CN111075415A - Low-energy-consumption zero-carbon-emission recovery and carbon circulation method for fossil energy - Google Patents

Abstract

The invention discloses a low-energy-consumption zero-carbon-emission recovery and carbon circulation method for fossil energy, which takes a natural system under strata of an oil field, a coal mine, a gas reservoir and the like as a chemical reaction system, low-value organic matters are fermented by composite indigenous microorganisms of the fossil energy, the obtained fermentation liquor, the composite indigenous microorganisms liquid, ultra-clean absorption liquid of the composite indigenous microorganisms of combustion tail gas passing through the fossil energy in the microbial electrosynthesis atmosphere, and/or carbon dioxide of other sources are continuously injected into the chemical reaction system by the absorption liquid of the indigenous composite microorganisms, free electrons e are introduced into the chemical reaction system, and meanwhile, artificial mass transfer is carried out through all well networks communicated with the oil/ore/gas reservoir, such as a production well, a water injection well, a gas injection well and the like, and natural energy elastic oil-displacement and gas recovery are mainly carried out. The invention is applicable to all oil, gas reservoirs and underground coal mines that are being mined, are already mined out, and have not yet been explored.

Description

Low-energy-consumption zero-carbon-emission recovery and carbon circulation method for fossil energy

Technical Field

The invention belongs to the technical field of fossil energy exploitation, and particularly relates to a low-energy-consumption zero-carbon-emission harvesting and carbon circulation method for fossil energy.

Technical Field

The content of carbon dioxide in the atmosphere is increased from 2.80 x 10 < -4 > (volume fraction, the same below) before world war II to 4.53 x 10 < -4 > (screening for U.S. data of 8 months in 2019), currently, scientific workers in various countries obtain certain achievements (mainly separation, fixation and/or sequestration) in the field of preventing the comprehensive utilization of carbon dioxide by the atmospheric greenhouse effect, but because carbon emission reduction is a negative effect on economic growth, the current global economic situation is not good enough, and various countries face choices for survival and development, so that the carbon emission reduction achievements of the scientific workers are not implemented on a large scale.

The carbon dioxide in the atmosphere is also rapidly increased (15 years to 19 years, from 3.56 multiplied by 10 < -4 > to 4.53 multiplied by 10 < -4 >) and the annual increase of the carbon dioxide in the atmosphere reaches 6.8 percent), and China has achieved 12 percent of major results of carbon emission reduction in 18 years (the data of 18 years is screened).

Under natural conditions, carbon dioxide in the atmosphere is mainly separated and converted through photosynthesis and chemothermy of plants, autotrophic microorganisms and the like in ecological environments such as land, rivers, lakes, marshes, oceans and the like.

The current carbon sequestration and carbon conversion work by utilizing amphibian plants is already in practice at the national level. The supplement and resource of the microorganism to the carbon dioxide are still in the bud.

The practice of the inventor shows that the carbon dioxide-converting microorganisms (releasing biocatalysts) can convert carbon dioxide into organic carbon under mild conditions (i.e. facultative, and/or facultative anaerobic, and/or anaerobic free electron-rich e and trace element-rich biosynthesis conditions), such as methane, methanol, ethanol, acetic acid, propionic acid and subsequent carbonate acrylate. The heavy oil adsorption device can adsorb a large amount of carbon dioxide, and simultaneously methanol, ethanol and carbonic acid acrylate are effective solvents of wax, asphalt and the like, so that the steric hindrance of the heavy oil is obviously reduced, the mass transfer process of biochemical reaction is facilitated, a good atmosphere is created for the conversion of heavy oil into light oil, the principle is also the microbiological principle of carbon dioxide oil displacement during crude oil extraction, the positive effect of carbon dioxide on crude oil extraction is realized, and simultaneously, huge benefits can be created, so that the artificial power for carbon emission reduction is more sufficient.

Formation of crude oil and coal with participation of microorganisms and/or component conversion process needs a large amount of free electrons e, carbon dioxide is an electron acceptor, resource needs to obtain free electrons e, and from which do the free electrons e come? To the inventors' knowledge, it is possible that both internal and external factors of mineral oil deposits: 1, is derived from the action of microorganisms on organic matters to form an electron donor, such as a large amount of free electrons e released when yeast is proliferated; 2, galvanic reactions generated by metal deposits with different reactivities, such as copper-zinc galvanic cells; 3, forming a natural fuel cell (or a microbial fuel cell) under the working condition of being rich in organic matters, catalysts and electrolytes; 4, electrons generated by decay of the associated radioactive reservoir; the outside of the oil/mineral/gas reservoir is also provided with 5. the static electricity formed by positive and negative ions generated by wind power friction is conducted to the oil/mineral/gas reservoir through the grounding action; lightning is led into the oil/ore/gas reservoir through grounding; 7, the autobiography and/or revolution of more than one celestial body cuts magnetic lines of force to generate an electric field; artificially emitted electromagnetic waves generate an electric field, 9 and/or an electric field generated by unknown reasons and the like, but external factors of the ore/oil/gas reservoir are greatly weakened due to the blocking and/or wave absorbing effects of ore layers such as iron, manganese, tungsten and the like between the earth surface and an oil/ore/gas reservoir, so that the resource utilization of carbon dioxide is realized by utilizing the natural conditions of the ore reservoir, electrons e are introduced into the oil/ore/gas reservoir by virtue of fluid which is led into the ore/oil reservoir by an oil well or a mine or a gas well, and are one of the root causes of slow biochemical reaction progress of crude oil, coal and/or natural gas under natural conditions, furthermore, the basic principle of determining the types and the quantity of microorganisms according to nutrients is inferred due to geological structures (such as poor water permeability, local trace element loss and the like), and/or the living environment of the microorganism is changed due to the crustal movement (stratum fracture and the like), so that the mass transfer process is hindered, namely, the nutrition cannot be fully contacted with the microorganism, the adaptation process is needed when the temperature is changed sharply, the condition for forming the target microorganism is lost is also one of the reasons, thirdly, the service life of the microorganism is generally short, the corpse of the microorganism is not completely decomposed by the corresponding microorganism, namely, an ecological system for mutually nourishing is not formed.

According to incomplete statistics of International Energy Agency (IEA), the total electricity generation amount in 2018 is more than 26 trillion degrees in the world, wherein 17 trillion degrees in thermal power generation are calculated according to 785 g of 1-degree electrical carbon emission, the carbon emission caused by global thermal power generation is at least 13.345 trillion kilograms, wherein 49794.7 trillion degrees in thermal power generation in China are 3.909 trillion kilograms in carbon emission caused by thermal power generation.

According to the chemical formula CH₄+2O₂＝CO₂+2H₂O, if carbon dioxide is recycled (converted to methane under anaerobic conditions) to methane, there are 1.421 trillion kilograms of methane, and about 1.985 trillion standard of natural gas (0.7174 kilograms per standard of natural gas).

In fact, in China, in addition to the heavy industries of thermal power, the output and the capacity of industries such as steel, glass, ceramics, cement, refining, coking, fossil energy mining (coal mines and oil fields) and the like are all in the front of the world, and the industries burn a large amount of fuel to generate a large amount of carbon dioxide.

According to the calculation of latest statistical data issued by China, the carbon emission of China in 2018 reaches 100 million tons, namely 10 trillion kilograms (for example, the carbon emission is converted into methane with 5.069 trillion standard square by resource), so that the carbon dioxide emitted by heavy industry except for thermal power in China is inferred to be 4-5 trillion kilograms.

Zhou cai, jin xing, jia cheng zao, Zhao wen zhi and so on, in the project of '973': 2014CB239000 conventional-unconventional natural gas theory, techniques and prospects are thus discussed: the world energy is converted from solid (wood and coal) and liquid (petroleum) to gas, the low carbonization of fossil energy, the large-scale new energy and the intelligentization of energy systems are becoming new trends of energy industry development, the energy application after 2010 is called as the fourth human scientific and technological revolution, the research on exploration, mining, storage, use and the like is fully carried out, the development prospect of China is predicted, and the mechanism of action of microorganisms in the formation of fossil energy and/or the mechanism of deep excavation of microorganism dynamics are not published in the huge academic contribution of Taidou-level old generations.

CN201810930180.1 an apparatus and method for producing methane by electric fermentation, described in the background of the university of agriculture and forestry of fujian: at present, the organic solid wastes such as livestock and poultry manure, domestic garbage, municipal sludge, agricultural and forestry wastes and the like generated in China each year exceed 50 hundred million tons, wherein the livestock and poultry manure is about 38 hundred million tons, the domestic garbage is about 4 hundred million tons, and the agricultural and forestry wastes are about 12 hundred million tons. The biomass energy-saving and energy-saving fertilizer is a great environmental pollution source, is a huge biomass resource and energy bank, has the energy value about 10 hundred million tons of standard coal, and has the fertilizer value (N, P, K and organic matters) exceeding the annual production of chemical fertilizers in China. The organic waste resource is the key of the two contradictions of environmental pollution and resource shortage.

The carbon dioxide emission reduction task in China is very difficult, carbon emission reduction is a challenge and opportunity, and in the sense of intelligence, pollutants are resources misplaced.

The inventor uses a biochemical method in: the method realizes zero carbon emission in medium-low concentration sewage treatment, medium-high concentration waste liquid, (kitchen squeezed liquid, antibiotic hypha, human and animal excrement, slaughter garbage percolate and the like), circulating water and boiler sewage treatment, black and odorous water body treatment, garbage landfill ecological restoration and polluted soil ecological restoration, and finds out a method for recycling carbon dioxide in tail gas of combustion equipment from theory and practice.

CN 201910378552.9A method for culturing targeted microorganisms and application thereof, inventors utilize lignite accompanying bacteria, crude oil accompanying bacteria and combustible ice accompanying bacteria to respectively culture, mix according to the mass ratio of active substances of 1:1:1, culture under aerobic conditions to obtain facultative aerobes, and obtain facultative anaerobes under facultative aerobes, wherein the number of viable bacteria in the obtained bacterial liquid reaches 50-100 hundred million/ml. When the method is applied, the facultative aerobes and the facultative anaerobes are inoculated into a target water body according to the ratio of 1: 1.

