CN111167476A - Carbon-carried RhNi-Ni (OH)2Preparation method of composite hydrogen evolution electrocatalyst - Google Patents
Carbon-carried RhNi-Ni (OH)2Preparation method of composite hydrogen evolution electrocatalyst Download PDFInfo
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- CN111167476A CN111167476A CN202010062374.1A CN202010062374A CN111167476A CN 111167476 A CN111167476 A CN 111167476A CN 202010062374 A CN202010062374 A CN 202010062374A CN 111167476 A CN111167476 A CN 111167476A
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 34
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 34
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 239000002131 composite material Substances 0.000 title claims abstract description 15
- 239000010411 electrocatalyst Substances 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 30
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000006185 dispersion Substances 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 8
- 238000004108 freeze drying Methods 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims abstract description 6
- SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 claims abstract description 6
- 238000000926 separation method Methods 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000012300 argon atmosphere Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229940053662 nickel sulfate Drugs 0.000 claims description 5
- RRIWRJBSCGCBID-UHFFFAOYSA-L nickel sulfate hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-]S([O-])(=O)=O RRIWRJBSCGCBID-UHFFFAOYSA-L 0.000 claims description 5
- 229940116202 nickel sulfate hexahydrate Drugs 0.000 claims description 5
- TYLYVJBCMQFRCB-UHFFFAOYSA-K trichlororhodium;trihydrate Chemical compound O.O.O.[Cl-].[Cl-].[Cl-].[Rh+3] TYLYVJBCMQFRCB-UHFFFAOYSA-K 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 abstract description 32
- 239000000243 solution Substances 0.000 abstract description 22
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract description 13
- 230000003197 catalytic effect Effects 0.000 abstract description 10
- 239000012670 alkaline solution Substances 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000010948 rhodium Substances 0.000 description 9
- 229910000510 noble metal Inorganic materials 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 1
- GPGGPRHLKWIJFR-UHFFFAOYSA-L [Ni](O)O.[Ni].[Rh] Chemical compound [Ni](O)O.[Ni].[Rh] GPGGPRHLKWIJFR-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002057 nanoflower Substances 0.000 description 1
- 239000002135 nanosheet Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000001075 voltammogram Methods 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/33—Electric or magnetic properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/892—Nickel and noble metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention relates to a carbon-carried RhNi-Ni (OH)2The preparation method of the composite hydrogen evolution electrocatalyst comprises the steps of adding a solution of nickel sulfate and rhodium chloride with a molar ratio of 1:3 to 3:1 into carbon powder dispersion liquid, wherein the mass ratio of metal elements to carbon powder is 3: 7; na is added dropwise2CO3A solution to adjust the pH to 9.0; then dropwise adding NaBH with the molar weight 40-80 times that of the metal element4The solution is fully reduced until no bubbles are generated, and then the RhNi-Ni (OH) is obtained after centrifugal separation, washing and freeze drying2and/C. RhNi-Ni (OH) prepared by the method2The composite catalyst shows good hydrogen evolution catalytic activity in alkaline solution. When the current density is 10mA cm‑2When the hydrogen evolution overpotential is even higher than that of Pt/C catalyst, therefore, the catalyst has good industrial applicationAnd 4, application prospect.
Description
Technical Field
The invention belongs to the technical field of electrocatalytic hydrogen evolution, and relates to a carbon-supported RhNi-Ni (OH)2A preparation method of (rhodium nickel-nickel hydroxide) composite hydrogen evolution electrocatalyst.
