CN111116176A - Light environment-friendly tundish dry material and preparation method thereof - Google Patents

Light environment-friendly tundish dry material and preparation method thereof Download PDF

Info

Publication number
CN111116176A
CN111116176A CN201911298520.4A CN201911298520A CN111116176A CN 111116176 A CN111116176 A CN 111116176A CN 201911298520 A CN201911298520 A CN 201911298520A CN 111116176 A CN111116176 A CN 111116176A
Authority
CN
China
Prior art keywords
granularity
percent
tundish dry
dry material
light environment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911298520.4A
Other languages
Chinese (zh)
Inventor
黄振兴
罗先进
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YIXING LONGCHEN FURNACE CHARGE CO Ltd
Original Assignee
YIXING LONGCHEN FURNACE CHARGE CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by YIXING LONGCHEN FURNACE CHARGE CO Ltd filed Critical YIXING LONGCHEN FURNACE CHARGE CO Ltd
Priority to CN201911298520.4A priority Critical patent/CN111116176A/en
Publication of CN111116176A publication Critical patent/CN111116176A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/03Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
    • C04B35/04Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite based on magnesium oxide
    • C04B35/043Refractories from grain sized mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C04B35/101Refractories from grain sized mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632Organic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206Magnesium oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/36Glass starting materials for making ceramics, e.g. silica glass
    • C04B2235/365Borosilicate glass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Ceramic Products (AREA)

Abstract

The invention discloses a light environment-friendly tundish dry material and a preparation method thereof, wherein the light environment-friendly tundish dry material is prepared by stirring and mixing the following components in percentage by weight: 40-60% of main material with the granularity of 1-0mm, 20-60% of waste brick material with the granularity of 1-0mm, 5.5-10% of bonding agent, 0.5-1.2% of sintering agent, 0.4-1.2% of lime powder, 7.5-33.58% of fine powder and 0.02-0.1% of white oil; the main material comprises one or two of magnesite with the granularity of 1-0mm and olivine with the granularity of 1-0 mm; the total adding amount of the main material and the waste brick material is 60-80%. The tundish dry material is environment-friendly, low in masonry cost, stable in structure and convenient to disassemble and turn over.

