CN111187006A - Low-melting-point powder special for high-temperature sintering printing ink and preparation method thereof - Google Patents
Low-melting-point powder special for high-temperature sintering printing ink and preparation method thereof Download PDFInfo
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- CN111187006A CN111187006A CN202010109282.4A CN202010109282A CN111187006A CN 111187006 A CN111187006 A CN 111187006A CN 202010109282 A CN202010109282 A CN 202010109282A CN 111187006 A CN111187006 A CN 111187006A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/01—Other methods of shaping glass by progressive fusion or sintering of powdered glass onto a shaping substrate, i.e. accretion, e.g. plasma oxidation deposition
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/1005—Forming solid beads
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
- C03C3/066—Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc
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- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the technical field of glass powder, and discloses a special low-melting-point powder for high-temperature sintering printing ink and a preparation method thereof, wherein the special low-melting-point powder comprises the following raw materials in parts by weight: 26-34 parts of quartz, 24-32 parts of boric acid, 11-19 parts of borax, 2-5 parts of aluminum oxide, 10-12 parts of bismuth oxide, 3-8 parts of zinc oxide, 1-3 parts of zirconium oxide, 3-6 parts of lithium carbonate, 3-6 parts of sodium carbonate and 3-6 parts of potassium carbonate; uniformly mixing the raw materials in the step 1), melting and cooling the raw materials in the step 2), and ball-milling and crushing the raw materials in the step 3). The low-melting-point powder special for the high-temperature sintering printing ink is good in compatibility, acid-base-resistant, capable of being used in a laminated mode, good in applicability to different pigments, free of scorching, capable of enabling the pigments and glass to be well fused together, and good in using effect.
Description
Technical Field
The invention relates to the technical field of glass powder, in particular to low-melting-point powder special for high-temperature sintering printing ink and a preparation method thereof.
Background
The glass powder is inorganic hard superfine particle powder, has good affinity and stronger steric hindrance capability after surface improvement, can be conveniently dispersed in the coating when being applied to the coating, can increase the fullness of the coating after film forming, and can be prepared into crystal transparent primer, thereby not only keeping clear transparency, but also providing good scratch resistance. The glass powder can also be used as a carrier to melt and attach the pigment substance to the surface of the glass body to achieve the required effect.
However, in the use of the glass powder products in the high temperature sintering field in the prior art, there are many problems of poor compatibility, for example, the glass powder used for white articles can not be applied to black articles, the universality is poor, and the glass powder is easy to generate a scorching problem when being used in a lamination manner, thereby seriously affecting the use of the glass powder.
Disclosure of Invention
The invention aims to solve the technical problem of providing the low-melting-point powder special for the high-temperature sintering printing ink and the preparation method thereof, the product has good compatibility, acid and alkali resistance, can be used in a laminated manner, has good applicability to different pigments, does not cause the problem of scorching, can well melt the pigments and glass together, and has good use effect.
In order to solve the technical problems, the technical scheme of the invention is as follows:
the low-melting-point powder special for the high-temperature sintering printing ink comprises the following raw materials in parts by weight: 26-34 parts of quartz, 24-32 parts of boric acid, 11-19 parts of borax, 2-5 parts of aluminum oxide, 10-12 parts of bismuth oxide, 3-8 parts of zinc oxide, 1-3 parts of zirconium oxide, 3-6 parts of lithium carbonate, 3-6 parts of sodium carbonate and 3-6 parts of potassium carbonate.
As a preferred embodiment, the low melting point powder special for high-temperature sintering printing ink comprises the following raw materials in parts by weight: 30 parts of quartz, 25 parts of boric acid, 15 parts of borax, 3 parts of aluminum oxide, 11 parts of bismuth oxide, 5 parts of zinc oxide, 2 parts of zirconium oxide, 5 parts of lithium carbonate, 5 parts of sodium carbonate and 5 parts of potassium carbonate.
As a preferred embodiment, the low melting point powder special for high-temperature sintering printing ink comprises the following raw materials in parts by weight: 28 parts of quartz, 26 parts of boric acid, 14 parts of borax, 4 parts of aluminum oxide, 12 parts of bismuth oxide, 6 parts of zinc oxide, 3 parts of zirconium oxide, 4 parts of lithium carbonate, 4 parts of sodium carbonate and 5 parts of potassium carbonate.