Background
Hydrogen is considered to be one of the ideal alternatives to fossil fuels as a clean, efficient renewable energy source. The hydrogen evolution reaction is a half-reaction of electrolysis of waterIs one of the important ways to prepare hydrogen. However, since the overvoltage of the hydrogen evolution reaction is high and a large amount of electric energy is consumed, it is necessary to develop an electrocatalyst having excellent catalytic performance to lower the energy barrier of the hydrogen evolution reaction. The hydrogen evolution catalyst with outstanding catalytic performance is mainly a noble metal catalyst, and the performance of the platinum-based catalyst is the most excellent at present. The hydrogen production reaction by water electrolysis is mostly carried out in alkaline solution, and for bulk phase catalyst, the catalytic activity of platinum in alkaline environment is nearly two orders of magnitude lower than that in acidic condition, while the catalytic activity of rhodium in alkaline and acidic solution is only about one order of magnitude different (see Jie Zheng, et al, Universal dependence of hydrogen oxidation and hydrolysis activity of platinum-group metals on pH and hydrogen generation, Sci.adv.,2016,2: e 1501602). Therefore, by regulating and controlling the components, the morphology and the structure of the rhodium-based catalyst, the hydrogen evolution catalytic performance more outstanding than that of a platinum catalyst in an alkaline solution is expected to be obtained. Currently, researchers have prepared Rh-based hydrogen evolution catalysts with excellent performance in alkaline environment, such as RhNi nano-sponge, Rh nanosheet, Rh nanoflower and the like, by regulating and controlling the morphology and components of the catalysts. However, the proportion of the noble metal element Rh in the Rh-based hydrogen evolution catalyst is still high, which is not favorable for reducing the production cost. Therefore, the development of a method for preparing the Rh-based hydrogen evolution catalyst with lower price has very important practical significance. Studies have found that the hydrogen evolution catalytic performance of noble metals in alkaline solutions can be greatly improved when transition metal hydroxides interact with noble metals (see the document Huajie Yin, et al, Ultrathinpnpinum nanowaus growth on single-layered aqueous reaction activity, Nature Communications,2015,6: 6430). In addition, the cost can be reduced by adding non-noble transition metal alloy elements into the noble metal catalyst, and the catalytic activity can be improved by the synergistic action of different elements. Based on The above theory and research foundation, The present invention provides a new idea of bright (Yu Chen, et al, The electrochemical performance of carbon ball supported RhCo allophanatities for The methanol oxidation reaction in alkalene media, Journal of Power Source, 2017,371)129-135) preparation of RhCo/C methanol oxidation electrocatalyst, research and development of RhNi-Ni (OH)2a/C hydrogen evolution electrocatalyst.
Disclosure of Invention
Technical problem to be solved
In order to avoid the defects of the prior art, the invention provides a carbon-supported RhNi-Ni (OH)2A preparation method of a composite hydrogen evolution electrocatalyst.
Technical scheme
Carbon-carried RhNi-Ni (OH)2The preparation method of the composite hydrogen evolution electrocatalyst is characterized by comprising the following steps:
step 1: heat-treating the carbon powder in argon atmosphere at 500 deg.C for 3 hr;
step 2: ultrasonically dispersing carbon powder for 1 hour at room temperature by using deionized water;
and step 3: dissolving nickel sulfate and rhodium chloride in a molar ratio of 1:3 to 3:1 in deionized water to form a solution;
and 4, step 4: adding the solution into carbon powder dispersion liquid to ensure that the mass ratio of the metal elements to the carbon powder is 3:7, and fully stirring and mixing;
and 5: then Na is added dropwise2CO3A solution to adjust the pH to 9.0;
step 6: heating and stirring the mixture in water bath at the temperature of between 60 and 70 ℃ for 5 to 7 hours;
and 7: then dropwise adding NaBH with the molar weight 40-80 times that of the metal element4The solution is fully reduced until no bubbles are generated, and then the RhNi-Ni (OH) is obtained after centrifugal separation, washing and freeze drying2/C。
And XC-72R carbon powder is adopted as the carbon powder.
The nickel sulfate adopts nickel sulfate hexahydrate.
The rhodium chloride adopts rhodium chloride trihydrate.