Description

Light environment-friendly tundish dry material and preparation method thereof
Technical Field
The invention relates to the field of fireproof tundish dry materials, in particular to a light environment-friendly tundish dry material and a preparation method thereof.
Background
The tundish is important equipment of a steelmaking continuous casting system, and molten steel in the ladle is connected with the crystallizer through the tundish to be poured into industrial products. In the past, a tundish is only used as a container for storing molten steel, but with the development of metallurgical industry, the technical requirements on the tundish are higher and higher, because the functional structure design and the material configuration scheme not only determine the content and distribution of molten steel inclusions, a molten steel temperature field and the like, but also have great influence on the operation cost and safe production of the tundish.
The tundish working lining in the current market is mainly constructed by using a magnesium dry vibration material, and compared with the construction by adopting a coating material, the construction method has the advantages of low labor intensity, simplicity and convenience. At present, most tundish dry materials used in the market are resin-bonded magnesium dry materials, and although the use of the tundish dry materials can basically meet the production requirements, the tundish dry materials still have certain defects:
firstly, the method comprises the following steps: the large density also causes the thermal conductivity coefficient of the dry material to be too large, and the heat of molten steel is dissipated too fast, thereby requiring the increase of the temperature of molten steel in the tundish, which can cause the increase of the smelting cost of a steel mill;
secondly, the method comprises the following steps: in the traditional magnesium dry material formula, the main material mainly comprises magnesia, so that the material cost is high, the raw material source is single, the market fluctuation is large, and the stability and the economic benefit of an enterprise in production are adversely affected;
thirdly, the method comprises the following steps: although the phenolic resin as a bonding agent has high strength, the resin material has high cost, is limited in economy and has certain smell;
fourthly: the fine powder in the traditional tundish dry material is directly added without any treatment, and the dust during production and construction has great influence on the environment and the physical health of workers;
fifth, the method comprises the following steps: the tundish dry material is attached to the surface of the permanent lining castable, so that not only is a certain normal-temperature strength demolding strength required, but also the medium-high temperature strength is required to reach a certain standard, otherwise, the tundish is easy to collapse in the baking process or in the casting process;
sixth: the tundish is difficult to disassemble and turn over after being used.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a light environment-friendly tundish dry material which is environment-friendly, low in masonry cost, stable in structure and convenient to disintegrate and turn over and a preparation method thereof.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the light environment-friendly tundish dry material comprises the following components in percentage by weight: 40-60% of main material with the granularity of 1-0mm, 20-60% of waste brick material with the granularity of 1-0mm, 5.5-10% of bonding agent, 0.5-1.2% of sintering agent, 0.4-1.2% of lime powder, 7.5-33.58% of fine powder and 0.02-0.1% of white oil; the main material comprises one or two of magnesite with the granularity of 1-0mm and olivine with the granularity of 1-0 mm; the total adding amount of the main material and the waste brick material is 60-80%.
Preferably, the waste brick material comprises one or two of waste magnesia carbon bricks with the granularity of 1-0mm and waste magnesia bricks with the granularity of 1-0 mm; the addition amount of the waste brick material of a single variety is 10-30% by weight percentage.
Preferably, the binding agent consists of glucose monohydrate and magnesium sulfate heptahydrate; the dextrose monohydrate accounts for 5 to 8 percent by weight; the magnesium sulfate heptahydrate is 0.5-2%.
Preferably, the sintering agent consists of boron glass powder and borax; the boron glass powder accounts for 0 to 0.8 percent by weight; 0 to 0.8 percent of borax and 0.5 to 1.2 percent of the total addition amount of the borax and the borax.
Preferably, the fine powder is 100-mesh fine powder of magnesite with purity of more than or equal to 90 percent or 100-mesh fine powder of waste magnesia carbon bricks.
Preferably, the particle size of the lime powder is 200 meshes.
A preparation method of a light environment-friendly tundish dry material comprises the following steps:
the method comprises the following steps: mixing the fine powder and the sintering agent according to a ratio of 5:1, adding the mixture into a ball mill, and grinding for about 1 hour to obtain a mixture, and bagging the mixture for later use;
step two: adding the main material, the waste brick material and the white oil into a stirrer, and stirring for 2 min;
step three: and (4) adding the mixture obtained in the step one and other materials into a stirrer, and stirring for 15-20min to obtain a finished product.
The invention has the beneficial effects that:
firstly, the method comprises the following steps: aiming at the problems of overlarge critical granularity (generally 5mm or 3 mm) and overlarge body density caused by unreasonable gradation, the critical granularity is adjusted to 1mm, the specific surface area of the material is greatly improved, the main material is mainly 1-0mm in granularity, accounts for 60-80%, and the balance is 100-mesh fine powder, a bonding agent, a sintering agent and the like, so that the stacking density of the dry material can be reduced by nearly 10-20% compared with the dry material adopting the critical granularity of 3mm or 5mm, after the critical granularity is reduced, segregation caused by vibration in the material construction process is greatly reduced, and the material integrity is good;
secondly, the method comprises the following steps: aiming at the problems that the main material in the traditional magnesium dry material formula is mainly magnesia, the material cost is high, the raw material source is single, the market fluctuation is large, and the stability and the economic benefit of an enterprise are adversely affected; the invention adopts the composition of different raw materials such as magnesite, olivine, waste magnesia carbon bricks, waste magnesia bricks and the like, greatly enriches the selection range of the raw materials, greatly reduces the cost and is environment-friendly; because the waste brick material has high quality fluctuation, the addition amount of the waste brick material of a single variety needs to be carefully controlled, the addition amount is controlled between 10 and 30 percent, and if the waste brick material is added according to two compounds, the total addition amount is controlled between 20 and 60 percent; because the magnesite and the olivine are new raw materials, the quality is relatively stable, the addition amount is relatively loose, and the adjustment can be carried out according to the technological requirements of clients;
thirdly, the method comprises the following steps: the problems of high cost and certain smell of the phenolic resin are solved; the invention uses dextrose monohydrate and magnesium sulfate heptahydrate to replace, thus improving the environmental protection;