In a preferred embodiment, the particle size of the low-melting-point powder specially used for the high-temperature sintering printing ink is 0.5-1 μm.
The preparation method of the low-melting-point powder special for the high-temperature sintering printing ink comprises the following steps of:
step 1) mixing uniformly: weighing the raw materials in parts by weight, and uniformly mixing to obtain a primary mixed material;
step 2) melting and cooling: adding the primary mixed material obtained in the step 1) into a glass melting furnace, burning the primary mixed material into a liquid state, and cooling the liquid state to obtain a cooled material;
step 3), ball milling and crushing: adding the cooling material obtained in the step 2) into a ball mill, grinding, drying, and crushing to obtain the low-melting-point powder special for the high-temperature sintering printing ink.
As a preferred embodiment, the glass melting furnace temperature is set at 1100-1200 ℃.
Adopt above-mentioned technical scheme, the raw materials are chooseed for use and the quantity ratio is proportioned, through compatibility each other for this product is compatible good, but the stromatolite is used, and is good to the suitability of different pigment, and can not produce the problem of scorching, can make and melt well between pigment and glass together, excellent in use effect, and this product exhibition of colour is good, and acid and alkali resistance is excellent, accords with the printing ink operation requirement, and is exclusively used in the printing ink. The low-melting-point powder special for the high-temperature sintering printing ink has a simple preparation method, and the performance of the obtained product can be effectively guaranteed.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without creative efforts.
FIG. 1 is a flow chart of the preparation process of the low-melting-point powder special for high-temperature sintering printing ink of the invention.
Detailed Description
The following further describes embodiments of the present invention with reference to the drawings. It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
In the description of the present invention, it is to be understood that the terms "first", "second" and the like are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implying any number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one such feature. In the description of the present invention, "a plurality" means at least two, e.g., two, three, etc., unless specifically limited otherwise.
The present invention is further described in conjunction with the appended drawings to enable those skilled in the art to better practice the invention.
Example 1
The low-melting-point powder special for the high-temperature sintering printing ink comprises the following raw materials in parts by weight: 26 parts of quartz, 24 parts of boric acid, 11 parts of borax, 2 parts of aluminum oxide, 10 parts of bismuth oxide, 3 parts of zinc oxide, 1 part of zirconium oxide, 3 parts of lithium carbonate, 3 parts of sodium carbonate and 3 parts of potassium carbonate.
The grain diameter of the low-melting-point powder special for the high-temperature sintering printing ink is 0.5-1 mu m.
The preparation method of the low-melting-point powder special for the high-temperature sintering printing ink comprises the following steps:
step 1) mixing uniformly: weighing the raw materials in parts by weight, and uniformly mixing to obtain a primary mixed material;
step 2) melting and cooling: adding the primary mixed material obtained in the step 1) into a glass melting furnace, burning the primary mixed material into a liquid state, and cooling the liquid state to obtain a cooled material; the glass furnace temperature was set at 1100 ℃;
step 3), ball milling and crushing: adding the cooling material obtained in the step 2) into a ball mill, grinding, drying, and crushing to obtain the low-melting-point powder special for high-temperature sintering printing ink.
Example 2
The low-melting-point powder special for the high-temperature sintering printing ink comprises the following raw materials in parts by weight: 34 parts of quartz, 32 parts of boric acid, 19 parts of borax, 5 parts of aluminum oxide, 12 parts of bismuth oxide, 8 parts of zinc oxide, 3 parts of zirconium oxide, 6 parts of lithium carbonate, 6 parts of sodium carbonate and 6 parts of potassium carbonate.
The grain diameter of the low-melting-point powder special for the high-temperature sintering printing ink is 0.5-1 mu m.
The preparation method of the low-melting-point powder special for the high-temperature sintering printing ink comprises the following steps:
step 1) mixing uniformly: weighing the raw materials in parts by weight, and uniformly mixing to obtain a primary mixed material;
step 2) melting and cooling: adding the primary mixed material obtained in the step 1) into a glass melting furnace, burning the primary mixed material into a liquid state, and cooling the liquid state to obtain a cooled material; the glass furnace temperature was set at 1200 ℃;
step 3), ball milling and crushing: adding the cooling material obtained in the step 2) into a ball mill, grinding, drying, and crushing to obtain the low-melting-point powder special for high-temperature sintering printing ink.
