CN111172469A - SWRH82B wire rod with low acid-soluble aluminum content - Google Patents
SWRH82B wire rod with low acid-soluble aluminum content Download PDFInfo
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- CN111172469A CN111172469A CN202010018835.5A CN202010018835A CN111172469A CN 111172469 A CN111172469 A CN 111172469A CN 202010018835 A CN202010018835 A CN 202010018835A CN 111172469 A CN111172469 A CN 111172469A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/30—Regulating or controlling the blowing
- C21C5/35—Blowing from above and through the bath
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/076—Use of slags or fluxes as treating agents
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/10—Handling in a vacuum
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
The embodiment of the invention provides a SWRH82B wire rod with low acid-soluble aluminum content, wherein the SWRH82B wire rod with low acid-soluble aluminum content comprises the following chemical components in percentage by weight: 0.80-0.83 wt%, Si: 0.15-0.30 wt%, Mn: 0.78-0.88 wt%, phosphorus P: less than or equal to 0.020 wt%, S: less than or equal to 0.015 wt%, aluminum Als: less than or equal to 0.0020 wt%, Cr: 0.20 to 0.33 wt%.
Description
Technical Field
The invention belongs to the field of steel production and manufacturing, and particularly relates to a SWRH82B wire rod with low acid-soluble aluminum content.
Background
Acid-soluble aluminum: the total aluminum content in the steel minus the aluminum content present as alumina (insoluble in acid) is acid soluble aluminum (soluble in acid).
SWRH82B Steel wire rodIs used for producing high-strength low-relaxation prestressed steel strands,
the wire rod needs to be drawn into the steel wire rod by continuous cold drawing
The steel wire has a deformation ratio as high as 84%, and Al in the steel wire2O3Large-particle and brittle inclusions like the above easily cause wire breakage in drawing, and simultaneously cause large fluctuation range of indexes such as strength and toughness of a drawn product and low qualification rate of a finished product, so that the requirements that Al is strictly controlled in production of SWRH82B steel are met2O3Number, size and type of inclusions. To control Al2O3The inclusion formation requires a reduction in the acid-soluble aluminum content of the steel. When the steel contains a certain amount of acid-soluble aluminum, the temperature of the molten steel is gradually reduced along with the continuous casting process, and the original aluminum oxygen equilibrium reaction is broken to generate Al2O3Impurities cannot be removed in time, and further the product quality is influenced. Therefore, there is a great need for a SWRH82B wire rod with low acid soluble aluminum content.
In the process of implementing the invention, the applicant finds that at least the following problems exist in the prior art: al in existing SWRH82B wire rod steel2O3Large-particle and brittle inclusions like the large particles are easy to cause wire breakage in drawing, and simultaneously, the fluctuation range of indexes such as strength, toughness and the like of a drawn product is large, the qualified rate of a finished product is low, and the existing SWRH82B wire rod steel cannot strictly control Al in production2O3The number, size and type of inclusions cannot meet the product quality requirements.
Disclosure of Invention
The embodiment of the invention provides a SWRH82B wire rod with low acid-soluble aluminum content, wherein the acid-soluble aluminum content is less than 0.0015%, the product quality requirement can be met, and the performance can meet the national standard requirement.
To achieve the above object, the present invention provides a SWRH82B wire rod with low acid soluble aluminum content, comprising:
the SWRH82B wire rod with low acid-soluble aluminum content comprises the following chemical components in percentage by weight: 0.80-0.83 wt%, Si: 0.15-0.30 wt%, Mn: 0.78-0.88 wt%, phosphorus P: less than or equal to 0.020 wt%, S: less than or equal to 0.015 wt%, aluminum Als: less than or equal to 0.0020 wt%, Cr: 0.20 to 0.33 wt%.
Further, the important chemical composition percentage of the low acid soluble aluminum content SWRH82B wire rod is carbon C: 0.8113 wt%, silicon Si: 0.2196 wt%, manganese Mn: 0.85 wt%, phosphorus P: 0.0158 wt%, sulfur S: 0.007 wt%, all-aluminum Alt: 0.0016 wt%, acid-soluble aluminum Als: 0.0015 wt%.