For medium-low concentration sewage, the composite archaea mother strain is inoculated to each process of an A/O system according to a certain proportion, the recycling of the original source (carbon dioxide generated in the system) and the external source (carbon dioxide in flue gas absorption liquid of combustion equipment or facilities) carbon dioxide is realized under the comprehensive action of the biochemical treasures and the microbial fuel cell electrode, a large amount of carbon sources are saved, and the atmosphere of the biochemical system after the biochemical treasures technology is modified is as follows: the method comprises the steps of electrically synthesizing an environment by microorganisms containing a large amount of free electrons in water, enabling the microorganisms to show high activity and quickly improve biomass under the participation of electric stimulation and a plurality of trace elements, eliminating the inhibition of charge accumulation on biochemical reaction and the potential difference of oxidation reduction by the existence of a microbial fuel cell electrode, intelligently controlling the dissolving concentration of trace mixed rare earth elements (controlling the dissolving and precipitating amounts by biochemical precious current), accelerating the biochemical reaction process, and leading carbon dioxide (including endogenous carbon dioxide generated by a system and/or exogenous carbon dioxide brought by absorption liquid of tail gas of combustion equipment) in facultative oxygen atmosphere to be resourced into fatty alcohol/acid, such as methanol, so as to improve the B/C ratio of industrial sewage, and simultaneously leading the carbon dioxide to be captured by photosynthetic bacteria to form high-grade biomolecules, such as microalgae, so as to generate a large amount of oxygen, gas: the water ratio is reduced to 0.8-1 from 10-15 (the oxygen supply power is saved by more than 90% compared with the traditional method), fish and insects with larger shapes are also found, a biochemical system forms a stable ecological system, meanwhile, biochemical excess sludge is resourced into nutrition of multi-level target microorganisms, the unbalanced cost for adjusting nutrient elements is effectively reduced, finally, water-soluble organic matters are finally utilized (the water is discharged to reach the standard), inorganic salt is filtered out of the system by a centrifugal filter in the form of sandstone (water scale), and the emission reduction of the biochemical excess sludge is more than 90%.

An A/C system (short for anaerobic methane-generating system) is mostly adopted for medium-high concentration sewage, the compound archaea is inoculated, under the comprehensive action of a biochemical device, the atmosphere of the biochemical system is a microbial electrosynthesis environment containing a large amount of free electrons in water, meanwhile, under the participation of electric stimulation and a plurality of trace elements, microorganisms show high activity and rapidly increase biomass, the recycling of carbon dioxide of a source (carbon dioxide generated in the system) and an external source (carbon dioxide in external combustion equipment or facility flue gas) is realized under the comprehensive action of the biochemical device, the starting and the stable operation can be realized within one month, then, the methane hardly contains carbon dioxide, ammonia nitrogen and hydrogen sulfide, the methane content reaches more than 80 percent, the methane yield is increased by more than one time, the biogas residues are not required to be discharged, the complete recycling is realized, and the cost for adjusting the unbalanced nutrition elements in a large amount is saved, finally, the effluent reaches the standard, and ammonia nitrogen and hydrogen sulfide in the marsh gas are almost zero, so that the working procedures of desulfurization and deamination are omitted. (the start-up of the traditional anaerobic biogas production system needs about 6 months to operate stably, the cost of inoculating granular sludge is very high, the discharge amount of biogas residues is huge, more than 1 ton of biogas residues are discharged according to the conventional COD, the content of carbon dioxide in the biogas is about 50 percent, the content of hydrogen sulfide and ammonia gas in the biogas is very high, and the COD of effluent is higher)

In the treatment of black and odorous water, the compound archaea stock plant is inoculated into silted river mud, the bio-chemical device is operated to ensure that the water state is a microbial electrosynthesis environment containing a large amount of free electrons, meanwhile, under the participation of electrical stimulation and a plurality of trace elements, the microorganisms show high activity, the biomass is rapidly improved, exogenous carbon dioxide is added (the archaea stock plant is compounded by desulfurization and denitrification waste liquid of combustion equipment), the addition of the exogenous carbon dioxide enables the carbon dioxide in the water to rapidly reach and maintain a saturated dissolved state, a large amount of microalgae is bred in only 10 days to release a large amount of oxygen, the black and odorous state is rapidly disappeared, organic matters in the river bottom mud are rapidly mineralized, the compound archaea enters a dormant state due to the loss of nutrition and/or is swallowed by introduced aquatic animals, the microalgae can naturally reach a certain quantity range, and the ecological restoration is completed, the black and odorous water body repaired by the method has very strong self-cleaning function and generally can not form a black and odorous state again.

(note: the Biochemical apparatus itself has a self-cleaning mechanism to effectively remove the scale formed on the electrode, and also can be used to assist in cleaning the scale during manual maintenance to maintain the function of the apparatus, and CN 201810930180.1A device and method for producing methane by electric fermentation, which cannot achieve the benefit of implementation in the industrial system due to the scale formation problem of the electrode.)

The technical scheme is that the energy field and the electrical stimulation are built under the environments of a biochemical system, a black and odorous water body, polluted soil, a garbage landfill and the like by utilizing the voltage mutagenesis of the composite archaea stock strain which is very easy to adapt to different pollutants and different environments and utilizing biochemical equipment to microorganisms and by utilizing the principle of a communicating vessel and the conductive property of an electrolyte aqueous solution, and the high-activity multilayer targeting ecological system in which the microorganisms exist can recycle the original source and exogenous carbon dioxide, and has positive significance in the aspects of zero carbon emission, environment restoration and the like of sewage.

However, when "CN 201910378552.9 a method for culturing bacteria by targeting microorganisms and its application" is implemented in heavy industries such as steel, glass, ceramics, cement, refining, coking, fossil energy mining (coal mine, oil field), and carbon emission households, a great problem is encountered: although 1, the perfect absorption of waste gas can be realized by utilizing the existing dust removal, desulfurization and denitration facilities, the emission standard is welcomed by owners, and the cost performance is high enough; but 2, if the absorbed carbon dioxide is resourced into methane, a huge biochemical reaction system needs to be built; 3, a large amount of low-value organic matters (the organic solid wastes exceed 50 hundred million tons per year, and/or industrial waste organic matters (most of which are listed in a dangerous waste name list) are needed, which needs to be coordinated and consistent by a plurality of functional departments, and needs to balance the economic interests of each unit and/or individual, so that the organic matters are difficult to obtain, and the quantity gap is large, such as straws of crops, straws, rice chaff, kitchen waste squeezing liquid, domestic waste squeezing liquid, waste gutter oil, waste oil of equipment and facilities (heat conduction oil and lubricating oil), waste organic solvents (methanol and ethanol) of chemical plants, waste oil of oil refineries, waste squeezing liquid of slaughter wastes, human and animal excreta and the like are all disposed by professional companies, and according to the environmental problems caused by the development requirement of the 'principle of who pollutes governance by the existing environmental laws and regulations in China', the national enterprises take the lead to the rush.

In order to realize the carbon emission reduction at the national level, the inventor conducts extensive research, and the current situation of fossil energy exploitation in China is as follows:

the current oil field situation is as follows: compared with the bent area, the oil deposit in China has generally higher content of wax, asphalt and inorganic salt and more viscous inferior crude oil (about 60 percent), which results in that the storage capacity is higher than the production capacity (the current situation is that the recovery ratio is less than 35 percent, such as the earliest Yumen oil field in China has the exploration storage capacity of 1.93 hundred million tons, the 80-year exploitation accumulated production capacity of 3826.5 ten thousand tons and the exploration storage capacity of 20 percent), and the mining cost is high, which causes resource waste, generates a large amount of oil-containing solid waste in the processes of oil exploitation, collection, transportation and storage, and the crude oil content in waste oil mud is generally 5 to 20 percent. The oily solid wastes not only have high flammability, but also present certain biotoxicity due to the existence of benzene, phenol and anthracene substances, and are harmful to surrounding water bodies, soil and environment, the oily solid wastes are classified as dangerous wastes by China, and the collection, transportation, storage and disposal of the oily solid wastes are strictly regulated.

The oil-containing hazardous waste mainly comprises ground oil soil, mining oil sludge, storage tank bottom mud and the like. About 20 million tons or more of oil-containing solid wastes are generated per 1,000 million tons of crude oil. Billions of tons of petroleum are produced in China, the oil-containing micro waste amount is not completely counted to be more than three million tons, and the wax content, the asphalt content, the salt content and the like bring great difficulty to subsequent processing along with the rapid increase of the output proportion of the continuous oil-containing solid waste produced by mining.

The huge demand in China causes that a large amount of crude oil is imported in China, and the total amount of oily waste residues, physicochemical sludge and biochemical sludge generated by three barrels of oil (medium petrochemicals, medium petroleum and medium sea oil) and oil refining (local oil refining enterprises) and the oily sludge in oil fields is more than 3000 ten thousand tons/year, which belong to dangerous waste, have extremely high disposal cost, and the disposal cost reaches more than 300 billion yuan per 1000 yuan/ton.

At present, most oil fields enter the high-cost oil recovery period of tertiary oil recovery.

In an oil field crude oil production system, because crude oil contains relatively more calcium magnesium silicon strontium barium plasma and waxy asphalt, the crude oil can be difficult to remove completely even if being subjected to strong acid washing in the problems of mixed scales and corrosion of an oil extraction high-pressure electric pump, a reinjection water high-pressure electric pump, a crude oil conveying pipeline, a crude oil storage tank and a storage tank circulating pump, the crude oil production system is very troublesome, equipment comprising natural gas and coal bed gas also has a serious scaling problem, and the production cannot be operated continuously and efficiently.

The current coal mine situation is as follows: the reserves of low-rank coal such as lignite bituminous coal in China are rich, but the cost performance of the low-rank coal is not high, and how to recycle the low-rank coal is one of the important tasks of scientific and technological workers in China under the global environmental protection pressure.

The coal bed gas is unconventional natural gas which is self-generated and self-stored in the coal bed, and the resource amount of the coal bed gas with the depth of more than 2000 m buried in China is 36.81 trillions of cubic meters and occupies the third place in the world. The development and utilization of the coal bed gas have the effects of achieving multiple purposes: the gas accident prevention level is improved, and the safety effect is achieved; the greenhouse gas is effectively reduced, and a good environment-friendly effect is generated; as a high-efficiency and clean energy source, the energy source device generates huge economic benefits, makes up the defects of conventional energy sources and improves the energy structure of China to a certain extent.

The extraction rate of the coal bed gas in China is low, the average extraction rate is only 23%, and the extraction rate of the coal bed gas in the main coal producing countries such as the United states, Australia and the like is more than 50%. Therefore, how to improve the yield of the coal bed gas and solve the bottleneck problem of coal bed gas exploitation is the key point of coal bed gas development and research.

At present, two coal bed gas mining modes in China mainly comprise underground pumping coal bed gas and ground well drilling coal bed gas mining. The auxiliary yield increasing measures adopted aiming at the coal bed gas produced by ground well drilling mainly comprise a fracturing technology, a pinnate well drilling technology, a gas injection yield increasing technology and a microbial degradation low-rank coal yield increasing technology.

The coal bed gas fracturing technology and the pinnate well drilling technology can only increase the yield of the coal bed gas in a short period, and cannot fundamentally solve the current development situation that the extraction rate of the coal bed gas is low in China.

