CN111106240A - Ink jet printing cartridge and method of manufacturing organic light emitting diode display device - Google Patents

Ink jet printing cartridge and method of manufacturing organic light emitting diode display device Download PDF

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Publication number
CN111106240A
CN111106240A CN201911349699.1A CN201911349699A CN111106240A CN 111106240 A CN111106240 A CN 111106240A CN 201911349699 A CN201911349699 A CN 201911349699A CN 111106240 A CN111106240 A CN 111106240A
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China
Prior art keywords
layer
print cartridge
organic light
light emitting
control switch
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CN201911349699.1A
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Chinese (zh)
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CN111106240B (en
Inventor
黄志达
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Shenzhen China Star Optoelectronics Semiconductor Display Technology Co Ltd
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Shenzhen China Star Optoelectronics Semiconductor Display Technology Co Ltd
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Publication of CN111106240A publication Critical patent/CN111106240A/en
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10Deposition of organic active material
    • H10K71/12Deposition of organic active material using liquid deposition, e.g. spin coating
    • H10K71/13Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing
    • H10K71/135Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing using ink-jet printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/21Ink jet for multi-colour printing
    • B41J2/2107Ink jet for multi-colour printing characterised by the ink properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/21Ink jet for multi-colour printing
    • B41J2/2121Ink jet for multi-colour printing characterised by dot size, e.g. combinations of printed dots of different diameter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J3/00Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed
    • B41J3/407Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J3/00Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed
    • B41J3/407Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material
    • B41J3/413Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material for metal
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

An inkjet print cartridge is used to manufacture an organic light emitting display device. The ink jet print cartridge includes a first print cartridge, a second print cartridge, a first control switch, and a second control switch. The first cartridge carries a soluble organic molecule solution and the second cartridge carries a blank solvent. The first control switch controls the first printing box, and when the amount of the soluble organic molecular solution reaches a first preset value, the first control switch closes the first printing box. The second control switch controls the second print cartridge and closes the second print cartridge when the blank solvent reaches a second preset value. The invention prepares the organic light-emitting diode display device by the ink-jet printing technology of mixing the soluble organic molecules and the blank solvent, reduces the using amount of the ink box, can also effectively control the process of drying and film forming, and achieves that each layer in the organic light-emitting diode display device has wider range of thickness.

