CN111172554A - Low-voltage electrolytic active oxygen hydrogen-rich generating device - Google Patents

Low-voltage electrolytic active oxygen hydrogen-rich generating device Download PDF

Info

Publication number
CN111172554A
CN111172554A CN202010090387.XA CN202010090387A CN111172554A CN 111172554 A CN111172554 A CN 111172554A CN 202010090387 A CN202010090387 A CN 202010090387A CN 111172554 A CN111172554 A CN 111172554A
Authority
CN
China
Prior art keywords
active oxygen
hydrogen
rich
barrel
medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010090387.XA
Other languages
Chinese (zh)
Inventor
陈祝毅
孙会达
赵顺麾
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hangzhou Shunxin Environmental Technology Co Ltd
Original Assignee
Hangzhou Shunxin Environmental Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hangzhou Shunxin Environmental Technology Co Ltd filed Critical Hangzhou Shunxin Environmental Technology Co Ltd
Priority to CN202010090387.XA priority Critical patent/CN111172554A/en
Publication of CN111172554A publication Critical patent/CN111172554A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/13—Ozone
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features

Abstract

The invention relates to the technical field of ozone preparation equipment, and provides a low-voltage electrolytic active oxygen and hydrogen rich generating device, which aims to solve the problems of a plurality of defects of the existing low-voltage electrolytic ozone preparation equipment and comprises a cylindrical shell, an upper cover and a bottom cover, wherein the upper cover and the bottom cover are respectively arranged at two ends of the shell; the active oxygen and hydrogen rich generation module comprises an active oxygen and hydrogen rich generation assembly, an active oxygen generation outlet and a hydrogen rich generation outlet which are arranged on the active oxygen and hydrogen rich generation assembly, and a medium inlet is arranged at the lower end of the active oxygen and hydrogen rich generation assembly; medium bucket I includes staving I, and the upper end of staving I covers there is top cap I. The invention is especially suitable for the preparation of active oxygen and rich hydrogen, and has higher social use value and application prospect.