Further, the important chemical composition percentage of the low acid soluble aluminum content SWRH82B wire rod is carbon C: 0.8103 wt%, silicon Si: 0.223 wt%, manganese Mn: 0.851 wt%, phosphorus P: 0.0152 wt%, sulfur S: 0.0076 wt%, all-aluminum Alt: 0.0013 wt%, acid-soluble aluminum Als: 0.0013 wt%.
Further, the important chemical composition percentage of the low acid soluble aluminum content SWRH82B wire rod is carbon C: 0.8247 wt%, silicon Si: 0.2585 wt%, manganese Mn: 0.833 wt%, phosphorus P: 0.0135 wt%, sulfur S: 0.0066 wt%, all-aluminum Alt: 0.0019 wt%, acid-soluble aluminum Als: 0.0013 wt%.
Further, the important chemical composition percentage of the low acid soluble aluminum content SWRH82B wire rod is carbon C: 0.8166 wt%, silicon Si: 0.2413 wt%, manganese Mn: 0.833 wt%, phosphorus P: 0.0143 wt%, sulfur S: 0.0054 wt%, all-aluminum Alt: 0.0012 wt%, acid-soluble aluminum Als: 0.0012 wt%.
Further, the important chemical composition percentage of the low acid soluble aluminum content SWRH82B wire rod is carbon C: 0.8004 wt%, silicon Si: 0.2363 wt%, manganese Mn: 0.81 wt%, phosphorus P: 0.0155 wt%, sulfur S: 0.0061 wt%, all-aluminum Alt: 0.0013 wt%, acid-soluble aluminum Als: 0.001 wt%.
Further, the production method of the SWRH82B wire rod with low acid-soluble aluminum content comprises the following steps: KR molten iron pre-desulfurization treatment, 150-ton top-bottom combined blowing converter, argon blowing after furnace, LF furnace refining, RH vacuum refining, 165mm × 165mm square billet continuous casting, casting blank heating, high-pressure water descaling, high-speed wire rolling, controlled cooling and coil collection.
Further, the 150-ton top-bottom combined blown converter: the molten iron fed into the furnace meets KR desulfurization requirements that S is less than or equal to 0.005Wt percent and P is less than or equal to 0.130Wt percent; a class of pure scrap is used.
Further, the LF furnace refining: adopting an acid slag process, and the target binary alkalinity R of the top slag of the station is CaO/SiO2Controlling the content of Al in the slag to be 0.8-1.22O3The content of FeO and MnO is controlled to be less than or equal to 6 percent and less than or equal to 1.5 percent, and the argon blowing time after acid slag is produced is more than or equal to 20 min.
Further, the RH vacuum refining: the ultimate vacuum time is more than or equal to 10 min; the net circulation time is more than or equal to 3 min; argon flow is less than or equal to 9m3The soft argon blowing time per hour is more than or equal to 8 min; the sedation time is more than or equal to 20 min; calcium treatment was not performed.
The technical scheme has the following beneficial effects: the invention provides an SWRH82B wire rod with low acid-soluble aluminum content, which controls the acid-soluble aluminum in SWRH82B wire rod steel to be relatively low by strictly controlling Al in raw materials, properly increasing the terminal oxygen of a converter, reducing the dosage of a deoxidizer, refining ladle top slag to produce low-alkalinity slag, reducing Si content control in steel, performing vacuum light treatment, eliminating calcium treatment and the like, and strictly controls Al2O3The quantity, size and type of the inclusions enable the inclusions to meet the product quality requirements.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In order to control the content of acid-soluble aluminum in SWRH82B steel, the invention aims to provide a SWRH82B wire rod with low content of acid-soluble aluminum, which can control the acid-soluble aluminum in the steel to a relatively low level by strictly controlling Al in raw materials, properly increasing the terminal oxygen of a converter, reducing the dosage of a deoxidizer, refining ladle top slag to produce low-alkalinity slag, reducing the content of Si in the steel, performing vacuum light treatment, eliminating calcium treatment and the like.