fourthly: aiming at the problems that the fine powder in the traditional tundish dry material is directly added without any treatment, and the dust during production and construction has great influence on the environment and the physical health of workers, the invention greatly reduces the precipitation of the dust by adding the industrial white oil during production, the addition amount of the white oil is controlled to be 0.02-0.1 percent, the white oil adding method comprises the steps of firstly adding the main material and the waste brick material into a stirrer, then adding the white oil, stirring for 2min, then adding other raw materials, and continuing stirring, thus greatly reducing the precipitation of the dust and improving the working environment;
fifth, the method comprises the following steps: the problem that the tundish collapses during baking or casting is easily caused by the fact that a certain normal-temperature strength demolding strength is required for a tundish dry material, and a certain standard is required for medium-high temperature strength; according to the invention, after a burdening scheme with the critical granularity of 1mm is adopted, the requirement on sintering strength is higher, the sintering of the material is promoted by compositely adding boron glass powder and borax, and the adding method of the sintering agent is as follows: mixing fine sand and sintering agent according to a ratio of 5:1, adding the mixture into a ball mill, grinding for about 1h, and discharging, so that the sintering agent can be fully dispersed in the material;
sixth: aiming at the problem that the tundish is difficult to disintegrate and turn over after being used, the invention adds 0.4-1.2% of lime powder with 200 meshes into the material, CaO in the lime powder reacts with silicon dioxide in the material at high temperature to generate dicalcium silicate, and the dicalcium silicate crystal forms are transformed into volume and expand to generate pulverization after being cooled, thereby promoting the disintegration of the tundish body.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below.
Example 1:
the light environment-friendly tundish dry material comprises the following components in percentage by weight: 20 percent of magnesite with the granularity of 1-0mm and the purity of more than or equal to 90, 30 percent of olivine with the granularity of 1-0mm, 25 percent of waste magnesia carbon brick with the granularity of 1-0mm, 16.3 percent of magnesite fine powder with the granularity of 100 meshes and the purity of more than or equal to 90, 7 percent of dextrose monohydrate, 0.5 percent of magnesium sulfate heptahydrate, 0.3 percent of boron glass powder, 0.3 percent of borax, 0.6 percent of lime powder and 0.05 percent of white oil.
A preparation method of a light environment-friendly tundish dry material comprises the following steps:
the method comprises the following steps: mixing 100-mesh magnesia fine powder with purity of more than or equal to 90, boron glass powder and borax according to a ratio of 5:1, adding the mixture into a ball mill, grinding for about 1 hour to obtain a mixture, and bagging for later use;
step two: adding magnesite with granularity of 1-0mm and purity not less than 90, olivine with granularity of 1-0mm, waste magnesia carbon brick with granularity of 1-0mm and white oil into a stirrer, and stirring for 2 min;
step three: and (4) adding the mixture obtained in the step one and other materials into a stirrer, and stirring for 15-20min to obtain a finished product.
Example 2
The light environment-friendly tundish dry material comprises the following components in percentage by weight: 35 percent of olivine with the granularity of 1-0mm, 20 percent of waste magnesia carbon brick with the granularity of 1-0mm, 20 percent of waste magnesia brick with the granularity of 1-0mm, 14.9 percent of magnesia fine powder with the purity of 100 meshes being more than or equal to 90, 7.5 percent of dextrose monohydrate, 1 percent of magnesium sulfate heptahydrate, 0.4 percent of boron glass powder, 0.4 percent of borax, 0.8 percent of lime powder and 0.05 percent of white oil.
A preparation method of a light environment-friendly tundish dry material comprises the following steps:
the method comprises the following steps: mixing 100-mesh magnesia fine powder with purity of more than or equal to 90, boron glass powder and borax according to a ratio of 5:1, adding the mixture into a ball mill, grinding for about 1 hour to obtain a mixture, and bagging for later use;
step two: adding olivine with particle size of 1-0mm, waste magnesia carbon brick with particle size of 1-0mm, waste magnesia brick with particle size of 1-0mm and white oil into a stirrer, and stirring for 2 min;
step three: and (4) adding the mixture obtained in the step one and other materials into a stirrer, and stirring for 15-20min to obtain a finished product.
Example 3
The light environment-friendly tundish dry material comprises the following components in percentage by weight: 20 percent of olivine with the granularity of 1-0mm, 30 percent of waste magnesia carbon brick with the granularity of 1-0mm, 25 percent of waste magnesia brick with the granularity of 1-0mm, 14.8 percent of magnesia fine powder with the purity of 100 meshes being more than or equal to 90, 7.5 percent of dextrose monohydrate, 1 percent of magnesium sulfate heptahydrate, 0.6 percent of boron glass powder, 0.6 percent of borax, 0.5 percent of lime powder and 0.07 percent of white oil.
A preparation method of a light environment-friendly tundish dry material comprises the following steps:
the method comprises the following steps: mixing 100-mesh magnesia fine powder with purity of more than or equal to 90, boron glass powder and borax according to a ratio of 5:1, adding the mixture into a ball mill, grinding for about 1 hour to obtain a mixture, and bagging for later use;
step two: adding olivine with particle size of 1-0mm, waste magnesia carbon brick with particle size of 1-0mm, waste magnesia brick with particle size of 1-0mm and white oil into a stirrer, and stirring for 2 min;
step three: and (4) adding the mixture obtained in the step one and other materials into a stirrer, and stirring for 15-20min to obtain a finished product.
Example 4
The light environment-friendly tundish dry material comprises the following components in percentage by weight: 45 percent of olivine with the granularity of 1-0mm, 30 percent of waste magnesia carbon brick with the granularity of 1-0mm, 10 percent of magnesia fine powder with the purity of 100 meshes being more than or equal to 90, 5.3 percent of waste magnesia brick fine powder with the granularity of 100 meshes, 7 percent of dextrose monohydrate, 1 percent of magnesium sulfate heptahydrate, 0.6 percent of boron glass powder, 0.6 percent of borax, 0.5 percent of lime powder and 0.07 percent of white oil.
A preparation method of a light environment-friendly tundish dry material comprises the following steps:
the method comprises the following steps: mixing 100-mesh magnesia fine powder with purity more than or equal to 90, 100-mesh waste magnesia brick fine powder, boron glass powder and borax according to a ratio of 5:1, adding the mixture into a ball mill, and grinding for about 1 hour to obtain a mixture, and bagging the mixture for later use;
step two: adding olivine with particle size of 1-0mm, waste magnesia carbon brick with particle size of 1-0mm and white oil into a stirrer, and stirring for 2 min;
step three: and (4) adding the mixture obtained in the step one and other materials into a stirrer, and stirring for 15-20min to obtain a finished product.
The embodiments described above are only a part of the embodiments of the present invention, and not all of them. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Claims (7)