Description

Ink jet printing cartridge and method of manufacturing organic light emitting diode display device
Technical Field
The invention relates to the technical field of preparation of display equipment by ink-jet printing, in particular to an ink-jet printing box and a method for preparing organic light-emitting diode display equipment.
Background
Since the polymer has a large molecular weight, spin coating or printing is mainly used, and inkjet printing is the best method for manufacturing an organic light emitting diode display device at present.
Currently, in the process of manufacturing an organic light emitting diode display device by ink jet printing, each ink box can only be loaded with one concentration of ink, because each pixel has a limited volume and the ink must be spread over the pixels. Thus, there are lower and upper limits on the volume of ink that can be loaded per pixel, resulting in a very limited range of thicknesses that can be printed with each concentration of ink. In addition, the ink jet printing technology has a very high requirement on the degree of drying, and in the process of manufacturing an organic light emitting diode display device, surface irregularities of a pixel layer are often caused in the drying process. Therefore, there is a need to provide an inkjet print cartridge for manufacturing an organic light emitting display device to solve the problems of the prior art.
Disclosure of Invention
The invention provides an ink-jet printing box which is used for preparing organic light-emitting display equipment and comprises a first printing box, a second printing box, a first control switch and a second control switch. The first cartridge carries a soluble organic molecule solution and the second cartridge carries a blank solvent. The first control switch controls the first printing box, and when the amount of the soluble organic molecular solution reaches a first preset value, the first control switch closes the first printing box. The second control switch controls the second print cartridge and closes the second print cartridge when the blank solvent reaches a second preset value.
In one embodiment of the present invention, the first print cartridge includes a first sub-print cartridge, a second sub-print cartridge, and a third sub-print cartridge, the first sub-print cartridge carries the red light-emitting organic molecular solution, the second sub-print cartridge carries the green organic molecular solution, and the third sub-print cartridge carries the blue organic molecular solution.
In one embodiment of the present invention, the hole injection layer, the hole transport layer, the organic light emitting layer, the electron transport layer, and the electron injection layer are formed to a thickness in a range of 0.1 nm to 175 nm by an inkjet print cartridge.
In an embodiment of the present invention, the first predetermined value is between 0.1 and 45 picoliters.
In an embodiment of the present invention, the second predetermined value is between 0.1 and 45 picoliters.
The invention provides a method for preparing an organic light-emitting diode display device by using the ink-jet printing box for printing, which comprises the steps of providing a substrate, forming an anode layer, spin-coating a hole injection layer, spin-coating a hole transport layer, forming an organic light-emitting layer by ink-jet printing, spin-coating an electron transport layer, spin-coating an electron injection layer and forming a cathode layer.
In an embodiment of the present invention, the thicknesses of the hole injection layer, the hole transport layer, the organic light emitting layer, the electron transport layer and the electron injection layer are in a range from 0.1 nm to 175 nm.
In an embodiment of the present invention, the thicknesses of the hole injection layer, the hole transport layer, the organic light emitting layer, the electron transport layer and the electron injection layer are in a range from 60 nm to 175 nm.
In an embodiment of the present invention, the thicknesses of the hole injection layer, the hole transport layer, the organic light emitting layer, the electron transport layer and the electron injection layer are in a range from 20 nm to 40 nm.
In an embodiment of the present invention, the thicknesses of the hole injection layer, the hole transport layer, the organic light emitting layer, the electron transport layer and the electron injection layer are in a range from 40 nm to 80 nm.
The embodiment of the invention prepares the organic light emitting diode display device by an inkjet printing technology of mixing soluble organic molecules and a blank solvent, simultaneously reduces the number of used ink boxes, can also effectively control the process of drying and film forming, and achieves that each layer in the organic light emitting diode display device has a wider range of thickness.
Drawings
FIG. 1 is a schematic view of an embodiment of the present invention as implemented by an ink jet print cartridge.
FIG. 2 is a graph showing the relationship between the film thickness and the volume of an organic light-emitting layer formed by ink-jet printing according to an embodiment of the present invention.
Detailed Description
According to fig. 1, the present invention provides an inkjet print cartridge 10 for use in preparing an organic light emitting display device. Inkjet print cartridge 10 includes a first print cartridge 11, a second print cartridge 12, a first control switch 110, and a second control switch 120. The first print cartridge 11 carries a soluble organic molecule solution and the second print cartridge 12 carries a blank solvent. The first control switch 110 controls the first print cartridge 11, and when the amount of the soluble organic molecular solution reaches a first preset value, wherein the first preset value is between 0.1 and 45 picoliters, the first control switch 110 closes the first print cartridge 11. Second control switch 120 controls second print cartridge 12 and second control switch 120 closes second print cartridge 12 when the blank solvent reaches a second preset value, wherein the second preset value is between 0.1 and 45 picoliters.