Example 3
The low-melting-point powder special for the high-temperature sintering printing ink comprises the following raw materials in parts by weight: 28 parts of quartz, 26 parts of boric acid, 14 parts of borax, 4 parts of aluminum oxide, 12 parts of bismuth oxide, 6 parts of zinc oxide, 3 parts of zirconium oxide, 4 parts of lithium carbonate, 4 parts of sodium carbonate and 5 parts of potassium carbonate.
The preparation method of the low-melting-point powder special for the high-temperature sintering printing ink comprises the following steps:
step 1) mixing uniformly: weighing the raw materials in parts by weight, and uniformly mixing to obtain a primary mixed material;
step 2) melting and cooling: adding the primary mixed material obtained in the step 1) into a glass melting furnace, burning the primary mixed material into a liquid state, and cooling the liquid state to obtain a cooled material; the glass furnace temperature was set to 1150 ℃;
step 3), ball milling and crushing: adding the cooling material obtained in the step 2) into a ball mill, grinding, drying, and crushing to obtain the low-melting-point powder special for high-temperature sintering printing ink.
Example 4
The low-melting-point powder special for the high-temperature sintering printing ink comprises the following raw materials in parts by weight: 30 parts of quartz, 25 parts of boric acid, 15 parts of borax, 3 parts of aluminum oxide, 11 parts of bismuth oxide, 5 parts of zinc oxide, 2 parts of zirconium oxide, 5 parts of lithium carbonate, 5 parts of sodium carbonate and 5 parts of potassium carbonate.
The preparation method of the low-melting-point powder special for the high-temperature sintering printing ink comprises the following steps:
step 1) mixing uniformly: weighing the raw materials in parts by weight, and uniformly mixing to obtain a primary mixed material;
step 2) melting and cooling: adding the primary mixed material obtained in the step 1) into a glass melting furnace, burning the primary mixed material into a liquid state, and cooling the liquid state to obtain a cooled material; the glass furnace temperature was set at 1200 ℃;
step 3), ball milling and crushing: adding the cooling material obtained in the step 2) into a ball mill, grinding, drying, and crushing to obtain the low-melting-point powder special for high-temperature sintering printing ink.
Example 5
The low-melting-point powder special for the high-temperature sintering printing ink comprises the following raw materials in parts by weight: 32 parts of quartz, 31 parts of boric acid, 14 parts of borax, 4 parts of aluminum oxide, 12 parts of bismuth oxide, 7 parts of zinc oxide, 2 parts of zirconium oxide, 5 parts of lithium carbonate, 4 parts of sodium carbonate and 4 parts of potassium carbonate.
The grain diameter of the low-melting-point powder special for the high-temperature sintering printing ink is 0.5-1 mu m.
The preparation method of the low-melting-point powder special for the high-temperature sintering printing ink comprises the following steps:
step 1) mixing uniformly: weighing the raw materials in parts by weight, and uniformly mixing to obtain a primary mixed material;
step 2) melting and cooling: adding the primary mixed material obtained in the step 1) into a glass melting furnace, burning the primary mixed material into a liquid state, and cooling the liquid state to obtain a cooled material; the glass furnace temperature was set at 1200 ℃;
step 3), ball milling and crushing: adding the cooling material obtained in the step 2) into a ball mill, grinding, drying, and crushing to obtain the low-melting-point powder special for high-temperature sintering printing ink.
Adopt above-mentioned technical scheme, the raw materials are chooseed for use and the quantity ratio is proportioned, through compatibility each other for this product is compatible good, but the stromatolite is used, and is good to the suitability of different pigment, and can not produce the problem of scorching, can make and melt well between pigment and glass together, excellent in use effect, and this product exhibition of colour is good, and acid and alkali resistance is excellent, accords with the printing ink operation requirement, and is exclusively used in the printing ink. The low-melting-point powder special for the high-temperature sintering printing ink has a simple preparation method, and the performance of the obtained product can be effectively guaranteed.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
The embodiments of the present invention have been described in detail with reference to the accompanying drawings, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, and the scope of protection is still within the scope of the invention.
Claims (6)
1. The special low-melting-point powder for high-temperature sintering printing ink is characterized by comprising the following raw materials in parts by weight: 26-34 parts of quartz, 24-32 parts of boric acid, 11-19 parts of borax, 2-5 parts of aluminum oxide, 10-12 parts of bismuth oxide, 3-8 parts of zinc oxide, 1-3 parts of zirconium oxide, 3-6 parts of lithium carbonate, 3-6 parts of sodium carbonate and 3-6 parts of potassium carbonate.
2. The special low-melting-point powder for high-temperature sintering printing ink according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 30 parts of quartz, 25 parts of boric acid, 15 parts of borax, 3 parts of aluminum oxide, 11 parts of bismuth oxide, 5 parts of zinc oxide, 2 parts of zirconium oxide, 5 parts of lithium carbonate, 5 parts of sodium carbonate and 5 parts of potassium carbonate.
3. The special low-melting-point powder for high-temperature sintering printing ink according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 28 parts of quartz, 26 parts of boric acid, 14 parts of borax, 4 parts of aluminum oxide, 12 parts of bismuth oxide, 6 parts of zinc oxide, 3 parts of zirconium oxide, 4 parts of lithium carbonate, 4 parts of sodium carbonate and 5 parts of potassium carbonate.
4. The low melting point powder for high temperature sintering printing ink according to claim 1, wherein: the particle size of the low-melting-point powder special for the high-temperature sintering printing ink is 0.5-1 mu m.
5. The preparation method of the special low-melting-point powder for the high-temperature sintering printing ink as claimed in any one of claims 1 to 4, characterized by comprising the following steps:
step 1) mixing uniformly: weighing the raw materials in parts by weight, and uniformly mixing to obtain a primary mixed material;
step 2) melting and cooling: adding the primary mixed material obtained in the step 1) into a glass melting furnace, burning the primary mixed material into a liquid state, and cooling the liquid state to obtain a cooled material;
step 3), ball milling and crushing: adding the cooling material obtained in the step 2) into a ball mill, grinding, drying, and crushing to obtain the low-melting-point powder special for the high-temperature sintering printing ink.
6. The method for preparing the low-melting-point powder special for the high-temperature sintering printing ink according to claim 5, wherein the method comprises the following steps: the temperature of the glass melting furnace is set to 1100-1200 ℃.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010109282.4A CN111187006A (en) | 2020-02-22 | 2020-02-22 | Low-melting-point powder special for high-temperature sintering printing ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010109282.4A CN111187006A (en) | 2020-02-22 | 2020-02-22 | Low-melting-point powder special for high-temperature sintering printing ink and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011136890A (en) * | 2009-12-29 | 2011-07-14 | Central Glass Co Ltd | Lead-free low-melting-point glass paste for insulation coating |
| CN106085006A (en) * | 2016-06-16 | 2016-11-09 | 江苏大学 | Glass surface inkjet printing bismuth silicon boron system low melting point ink and preparation method thereof |
| CN106082682A (en) * | 2016-06-16 | 2016-11-09 | 江苏大学 | Glass air brushing bismuth silicon boron system's low-melting-point nano glass dust suspension and preparation method |
| CN109336399A (en) * | 2018-11-23 | 2019-02-15 | 刘世伟 | A kind of decorative devitrified glass material |
| CN110092589A (en) * | 2019-06-24 | 2019-08-06 | 湖南衡义材料科技有限公司 | Household electrical appliance shock resistance ink low-temperature lead-free glass powder and preparation method thereof |
-
2020
- 2020-02-22 CN CN202010109282.4A patent/CN111187006A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011136890A (en) * | 2009-12-29 | 2011-07-14 | Central Glass Co Ltd | Lead-free low-melting-point glass paste for insulation coating |
| CN106085006A (en) * | 2016-06-16 | 2016-11-09 | 江苏大学 | Glass surface inkjet printing bismuth silicon boron system low melting point ink and preparation method thereof |
| CN106082682A (en) * | 2016-06-16 | 2016-11-09 | 江苏大学 | Glass air brushing bismuth silicon boron system's low-melting-point nano glass dust suspension and preparation method |
| CN109336399A (en) * | 2018-11-23 | 2019-02-15 | 刘世伟 | A kind of decorative devitrified glass material |
| CN110092589A (en) * | 2019-06-24 | 2019-08-06 | 湖南衡义材料科技有限公司 | Household electrical appliance shock resistance ink low-temperature lead-free glass powder and preparation method thereof |
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