Advantageous effects
The invention provides a carbon-carried RhNi-Ni (OH)2The preparation method of the composite hydrogen evolution electrocatalyst comprises the step of adding a solution of nickel sulfate and rhodium chloride with a molar ratio of 1:3 to 3:1 into carbon powder dispersion liquid to ensure that the mass ratio of metal elements to carbon powder is3: 7; na is added dropwise2CO3A solution to adjust the pH to 9.0; then dropwise adding NaBH with the molar weight 40-80 times that of the metal element4The solution is fully reduced until no bubbles are generated, and then the RhNi-Ni (OH) is obtained after centrifugal separation, washing and freeze drying2and/C. RhNi-Ni (OH) prepared by the method2The composite catalyst shows good hydrogen evolution catalytic activity in alkaline solution. When the current density is 10mA cm-2When the catalyst is used, the hydrogen evolution overpotential is even higher than that of a Pt/C catalyst, so that the catalyst has good industrial application prospect.
The invention has the following beneficial effects:
(1) the carbon carrier is subjected to heat treatment in an inert gas environment, so that pollutants on the surface of the carbon black can be decomposed, and the content of oxygen-containing functional groups on the surface is increased, so that the dispersity of the catalyst particles on the surface is effectively improved. Compared with other preparation methods, the method does not need high-temperature acid washing on the carbon carrier, thereby avoiding the volatilization of corrosive gas and the generation of toxic gas, and shortening the preparation time and difficulty.
(2) The invention mixes transition metal hydroxide Ni (OH)2The catalyst is combined with metal alloy RhNi to form a composite catalyst, so that compared with a commercial Rh/C, Pt/C catalyst, the use amount of noble metals in the preparation process is greatly reduced, and the production cost is obviously reduced.
(3) The carbon ball prepared by the invention loads RhNi-Ni (OH)2The composite catalyst exhibits better hydrogen evolution activity in alkaline solution than commercial Pt/C catalysts, e.g., when the current density is 10mA cm-2When the catalyst is used, the hydrogen evolution overpotential is higher than that of a Pt/C catalyst, so that the catalytic efficiency of the catalyst is higher than that of the Pt/C catalyst.
Drawings
FIG. 1 shows the carbon-supported RhNi-Ni (OH) prepared in example 1 of the present invention2TEM topography of hydrogen evolution catalysts;
FIG. 2 is carbon-supported RhNi-Ni (OH) prepared in example 12XRD pattern of electrocatalyst;
FIG. 3 is a carbon loaded RhNi-Ni (OH) with different rhodium to nickel ratios2Electrocatalyst and linearity of noble metals Pt/C in alkaline solutionSweep voltammograms.
Detailed Description
The invention will now be further described with reference to the following examples and drawings:
example 1
Heat-treating XC-72R carbon powder for 3 hours in an argon atmosphere at 500 ℃, dispersing the heat-treated carbon powder in deionized water by using ultrasonic waves, preparing 2mL of nickel sulfate hexahydrate and rhodium chloride trihydrate solution with the molar ratio of 1:1, adding the solution into the carbon powder dispersion liquid, fully stirring and uniformly mixing, then dropwise adding 0.5mol/L sodium carbonate solution to adjust the pH value to 9.0, heating and stirring in a water bath at 60 ℃ for 7 hours, and adding 4mL of NaBH containing 70 times of metal salt at room temperature4Dripping the solution into the dispersion, fully stirring until the reaction is complete and no bubbles are generated, centrifugally separating the dispersion, fully washing with deionized water, and freeze-drying for 12 hours to obtain RhNi-Ni (OH)2A catalyst.
Example 2
Heat-treating XC-72R carbon powder for 3 hours in an argon atmosphere at 500 ℃, dispersing the heat-treated carbon powder in deionized water by using ultrasonic waves, preparing 2mL of nickel sulfate hexahydrate and rhodium chloride trihydrate solution with the molar ratio of 3:1, adding the solution into the carbon powder dispersion liquid, fully stirring and uniformly mixing, then dropwise adding 0.5mol/L sodium carbonate solution to adjust the pH value to 9.0, heating and stirring in a water bath at 65 ℃ for 6 hours, and adding 4mL of NaBH containing 60 times of metal salt in molar weight at room temperature4Dripping the solution into the dispersion, fully stirring until the reaction is complete and no bubbles are generated, centrifugally separating the dispersion, fully washing with deionized water, and freeze-drying for 12 hours to obtain RhNi-Ni (OH)2A catalyst.