Specifically, the first print cartridge includes a first sub-print cartridge, a second sub-print cartridge, and a third sub-print cartridge, the first sub-print cartridge carrying a red light emitting organic molecular solution, the second sub-print cartridge carrying a green organic molecular solution, and the third sub-print cartridge carrying a blue organic molecular solution. In addition, a hole injection layer, a hole transport layer, an organic light emitting layer, an electron transport layer, and an electron injection layer are formed to a thickness ranging from 0.1 nm to 175 nm by the inkjet print cartridge.
In addition, the invention also provides a method for preparing the organic light-emitting diode display device by using the ink-jet printing box printing, which comprises the steps of providing a substrate, forming an anode layer, spin-coating a hole injection layer, spin-coating a hole transport layer, forming an organic light-emitting layer by ink-jet printing, spin-coating an electron transport layer, spin-coating an electron injection layer and forming a cathode layer.
Specifically, a substrate is first provided, which is glass or a flexible material, and a patterned anode layer is formed on the substrate, where the anode layer includes a metal layer or a metal oxide layer, and preferably, the metal oxide layer includes indium tin oxide or tin oxide. And sequentially spin-coating a hole injection layer and a hole transport layer on the patterned anode layer and forming an organic light-emitting layer by ink-jet printing. In the process of forming the organic light emitting layer by inkjet printing, the organic light emitting layer is formed by spraying an organic mixture, specifically, the organic mixture includes soluble organic molecules and a blank solvent, and the soluble organic molecules further include red soluble organic molecules, green soluble organic molecules, and blue soluble organic molecules. In the inkjet printing process, an organic mixture of red soluble organic molecules and a blank solvent is inkjet printed to form a red light emitting layer thin film, and the remaining organic mixture is removed. And then ink-jet printing an organic mixture of green soluble organic molecules and a blank solvent to form a green light-emitting layer film, and removing the residual organic mixture. And finally, ink-jet printing the organic mixture of the blue soluble organic molecules and the blank solvent to form a blue light-emitting layer film, and removing the residual organic mixture. The processes of forming the red light emitting layer thin film, the green light emitting layer thin film and the blue light emitting layer thin film do not need to be in order, and the red light emitting layer thin film, the green light emitting layer thin film and the blue light emitting layer thin film can be simultaneously formed by appropriate adjustment, so that the present invention is not limited to this embodiment.
Further, the thicknesses of the hole injection layer, the hole transport layer and the organic light emitting layer are in the range of 0.1 nm to 175 nm. Preferably, the thicknesses of the hole injection layer, the hole transport layer and the organic light emitting layer are in the range of 60 nm to 175 nm. More preferably, the thicknesses of the hole injection layer, the hole transport layer and the organic light emitting layer are in the range of 40 nm to 80 nm. Still more preferably, the thickness of the hole injection layer, the hole transport layer, the organic light emitting layer is in the range of 20 nm to 40 nm.
When the organic light emitting layer is formed by ink jet printing, an electron transport layer and an electron injection layer are spin-coated, and preferably, the thickness of the electron transport layer and the electron injection layer is in the range of 60 nm to 175 nm. More preferably, the electron transport layer and the electron injection layer have a thickness in the range of 40 nm to 80 nm. Still more preferably, the electron transport layer and the electron injection layer have a thickness in the range of 20 nm to 40 nm. And after the electron transmission layer and the electron injection layer are formed, evaporating a metal cathode layer, adhering a glass packaging sheet with epoxy resin, and curing to obtain the organic light-emitting diode display device.
Referring to fig. 2, fig. 2 is a graph showing the relationship between the film thickness and the volume of the organic light-emitting layer formed by inkjet printing according to the embodiment of the present invention. Ink jet printing of an organic mixture of soluble organic molecules and a blank solvent can form an organic light-emitting layer having a thickness in the range of 0.1 nm to 175 nm. Ink-jet printing of solutions containing only soluble organic molecules can only form organic light-emitting layers with thicknesses in the range of 60 nm to 175 nm. Obviously, an ink containing a mixture of soluble organic molecules and a solvent blank can produce an organic light-emitting layer having a wider thickness range, compared to an ink containing only soluble organic molecules which can produce an organic light-emitting layer having a narrower thickness range.
The embodiment of the invention prepares the organic light emitting diode display device by an inkjet printing technology of mixing soluble organic molecules and a blank solvent, simultaneously reduces the number of used ink boxes, can also effectively control the process of drying and film forming, and achieves that each layer in the organic light emitting diode display device has a wider range of thickness.
While the invention has been described in conjunction with specific embodiments thereof, it is to be understood that many alternatives, modifications, and variations will be apparent to those skilled in the art. Accordingly, it is intended to embrace all such alternatives, modifications, and variations that fall within the scope of the included claims.

