preparation method and application thereof |
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Application publication date: 20200529 |