1. The light environment-friendly tundish dry material is characterized in that: comprises the following components in percentage by weight: 40-60% of main material with the granularity of 1-0mm, 20-60% of waste brick material with the granularity of 1-0mm, 5.5-10% of bonding agent, 0.5-1.2% of sintering agent, 0.4-1.2% of lime powder, 7.5-33.58% of fine powder and 0.02-0.1% of white oil; the main material comprises one or two of magnesite with the granularity of 1-0mm and olivine with the granularity of 1-0 mm; the total adding amount of the main material and the waste brick material is 60-80%.
2. The light environment-friendly tundish dry material according to claim 1, characterized in that: the waste brick material comprises one or two of waste magnesia carbon bricks with the granularity of 1-0mm and waste magnesia bricks with the granularity of 1-0 mm; the addition amount of the waste brick material of a single variety is 10-30% by weight percentage.
3. The light environment-friendly tundish dry material according to claim 1, characterized in that: the binding agent consists of dextrose monohydrate and magnesium sulfate heptahydrate; the dextrose monohydrate accounts for 5 to 8 percent by weight; the magnesium sulfate heptahydrate is 0.5-2%.
4. The light environment-friendly tundish dry material according to claim 1, characterized in that: the sintering agent consists of boron glass powder and borax; the boron glass powder accounts for 0 to 0.8 percent by weight; 0 to 0.8 percent of borax and 0.5 to 1.2 percent of the total addition amount of the borax and the borax.
5. The light environment-friendly tundish dry material according to claim 1, characterized in that: the fine powder is 100-mesh magnesia fine powder with the purity of more than or equal to 90 percent or 100-mesh waste magnesia carbon brick fine powder.
6. The light environment-friendly tundish dry material according to claim 1, characterized in that: the particle size of the lime powder is 200 meshes.
7. A method for preparing a light-weight environment-friendly tundish dry material according to any one of claims 1 to 6, which is characterized in that: the method comprises the following steps:
the method comprises the following steps: mixing the fine powder and the sintering agent according to a ratio of 5:1, adding the mixture into a ball mill, and grinding for about 1 hour to obtain a mixture, and bagging the mixture for later use;
step two: adding the main material, the waste brick material and the white oil into a stirrer, and stirring for 2 min;
step three: and (4) adding the mixture obtained in the step one and other materials into a stirrer, and stirring for 15-20min to obtain a finished product.
CN201911298520.4A 2019-12-17 2019-12-17 Light environment-friendly tundish dry material and preparation method thereof Pending CN111116176A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911298520.4A CN111116176A (en) 2019-12-17 2019-12-17 Light environment-friendly tundish dry material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911298520.4A CN111116176A (en) 2019-12-17 2019-12-17 Light environment-friendly tundish dry material and preparation method thereof