Description

Low-voltage electrolytic active oxygen hydrogen-rich generating device
Technical Field
The invention relates to the technical field of ozone preparation equipment, in particular to a low-pressure electrolytic active oxygen hydrogen-rich generating device.
Background
Ozone has the chemical formula O3, formula weight 47.998, an allotrope of oxygen, and a light blue gas with a fishy smell. Ozone has strong oxidizing property, is a stronger oxidant than oxygen, and can perform oxidation reaction at a lower temperature; ozone is a powerful bleaching agent in the presence of water and can be used as a powerful oxidant, a bleaching agent, a fur deodorizer, an air purifying agent, a sanitizer and disinfection and deodorization of drinking water; ozone can be used for replacing a plurality of catalytic oxidations or high-temperature oxidations in chemical production, thereby simplifying production process and improving productivity; liquid ozone can also be used as a rocket fuel.
The reduction process of the ozone completes the functions of sterilization, deodorization, disinfection, bleaching, fresh-keeping and purification, so the ozone has the characteristics of broad-spectrum sterilization, instantaneous sterilization and no residue. Ozone is mainly applied to sterilization and disinfection treatment of air and water in real life. The ozone disinfection can completely avoid the harm of chemical disinfectants to the environment, and is an ideal sterilization and disinfection method.
The ozone technology is widely used in the countries such as the United states, Japan, Europe and the like at present, and the domestic ozone industry is rapidly developed in recent years, so that the ozone technology is a new industry with a bright prospect and a good trend. The appearance of low-voltage electrolytic ozone technology is a technical revolution of ozone preparation, but existing preparation equipment on the market has a plurality of defects.
Therefore, a low-pressure electrolytic active oxygen hydrogen-rich generator is provided.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a low-voltage electrolytic active oxygen hydrogen-rich generating device, which overcomes the defects of the prior art, has reasonable design and compact structure and aims to solve the problems of a plurality of defects of the existing low-voltage electrolytic ozone preparation equipment.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme:
a low-voltage electrolytic active oxygen and hydrogen rich generating device comprises a cylindrical shell, an upper cover and a bottom cover which are respectively arranged at two ends of the shell, wherein a medium barrel I and a medium barrel II are arranged in parallel at the upper part of an inner cavity of the shell, and an active oxygen and hydrogen rich generating module is arranged below the medium barrel I and the medium barrel II;
the active oxygen and hydrogen rich generation module comprises an active oxygen and hydrogen rich generation assembly, an active oxygen generation outlet and a hydrogen rich generation outlet which are arranged on the active oxygen and hydrogen rich generation assembly, and a medium inlet is arranged at the lower end of the active oxygen and hydrogen rich generation assembly;
the medium barrel I comprises a barrel body I, a top cover I covers the upper end of the barrel body I, a live hydrogen outlet pipe and two ends, located at the upper side, of a U-shaped cooling pipe I are inserted into the top cover I, the U-shaped portion of the lower side of the U-shaped cooling pipe I extends into the inner cavity of the barrel body I, and the lower end of the barrel body I is communicated with a live oxygen generation outlet through a connecting pipe I;
the medium barrel II comprises a barrel body II, a top cover II covers the upper end of the barrel body II, a live hydrogen outlet pipe and two ends, located on the upper side, of a U-shaped cooling pipe II are inserted into the top cover II, the U-shaped portion of the lower side of the U-shaped cooling pipe II extends into an inner cavity of the barrel body II, and the lower end of the barrel body II is connected with a hydrogen-rich generation outlet in a penetrating mode through a connecting pipe II.
Furthermore, the lower parts of the medium barrel I and the medium barrel II are communicated and connected through a communicating pipe.
Furthermore, the middle part of the communicating pipe is provided with a liquid level pipe in a penetrating way, and the other end of the liquid level pipe penetrates through the bottom cover and extends to the outer cavity of the shell.
Furthermore, an extension pipe is arranged at the joint of the liquid level pipe and the middle part of the communicating pipe, and the other end of the extension pipe penetrates through the rear wall of the shell and is provided with a liquid level detection device.
Furthermore, a liquid change valve is arranged on a section of the extension pipe positioned on the outer cavity of the shell.
Furthermore, the lower parts of the medium barrel I and the medium barrel II are communicated with the medium inlet of the active oxygen hydrogen-rich generation module through a connecting bent pipe.
Furthermore, two mounting holes which are respectively matched with the medium barrel I and the medium barrel II are formed in the upper end of the upper cover.