Through retrieval of the existing fossil energy harvesting technology, the surface of the fossil energy harvesting technology is completely covered, but the existing technology is more sophisticated due to the fact that the existing technology is carefully pushed and knocked: 1 neither disclose a practical method of electricity usage; 2, the carbon dioxide is used for driving, and the function of microorganisms is not involved, but the carbon dioxide is only used for driving a solvent and gas; 3, the use of microorganisms is to sell microorganisms to earn money, and is not involved in stimulating the system to breed microorganisms naturally; 4, the neglect of nutrition that hydrocarbon is itself nutrition, but the lack of conditions under which microorganisms can utilize it as nutrition (trace elements, rare earth elements, suppression of cadavers of dead microorganisms); 5 there is no clear model for the action of microorganism in the process of fossil energy formation and composition conversion, the catalytic reaction of trace elements, rare earth elements and the like, and the comprehensive inoculation of nature and the like. Such as:

CN201780086275.3 microbial products and their use in bioremediation and removal of paraffins and other pollutants in oil and gas production and processing equipment, track oil IP llc us 2019, month 9 27, chinese bulletin summary: the present invention provides microorganism-based products and their use to effectively remove contaminant compositions such as biofilm, scale, paraffin, and/or asphaltenes from oil production equipment and oil-bearing formations while simultaneously enhancing oil recovery from an oil well. The invention can also be used to disperse paraffin and asphaltene precipitates and reduce the viscosity of heavy crude oils. The invention further provides materials and methods for bioremediating hydrocarbon contaminated sites. Since the yeast is unicellular microorganism and is negatively charged, and a large amount of self-owned electrons e are released in the proliferation process, the application concludes that the method can inhibit and remove the composite scale formed by metal ions and waxy asphalt, and is feasible for improving the production efficiency because of no scale.

The basis for the inference is: the inventor develops a gold paddle oil-water system scale-free device in CN201210311135.0 electric shock/piezoelectric material preparation method and application thereof, when the gold paddle oil-water system scale-free device is used for scale prevention and corrosion prevention of an oil extraction electric pump, a water injection pump, an oil pipeline and a crude oil storage tank in an oil field, wax and asphalt are in a dispersion state, the viscosity of crude oil is reduced by more than 50 percent, the biomass in the crude oil is increased by more than 100 times, and the reason is that: the touch/piezoelectric material generates a large amount of free electrons under the extrusion or friction action and forms a biosynthesis atmosphere, meanwhile, the touch material dissolves rare earth elements and transition metal elements in high-salt crude oil, the conditions activate the activity of the original microorganism, the proliferation rate of the original microorganism reaches exponential times, a large amount of negatively charged microorganisms adsorb metal cations such as calcium, magnesium, strontium, barium, iron, manganese and the like, the salt formation is blocked, even the salt formation is realized, the crystal dispersion cannot grow under the participation of a large amount of free electrons e, so the particles are soft scale (spherical or needle-shaped aragonite state), the particles are used on a biochemical system afterwards, a direct current electric field is additionally arranged, a mechanism for automatically cleaning electrode scale is established, each process of the sewage system is used as a microbial electrosynthesis bacteria culture system, a microbial fuel cell electrode is additionally arranged, the microbial synergy is very obvious, and the inventor discloses CN201510572031.9 auxiliary equipment of the biochemical system and application thereof, furthermore, the method takes the associated bacteria of combustible ice, the associated bacteria of crude oil and the associated bacteria of lignite as mother plants, compounds (the combination comprises the indigenous microorganisms of coal, the indigenous microorganisms of crude oil and the indigenous microorganisms of combustible ice) mixed according to the mass ratio of 1:1:1 active matters can culture and domesticate multi-level targeted microorganisms suitable for various organic matters under the comprehensive action of biochemical treasures, can degrade the targeted microorganisms step by step, and comprises biochemical residual sludge, organic garbage and VOCS containing phosmet, and the practical method for tail gas absorption and biochemical treatment of combustion equipment also comprises industrial garbage such as low-rank coal, wax, asphalt and the like. The inventor also discloses a CN201910378552.9 method for culturing the targeted microorganisms and application thereof.

The deficiencies of this us application:

1, the added nutrients are high-quality carbon sources, cheap carbon dioxide is not considered as the high-quality carbon source, the carbon dioxide can produce high-quality carbon sources such as fatty acid, alcohol and the like under the comprehensive action of the biochemical fertilizer and the action of facultative microorganisms, and the vitamins can be produced by the microorganisms, for example, VB12 which is the most difficult in vitamin biosynthesis can be extracted from biochemical residual sludge discharged from a sewage treatment system, so that the application does not deeply excavate the microbial potential by utilizing the microorganisms and does not consider carbon emission reduction in production. The organic carbon source and the vitamin are continuously added, the organic carbon source and the vitamin are favorable from the commercial perspective, but the fossil energy is a gift for the nature to the human, and the non-renewable perspective, the predation is not considered in the application, the invention is equivalent to eating an excitant for an oil well, namely providing high-quality nutrition for yeast to quickly increase the biomass so as to increase the yield of the yeast, the predation of the human to the natural resource is increased, and the 'natural and natural' technological innovation principle is violated, so that the 'natural change is not needed, but the natural' is needed to be followed by the technological workers;

2, only one aspect of increasing the yield of the crude oil is considered about the addition of the trace elements such as iron, zinc, nickel, manganese, copper, chromium, lead and the like, and heavy metals are not considered to belong to pollutants in the subsequent refining process;

3, regarding the addition of antibiotics, the possibility that microorganisms can induce super bacteria or viruses under the action of the antibiotics is considered, especially in an oil field with abundant nutrition, once the situation is disastrous to the whole human, the microorganisms are not necessarily added with the antibiotics under the implementation condition of the patent, people only imagine that the inhibition of iron bacteria and sulfate reducing bacteria is needed, and the most important attribute of the microorganisms is nutrition competition, so that when the added yeast is enough and active, the inhibition of the iron bacteria and the sulfate reducing bacteria is not possible at all (although the antibiotics are generally applied to the oil field, the huge hidden danger of the side effect of the antibiotics on the ecological environment is mostly ignored);

with respect to the remediation of crude oil contaminated soil, the application is actually only sanitary, belongs to a pollution transfer method, can be cleaned, and is possibly lower in cost than other removal methods, ecological remediation needs to further recycle organic matters, and complete inorganization which cannot be recycled is required, but the application does not provide a further scheme for environmental remediation, so the claim cannot be implemented, and is only conceptual;

5, the experimental test means applied in the oil well production increasing process is complex, the production increasing purpose can be realized only by the attendance of expert personnel, the cost is high, and the cost performance is not high.

CN200910014037.9 method for improving crude oil recovery ratio by using industrial waste water and industrial waste gas, oil extraction process research institute of China petrochemical Living oil field division, abstract: a method for improving the recovery ratio of crude oil by using industrial wastewater and industrial waste gas comprises the steps of injecting the industrial wastewater containing carbohydrate and the industrial waste gas containing carbon dioxide into an oil layer, and carrying out fermentation reaction under the environment of the oil layer to generate metabolites such as biosurfactant, CO2, H2 and the like, wherein the method comprises the following steps: A. pretreating industrial wastewater, removing large particulate matters and adjusting the pH value to 6.0-9.0; B. the ratio of the pretreated industrial wastewater to the activator and the zymocyte liquid is 100000: 10-100: 1-5, the industrial wastewater and the activating agent are injected into the stratum together with the oil well injection water at the discharge capacity of 5-100 m3/h and the industrial waste gas and the oil well injection water at the discharge capacity of 0.5-10 multiplied by 103Nm3/h under the condition that the discharge capacity is lower than the oil layer fracture pressure; C. continuously injecting the mixture and the injected water of the oil well into the stratum together in any proportion for a long time, and carrying out microbial fermentation reaction in the stratum to generate a metabolite which is beneficial to improving the recovery ratio of the crude oil in the stratum. The invention is widely applied to the petroleum development and exploitation process.

This application has the following problems and cannot be implemented:

1, the transportation of industrial sewage, especially chemical sewage, is strictly supervised by functional departments such as environmental protection and the like, so that the transportation cannot be implemented at all;

2, the industrial waste gas has the same limits of laws and regulations, and is difficult to implement;

even if the industrial sewage and the industrial waste gas do not have the limits of laws and regulations, a is analyzed according to the conventional situation, in the application, the treatment cost of the industrial sewage is higher than that of most industrial sewage due to the continuous addition of zymophyte liquid (the addition amount of the zymophyte liquid is 10-50PPm) and an activator (the addition amount of the activator is 100-1,000 PPm); and b, gas transportation also has a serious cost performance problem, and if mixed combustion tail gas is compressed into a liquid state, due to complex components, a plurality of technical problems are not solved at present, so that the method is not suitable for large-scale implementation. Therefore, it is known from "a" and "b" that the application cannot be carried out;

4, the application does not give the method and kind of the zymophyte liquid, which further hinders the application.

CN200980116909.0 method for stimulating biogenic methane production from hydrocarbon-bearing formations, synthetic genome incorporated, inc (usa), abstract: methods of identifying a stimulant for biogenic production of methane in a hydrocarbon-bearing formation are described. The methods include the use of microbial nucleic acid sequence information for determining gene products, i.e., enzymes in various pathways involved in the conversion of hydrocarbons to methane. The enzymes and stimulating agents identified by the methods of the invention can be used in processes for enhancing biogenic methane production, for example, by addition to coal and coal-bed gas wells.

This patent application, which introduces into the coal bed an enzyme for hydrocarbon decomposition and a defined aggregate of microorganisms producing said enzyme identified by the method described in the application, together with said substrate, reactant or cofactor, to facilitate the decomposition of hydrocarbons and the production of methane, does not give a cost effective method of obtaining an enzyme capable of decomposing hydrocarbons to produce methane and a corresponding aggregate of microorganisms producing the enzyme, said substrate, reactant or cofactor, which makes this application impractical or impractical to implement on the scale of hydrocarbon-bearing formations.

What is said in this application in the background with respect to coalbed methane is erroneous, coalbed methane biogenic production being mistakenly interpreted as a result of microbial degradation of coal; the heat source is generated as a result of the thermal cracking of the organic matter or oil, and the principle is unclear, resulting in errors in the direction of research and implementation.

CN 201910378552.9A method for culturing targeted microorganisms and the application thereof describe the generation process of methane, and the following are extracted: the biochemical system auxiliary equipment (gold paddle biochemical treasure) is applied to the mechanism exploration of A/C anaerobic biogas production: the method for treating the medium and high concentration organic pollutants is anaerobic biogas production, and the action process is as follows:

the first step, hydrolysis: that is, water-insoluble carbohydrates, polysaccharides (cell wall-cellulose, cell membrane-chitosan), proteins, fats are dissolved and digested under facultative anaerobic conditions;

secondly, the metabolites (carbohydrate, peptide, higher fatty acid, etc.) in the first step are further degraded by acid-producing microorganisms under the condition of facultative anaerobism to produce lower fatty acid, alcohol, hydrogen and carbon dioxide;

thirdly, acetyl-producing microorganisms which produce acetate by using various organic acids and alcohols;

fourthly, methane production: acetate is directly utilized by methanogens to produce CH4, carbon-containing compounds (methanol, formic acid, methylamine and the like), CO2 and H2, and is utilized by hydrogenophilic methanogens (or acetogenic methanogens) to produce CH 4;

the fifth step, which is essentially simultaneous with the first step, and/or the second step, and/or the third step, and/or the fourth step, produces the corresponding microorganism, but the life span of the microorganism is short and a good ecosystem must be established for a sustained and stable occurrence.