The technical scheme is as follows:
the invention controls the oxidation and reduction reaction of acid-soluble aluminum in molten steel to achieve the aim ofThe content of acid-soluble aluminum in the SWRH82B steel is effectively controlled. According to the thermodynamic principle of metallurgy, the content of acid-soluble aluminum in molten steel is controlled to be lower effectively, and the amount of aluminum brought into the molten steel by steelmaking raw materials is reduced; secondly, Al brought into ladle top slag by refining slagging material is reduced2O3And thirdly, the content of free oxygen in the molten steel and the activity of a corresponding oxidant in refined ladle top slag are properly increased, and the activity of a corresponding product in the molten steel is reduced, so that the forward movement of the following reaction balance can be promoted, and the content of acid-soluble aluminum in the SWRH82B steel can be effectively controlled. The main metallurgical reaction principle is as follows:
2[Al]+3[O]＝Al2O3(1)
4[Al]+3(SiO2)＝2(Al2O3)+3[Si](2)
3[C]+(Al2O3)＝2[Al]+3CO (3)
3[Ca]+(Al2O3)＝3(CaO)+2[Al](4)
the invention provides a SWRH82B wire rod with low acid-soluble aluminum content, which comprises:
the SWRH82B wire rod with low acid soluble aluminum content comprises the following chemical components by weight percent: 0.80-0.83 wt%, Si: 0.15-0.30 wt%, Mn: 0.78-0.88 wt%, phosphorus P: less than or equal to 0.020 wt%, S: less than or equal to 0.015 wt%, aluminum Als: less than or equal to 0.0020 wt%, Cr: 0.20 to 0.33 wt%. Namely, as shown in Table 1:
TABLE 1 SWRH82B melting chemical composition Range (wt%)
Further, the important chemical composition percentage of the low acid soluble aluminum content SWRH82B wire rod is carbon C: 0.8113 wt%, silicon Si: 0.2196 wt%, manganese Mn: 0.85 wt%, phosphorus P: 0.0158 wt%, sulfur S: 0.007 wt%, all-aluminum Alt: 0.0016 wt%, acid-soluble aluminum Als: 0.0015 wt%.
Further, the important chemical composition percentage of the low acid soluble aluminum content SWRH82B wire rod is carbon C: 0.8103 wt%, silicon Si: 0.223 wt%, manganese Mn: 0.851 wt%, phosphorus P: 0.0152 wt%, sulfur S: 0.0076 wt%, all-aluminum Alt: 0.0013 wt%, acid-soluble aluminum Als: 0.0013 wt%.
Further, the important chemical composition percentage of the low acid soluble aluminum content SWRH82B wire rod is carbon C: 0.8247 wt%, silicon Si: 0.2585 wt%, manganese Mn: 0.833 wt%, phosphorus P: 0.0135 wt%, sulfur S: 0.0066 wt%, all-aluminum Alt: 0.0019 wt%, acid-soluble aluminum Als: 0.0013 wt%.
Further, the important chemical composition percentage of the low acid soluble aluminum content SWRH82B wire rod is carbon C: 0.8166 wt%, silicon Si: 0.2413 wt%, manganese Mn: 0.833 wt%, phosphorus P: 0.0143 wt%, sulfur S: 0.0054 wt%, all-aluminum Alt: 0.0012 wt%, acid-soluble aluminum Als: 0.0012 wt%.
Further, the important chemical composition percentage of the low acid soluble aluminum content SWRH82B wire rod is carbon C: 0.8004 wt%, silicon Si: 0.2363 wt%, manganese Mn: 0.81 wt%, phosphorus P: 0.0155 wt%, sulfur S: 0.0061 wt%, all-aluminum Alt: 0.0013 wt%, acid-soluble aluminum Als: 0.001 wt%.
Further, the production method of the SWRH82B wire rod with low acid-soluble aluminum content comprises the following steps: KR molten iron pre-desulfurization treatment, 150-ton top-bottom combined blowing converter, argon blowing after furnace, LF furnace refining, RH vacuum refining, 165mm × 165mm square billet continuous casting, casting blank heating, high-pressure water descaling, high-speed wire rolling, controlled cooling and coil collection; or the SWRH82B wire rod with low acid-soluble aluminum content has the following process route: the method comprises the steps of molten iron pre-desulfurization, smelting of 150-ton converter molten steel, argon blowing and stirring in an argon station, ladle furnace refining, component fine adjustment, RH vacuum furnace, billet continuous casting, high-speed wire rod rolling and finished wire rod production.
Further, the 150-ton top-bottom combined blown converter: the molten iron fed into the furnace meets KR desulfurization requirements that S is less than or equal to 0.005Wt percent and P is less than or equal to 0.130Wt percent; materials such as deoxidizer with high Al and Ti contents, silicon manganese and the like cannot be used; pure steel scrap or low-P low-S sponge iron is adopted to ensure P, S hit internal control.