Example 3
Heat-treating XC-72R carbon powder for 3 hours in argon atmosphere at 500 ℃, dispersing the heat-treated carbon powder in deionized water by using ultrasonic waves, preparing 2mL of nickel sulfate hexahydrate and rhodium chloride trihydrate solution with the molar ratio of 1:3, adding the solution into the carbon powder dispersion liquid, fully stirring and uniformly mixing, then dropwise adding 0.5mol/L sodium carbonate solution to adjust the pH value to 9.0, heating and stirring in water bath at 70 ℃ for 5 hoursFor a while, 4mL of NaBH containing a molar amount 80 times that of the metal salt was added at room temperature4Dripping the solution into the dispersion, fully stirring until the reaction is complete and no bubbles are generated, centrifugally separating the dispersion, fully washing with deionized water, and freeze-drying for 12 hours to obtain RhNi-Ni (OH)2A catalyst.
Claims (4)
1. Carbon-carried RhNi-Ni (OH)2The preparation method of the composite hydrogen evolution electrocatalyst is characterized by comprising the following steps:
step 1: heat-treating the carbon powder in argon atmosphere at 500 deg.C for 3 hr;
step 2: ultrasonically dispersing carbon powder for 1 hour at room temperature by using deionized water;
and step 3: dissolving nickel sulfate and rhodium chloride in a molar ratio of 1:3 to 3:1 in deionized water to form a solution;
and 4, step 4: adding the solution into carbon powder dispersion liquid to ensure that the mass ratio of the metal elements to the carbon powder is 3:7, and fully stirring and mixing;
and 5: then Na is added dropwise2CO3A solution to adjust the pH to 9.0;
step 6: heating and stirring the mixture in water bath at the temperature of between 60 and 70 ℃ for 5 to 7 hours;
and 7: then dropwise adding NaBH with the molar weight 40-80 times that of the metal element4The solution is fully reduced until no bubbles are generated, and then the RhNi-Ni (OH) is obtained after centrifugal separation, washing and freeze drying2/C。
2. The carbon-supported RhNi-Ni (OH) according to claim 12The preparation method of the composite hydrogen evolution electrocatalyst is characterized by comprising the following steps: and XC-72R carbon powder is adopted as the carbon powder.
3. The carbon-supported RhNi-Ni (OH) according to claim 12The preparation method of the composite hydrogen evolution electrocatalyst is characterized by comprising the following steps: the nickel sulfate adopts nickel sulfate hexahydrate.
4. The carbon-supported RhNi-Ni (OH) according to claim 12Composite hydrogen evolution electrocatalystThe preparation method is characterized by comprising the following steps: the rhodium chloride adopts rhodium chloride trihydrate.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113774428A (en) * | 2021-07-28 | 2021-12-10 | 浙江大学衢州研究院 | Preparation method of efficient cobalt rhodium hydroxide nanoparticle/carbon cloth electrode, product and application thereof |
| CN115138362A (en) * | 2022-07-13 | 2022-10-04 | 浙江大学 | Metal-hydroxyl cluster modified noble metal catalyst and application thereof |
| CN115532282A (en) * | 2022-10-10 | 2022-12-30 | 三峡大学 | Preparation method and application of hydroxide-loaded metal nanoparticles |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113774428A (en) * | 2021-07-28 | 2021-12-10 | 浙江大学衢州研究院 | Preparation method of efficient cobalt rhodium hydroxide nanoparticle/carbon cloth electrode, product and application thereof |
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| CN115138362A (en) * | 2022-07-13 | 2022-10-04 | 浙江大学 | Metal-hydroxyl cluster modified noble metal catalyst and application thereof |
| CN115532282A (en) * | 2022-10-10 | 2022-12-30 | 三峡大学 | Preparation method and application of hydroxide-loaded metal nanoparticles |
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