Furthermore, the device also comprises a control assembly, wherein the control assembly is used for controlling the operation of the active oxygen hydrogen-rich generation module and the cooling of the media in the medium barrel I and the medium barrel II.
(III) advantageous effects
The embodiment of the invention provides a low-voltage electrolytic active oxygen hydrogen-rich generating device, which has the following beneficial effects:
1. through the combined structure of the medium barrel I, the medium barrel II and the active oxygen and hydrogen rich generation module, the active oxygen generation outlet of the active oxygen and hydrogen rich generation module is an anode to generate active oxygen which is discharged through the active hydrogen outlet pipe on the medium barrel I; the hydrogen-rich generation outlet is a cathode to generate hydrogen-rich, and the hydrogen-rich outlet pipe on the medium barrel II is used for discharging the hydrogen-rich, so that the generation of active oxygen and hydrogen-rich is effectively ensured, the preparation of ozone is effectively ensured, the purity of the produced hydrogen-rich is close to that of pure hydrogen, and the added value can be improved.
2. Through the setting of U-shaped cooling tube I and U-shaped cooling tube II, the hydrogen-rich hydrogen generation module of active oxygen can produce the heat simultaneously at the electrolysis, the heat is along with the continuous intensification of circulating medium, after exceeding the uniform temperature, the coolant liquid flows through U-shaped cooling tube I and U-shaped cooling tube II, the coolant liquid is when passing, carry out the heat exchange with the circulating medium in staving I and the staving II, accomplish the cooling flow of medium in medium bucket I and the medium bucket II, the hydrogen-rich hydrogen of active oxygen of assurance device takes place, ozone is prepared, the hydrogen-rich purity of while output is close pure hydrogen, can improve added value, realize economic benefits.
Drawings
The above features, technical features, advantages and modes of realisation of a low pressure electrolysis type active oxygen hydrogen rich generator will be further described in the following description of preferred embodiments in a clearly understandable manner with reference to the accompanying drawings.
FIG. 1 is a schematic external view of the present invention;
FIG. 2 is a schematic diagram of a disassembled structure of the housing of the present invention;
FIG. 3 is a schematic view of the internal structure of the present invention;
FIG. 4 is a schematic structural view of a medium barrel I according to the present invention;
FIG. 5 is an exploded view of the medium barrel II according to the present invention;
FIG. 6 is a top view of the structure of the present invention;
FIG. 7 is a schematic view of a connection elbow of the present invention;
FIG. 8 is a schematic structural diagram of the active oxygen-rich hydrogen generation module according to the present invention.
In the figure: the device comprises a shell 1, an upper cover 2, a bottom cover 3, a mounting hole 4, a medium barrel I5, a live hydrogen outlet pipe 51, a barrel body I52, a U-shaped cooling pipe I53, a top cover I54, a connecting pipe I55, a medium barrel II 6, a hydrogen-rich outlet pipe 61, a barrel body II 62, a U-shaped cooling pipe II 63, a top cover II 64, a connecting pipe II 65, a live oxygen hydrogen-rich generation module 7, a low-pressure electrolysis type live oxygen hydrogen-rich generation assembly 71, a live oxygen generation outlet 72, a hydrogen-rich generation outlet 73, a connecting bent pipe 8, a liquid level pipe 9 and a communicating pipe 10.
Detailed Description
The invention will be further illustrated with reference to the following figures 1 to 8 and examples:
example 1
A low-voltage electrolytic active oxygen hydrogen-rich generating device comprises a cylindrical shell 1, and an upper cover 2 and a bottom cover 3 which are respectively arranged at two ends of the shell 1, wherein a medium barrel I5 and a medium barrel II 6 are arranged in parallel at the upper part of an inner cavity of the shell 1, media for electrolysis are respectively contained in the medium barrel I5 and the medium barrel II 6, and an active oxygen hydrogen-rich generating module 7 is arranged below the medium barrel I5 and the medium barrel II 6 and is used for performing electrolysis on the media to illustrate active oxygen (about 20% ozone, 80% pure oxygen) and hydrogen-rich (close to pure hydrogen);
in this embodiment, as shown in fig. 3 and 8, the active oxygen-rich hydrogen generation module 7 includes an active oxygen-rich hydrogen generation assembly 71, and an active oxygen generation outlet 72 and a hydrogen-rich hydrogen generation outlet 73 which are provided on the active oxygen-rich hydrogen generation assembly 71, and a medium inlet is provided at the lower end of the active oxygen-rich hydrogen generation assembly 71, it can be understood that the active oxygen-rich hydrogen generation assembly 71 is of a low-pressure electrolysis type, and it is more easily understood that the active oxygen generation outlet 72 is an anode to generate active oxygen, and the hydrogen-rich hydrogen generation outlet 73 is a cathode to generate hydrogen-rich;