Further, the LF furnace refining: adopting an acid slag process, and the target binary alkalinity R of the top slag of the station is CaO/SiO2Controlling the content of Al in the slag to be 0.8-1.22O3Is controlled to be less than or equal to 6 percent, and aims to reduce the oxidability of top slag and reduce the top slag to molten steelThe oxygen transfer leads to the increase of oxide inclusions in steel, FeO + MnO is controlled to be less than or equal to 1.5%, and the argon blowing time after acid slag is manufactured is controlled to be more than or equal to 20min, so that the non-metallic inclusions in the molten steel are fully polymerized and float upwards and are adsorbed by top slag, and the cleanliness of the steel is improved.
Further, the RH vacuum refining: controlling the ultimate vacuum time with the vacuum degree of 67Pa to be more than or equal to 10min in order to remove the hydrogen in the molten steel to be less than 0.0002 percent and the nitrogen to be less than 0.0030 percent; the net circulation time is more than or equal to 3 min; argon flow is less than or equal to 9m3The soft argon blowing time per hour is more than or equal to 8 min; the sedation time is more than or equal to 20min to ensure that the non-metallic inclusions in the molten steel fully float upwards, thereby further improving the cleanliness of the steel; calcium treatment was not performed.
And (3) square billet continuous casting: controlling the superheat degree of the molten steel to be less than or equal to 35 ℃; must be produced under conditions of normal use with electrical agitation; the middle package uses low alkalinity covering agent (CaO/SiO of the low alkalinity covering agent)2CaO/SiO of 0.2 or less, an alkaline covering agent210 or more); using special high-carbon steel covering slag; the first cooling system is strong cooling (the water flow of the square billet first cooling single flow is 2800L/min, and the normal flow is 2400/min); the casting blank single flow pulling speed is 1.80-1.90 m/min.
Rolling the high-speed wire rods: the rolling channel is checked before production, so that the channel is ensured to be well lubricated; controlling the heating temperature of a casting blank to be 1100-1150 ℃, the initial rolling temperature to be 1000-1050 ℃, the finish rolling temperature to be 900-950 ℃ and the spinning temperature to be 850-900 ℃; the heat preservation cover on the stelmor roller way is fully opened, and the No. 1-10 fan is fully opened, so that the sorbite tissue proportion of the finished product is ensured to be more than 90%.
Based on the principle, the invention discloses a SWRH82B wire rod with low acid-soluble aluminum content, which comprises the following specific technical measures:
1. si element control in steel
As shown in the acid-soluble aluminum control reaction formula (1), in order to ensure that the sufficient free oxygen content in the molten steel reacts with acid-soluble aluminum in the molten steel for the silicon killed steel with the SWRH82B, the content of deoxidizing elements of steel grades is controlled well in addition to the terminal oxygen content of the converter, and the content of the deoxidizing elements in the steel grades is reduced as much as possible within the allowable component range of the steel. Further, from the reaction formula (2), it is found that the reaction equilibrium is directed toward Al2O3In addition to improving the top slag of the refining ladleSiO 22Activity of the refining ladle and reduction of Al in the top slag of the refining ladle2O3In addition to the activity of (1), it is necessary to minimize the activity of Si element in steel to promote the equilibrium of reaction toward Al2O3Is performed in the same direction. Therefore, the Si element in the steel is controlled to be 0.15 to 0.20 percent.
2. Converter endpoint oxygen control
The converter end-point oxygen control is directly related to the total oxygen content T [ O ] in the molten steel after tapping, and directly related to the free oxygen content in the molten steel after vacuum tapping. Therefore, under the condition that the used raw materials and other process conditions are not changed, a certain amount of oxygen in the molten steel before deoxidation alloying must be ensured. The converter end-point oxygen for effectively controlling the acid-soluble aluminum content of the steel grade below 0.0015% should be controlled to be 350-450 ppm as far as possible, but the end-point oxygen is not easy to be controlled too high, so that the alloy recovery rate is reduced to increase the production cost, and the proportion of inclusions in the steel is increased along with the deoxidation alloying process to be not beneficial to quality control.
3. Post-furnace deoxidation alloying process
During deoxidation and alloying, silicon-calcium-barium deoxidizer is not used for deoxidizing and increasing Si of molten steel, and silicon-manganese alloy with low aluminum content and relative stability is used for increasing silicon and manganese. Because the silicon-calcium-barium used as a deoxidizer contains a certain amount of Ca element and Ba element, the activity of the two elements are very active metal elements which are stronger than that of aluminum, and the silicon-calcium-barium is very easy to combine with oxygen in steel to generate corresponding oxides, so that free oxygen in the steel is reduced, and the control of acid-soluble aluminum in the steel is not facilitated. By adopting the process of deoxidizing and increasing silicon of the molten steel, silicon, calcium and barium are adopted, a large amount of aluminum can be actively brought into the molten steel, and meanwhile, the silicon is used as a deoxidizer to increase the activity of free oxygen in the molten steel, so that the control of the total acid-soluble aluminum in the molten steel is not facilitated, and the quality control of SWRH82B is greatly influenced.
4. Basicity of top slag of refining ladle and Al in slag2O3Content control
The reaction formula (2) is controlled by acid-soluble aluminum: in the refining process, if the content of acid-soluble aluminum in steel needs to be reduced, SiO in the top slag of a refining ladle needs to be improved2Activity, lowering Al2O3Activity, promoting the equilibrium of the reaction towards the oxidation of aluminiumAnd (6) rows. Therefore, LF refining process adopts low-alkalinity slag refining process, SiO2With Al2O3The binary alkalinity of the slag is controlled to be 0.8-1.2, and Al is strictly forbidden to be used in slag making materials2O3The material of (1). In order to ensure that the low-alkalinity refining slag has sufficient time to participate in slag-gold interface reaction after being manufactured, soft argon blowing is required to be carried out for more than 20min after the low-alkalinity refining slag is manufactured, so that the reaction is fully carried out.
5. Vacuum light treatment
The vacuum treatment of the SWRH82B aims to remove impurities mainly through degassing and deoxidation, but the reaction of the formula (3) and the carbon deoxidation reaction occur in the high-carbon steel during the vacuum treatment process, so that the oxygen content in the molten steel is reduced, and the aluminum content is increased. The lower the vacuum degree is, the longer the treatment time is, the deeper the molten steel is deoxidized, and the more the molten steel is aluminized. Therefore, it is considered that the vacuum degree is increased to 20 to 25KPa and the vacuum treatment time is shortened to 15 to 17min under the premise of meeting the requirements of degassing and impurity removal.
6. Without calcium treatment
The SWRH82B vacuum procedure did not involve calcium treatment. The calcium treatment can increase calcium to the molten steel to lead [ Ca ] in the molten steel]The activity is increased, on one hand, the affinity of calcium element and oxygen is much stronger than that of aluminum, so that free oxygen in molten steel can be further reduced, and the reaction balance of the formula (1) is not facilitated to be carried out towards the direction of aluminum oxidation; on the other hand, the calcium element can be partially (Al) in the top slag of the refining ladle2O3) The reaction of equation (4) occurs to increase the aluminum content of the molten steel, and therefore calcium treatment is not favorable for controlling brittle inclusions in the SWRH82B steel.
DETAILED DESCRIPTION OF EMBODIMENT (S) OF INVENTION
The embodiment is a wire rod for producing a prestressed steel strand with the trademark of SWRH82B, and the production process comprises the following steps: preparing smelting raw materials according to the chemical composition of the SWRH82B wire rod, and sequentially carrying out KR molten iron pre-desulfurization treatment → 150 tons of top-bottom combined blowing converter → argon blowing behind the furnace → LF furnace refining → RH vacuum refining → 165mm × 165mm square billet continuous casting → casting blank heating → high-pressure water descaling → high-speed wire rolling → controlled cooling → coil collection → inspection, packaging and warehousing.
The final oxygen of the converter is actually controlled to be 382-447 ppm, silicon-manganese alloy which is low in aluminum content and relatively stable is adopted for silicon increasing, manganese increasing and deoxidation, the adding amount of the silicon-manganese alloy is 10.29-10.63 kg/t, LF refining is carried out by slagging by using lime, quartz sand and fluorite, the binary alkalinity of top slag is actually controlled to be 0.89-0.97, and soft argon blowing time is more than 20min after top slag is manufactured, so that the reaction is ensured to be fully carried out. The vacuum degree of the RH vacuum refining process is controlled to be 20.5-24.7 KPa, the vacuum treatment time is controlled to be 15-17 min, the purpose of degassing and impurity removal is achieved, aluminum increase caused by over-deep deoxidation of molten steel is avoided, calcium treatment is not performed after the vacuum treatment is finished, and after the vacuum treatment is stopped for 20-35 min, the molten steel is hoisted to a continuous casting station for casting. The specific process parameters of this example are shown in table 1, and the chemical composition of the final product by the control method of the present invention is shown in table 2.
TABLE 1 specific Process parameters for this example
TABLE 2 product chemistry (wt%)
| Examples of the invention | C | Si | Mn | P | S | Alt | Alsol |
| Example 1 | 0.8113 | 0.2196 | 0.85 | 0.0158 | 0.007 | 0.0016 | 0.0015 |
| Example 2 | 0.8103 | 0.223 | 0.851 | 0.0152 | 0.0076 | 0.0013 | 0.0013 |
| Example 3 | 0.8247 | 0.2585 | 0.833 | 0.0135 | 0.0066 | 0.0019 | 0.0013 |
| Example 4 | 0.8166 | 0.2413 | 0.833 | 0.0143 | 0.0054 | 0.0012 | 0.0012 |
| Example 5 | 0.8004 | 0.2363 | 0.81 | 0.0155 | 0.0061 | 0.0013 | 0.001 |
Heating the SWRH82B continuous casting slab in a heating furnace in a neutral atmosphere to 1137-1182 ℃, preserving heat for 80-90 min, discharging, performing high-pressure water descaling treatment, rolling to a phi 12.5mm specification by a 28-frame rolling mill, controlling the start rolling temperature to be 1012-1137 ℃, controlling the finish rolling temperature to be 905-951 ℃, controlling the spinning temperature to be 866-897 ℃, and opening a No. 1-10 fan to be 100%, fully opening a heat preservation cover, wherein the mechanical properties and the drawing broken wire condition of the finished wire rod are shown in Table 3.
TABLE 3 mechanical Properties of wire rod and drawing filament breakage
| Examples of the invention | Tensile strength/MPa | Reduction of area/%) | Drawing breakage rate/%) |
| Example 1 | 1158 | 34 | 0 |
| Example 2 | 1173 | 31 | 0 |
| Example 3 | 1171 | 31 | 0 |
| Example 4 | 1160 | 33 | 0 |
| Example 5 | 1185 | 32 | 0 |
It should be understood that the specific order or hierarchy of steps in the processes disclosed is an example of exemplary approaches. Based upon design preferences, it is understood that the specific order or hierarchy of steps in the processes may be rearranged without departing from the scope of the present disclosure. The accompanying method claims present elements of the various steps in a sample order, and are not intended to be limited to the specific order or hierarchy presented.
In the foregoing detailed description, various features are grouped together in a single embodiment for the purpose of streamlining the disclosure. This method of disclosure is not to be interpreted as reflecting an intention that the claimed embodiments of the subject matter require more features than are expressly recited in each claim. Rather, as the following claims reflect, invention lies in less than all features of a single disclosed embodiment. Thus, the following claims are hereby expressly incorporated into the detailed description, with each claim standing on its own as a separate preferred embodiment of the invention.
The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are merely exemplary embodiments of the present invention, and are not intended to limit the scope of the present invention, and any modifications, equivalent substitutions, improvements and the like made within the spirit and principle of the present invention should be included in the scope of the present invention.
Claims (10)
1. A low acid soluble aluminum content SWRH82B wire rod, characterized by:
the SWRH82B wire rod with low acid-soluble aluminum content comprises the following chemical components in percentage by weight: 0.80-0.83 wt%, Si: 0.15-0.30 wt%, Mn: 0.78-0.88 wt%, phosphorus P: less than or equal to 0.020 wt%, S: less than or equal to 0.015 wt%, acid-soluble aluminum Als: less than or equal to 0.0020 wt%, Cr: 0.20 to 0.33 wt%.
2. The low acid soluble aluminum content SWRH82B wire rod of claim 1, wherein:
the SWRH82B wire rod with low acid soluble aluminum content comprises the following chemical components by weight percent: 0.8113 wt%, silicon Si: 0.2196 wt%, manganese Mn: 0.85 wt%, phosphorus P: 0.0158 wt%, sulfur S: 0.007 wt%, all-aluminum Alt: 0.0016 wt%, acid-soluble aluminum Als: 0.0015 wt%.
3. The low acid soluble aluminum content SWRH82B wire rod of claim 1, wherein:
the SWRH82B wire rod with low acid soluble aluminum content comprises the following chemical components by weight percent: 0.8103 wt%, silicon Si: 0.223 wt%, manganese Mn: 0.851 wt%, phosphorus P: 0.0152 wt%, sulfur S: 0.0076 wt%, all-aluminum Alt: 0.0013 wt%, acid-soluble aluminum Als: 0.0013 wt%.
4. The low acid soluble aluminum content SWRH82B wire rod of claim 1, wherein:
the SWRH82B wire rod with low acid soluble aluminum content comprises the following chemical components by weight percent: 0.8247 wt%, silicon Si: 0.2585 wt%, manganese Mn: 0.833 wt%, phosphorus P: 0.0135 wt%, sulfur S: 0.0066 wt%, all-aluminum Alt: 0.0019 wt%, acid-soluble aluminum Als: 0.0013 wt%.
5. The low acid soluble aluminum content SWRH82B wire rod of claim 1, wherein:
the SWRH82B wire rod with low acid soluble aluminum content comprises the following chemical components by weight percent: 0.8166 wt%, silicon Si: 0.2413 wt%, manganese Mn: 0.833 wt%, phosphorus P: 0.0143 wt%, sulfur S: 0.0054 wt%, all-aluminum Alt: 0.0012 wt%, acid-soluble aluminum Als: 0.0012 wt%.
6. The low acid soluble aluminum content SWRH82B wire rod of claim 1, wherein:
the SWRH82B wire rod with low acid soluble aluminum content comprises the following chemical components by weight percent: 0.8004 wt%, silicon Si: 0.2363 wt%, manganese Mn: 0.81 wt%, phosphorus P: 0.0155 wt%, sulfur S: 0.0061 wt%, all-aluminum Alt: 0.0013 wt%, acid-soluble aluminum Als: 0.001 wt%.
7. The low acid soluble aluminum content SWRH82B wire rod of claim 1, wherein:
the production method of the SWRH82B wire rod with low acid-soluble aluminum content comprises the following steps: KR molten iron pre-desulfurization treatment, 150-ton top-bottom combined blowing converter, argon blowing after furnace, LF furnace refining, RH vacuum refining, 165mm × 165mm square billet continuous casting, casting blank heating, high-pressure water descaling, high-speed wire rolling, controlled cooling and coil collection.
8. The low acid soluble aluminum content SWRH82B wire rod of claim 7, wherein:
the 150-ton top-bottom combined blown converter comprises the following components: the molten iron fed into the furnace meets KR desulfurization requirements that S is less than or equal to 0.005Wt percent and P is less than or equal to 0.130Wt percent; a class of pure scrap is used.
9. The low acid soluble aluminum content SWRH82B wire rod of claim 7, wherein:
and refining in the LF furnace: adopting acid slag process, and dischargingTop slag target binary alkalinity R-CaO/SiO2Controlling the content of Al in the slag to be 0.8-1.22O3The content of FeO and MnO is controlled to be less than or equal to 6 percent and less than or equal to 1.5 percent, and the argon blowing time after acid slag is produced is more than or equal to 20 min.
10. The low acid soluble aluminum content SWRH82B wire rod of claim 7, wherein:
and RH vacuum refining: the ultimate vacuum time is more than or equal to 10 min; the net circulation time is more than or equal to 3 min; argon flow is less than or equal to 9m3The soft argon blowing time per hour is more than or equal to 8 min; the sedation time is more than or equal to 20 min; calcium treatment was not performed.
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Effective date of registration: 20220816 Address after: 545002, 117 North Bird Road, the Guangxi Zhuang Autonomous Region, Liuzhou Patentee after: Liuzhou Iron&Steel Co.,Ltd. Patentee after: GUANGXI LIUZHOU IRON AND STEEL GROUP Co.,Ltd. Address before: 545002, 117 North Bird Road, the Guangxi Zhuang Autonomous Region, Liuzhou Patentee before: Liuzhou Iron&Steel Co.,Ltd. |