Publications (1)

Publication Number Publication Date
CN111116176A true CN111116176A (en) 2020-05-08

Family

ID=70500033

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201911298520.4A Pending CN111116176A (en) 2019-12-17 2019-12-17 Light environment-friendly tundish dry material and preparation method thereof

Country Status (1)

Country Link
CN (1) CN111116176A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111960833A (en) * 2020-08-26 2020-11-20 廊坊森德科技有限公司 Environment-friendly dry type vibration bonding agent

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005289724A (en) * 2004-03-31 2005-10-20 Sumitomo Metal Ind Ltd REFRACTORY FOR DRY PROCESS VIBRATION CONSTRUCTION WORK CONTAINING WASTE MATERIAL OF MgO-C BRICK
CN101613216A (en) * 2009-04-09 2009-12-30 北京利尔高温材料股份有限公司 A kind of environment-friendly flowing tundish dry material and preparation method thereof
CN106565257A (en) * 2016-11-22 2017-04-19 江苏嘉耐高温材料有限公司 Dry vibration material with good fluidity for magnesium tundish and preparation method thereof
CN107879751A (en) * 2017-10-25 2018-04-06 新疆八钢铁股份有限公司 A kind of method that tundish dry material is manufactured using waste magnesia carbon brick
CN109231968A (en) * 2018-09-17 2019-01-18 武汉钢铁有限公司 Continuous casting production working lining dry materials and preparation method thereof
CN110526723A (en) * 2019-09-12 2019-12-03 通化耐博新材料股份有限公司 Environment-friendly type tundish dry material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005289724A (en) * 2004-03-31 2005-10-20 Sumitomo Metal Ind Ltd REFRACTORY FOR DRY PROCESS VIBRATION CONSTRUCTION WORK CONTAINING WASTE MATERIAL OF MgO-C BRICK
CN101613216A (en) * 2009-04-09 2009-12-30 北京利尔高温材料股份有限公司 A kind of environment-friendly flowing tundish dry material and preparation method thereof
CN106565257A (en) * 2016-11-22 2017-04-19 江苏嘉耐高温材料有限公司 Dry vibration material with good fluidity for magnesium tundish and preparation method thereof
CN107879751A (en) * 2017-10-25 2018-04-06 新疆八钢铁股份有限公司 A kind of method that tundish dry material is manufactured using waste magnesia carbon brick
CN109231968A (en) * 2018-09-17 2019-01-18 武汉钢铁有限公司 Continuous casting production working lining dry materials and preparation method thereof
CN110526723A (en) * 2019-09-12 2019-12-03 通化耐博新材料股份有限公司 Environment-friendly type tundish dry material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111960833A (en) * 2020-08-26 2020-11-20 廊坊森德科技有限公司 Environment-friendly dry type vibration bonding agent

Similar Documents

Publication Publication Date Title
CN104355634B (en) A kind of aluminum oxide electric furnace cover and preparation method thereof
CN102674852A (en) Preparation method of tundish working lining
CN109879661B (en) Tundish coating material and preparation method thereof
CN102756112B (en) Composite slag remover for casting
CN106495712A (en) Unburned ladle brick and preparation method thereof pressed by magnesium gel combined corundum spinelle machine
CN101654375A (en) Low-carbon magnesia carbon brick
JP5420815B2 (en) Heat resistant material for low melting point metal casting equipment
CN105220058A (en) A kind of preparation method of thin-walled chilling part nucleating agent and application thereof
CN109678479A (en) The steel ladle bottom argon blowing air brick of smelting high-purity clear height manganese steel
CN103396135B (en) A kind of mould material for noting recrement basin grid wall and preparation method thereof and using method
CN106521297B (en) A kind of method for reducing Form in High Nickel Austenite Nodular Cast Iron turbine case internal flaw
CN111116176A (en) Light environment-friendly tundish dry material and preparation method thereof
CN102775160A (en) Slag stopping weir for tundish and preparation method
CN101786891A (en) Air-set mold bulk material for continuous casting tundish and preparation method thereof
CN109732048A (en) Covering slag, preparation method and application for Automobile Plate steel continuous casting crystallizer
RU2356687C2 (en) Slag-forming mixture for tundish ladle
CN112430105A (en) Aluminum-magnesium-carbon brick prepared from regenerated tabular corundum and preparation method thereof
CN102773404B (en) Anti-whiting coating for cast iron and methods for preparing and using anti-whiting coating for cast iron
CN101733371B (en) Function protective materials for oblong taperless steel ingots
CN101381239A (en) Magnesium oxide precast refractory material and construction method thereof
CN104311053A (en) High-strength washing-resistant castable material for tundish of continuous casting machine
CN103073309A (en) Environment-friendly furnace lining material for medium-frequency induction furnace and preparation method of environment-friendly furnace lining material
CN104084574B (en) A kind of environment-friendly type liner in dundish and forming method thereof
US4210619A (en) Cement bonded agglomerate containing boron
CN105481388A (en) Environmentally-friendly dry working lining for tundish and preparation method of environmental-protection type dry working lining

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20200508