in this embodiment, as shown in fig. 4, the medium barrel i 5 includes a barrel body i 52, the upper end of the barrel body i 52 is covered with a top cover i 54, the top cover i 54 is inserted with a live hydrogen outlet pipe 51 and two ends of a U-shaped cooling pipe i 53 positioned at the upper side, the U-shaped part at the lower side of the U-shaped cooling pipe i 53 extends into the inner cavity of the barrel body i 52, and the lower end of the barrel body i 52 is connected with a live oxygen generation outlet 72 through a connecting pipe i 55;
in this embodiment, as shown in fig. 5, the medium barrel ii 6 includes a barrel body ii 62, an upper end of the barrel body ii 62 is covered with a top cover ii 64, the live hydrogen outlet pipe 5 and two ends of the U-shaped cooling pipe ii 63 located at the upper side are inserted into the top cover ii 64, a U-shaped portion of the lower side of the U-shaped cooling pipe ii 63 extends into an inner cavity of the barrel body ii 62, and a lower end of the barrel body ii 62 is connected to the hydrogen-rich generation outlet 73 through a connecting pipe ii 65.
In this embodiment, the active oxygen hydrogen-rich generation module 7 can generate heat during electrolysis, the heat rises along with the continuous temperature rise of the circulating medium, after exceeding a certain temperature, the cooling liquid flows through the U-shaped cooling pipe I53 and the U-shaped cooling pipe II 63, and when passing through, the cooling liquid exchanges heat with the circulating medium in the barrel body I52 and the barrel body II 62, completes the cooling process of the medium in the medium barrel I5 and the medium barrel II 6, and ensures that the active oxygen hydrogen-rich generation of the device occurs.
In this embodiment, as shown in fig. 3, the lower portions of the first medium barrel 5 and the second medium barrel 6 are connected through a communicating pipe 10, so as to ensure the communication and the liquid level balance of the media in the two medium barrels.
In this embodiment, as shown in fig. 3 and 7, a liquid level tube 9 is installed in the middle of the communication tube 10 in a penetrating manner, and the other end of the liquid level tube 9 penetrates through the bottom cover 3 and extends to the outer cavity of the housing 1 for observing the liquid level of the medium with the naked eye from the outside.
In this embodiment, as shown in fig. 3, the lower portions of the medium barrel i 5 and the medium barrel ii 6 are both connected to the medium inlet of the active oxygen and hydrogen-rich generation module 7 through the connection elbow 8, so that when active oxygen and hydrogen-rich are emitted upwards, the media in the medium barrel can be driven to flow to the medium barrel i 5 and the medium barrel ii 6 respectively, and the media in the connection elbow 8 is driven to flow to the active oxygen and hydrogen-rich generation module 7 from the medium barrel i 5 and the medium barrel ii 6 to continue electrolysis.
In this embodiment, as shown in fig. 2, two mounting holes 4 respectively matched with the first medium barrel 5 and the second medium barrel 6 are formed in the upper end of the upper cover 2, so as to ensure the fixed mounting of the first medium barrel 5 and the second medium barrel 6.
In this embodiment, (not shown in the figure) further comprises a control component, and the control component is used for controlling the operation of the active oxygen and hydrogen rich generating module 7 and the cooling of the media in the media barrel I5 and the media barrel II 6 so as to ensure the stable operation of the active oxygen and hydrogen rich generating device.
Example 2
The difference between this embodiment and embodiment 1 is that, as shown in fig. 7, an extension pipe is disposed at the connection between the middle of the liquid level pipe 9 and the communication pipe 10, and the other end of the extension pipe penetrates through the rear wall of the housing 1 and is installed with a liquid level detection device to cooperate with the control of the external device node.
In this embodiment, a liquid changing valve is installed on a section of the extension pipe located in the outer cavity of the housing 1, and the extension pipe can be used as a medium changing inlet in cooperation with the liquid changing valve, so that the medium in the barrel body I52 and the medium in the barrel body II 62 can be changed.
Other undescribed structures refer to example 1.
According to the low-voltage electrolytic active oxygen-rich hydrogen generation device disclosed by the embodiment of the invention, the cooling of the media in the media barrel I5 and the media barrel II 6 can be carried out in series cooling or in parallel cooling according to the requirement so as to meet the normal working temperature of the active oxygen-rich hydrogen generation module 7; otherwise, if the startup state is lower than the normal working requirement of the active oxygen and hydrogen-rich generation module 7, the appropriate temperature exchange liquid is introduced to meet the startup requirement, and the use of the device is ensured.
The embodiments of the present invention are disclosed as the preferred embodiments, but not limited thereto, and those skilled in the art can easily understand the spirit of the present invention and make various extensions and changes without departing from the spirit of the present invention.