Obviously, increasing the coal bed methane, firstly, enough raw materials for producing the methane, namely the products of the fourth step, are needed, the raw materials are derived from low-rank coal such as lignite, bituminous coal and the like, the volatile matters of the high-rank coal are degraded step by step, associated bacteria of archaea for producing the methane are needed, enzymes are generated by the corresponding associated bacteria, if the raw materials are prepared by artificial fermentation and then added according to the application, the inoculation and the grant of the nature are abandoned, and the obtained value is far less than the input cost; equally important, enough methanogens need to be used for producing methane, the methanogens need to be proliferated in CN201510572031.9, a biochemical system auxiliary device and application thereof, and CN201910378552.9, a method for culturing targeted microorganisms and application thereof, the method disclosed in the two applications is far higher in cost performance than that of the application, the operation is very simple, and expert staff is not needed for watching, so that the operability of the application has a great problem.

CN201180023725.7 in situ electrical stimulation for bioconversion of carbon-containing formations, kris energy limited (usa), abstract: methods for stimulating microbial populations, such as microbial populations comprising methanogens and other bacteria, in a subterranean formation, for producing methane and other fuels or fuel precursors from coal or other carbonaceous materials, and for enhancing the bioconversion of carbonaceous materials, such as coal, to methane and other useful hydrocarbon products, wherein the microbial populations respond to physical or chemical electrical stimulation, are disclosed. This application has the following problems:

firstly, 1, an electrode placed in a stratum loses the function of electrical stimulation due to rapid scaling, so that the electrical stimulation and the input of free electrons e cannot be realized on indigenous or exogenous microorganisms;

2. again, due to the particular structure of the two sides of the cell wall or membrane of the microorganism, which is not responsive to continuous electrical stimulation, generally an intermittently powered dc power source is selected, but the "wherein the delivery of electrical energy is continuous" as claimed in all claims 1-20 fails to teach the most effective way of electrical stimulation.

The application is not feasible as shown by '1' and '2'.

Secondly, the formation environment is a huge biological reaction system, and the operations of adding nutrient elements and trace elements, preparing buffer solution, introducing exogenous microorganisms and the like are only suitable for a small system with excellent mass transfer condition, sufficient reaction and controllable risk in a laboratory scale and are used for mechanism research. As implemented in a extensive stratigraphic environment, but without teaching, and/or demonstrating in the examples, specific implementations have difficulty with many practical problems and are not possible to implement.

Thirdly, the principle of the conversion of carbon dioxide to methane is not understood, and the application wrongly believes that the chemical equation of the conversion of carbon dioxide to methane by microorganisms is as follows: CO2₂+8H++8e-→CH₄+2H₂O。

It is acknowledged that although the form of carbon dioxide is simple, the carbon dioxide is converted into methane, but the life process is very complex, and the conversion is completed under the action of various enzymes (catalysts) and special structures or attributes of microorganisms, and the carbon dioxide cannot generate methane under the participation of acid radical ions and electrons. Two approaches are known in the industry:

a, with sufficient hydrogen and a lower redox potential (-below 400 mv), converts hydrogen and carbon dioxide to methane by the action of hydrogenophilic methanogens, which U.S. applicants neglect the natural difference between H + and H2;

b, when the oxidation-reduction potential is higher (-400-100 mv) and hydrogen is insufficient, methanol is generated under the condition of microbial electrosynthesis, and acetate is formed under the action of acetogenic microorganisms to be utilized by methanogen acetylproducting. This was verified in the anaerobic and facultative systems of the sewage system, see (CN 201910378552.9A method for the cultivation of targeted microorganisms and the anaerobic and hydrolytic acidification systems in the implementation of their applications)

The resource recovery of the oil sludge is explored a lot, the solvent extraction method and the coking method are the most perfect, but the large-scale implementation is not achieved due to the reasons of large investment, high energy consumption, secondary pollution and the like; many microbiological methods are involved, a plurality of microorganisms capable of digesting hydrocarbons and derivatives thereof are found and collected, and a plurality of patents and documents are disclosed, but the progress at home and abroad is mostly in a mechanism research stage, and the research is not implemented on a large scale due to various reasons, but the common points of all microbiological methods are as follows: neglecting the basic fact that the indigenous microorganisms in the oil field are not killed due to the production of crude oil to the ground, and are very easy to adapt to various environments, for example, various microorganisms which can be digested and/or are nutritious by crude oil can be separated from crude oil, crude oil production wells, oil falling to the ground, oil sludge piled in the open air, soil polluted by crude oil, oil separation tanks, flotation tanks and oil storage tanks, and oil-containing sewage biochemical treatment systems of oil extraction and refining enterprises.

The inventor discovers that under the comprehensive action of a biochemical device, when the concentration of microorganisms reaches the concentration level of hundred million/milliliter, organic components and inorganic components of oil sludge can be stripped, the salt content (TDS) of crude oil can be reduced from about 30 ten thousand mg/L to below 5,000mg/L, and inorganic silt containing almost no oil is obtained, so that the biochemical device shows extremely strong cleaning and washing functions and electrolyte adsorption functions of targeted microorganisms, and the utilized principle is as follows: the multiplication of the composite archaea is exponentially multiplied under the appropriate microbial electrosynthesis atmosphere and the environment with various trace elements, and the composite archaea is not required to be continuously added as long as nutrition is provided and the conditions are appropriate.

CN201510664969.3 a method for recovering crude oil from oil-containing hazardous waste by using microorganisms, the university of beijing physiognomy, abstract: the invention relates to a method for recycling ground oil soil/oil sludge/bottom mud by utilizing efficient microorganisms, belonging to the technical field of solid waste recycling treatment. Sieving ground oil soil/oil sludge/bottom mud from oil extraction and oil refining industry to remove fragments, putting the ground oil soil/oil sludge/bottom mud and inorganic salt nutrient solution into a biological mud reactor according to a certain solid-to-liquid ratio, inoculating high-efficiency microbial flora, separating crude oil from a substrate after running for 3-9 days, floating up to the liquid surface under the action of aeration to realize recovery, wherein the recovery rate of the crude oil is 60-90%, and the mass ratio of the residual quantity of dangerous waste crude oil is 0.5-3.0%. According to the invention, the microorganism compound bacteria are utilized to separate and extract the crude oil in the oil-containing hazardous waste, so that the crude oil content in the oil soil/oil sludge/bottom mud is greatly reduced.

The application reduces the oil content of the oil sludge by 60-90%, has certain positive significance, but the front and the back are contradictory: on one hand, the strain source is the indigenous microorganism of oil fields in various regions, but a method for utilizing the indigenous microorganism is not provided, and a large amount of artificially cultured microorganism strains are required to be added, so that the operation cost is high, and the cost performance is reduced during large-scale application; 2, the crude oil microorganisms are recycled and collected only, and the potential of the indigenous microorganisms is not further exploited! Moreover, no feasible collection scheme is given, but the concept is put forward and not implemented in the application; 3, oil contained in sand, garbage and sundries does not provide a proper solution; 4, the subsequent treatment of mud, oily impurities, base substances which have been removed by 60-90% and contain partial crude oil, such as oil sludge, oil soil, oily dirt at the bottom of a storage tank and the like, does not give a proposal, and the treatment is defined as hazardous wastes, and the existence of the hazardous wastes causes incomplete solution, impossible to implement on a large scale and possible increase of the total treatment amount of the hazardous wastes.

CN200980111019.0 low emission power generation and hydrocarbon recovery system and method, exxonmobil, abstract, provides a method and system for low emission power generation in a hydrocarbon recovery process. One system includes an integrated pressure maintenance and miscible drive system for low emission power generation. Alternative systems provide for low emission power generation, carbon separation, Enhanced Oil Recovery (EOR), or carbon dioxide sales using a hot gas expander and an external combustor. Another alternative system provides low emission power generation using a gas power turbine to compress air in an inlet compressor and charge the gas with hot carbon dioxide in an expander. Other efficiencies may be obtained by combining thermal cross-exchange, desalination plants, co-production, and other features.

This patent application relates to a method and apparatus for generating electricity from nitrogen, oxygen, carbon dioxide, hydrocarbon fuels in a low emission hydrocarbon recovery process that is theoretically feasible for the expansion of flue gases for the production of electricity, but which entails a series of problems that must actually occur, such as flue gas cleanup, acid dew point control, generator impeller fouling prevention, dynamic balancing, etc., and does not address the above problems, nor does it address the efforts of directing microorganisms to convert hydrocarbons in mines/reservoirs directly into human-needed and inexpensive-to-produce components, and EOR becomes unnecessary, or lower emission technologies, making the method and apparatus completely unnecessary.

A CN201180066823.9 zero-emission steam generation method, clean energy systems, Inc.; paxoton corporation; the present invention provides a novel method to directly generate steam from untreated water produced simultaneously with thermally recovered crude oil, and to inject the steam and combustion products into a hydrocarbon reservoir to recover hydrocarbons and sequester a portion of the carbon dioxide produced during steam generation. The present invention removes the need for continuous additional water for thermal oil recovery and the need for surface treatment for reuse of produced water, resulting in improved process efficiency, reduced environmental impact and improved economic value. The core is the use of an "oxy-fuel steam generator" as taught in us patent 5,680,764 and 6,170,624, which uses crude oil containing water directly into the "oxy-fuel steam generator" without desalting and degreasing, and the steam produced mixes with the combustion gases, removing all heat transfer surfaces and resulting in higher thermal efficiency than a typical drum boiler or once-through steam generator, since no heat is lost with the flue gas, resulting in zero emissions.

This application does not disclose how to accomplish the hypersalinity, and the condition such as scale deposit, corruption, maintenance and the like in the continuous operation when oily "dirty" water gets into "steam generator", also no water scale discharges in the embodiment, obviously does not have sustainability, and zero release that is not strict: the scale containing oil, salt and heavy metal formed by the evaporation of the dirty water belongs to the category of dangerous waste, and zero emission is only carbon dioxide.

Furthermore, parameters such as the amount of generated steam, temperature and pressure and the like are not disclosed, and whether the requirements of thermal oil recovery can be met is also unknown. There is a problem of availability.

The inventor applies CN201210311135.0 a preparation method of electric shock/piezoelectric material and its application in waste heat power generation boiler with evaporation capacity of 60 ton/h in a steel plant in 7, 9, 2010, under the condition of not adding any medicament and not using electricity, river water is used as boiler water inlet to generate a large amount of free electrons e under the action of friction force when passing through the electric shock material, so that ions such as Ca-Mg-Si-Fe-Mn-Sr-Ba in the water, which are easy to scale, are formed during evaporation concentration, aragonitic soft scale (spherical or needle-shaped) is not attached to a heated surface and is discharged along with boiler sewage discharge, simultaneously, the scale removing and dissolving effects are very obvious, old scale during brine removal is dissolved and dropped, corrosion during medicament application is repaired, a new passivation film is formed, thereby ensuring that the boiler can continuously run, the quality of steam passing through a superheater meets the standard of power inlet steam turbine for power generation in national guide rules, has been in operation for more than 9 years; on a 6 ton/hour evaporation capacity waste heat boiler of a certain glass plant in 11/2/2010, the sewage of circulating water directly enters the boiler through an electric shock material, the effects of descaling, scale dissolving, scale prevention and corrosion prevention are very obvious under the working conditions of no electricity and any medicament, and the boiler is continuously operated for more than 9 years at present.

In order to solve the problem that the electric shock material needs regular maintenance due to scaling, the electric shock material is divided into two groups of electrodes which are communicated with each other by an insulating pipe, a direct current electric field is applied between the two groups of electrodes to form a direct current constant current circuit, the surface of the electric shock material is kept clean by automatically detecting resistance and dielectric breakdown between the two electrode groups, the electrode polarity is automatically switched to further clean the surface of the auxiliary electrode, scale is further removed from a pollution discharge device to eliminate accumulated hidden dangers, and furthermore, a bypass and a partition valve are arranged to facilitate manual maintenance without stopping production at any time so as to ensure the normal development of production.

There is a serious problem in judging the novelty and utility of this us application.

Disclosure of Invention

In order to overcome the defects of the prior art, the invention aims to provide a method for recovering fossil energy with low energy consumption and zero carbon emission and carbon circulation. And only need when the ground temperature is lower in winter, need provide suitable temperature to oil sludge sand when changing waste oil mud into resources, in order to make it totally inorganize, organic matter resource of low value, but not the harsh condition of the oil recovery of heating power, and induce the microorganism of targeting, oil/mineral deposit take gas (methane) to give first place to, light oil is supplementary, reduce the cost of tertiary oil recovery to the cost of primary oil recovery, breed and pass the circulating exploitation, but not the predatory exploitation, the steam generator developed, has really accomplished zero emission: the combustion tail gas and heat energy are recycled, and the oil sand, oil sludge and oil dirt are recycled into building materials or oil/mining area soil remediation.

Furthermore, the invention is a coal mining, oil extraction and gas production zero-carbon emission technology, which takes mined or underground coal mine/oil field/gas reservoir as a huge chemical reaction system, leads or induces the indigenous microorganisms of the underground oil/ore/gas reservoir, 1, provides proper temperature (generally reservoir temperature does not need to be adjusted), 2, mass transfer means such as huff and puff, fracturing, 3, provides indigenous trace elements and rare earth elements, 4, provides microorganism electrosynthesis atmosphere rich in free electrons, 5, induces multilayer target microorganisms for decomposing organic components in wax, asphalt, colloid and low-rank coal, decomposing corpse of the indigenous microorganisms and the like by compounding the indigenous microorganisms, excites the activity of the microorganisms and proliferates biomass under the combined action and the cooperation of the factors, thereby establishing a mutually nutritional ecological system of the indigenous microorganisms of the fossil energy reservoir, the method mainly comprises the steps of producing methane and/or light oil, decomposing wax and asphalt in the heavy oil into light crude oil to facilitate mining, cooperatively or specially treating low-value organic waste, combustion tail gas absorbed by targeted microorganisms, absorption liquid of VOCS and the like, cleaning waste bacteria liquid of oil sand, oil sludge and oil dirt by the targeted microorganisms, injecting the waste bacteria liquid into an oil/ore/gas reservoir, and accordingly completing carbon cycle of fossil energy in China to permanently recover oil and gas and mainly achieve natural elastic flooding gas recovery with low cost.

Furthermore, the method is characterized in that biochemical treasure equipment is additionally arranged in all working procedures of a steam injection well, a production well, a reinjection well, a storage tank, an oil separation tank, a reinjection water treatment system and the like of an oil field/coal mine/gas reservoir, the CN201910378552.9 microbial cultivation method and the application thereof disclosed in the mixed archaea mother strain are added into the oil field/coal mine/gas field, the primary addition amount is the sum of the liquid amount extracted in a single day, a tail gas absorption liquid of a combustion device is added, the absorption liquid is derived from carbon dioxide, nitric oxide, hydrocarbon, carbon monoxide, sulfur dioxide and trace elements contained in flue gas of fossil fuel combustion, nickel, chromium, copper, phosphorus, iron, manganese, lead, alum, arsenic, mercury and all rare earth elements in the rare earth alloy which are selectively adsorbed by targeted microbes in the CN201910378552.9 microbial cultivation method and the application thereof, and the mineral/oil/gas reservoir is introduced, wherein the concentration of microorganisms in the microorganism absorption liquid is not less than 1 hundred million/ml.

Furthermore, waste oil sand in an oil field, waste oil dirt in an evaporator, oil-containing waste kettle residue in a distillation kettle of an oil refining enterprise, tank cleaning oil sludge in an oil-containing three-sludge storage tank, oil dirt serving as a target pollutant, a bacteria culture system for culturing multi-level targeted microorganisms by using biochemical equipment is arranged, crude oil in the oil sludge, the oil sand and the oil dirt is cleaned to the oil content of 0.1-0.3%, the crude oil is used for soil remediation (or sold) on the earth surface of an oil/ore/gas reservoir and is recovered, and then the cultured multi-level targeted microorganisms are injected into the underground ore/oil/gas reservoir through a reinjection well.

Furthermore, a wind power generation device is arranged, the obtained alternating current is converted into direct current, the direct current is rectified and boosted, electrons are directly introduced into an ore/oil/gas reservoir through fluid in a well network, the defect that an electric shock material electrode plate is inconvenient to use infinitely is overcome, dielectric breakdown water scale and polarity periodic conversion can be set through constant current of a power supply controller, the transmission efficiency of the electrons is prevented from being blocked due to well network scaling, and the requirement that carbon dioxide is used as an electron acceptor to synthesize methane, methanol or other aliphatic hydrocarbons or derivatives thereof under the action of microorganisms and a large amount of free electrons is met.

Furthermore, a solar photovoltaic power generation device is arranged, the obtained direct current is boosted, then electrons are introduced into an ore/oil/gas reservoir through fluid in a well network, the defect that an electric shock material electrode plate is inconvenient to use infinitely is overcome, the transmission efficiency of electrons is prevented from being blocked due to well network scaling by setting dielectric breakdown water scale and polarity periodic conversion through constant current of a power supply controller, and a large amount of free electrons needed by synthesizing methane, methanol or other aliphatic hydrocarbons or derivatives thereof under the action of microorganisms by using carbon dioxide as an electron acceptor are met.

Furthermore, an electromagnetic wave receiving device, a lightning receiving device and a grounding network are arranged, and electrons are directly introduced into the mine/oil/gas reservoir together with the static electricity of equipment facilities, so that the defect that an electric shock material electrode plate is not cheap and infinite is overcome, and a large amount of free electrons needed by carbon dioxide serving as an electron acceptor for synthesizing methane, methanol or other aliphatic hydrocarbons or derivatives thereof under the action of microorganisms are met.

To facilitate an understanding of the present invention, it is further noted that:

1. nickel, chromium, copper, calcium, magnesium, iron, manganese, lead, vanadium, arsenic, mercury, strontium, barium and various rare earth elements can form molecular states under the atmosphere rich in electrons e, such as calcium carbonate, barium sulfate and the like, but crystals can not grow large, and the elements have huge specific surface areas, and exist in the form of insoluble nano-scale double salts, and the structure has extremely strong catalytic activity, can form micro-environments and/or catalytic beds of chemical reactions as an implantation material of nutrition and microorganisms, belongs to one of nano application technologies, is similar to the nano structures of natural montmorillonite, attapulgite, sepiolite and the like before stabilization, and the structures enable the amount of the microorganisms in oil/ore/gas reservoirs to be large enough to be possible;

2. the models for the effects of hydrocarbon fuels are: the invention is based on the fact that biochemical reaction, which mainly follows the principle of nature and mainly guides natural force, such as solar photovoltaic power generation, wind power generation, thunder and lightning, universal gravitation and the like, and is assisted by a voltage/electric shock material and a direct current electric field, the original microbes, the original trace elements, the multi-level rare earth elements and the carbon dioxide of fossil fuel are added into an ore/oil reservoir to ensure that the fossil fuel is inhibited under the conditions of relatively good mass transfer and sufficient free electrons under the atmosphere of oil/ore/gas reservoir and under the conditions of normal temperature and normal pressure and huge anoxic atmosphere of oil/ore/gas reservoir (the high-temperature and high-pressure environment of the reservoir reaches the ground), Contacting air, electrical stimulation, heavy metal, radioactivity, etc.) to quickly start a reproduction mechanism, and complete the conversion of carbon dioxide into the required small-molecule clean energy such as methane and methanol under the stratum, thereby realizing the carbon cycle of fossil energy;

3. the inventor deduces that based on the cognition of visible biochemical systems, such as sewage treatment systems (AO and/or AC), fishing ground, aquaculture, black and odorous water body, landfill, marsh, lake and other biochemical systems, the ecological system which is nutrient to each other is difficult to form due to the mass transfer resistance and the limited target species, and the following biological systems are provided: the biochemical system of oil/mineral deposit cannot form ecological systems which are mutually nutritious due to factors such as geological structure and/or crust change, and the cell walls and cell membranes (cellulose, lignin, chitin and the like) of dead microorganisms can accumulate due to short life of the microorganisms, so that the inventor supposes that the colloidal substances and/or the asphaltene precursors in crude oil may be formed.

4. The depth of the oil/mineral reservoir is between 600-5000 meters, the majority is 1300-1500 meters, the corresponding temperature is between 60-150 ℃, and the majority is not more than 100 ℃, the inventor also finds that even under the extreme severe conditions of the oil/mineral/gas reservoir, such as high temperature (more than 100 ℃), high pressure (up to 500MPa), high salinity (up to 30 ten thousand mg/L), relative sealing and other extreme conditions, the indigenous microorganism still exists in the form of dead bacteria, can revive in a certain form after reaching the ground surface and shows extremely high biological activity, the oil/mineral/gas reservoir in China only rarely exceeds 100 ℃, so the temperature and the pressure of the oil reservoir are secondary factors when the oil/mineral/gas reservoir is used as a chemical reaction (including biochemical reaction) system, and the high salinity is beneficial to electronic conduction, artificial mass transfer such as free electron e quantity and throughput, biomass of indigenous microorganisms, trace elements and rare earth catalysts are the most important consideration conditions.

Drawings

The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the invention and together with the description, serve to explain the principles of the invention. It is obvious that the drawings in the following description are only some embodiments of the invention, and that for a person skilled in the art, other drawings can be derived from them without inventive effort.

FIG. 1 is a schematic general view of the process of the present invention.

FIG. 2 is a schematic diagram of a process flow for achieving zero emission of oil extraction and oil refining by fermenting oil-containing waste and tail gas VOCS with composite indigenous microorganisms, washing and absorbing.

FIG. 3 is a schematic view of a process flow for converting exogenous (outside petrochemical system) low-value organic matter into indigenous microorganisms by using composite indigenous microorganisms.

Fig. 4 is a schematic flow chart of a heat source and a zero-emission steam generator for recycling low-value organic matters by using composite indigenous microorganisms and controlling the temperature of an oil/ore/gas reservoir.

Fig. 5 is a schematic diagram of the arrangement and installation of mass transfer throughput of the oil/ore/gas reservoir and the biochemical equipment acting on the oil/ore/gas reservoir well pattern.

FIG. 6 is a reservoir reduced pressure isobgram.

Detailed Description

The present invention will be further described with reference to the following specific examples.

The low-energy-consumption zero-carbon-emission harvesting and carbon circulating method of fossil energy is characterized in that: taking a natural system under stratum such as an oil field, a coal mine, a gas reservoir and the like as a chemical reaction system, fermenting low-value organic matters by using composite indigenous microorganisms of fossil energy, continuously injecting obtained fermentation liquor, composite indigenous microorganism liquor, ultra-clean absorption liquid of combustion tail gas passing through the composite indigenous microorganisms of the fossil energy under the microbial electrosynthesis atmosphere and/or absorption liquid of carbon dioxide from other sources by the indigenous composite microorganisms into the chemical reaction system, introducing free electrons e as much as possible into the chemical reaction system, simultaneously carrying out artificial mass transfer (huff and puff) through all well nets communicated with the oil/ore/gas reservoir such as a production well, a water injection well, a gas injection well and the like, mainly inoculating, only elastically driving a small amount of natural energy to recover oil and gas, mainly recovering gas, simultaneously recovering oil and gas after one year, but mainly recovering gas from a self-injection well, in no special case is the result of human predation.

CN 201910378552.9A method for culturing targeted microorganisms in combustion exhaust gas generated by combustion of fossil energy, biomass and other fuels and application thereof, when carbon dioxide, nitrogen oxide, hydrocarbon, carbon monoxide, sulfur dioxide selectively adsorbed by targeted microorganisms and trace elements contained in flue gas generated by combustion of fossil fuels, nickel, chromium, copper, phosphorus, iron, manganese, lead, vanadium, arsenic, mercury and all rare earth elements in rare earth alloy are introduced into a mineral/oil/gas reservoir, wherein the concentration of microorganisms in a microorganism absorption liquid is not less than 1 hundred million/ml, and the implementation method is as follows in consideration of large area and difficult mass transfer of oil fields/gas fields/coal mines and the like: and (3) injecting the oil/ore/gas reservoir by multiple wells every day, and fully utilizing all channels of the oil well, the reinjection well, the steam injection well and the like.

The low-value organic matters are divided into two types and the resource utilization method comprises the following steps: one type is low-value organic matters in a petrochemical system, specifically one or two or more of oily wastes generated by a crude oil exploitation, transportation, storage and oil refining chemical plant, VOCS (volatile organic Compounds), carbonitriding sulfur and nitrogen containing tail gas generated by a deep processing product, oily scale generated by a steam generator, waste engine oil generated by equipment, waste lubricating oil, waste heat conduction oil, oily waste kettle residues, oil sludge of a three-sludge storage tank generated by a refining sewage treatment system and the like, CN201910378552.9 a method for culturing targeted microorganisms and application thereof are implemented, under the comprehensive action of biochemical equipment, the targeted microorganisms are cultured by fermenting composite indigenous microorganisms of fossil energy in a microbial electrosynthesis atmosphere, the targeted microorganisms are cultured, the targeted pollutants are waxiness, asphaltene and colloid, the index of the targeted microorganisms is multiplied, the oily wastes are washed to be free of oil by targeted bacteria liquid and are used as soil for greening the ground surface of a mining area, recovering oil, injecting waste bacteria liquid into ore/oil/gas reservoir to increase biomass and nutrition and convert crude oil into light oil;

the other type is described in the background, and at present, the method for recycling organic solid wastes such as livestock and poultry manure, domestic garbage, municipal sludge, agricultural and forestry wastes and the like generated every year in China comprises the following steps: the CN201910378552.9 method for culturing the targeted microbes and the application thereof are implemented, the composite archaea inoculated with petrochemical energy is used for resourcing the targeted microbes into microbial nutrition of an oil/ore/gas reservoir under the comprehensive action of biochemicals, the biomass is increased, target pollutants are lignin, cellulose and cell walls and cell membranes of animals and plants, the asphaltene and colloid in crude oil are hopefully decomposed into light crude oil, humus in low-rank coal and volatile matters in high-rank coal are decomposed into precursors of methane, and fermentation liquor is injected into the oil/ore/gas reservoir.

The way to introduce the electron e into the oil/ore/gas reservoir is:

the biochemical equipment loads a direct current electric field on the passing fluid, and because the electrolyte in the fluid is a conductor, the current can be led into the chemical reaction system (oil/ore/gas reservoir system), meanwhile, under the working condition of being rich in electron e, trace rare earth elements, trace transition metal elements, carbon, nitrogen, sulfur, phosphorus and other nutrients, the indigenous microorganisms from the reservoir can be instantly activated, so that the index of the indigenous microorganisms is multiplied, under the working condition, the wax, the asphaltene and the colloid are in a dispersed state, so that mixed dirt can not be formed to block an oil throat, a tubular pile, a shaft, a filter, a flowmeter and a storage tank, even if the temperature is changed to 70 ℃ to 25 ℃ for example, wax precipitation scaling and corrosion can not occur, the metal corrosion is oxygen corrosion which is a process of losing electrons, therefore, the coating has good anti-corrosion effect, and simultaneously, carbon dioxide cannot overflow, so that the coating is a zero-carbon emission process;

arranging a wind power generation device, converting mechanical energy into electric energy, converting Alternating Current (AC) into Direct Current (DC) through a power controller, boosting the voltage to 300-600V, transmitting electrons into the chemical reaction system (oil/mine/gas reservoir system) through fluid of a well network in a constant-current mode, and periodically converting the polarity of a power supply input into the well network so as to prevent the well network from scaling;

arranging a solar photovoltaic power generation device, converting light energy into electric energy, boosting the electric energy to 300-600V through a power controller, transmitting electrons into the chemical reaction system (oil/ore/gas reservoir system) through fluid of a well network in a constant-current mode, and periodically converting the polarity of a power supply input into the well network to prevent the well network from scaling;

arranging electromagnetic waves, a lightning receiving device and a grounding grid, and directly introducing electrons into the chemical reaction system (oil/mine/gas reservoir system) together with equipment and facility static electricity;

to ensure that electrons can be smoothly introduced into the chemical reaction system, the fluid in the well should be kept in a full state.

The temperature for fermenting low-value organic oily waste in a petrochemical system and cleaning with a targeted microbial liquid is 30-40 ℃, preferably 35 ℃, the larger garbage, stones and other garbage are cleaned to be oilless by bacterial liquid and then used as building materials, the silt is cleaned to be oilless and then used as soil for surface greening, and the oil/ore/gas reservoir on the seabed is used as island-making soil;

the temperature for inoculating the low-value organic matters outside the petrochemical system with the fossil energy compound archaea for fermentation is controlled to be more than 16 ℃, preferably 25-35 ℃, and the fermented organic matters with the thickness of less than 1mm, such as slaughter waste residues, bagasse, husks, crop straws, kitchen squeezing residues, fruit and vegetable squeezing residues and pig, horse, cattle and sheep excrement residues, can be directly injected into the chemical reaction system (an oil/ore/gas storage system) without complete dissolution when the biomass is detected to be more than 10 hundred million/g.

The zero-emission steam generator is characterized in that: the method has the advantages of zero wastewater discharge, zero waste heat discharge and zero combustion tail gas discharge, wherein the indissolvable inorganic salt contained in the blowdown of the steam generator and the steam separator is an extremely rare nano-grade material which can be used as a carrier of microorganisms, has extremely strong adsorption function and catalytic reaction activity and is very beneficial to a biochemical reaction system, and the carbon dioxide in the steam separator can be directly resourced into methanol in the multi-level targeted microorganism culture system.

The water inlet of the steam generator is well water and/or water contained in produced liquid and/or seawater, the water enters the steam generator through a two-stage oil-water system scale-free device (a scale-free device for short) which is connected in series, the two-stage scale-free device is connected by an insulating pipe, electrolyte contained in the water is used as a conductor, a complete direct current loop is formed by a power controller, a main circuit of the power controller is an H bridge circuit, Alternating Current (AC)220V input and Direct Current (DC)20-800V output are adjustable, resistance between the two scale-free devices is automatically monitored by a resistance sensor, when the resistance of the water between the two stages is increased to more than 20%, the power controller automatically releases pulse high voltage, water scale is subjected to dielectric breakdown, then the resistance between the two stages which are positive and negative returns to the normal value to the original constant current operation, the operation is repeated, and a periodic polarity interchange program of the two electrodes is also set, and a bypass and a valve are arranged, so that the online manual maintenance can be carried out at any time, the surface of a medium-voltage/electric shock material of the scale-free device is ensured to be clean, and a blowdown device is arranged at the bottom of the outlet end of each scale-free device to regularly remove sandstone scale;

the fuel of the steam generator is methane or crude oil, the combustion improver is oxygen and/or air, the generated steam and combustion tail gas are mixed in a steam separator, and finally the pollution discharge of the scale-free device, the pollution discharge of the steam generator, the pollution discharge of the steam separator and the steam and carbon dioxide generated by the steam generator are used as heat sources of the chemical reaction system, and/or heat sources for low-value organic matter fermentation, and/or other applications, such as heating, power generation and the like.

The method is suitable for all gas fields, oil fields and underground coal mines, and can be understood as that the conditions of the invention are anoxic, underground, relatively closed spaces with certain temperature, including those being exploited, which have not been exploited by the ascertained reserves, especially for those already exploited, and the exploitation means that the cost of one investment can be greatly reduced by the existing well patterns, auxiliary facilities and skilled industrial personnel. Also comprises carbon dioxide gas field, such as Yingge sea carbon dioxide gas field, which is ascertained in 2009 in China, with storage capacity of 545 hundred million m³The distribution area is 324 square kilometers, the reservoir depth is 1200-1600 meters, and the method is implemented according to the same method, the amount of the indigenous microorganisms needing petrochemical energy mixing is increased a little, the low-value organic matters are more, the number of the electrons needing to be introduced is more, and the incubation time is longer, but the 'low-value organic matters needing more' which always coexist with the challenges and opportunities means that more organic wastes can be consumed, and the method can make greater contribution to the country and is close to the development of economyThe bead triangles with a large population have the advantage of low-cost marine water transportation cost compared with the long triangles, and the method can be expected to become an inexhaustible natural gas field and light oil field after the inoculation of the warble sea carbon dioxide gas field, and the harvesting cost is extremely low, so that the warble sea carbon dioxide gas field becomes a 'Jinshan Yinshan';

the artificial mass transfer comprises well pattern arrangement, is uniform in mass transfer, and is preferably area well arrangement: the liquid injection well and the oil/gas well are arranged in the whole development area in equal area for liquid injection and huff and puff according to certain geometric shape and density, an oil and gas layer pressure conversion isobaric diagram is drawn (the drawing method is the same as the oil layer static pressure isobaric diagram), the chemical reaction system, local and/or integral production and injection allocation scheme can be scientifically drawn, and the self-injection well oil extraction and gas production with low energy cost is mainly pressurized by manual liquid injection, gas injection and system gas production (carbon dioxide is converted into methane, kerogen is decomposed into micromolecular hydrocarbon gas, humic acid of low-rank coal, and/or volatile of high-rank coal is generated into methane and the like).

The fossil energy composite archaea is disclosed in 'CN 201910378552.9 a method for culturing targeted microorganisms and application thereof', and the method comprises the steps of respectively culturing associated bacteria of lignite, associated bacteria of crude oil and associated bacteria of combustible ice, compounding the obtained active substances according to the mass ratio of 1:1:1, culturing under aerobic condition to obtain facultative aerobic bacteria, culturing under facultative condition to obtain facultative anaerobic bacteria, and culturing under facultative aerobic condition according to the facultative aerobic bacteria: the facultative anaerobe is inoculated to a biochemical system in a ratio of 1:1, the number of viable bacteria of the golden paddle microorganism containing compound archaea in each milliliter of bacterial liquid is 50-100 hundred million, and the inoculation is only needed once without continuous addition;

the biochemical precious equipment is the biochemical system auxiliary equipment disclosed in 'CN 201510572031.9A Biochemical System auxiliary equipment and application thereof', and the gold paddle board biochemical precious equipment applied in the invention;

the oil-water system scale-free device in the zero-emission steam generator is developed based on a preparation method and application of an electric shock/piezoelectric material CN201210311135.0, and the invention is applied to the gold-paddle oil-water system scale-free device; the power controller recited in claim 7 is a golden paddle power controller disclosed in "CN 201510572031.9 a biochemical system auxiliary device and its applications", and similarly, the power controllers for wind power generation and solar photovoltaic power generation all have 7 output modes, all have constant current output modes, and have a function of dielectric breakdown of scale and a function of periodic exchange of electrode polarity.

The screening used in the fermentation process of the low-value organic matters mainly aims at culturing multi-level target microorganisms by a zoogloea formed by the target microorganisms but cannot pass through a 80-100-mesh screen under low pressure, the principle is not explained in the 'CN 201910378552.9 method for culturing the target microorganisms and the application thereof', and the screen is a centrifugal filter which is a gold paddle centrifugal filter.

Example 1

Yumen oil field status quo: yumen oil field has developed 7 oil fields, which are: laojun temple, petroleum ditch, duck gorge, poplar river, single north, west and wine east, the geological reserves are found to be 1.93 million tons, the oil production is 3826.5 million tons accumulated in 80 years, and the reserves are not found to be 20 percent), that is, at least 80 percent of the reserves are not extracted in the reservoir, the liquid production is 160 million tons every year in 2015, the water injection is 200 million tons every year, the crude oil is 46 million tons every year, the average daily oil production of a single well is 0.86 tons, and the annual loss is hundreds of millions of yuan. The implementation of the invention starts from the Laojun temple oil field, and extends to other six oil fields after obtaining obvious benefits.

Geological conditions are as follows: in a spring basin, mainly a layered sandstone reservoir, the permeability is low and medium, the temperature of the oil field reservoir of the Laojun temple is 30 ℃, the temperature of the existing oil well is 1062, the mouth of a reinjection well is 393, the oil reservoir area is 134 square kilometers of oil, the total liquid yield is 3188 tons/day, the waste oil sludge is about 25 tons/day, the carbon dioxide discharge capacity of an oil field power plant is not lower than 881.78 tons/day (320 tons of methane can be obtained by resource utilization, namely 451616 square methane/day, 11.68 ten thousand tons of methane can be produced in the year) (785 g of carbon dioxide/degree electricity is discharged according to 4.1 hundred million DEG per year)

The implementation scheme is as follows:

the gold paddle oil-water system scale-free device developed by utilizing the preparation method and the application of the 201210311135.0-based electric shock/piezoelectric material is provided with a steam generator, and aims to provide waste oil silt, waste oil in an oil separation tank, waste oil sludge in a storage tank, and three mud in a refinery sewage treatment system, the waste oil silt in the storage tank, oil scale, oil-containing waste kettle residue in a distillation kettle, waste engine oil, waste lubricating oil, waste heat conducting oil and other low-value oil-containing hazardous wastes for resource treatment. The device is positioned close to a gas production well and a reinjection well so as to directly inject the flue gas and the flue gas absorption liquid into a reservoir stratum and directly recycle water and carbon dioxide in the flue gas, and a water source is oil field well water (the water source can directly enter the steam generator without any softening and desalting treatment);

secondly, recycling carbon dioxide generated by the power plant: when the CN201910378552.9 method for culturing the targeted microorganisms and the application thereof are implemented, carbon dioxide, nitrogen oxides, hydrocarbons, carbon monoxide, sulfur dioxide selectively adsorbed by the targeted microorganisms, trace elements contained in flue gas generated by burning fossil fuel, nickel, chromium, copper, phosphorus, iron, manganese, lead, vanadium, arsenic, mercury and all rare earth elements in the rare earth alloy are introduced into an ore/oil/gas reservoir, wherein the concentration of the microorganisms in the microorganism absorption liquid is not lower than 1 hundred million/ml, and the implementation method is implemented by considering that the area of an oil field is large and mass transfer is difficult: and (3) injecting the oil from multiple wells every day, and fully utilizing all channels between the oil wells, the reinjection wells, the steam injection wells and the like and the oil reservoir.

Establishing a targeted microorganism culture system according to the CN201910378552.9 targeted microorganism culture method and the application thereof, wherein the targeted pollutants (low-value organic matters or called nutrients) are as follows: the most easily obtained three-mud of a refinery, waste oil and mud sand of a storage tank, oil dirt, oil-containing waste kettle residue, waste heat conduction oil, waste engine oil, waste lubricating oil, waste oil and mud sand of an oil field, waste oil and mud dirt of a steam generator and the like are cleaned by high-concentration targeted microbial liquid until the oil content is 0.1-0.3 percent, then the silt without oil is used for ecological restoration of the surface of the oil field, the oil is recovered, and the waste bacterial liquid is injected into the oil reservoir;

fourthly, establishing a low-value organic matter culture system according to the CN201910378552.9 targeted microorganism culture method and the application thereof, wherein the target pollutants are as follows: the method comprises the following steps of (1) directly injecting municipal waste leachate, kitchen squeezed liquid, organic waste residues of the kitchen squeezed liquid, crop straw fermented leachate, fruit and vegetable waste fermentation liquor and other low-value organic matters into an oil reservoir;

fifthly, directly injecting VOCS absorption liquid absorbed by the targeted microorganisms into an oil reservoir in a refinery and/or other chemical plants according to CN201910378552.9 a targeted microorganism culture method and application thereof;

sixthly, converting the electric energy generated by wind power and solar photovoltaic into direct current (with highest efficiency) by a golden paddle biochemical power supply controller, preventing the contact point between the oil well wall and the introduced oil reservoir from influencing the electron conduction efficiency due to scaling, providing electric stimulation and simultaneously providing free electrons e for the injected carbon dioxide;

well grounding an oil field grounding net, an equipment shielding net and a well net, and leading electric energy generated by various modes such as thunder, static electricity and electromagnetic waves into an oil reservoir (although the efficiency is not high, the cost is low, the potential is excavated);

eighthly, installing biochemicals in all production wells, reinjection wells and gas injection wells, injecting 3188 tons of compound archaea stock strain liquid once (the daily liquid yield is 3188 tons and only one time of introduction is needed), then huffing and huffing for 45 days, wherein the huffing and puff benefits not only the mass transfer effect but also the activation effect of the indigenous microorganisms.

The implementation effect is as follows: 1, the present embodiment allows the following conditions to be achieved for the reservoir: under the working condition of existence of high-concentration indigenous microorganisms and a large amount of free electrons e, not only can composite scales formed by colloid, wax, asphaltene and inorganic salt be dissolved, the difficult problem of blockage of a pipe pile, an oil throat, an oil reservoir, a storage tank, an oil pipeline and a high-pressure pump be solved, but also the separation and blockage removal of oil and fine sand mud are realized, the produced oil of the self-blowing well hardly contains sand, colloid and asphaltene, and the problem of secondary scaling blockage is thoroughly solved in principle; 2, targeted microorganisms decompose wax, colloid and asphaltene, so that the quality of the crude oil is developed to light weight and low salinization; 3, the carbon dioxide is recycled by generating methane, methanol and the like under the action of anaerobic, free electron-rich and targeted microorganisms, and the yield can be increased by 3.3 million yuan/year only by recycling the carbon dioxide in an oil field, and the yield can be estimated to be more than 1000 million tons of carbon dioxide in 7 oil fields of Yumen oil fields (note: the natural gas contains little carbon dioxide and hydrogen sulfide and little nitrogen), the yield can be expected to be more than 100 million yuan when the methane is recycled by 364 million tons/year, and 200 million dollars can be obtained in carbon trading (the international carbon trading is 20 dollars/ton carbon dioxide accounting). The expected yield is far higher than the yield of oil production!

The method can be popularized to other 6 oil fields of Yumen oil field, other oil fields, gas reservoirs and underground coal mines.

Claims (10)

1. The low-energy-consumption zero-carbon-emission harvesting and carbon circulating method of fossil energy is characterized in that: taking a natural system under stratum such as an oil field, a coal mine, a gas reservoir and the like as a chemical reaction system, fermenting low-value organic matters by using composite indigenous microorganisms of fossil energy, continuously injecting obtained fermentation liquor, composite indigenous microorganism liquor, ultra-clean absorption liquid of combustion tail gas passing through the composite indigenous microorganisms of the fossil energy under the microbial electrosynthesis atmosphere and/or absorption liquid of carbon dioxide from other sources by the indigenous composite microorganisms into the chemical reaction system, introducing free electrons e as much as possible into the chemical reaction system, simultaneously carrying out artificial mass transfer (huff and puff) through all well nets communicated with the oil/ore/gas reservoir such as a production well, a water injection well, a gas injection well and the like, mainly inoculating, only elastically driving a small amount of natural energy to recover oil and gas, mainly recovering gas, simultaneously recovering oil and gas after one year, but mainly recovering gas from a self-injection well, in no special case is the result of human predation.

2. The low-energy zero-carbon-emission recovery and carbon-recycling method of fossil energy according to claim 1, characterized by: CN 201910378552.9A method for culturing targeted microorganisms in combustion exhaust gas generated by combustion of fossil energy, biomass and other fuels and application thereof, when carbon dioxide, nitrogen oxide, hydrocarbon, carbon monoxide, sulfur dioxide selectively adsorbed by targeted microorganisms and trace elements contained in flue gas generated by combustion of fossil fuels, nickel, chromium, copper, phosphorus, iron, manganese, lead, vanadium, arsenic, mercury and all rare earth elements in rare earth alloy are introduced into a mineral/oil/gas reservoir, wherein the concentration of microorganisms in a microorganism absorption liquid is not less than 1 hundred million/ml, and the implementation method is as follows in consideration of large area and difficult mass transfer of oil fields/gas fields/coal mines and the like: and (3) injecting the oil/ore/gas reservoir by multiple wells every day, and fully utilizing all channels of the oil well, the reinjection well, the steam injection well and the like.

3. The low-energy zero-carbon-emission recovery and carbon-recycling method of fossil energy according to claim 1, characterized by: the low-value organic matters are divided into two types and the resource utilization method comprises the following steps: one type is low-value organic matters in a petrochemical system, specifically one or two or more of oily wastes generated by a crude oil exploitation, transportation, storage and oil refining chemical plant, VOCS (volatile organic Compounds), carbonitriding sulfur and nitrogen containing tail gas generated by a deep processing product, oily scale generated by a steam generator, waste engine oil generated by equipment, waste lubricating oil, waste heat conduction oil, oily waste kettle residues, oil sludge of a three-sludge storage tank generated by a refining sewage treatment system and the like, CN201910378552.9 a method for culturing targeted microorganisms and application thereof are implemented, under the comprehensive action of biochemical equipment, the targeted microorganisms are cultured by fermenting composite indigenous microorganisms of fossil energy in a microbial electrosynthesis atmosphere, the targeted microorganisms are cultured, the targeted pollutants are waxiness, asphaltene and colloid, the index of the targeted microorganisms is multiplied, the oily wastes are washed to be free of oil by targeted bacteria liquid and are used as soil for greening the ground surface of a mining area, recovering oil, injecting waste bacteria liquid into ore/oil/gas reservoir to increase biomass and nutrition and convert crude oil into light oil;

the other type is described in the background, and at present, the method for recycling organic solid wastes such as livestock and poultry manure, domestic garbage, municipal sludge, agricultural and forestry wastes and the like generated every year in China comprises the following steps: the CN201910378552.9 method for culturing the targeted microbes and the application thereof are implemented, the composite archaea inoculated with petrochemical energy is used for resourcing the targeted microbes into microbial nutrition of an oil/ore/gas reservoir under the comprehensive action of biochemicals, the biomass is increased, target pollutants are lignin, cellulose and cell walls and cell membranes of animals and plants, the asphaltene and colloid in crude oil are hopefully decomposed into light crude oil, humus in low-rank coal and volatile matters in high-rank coal are decomposed into precursors of methane, and fermentation liquor is injected into the oil/ore/gas reservoir.

4. The low-energy zero-carbon-emission recovery and carbon-recycling method of fossil energy according to claim 1, characterized by: the way to introduce the electron e into the oil/ore/gas reservoir is:

the biochemical equipment loads a direct current electric field on the passing fluid, and because the electrolyte in the fluid is a conductor, the current can be led into the chemical reaction system (oil/ore/gas reservoir system), meanwhile, under the working condition of being rich in electron e, trace rare earth elements, trace transition metal elements, carbon, nitrogen, sulfur, phosphorus and other nutrients, the indigenous microorganisms from the reservoir can be instantly activated, so that the index of the indigenous microorganisms is multiplied, under the working condition, the wax, the asphaltene and the colloid are in a dispersed state, so that mixed dirt can not be formed to block an oil throat, a tubular pile, a shaft, a filter, a flowmeter and a storage tank, even if the temperature is changed to 70 ℃ to 25 ℃ for example, wax precipitation scaling and corrosion can not occur, the metal corrosion is oxygen corrosion which is a process of losing electrons, therefore, the coating has good anti-corrosion effect, and simultaneously, carbon dioxide cannot overflow, so that the coating is a zero-carbon emission process;

arranging a wind power generation device, converting mechanical energy into electric energy, converting Alternating Current (AC) into Direct Current (DC) through a power controller, boosting the voltage to 300-600V, transmitting electrons into the chemical reaction system (oil/mine/gas reservoir system) through fluid of a well network in a constant-current mode, and periodically converting the polarity of a power supply input into the well network so as to prevent the well network from scaling;

arranging a solar photovoltaic power generation device, converting light energy into electric energy, boosting the electric energy to 300-600V through a power controller, transmitting electrons into the chemical reaction system (oil/ore/gas reservoir system) through fluid of a well network in a constant-current mode, and periodically converting the polarity of a power supply input into the well network to prevent the well network from scaling;

electromagnetic waves, lightning receiving devices and grounding nets are arranged, and electrons are directly led into the chemical reaction system (oil/mine/gas reservoir system) together with equipment and facilities static electricity.

5. The low-energy zero-carbon-emission recovery and carbon-recycling method of fossil energy according to claim 1, characterized by: to ensure that electrons can be smoothly introduced into the chemical reaction system, the fluid in the well should be kept in a full state.

6. The low-energy zero-carbon-emission recovery and carbon-recycling method of fossil energy according to claim 1, characterized by: the temperature for fermenting low-value organic oily waste in a petrochemical system and cleaning with a targeted microbial liquid is 30-40 ℃, preferably 35 ℃, the larger garbage, stones and other garbage are cleaned to be oilless by bacterial liquid and then used as building materials, the silt is cleaned to be oilless and then used as soil for surface greening, and the oil/ore/gas reservoir on the seabed is used as island-making soil;

the temperature for inoculating the low-value organic matters outside the petrochemical system with the fossil energy compound archaea for fermentation is controlled to be more than 16 ℃, preferably 25-35 ℃, and the fermented organic matters with the thickness of less than 1mm, such as slaughter waste residues, bagasse, husks, crop straws, kitchen squeezing residues, fruit and vegetable squeezing residues and pig, horse, cattle and sheep excrement residues, can be directly injected into the chemical reaction system (an oil/ore/gas storage system) without complete dissolution when the biomass is detected to be more than 10 hundred million/g.

7. The low-energy zero-carbon-emission recovery and carbon-recycling method of fossil energy according to claim 1, characterized by: the zero-emission steam generator is characterized in that: the method has the advantages of zero wastewater discharge, zero waste heat discharge and zero combustion tail gas discharge, wherein the indissolvable inorganic salt contained in the blowdown of the steam generator and the steam separator is an extremely rare nano-grade material which can be used as a carrier of microorganisms, has extremely strong adsorption function and catalytic reaction activity and is very beneficial to a biochemical reaction system, and the carbon dioxide in the steam separator can be directly resourced into methanol in the multi-level targeted microorganism culture system.

The water inlet of the steam generator is well water and/or water contained in produced liquid and/or seawater, the water enters the steam generator through a two-stage oil-water system scale-free device (a scale-free device for short) which is connected in series, the two-stage scale-free device is connected by an insulating pipe, electrolyte contained in the water is used as a conductor, a complete direct current loop is formed by a power controller, a main circuit of the power controller is an H bridge circuit, Alternating Current (AC)220V input and Direct Current (DC)20-800V output are adjustable, resistance between the two scale-free devices is automatically monitored by a resistance sensor, when the resistance of the water between the two stages is increased to more than 20%, the power controller automatically releases pulse high voltage, water scale is subjected to dielectric breakdown, then the resistance between the two stages which are positive and negative returns to the normal value to the original constant current operation, the operation is repeated, and a periodic polarity interchange program of the two electrodes is also set, and a bypass and a valve are arranged, so that the online manual maintenance can be carried out at any time, the surface of a medium-voltage/electric shock material of the scale-free device is ensured to be clean, and a blowdown device is arranged at the bottom of the outlet end of each scale-free device to regularly remove sandstone scale;

the fuel of the steam generator is methane or crude oil, the combustion improver is oxygen and/or air, the generated steam and combustion tail gas are mixed in a steam separator, and finally the pollution discharge of the scale-free device, the pollution discharge of the steam generator, the pollution discharge of the steam separator and the steam and carbon dioxide generated by the steam generator are used as heat sources of the chemical reaction system, and/or heat sources for low-value organic matter fermentation, and/or other applications, such as heating, power generation and the like.

8. The low-energy zero-carbon-emission recovery and carbon-recycling method of fossil energy according to claim 1, characterized by: the method is suitable for all gas fields, oil fields and underground coal mines, and can be understood as that the conditions of the invention are anoxic, underground, relatively closed spaces with certain temperature, including those being exploited, which have not been exploited by the ascertained reserves, especially for those already exploited, and the exploitation means that the cost of one investment can be greatly reduced by the existing well patterns, auxiliary facilities and skilled industrial personnel. Also included are carbon dioxide gas fields, e.g.The carbon dioxide gas field of the origanum sea, which is explored in 2009 in China, has the reserve of 545 hundred million meters³The distribution area is 324 square kilometers, the reservoir depth is 1200-1600 meters, and the method is implemented according to the same method, the amount of the fossil energy mixed indigenous microorganisms is increased a little, the low-value organic matters are more, the number of the electrons to be introduced is more, and the incubation time is longer, but the low-value organic matters which always coexist with the opportunity are challenged to be more, so that more organic wastes can be consumed, the country can be greatly contributed, the offshore low-cost water transportation cost advantage is provided by approaching to a large number of bead triangles of economically developed population and the long triangle, and the method is expected to become an inexhaustible natural gas field and a light oil field after the inoculation of the Yinghai carbon dioxide gas field, and the recovery cost is extremely low, so that the Yinshan mountain can be really formed.

9. The low-energy zero-carbon-emission recovery and carbon-recycling method of fossil energy according to claim 1, characterized by: the artificial mass transfer comprises well pattern arrangement, is uniform in mass transfer, and is preferably area well arrangement: the liquid injection well and the oil/gas well are arranged in the whole development area in equal area for liquid injection and huff and puff according to certain geometric shape and density, an oil and gas layer pressure conversion isobaric diagram is drawn (the drawing method is the same as the oil layer static pressure isobaric diagram), the chemical reaction system, local and/or integral production and injection allocation scheme can be scientifically drawn, and the self-injection well oil extraction and gas production with low energy cost is mainly pressurized by manual liquid injection, gas injection and system gas production (carbon dioxide is converted into methane, kerogen is decomposed into micromolecular hydrocarbon gas, humic acid of low-rank coal, and/or volatile of high-rank coal is generated into methane and the like).

10. The low-energy zero-carbon-emission recovery and carbon-recycling method of fossil energy according to claim 1, characterized by: the fossil energy composite archaea is disclosed in 'CN 201910378552.9 a method for culturing targeted microorganisms and application thereof', and the method comprises the steps of respectively culturing associated bacteria of lignite, associated bacteria of crude oil and associated bacteria of combustible ice, compounding the obtained active substances according to the mass ratio of 1:1:1, culturing under aerobic condition to obtain facultative aerobic bacteria, culturing under facultative condition to obtain facultative anaerobic bacteria, and culturing under facultative aerobic condition according to the facultative aerobic bacteria: the facultative anaerobe is inoculated to a biochemical system in a ratio of 1:1, the number of viable bacteria of the golden paddle microorganism containing compound archaea in each milliliter of bacterial liquid is 50-100 hundred million, and the inoculation is only needed once without continuous addition;

the biochemical precious equipment is the biochemical system auxiliary equipment disclosed in 'CN 201510572031.9A Biochemical System auxiliary equipment and application thereof', and the gold paddle board biochemical precious equipment applied in the invention;

the oil-water system scale-free device in the zero-emission steam generator is developed based on a preparation method and application of an electric shock/piezoelectric material CN201210311135.0, and the invention is applied to the gold-paddle oil-water system scale-free device; the power controller recited in claim 7 is a golden paddle power controller disclosed in "CN 201510572031.9 a biochemical system auxiliary device and its applications", and similarly, the power controllers for wind power generation and solar photovoltaic power generation all have 7 output modes, all have constant current output modes, and have a function of dielectric breakdown of scale and a function of periodic exchange of electrode polarity.

The screening used in the fermentation process of the low-value organic matters mainly aims at culturing multi-level target microorganisms by a zoogloea formed by the target microorganisms but cannot pass through a 80-100-mesh screen under low pressure, the principle is not explained in the 'CN 201910378552.9 method for culturing the target microorganisms and the application thereof', and the screen is a centrifugal filter which is a gold paddle centrifugal filter.

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