Claims (10)

1. An ink jet print cartridge for use in making an organic light emitting display device, comprising:
a first print cartridge;
a second print cartridge;
a first control switch; and
a second control switch;
wherein the first print cartridge carries a soluble organic molecule solution and the second print cartridge carries a blank solvent; the first control switch controls the first printing box, and when the amount of the soluble organic molecular solution reaches a first preset value, the first control switch closes the first printing box; and the second control switch controls the second printing box, and when the blank solvent reaches a second preset value, the second control switch closes the second printing box.
2. The inkjet print cartridge of claim 1, wherein the first print cartridge includes a first sub-cartridge, a second sub-cartridge, and a third sub-cartridge, the first sub-cartridge carrying a red light emitting organic molecular solution, the second sub-cartridge carrying a green organic molecular solution, and the third sub-cartridge carrying a blue organic molecular solution.
3. The inkjet print cartridge of claim 1, wherein the hole injection layer, the hole transport layer, the organic light emitting layer, the electron transport layer, and the electron injection layer are formed by the inkjet print cartridge to a thickness in a range from 0.1 nanometers to 175 nanometers.
4. The inkjet print cartridge of claim 1, wherein the first preset value is between 0.1 and 45 picoliters.
5. The inkjet print cartridge of claim 1, wherein the second preset value is between 0.1 and 45 picoliters.
6. A method of making an organic light emitting diode display device using the inkjet print cartridge of claim 1, comprising:
providing a substrate;
forming an anode layer;
spin coating a hole injection layer;
spin coating a hole transport layer;
forming an organic light-emitting layer by ink-jet printing;
spin coating an electron transport layer;
spin coating an electron injection layer; and
forming a cathode layer.
7. The method of claim 6, wherein the hole injection layer, the hole transport layer, the organic light emitting layer, the electron transport layer, and the electron injection layer have a thickness in a range from 0.1 nm to 175 nm.
8. The method according to claim 6, wherein the hole injection layer, the hole transport layer, the organic light emitting layer, the electron transport layer, and the electron injection layer have a thickness in a range of 60 nm to 175 nm.
9. The method of claim 6, wherein the hole injection layer, the hole transport layer, the organic light emitting layer, the electron transport layer, and the electron injection layer have a thickness in a range from 20 nm to 40 nm.
10. The method of claim 6, wherein the hole injection layer, the hole transport layer, the organic light emitting layer, the electron transport layer, and the electron injection layer have a thickness in a range from 40 nm to 80 nm.
CN201911349699.1A 2019-12-24 2019-12-24 Ink jet print cartridge and method for preparing organic light emitting diode display device Active CN111106240B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112428700A (en) * 2020-11-11 2021-03-02 大连理工大学 Integrated ink-jet printing manufacturing device and method for flexible bendable OLED screen

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JP2003142261A (en) * 2001-11-02 2003-05-16 Tdk Corp Manufacturing method of organic el display element, and organic el display element
JP2009064642A (en) * 2007-09-05 2009-03-26 Sharp Corp Manufacturing method of organic electroluminescent display device, and manufacturing apparatus
CN107623076A (en) * 2017-09-29 2018-01-23 深圳市华星光电半导体显示技术有限公司 Whole soln OLED and preparation method thereof
CN108447998A (en) * 2018-03-19 2018-08-24 京东方科技集团股份有限公司 Quantum dot light emitting device and preparation method, quantum dot light emitting display device
CN110112327A (en) * 2019-04-08 2019-08-09 深圳市华星光电半导体显示技术有限公司 Organic light emitting diode display and its manufacturing method
CN110311050A (en) * 2019-07-22 2019-10-08 深圳市华星光电半导体显示技术有限公司 A kind of organic LED display device and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003142261A (en) * 2001-11-02 2003-05-16 Tdk Corp Manufacturing method of organic el display element, and organic el display element
JP2009064642A (en) * 2007-09-05 2009-03-26 Sharp Corp Manufacturing method of organic electroluminescent display device, and manufacturing apparatus
CN107623076A (en) * 2017-09-29 2018-01-23 深圳市华星光电半导体显示技术有限公司 Whole soln OLED and preparation method thereof
CN108447998A (en) * 2018-03-19 2018-08-24 京东方科技集团股份有限公司 Quantum dot light emitting device and preparation method, quantum dot light emitting display device
CN110112327A (en) * 2019-04-08 2019-08-09 深圳市华星光电半导体显示技术有限公司 Organic light emitting diode display and its manufacturing method
CN110311050A (en) * 2019-07-22 2019-10-08 深圳市华星光电半导体显示技术有限公司 A kind of organic LED display device and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112428700A (en) * 2020-11-11 2021-03-02 大连理工大学 Integrated ink-jet printing manufacturing device and method for flexible bendable OLED screen

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