Claims (8)

1. A low-voltage electrolytic active oxygen hydrogen-rich generating device comprises a cylindrical shell, an upper cover and a bottom cover which are respectively arranged at two ends of the shell, and is characterized in that a medium barrel I and a medium barrel II are arranged in parallel at the upper part of an inner cavity of the shell, and an active oxygen hydrogen-rich generating module is arranged below the medium barrel I and the medium barrel II;
the active oxygen and hydrogen rich generation module comprises an active oxygen and hydrogen rich generation assembly, an active oxygen generation outlet and a hydrogen rich generation outlet which are arranged on the active oxygen and hydrogen rich generation assembly, and a medium inlet is arranged at the lower end of the active oxygen and hydrogen rich generation assembly;
the medium barrel I comprises a barrel body I, a top cover I covers the upper end of the barrel body I, a live hydrogen outlet pipe and two ends, located at the upper side, of a U-shaped cooling pipe I are inserted into the top cover I, the U-shaped portion of the lower side of the U-shaped cooling pipe I extends into the inner cavity of the barrel body I, and the lower end of the barrel body I is communicated with a live oxygen generation outlet through a connecting pipe I;
the medium barrel II comprises a barrel body II, a top cover II covers the upper end of the barrel body II, a live hydrogen outlet pipe and two ends, located on the upper side, of a U-shaped cooling pipe II are inserted into the top cover II, the U-shaped portion of the lower side of the U-shaped cooling pipe II extends into an inner cavity of the barrel body II, and the lower end of the barrel body II is connected with a hydrogen-rich generation outlet in a penetrating mode through a connecting pipe II.
2. A low-pressure electrolytic active oxygen-rich hydrogen generating apparatus according to claim 1, wherein: the lower parts of the medium barrel I and the medium barrel II are communicated and connected through a communicating pipe.
3. A low-pressure electrolytic active oxygen-rich hydrogen generating apparatus according to claim 2, wherein: the middle part of the communicating pipe is provided with a liquid level pipe in a run-through mode, and the other end of the liquid level pipe penetrates through the bottom cover and extends to the outer cavity of the shell.
4. A low-pressure electrolytic active oxygen-rich hydrogen generating apparatus according to claim 3, wherein: the middle part junction of liquid level pipe and communicating pipe is equipped with the extension pipe, and the other end of extension pipe runs through the back wall of casing and installs liquid level detection device.
5. The low-pressure electrolytic active oxygen-rich hydrogen generating device according to claim 4, wherein: and a liquid change valve is arranged on one section of the extension pipe positioned on the outer cavity of the shell.
6. A low-pressure electrolytic active oxygen-rich hydrogen generating apparatus according to claim 1, wherein: the lower parts of the medium barrel I and the medium barrel II are communicated with the medium inlet of the active oxygen hydrogen-rich generation module through a connecting bent pipe.
7. A low-pressure electrolytic active oxygen-rich hydrogen generating apparatus according to claim 1, wherein: two mounting holes respectively matched with the medium barrel I and the medium barrel II are formed in the upper end of the upper cover.
8. A low-pressure electrolytic active oxygen-rich hydrogen generating apparatus according to claim 1, wherein: the device also comprises a control assembly, wherein the control assembly is used for controlling the operation of the active oxygen hydrogen-rich generation module and the cooling of media in the medium barrel I and the medium barrel II.
CN202010090387.XA 2020-02-13 2020-02-13 Low-voltage electrolytic active oxygen hydrogen-rich generating device Pending CN111172554A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010090387.XA CN111172554A (en) 2020-02-13 2020-02-13 Low-voltage electrolytic active oxygen hydrogen-rich generating device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010090387.XA CN111172554A (en) 2020-02-13 2020-02-13 Low-voltage electrolytic active oxygen hydrogen-rich generating device

Publications (1)

Publication Number Publication Date
CN111172554A true CN111172554A (en) 2020-05-19

Family

ID=70646897

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010090387.XA Pending CN111172554A (en) 2020-02-13 2020-02-13 Low-voltage electrolytic active oxygen hydrogen-rich generating device

Country Status (1)

Country Link
CN (1) CN111172554A (en)

Similar Documents

Publication Publication Date Title
WO2003041187A3 (en) Method and apparatus for generating hydrogen inside of a fuel cell
CN110642362B (en) Supercritical water reactor integrating material preheating, pollutant multistage enhanced degradation, corrosion prevention and control functions
CN211570783U (en) Low-voltage electrolytic active oxygen hydrogen-rich generating device
CN111172554A (en) Low-voltage electrolytic active oxygen hydrogen-rich generating device
CN112281184A (en) Device and method for electrochemically generating hydrogen peroxide
CN212316259U (en) Active oxygen and hydrogen-rich integrated generator
CN111748824A (en) Active oxygen and hydrogen-rich integrated generator
CN214141585U (en) Gas stripping type chlorine dioxide generator
JP2007299730A (en) Fuel cell system having unreacted anode gas discharge processor
CN214032064U (en) Active oxygen generating device
CN210915877U (en) Utilize formaldehyde production system of methyl alcohol oxidation reaction steam gasification liquid ammonia
CN110627190A (en) Reverse osmosis direct drinking machine using low-voltage electrolysis technology for disinfection
CN109607709A (en) A kind of electrochemistry deoxygen apparatus
CN216168916U (en) Preparation device of ozonized oil
CN220467671U (en) Sewage catalytic oxidation device
CN210698326U (en) Sterilizing machine
CN215048666U (en) Ozone generating device for sewage treatment
CN220202050U (en) Electrolytic ozone generating device
CN218296248U (en) Heat exchanger convenient to dredge and used in coating production wastewater treatment
CN217385690U (en) Electrode life testing device
CN214881851U (en) PEM low-voltage electrolysis ozone generating device
CN218880084U (en) Alkaline water electrolysis hydrogen production thermoelectric coupling system
CN218059235U (en) Domestic portable hypochlorous acid water generator
CN215050735U (en) Compact folding type sodium hypochlorite generator electrolytic tank
CN210559587U (en) Active oxygen water machine

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination