CN111068487A - Waste gas purification device and method for baking line of rubber shock pad - Google Patents

Waste gas purification device and method for baking line of rubber shock pad Download PDF

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CN111068487A
CN111068487A CN202010052781.4A CN202010052781A CN111068487A CN 111068487 A CN111068487 A CN 111068487A CN 202010052781 A CN202010052781 A CN 202010052781A CN 111068487 A CN111068487 A CN 111068487A
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waste gas
gas purification
odor
washing
purification device
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李云飞
周永毅
覃瑞卿
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Liaoning Zike Environmental Protection Technology Co Ltd
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Liaoning Zike Environmental Protection Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
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    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • B01D53/323Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 by electrostatic effects or by high-voltage electric fields
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/485Sulfur compounds containing only one sulfur compound other than sulfur oxides or hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
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    • B01D53/46Removing components of defined structure
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    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
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    • B01D2257/306Organic sulfur compounds, e.g. mercaptans
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01D2257/00Components to be removed
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    • B01D2257/702Hydrocarbons
    • B01D2257/7027Aromatic hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/90Odorous compounds not provided for in groups B01D2257/00 - B01D2257/708
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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Abstract

The invention discloses a waste gas purification device of a rubber shock pad baking line, wherein an alkali liquor washing device, an integrated device, a gas distribution device and an odor controller are sequentially communicated through connecting pipes, the inside of the integrated device comprises a low-temperature plasma structure, a composite photocatalytic structure and an active carbon adsorption structure, waste gas is washed by the alkali liquor washing device and is dehydrated in the washing process, the dehydrated waste gas enters the low-temperature plasma structure to eliminate gaseous pollutants, then enters the composite photocatalytic structure to decompose organic matters, the active carbon adsorption structure adsorbs undegradable components in the waste gas, and then the waste gas enters the gas distribution device and the odor controller to be deodorized, above-mentioned rubber shock pad toasts line exhaust gas purification device has diversity, variability, and the exhaust gas purification effect that pollutant concentration is high and handle characteristics such as the amount of wind is big better, and exhaust gas monitoring concentration is less than environmental protection emission standard far away. The invention also relates to a waste gas purification method of the rubber shock pad baking line.

Description

Waste gas purification device and method for baking line of rubber shock pad
Technical Field
The invention relates to waste gas purification, in particular to a waste gas purification device for a rubber shock pad baking line.
Background
The waste gas pollution factors of the rubber shock pad baking line are oil smoke, industrial oil, benzene, toluene, xylene, non-methane total alkane, stink and other pollutants. The generated waste gas has high temperature, large pollution, large discharge amount and complex and variable pollution components, particularly, the foul components in the waste gas easily cause great pollution to the surrounding environment and the plant area environment, and the phenomenon of disturbing residents is difficult to avoid.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide the waste gas purification device for the baking line of the rubber shock pad, which can aim at the characteristics of diversity, variability, high pollution concentration, large air handling capacity and the like of waste gas.
In order to overcome the defects of the prior art, the invention also aims to provide a method for purifying the waste gas of the baking line of the rubber shock pad, which can aim at the characteristics of diversity, variability, high pollution concentration, large air handling capacity and the like of the waste gas.
One of the purposes of the invention is realized by adopting the following technical scheme:
the utility model provides a rubber shock pad toasts line exhaust gas purification device, includes a plurality of connecting pipes, alkali lye washing device, integration equipment, cloth gas device and peculiar smell controller, alkali lye washing device integration equipment cloth gas device reaches the peculiar smell controller communicates through the connecting pipe in proper order, inside low temperature plasma structure, compound photocatalysis structure, the active carbon adsorption structure of including of integration equipment, waste gas warp alkali lye washing device washing and dewatering at the washing in-process, the waste gas after the dewatering gets into gaseous pollutant is eliminated to low temperature plasma structure, later gets into compound photocatalysis structure decomposes the organic matter, the active carbon adsorption structure adsorbs the composition of unable degradation in with waste gas, later waste gas gets into cloth gas device reaches peculiar smell controller deodorization.
Further, the alkali liquor washing device comprises a cross-flow washing tank, a packed bed arranged in the cross-flow washing tank, a spraying structure arranged at the top of the packed bed and a circulating water tank, wherein in the cross-flow washing tank, waste gas horizontally passes through one or more packed beds to be purified, the packed bed is cleaned from the top, cleaning liquid is sprayed on the top of the packed bed and flows into the circulating water tank after flowing through the packed bed, and the cleaning liquid is NaOH solution or lime water.
Furthermore, the low-temperature plasma structure comprises a molecular exciter, waste gas passes through the low-temperature plasma excitation area and generates high-energy electrons under the acceleration action of an electric field, and when the average energy of the electrons exceeds the molecular chemical bond energy of a target treatment substance, the molecular bonds are broken, so that the aim of eliminating gaseous pollutants is fulfilled.
Further, the composite photocatalytic structure comprises a pretreatment section, the pretreatment section comprises a plurality of modularized composite fibers, and the composite fibers adsorb harmful chemical gases in waste gases.
Further, the composite photocatalytic structure also comprises a composite photocatalytic section, the composite photocatalytic section comprises a high-energy ultraviolet lamp, and waste gas is irradiated by a high-energy ultraviolet lamp beam to decompose organic matters.
Further, the ultraviolet wavelength of the high-energy ultraviolet lamp is 182nm, 254nm or 365 nm.
Further, the activated carbon adsorption structure includes packed activated carbon that adsorbs undegradable components in the exhaust gas.
Further, the gas distribution device distributes gas to the peculiar smell controller, the peculiar smell controller comprises a deodorization diaphragm, deodorization particles are uniformly distributed on the surface of the deodorization diaphragm, deodorization microparticles can rapidly and actively capture odor gas molecules in the air and wrap the odor particles to generate non-covalent combination, and sedimentation is generated due to the increase of specific gravity after combination.
Further, the waste gas purification device of the rubber shock pad baking line further comprises a medium-low pressure centrifugal fan and a chimney, and the waste gas deodorized by the peculiar smell controller flows into the chimney through the medium-low pressure centrifugal fan to be discharged.
The second purpose of the invention is realized by adopting the following technical scheme:
a waste gas purification method for a rubber shock pad baking line comprises the following steps:
washing with alkali liquor: collecting and conveying the waste gas to a multi-stage cross-flow washing tank, wherein in the cross-flow washing tank, the gas is purified after horizontally passing through one or more packing beds, the packing is cleaned from the top, cleaning liquid is sprayed on the top of the packing, the cleaning liquid flows through the packing and enters a circulating water tank, NaOH solution or lime water is added into the circulating water tank, and substances such as NH3, H2S, thiol and fatty acid which is difficult to decompose are removed;
and (3) dehydration treatment: when the gas with mist rises through the spraying washing layer at a certain speed, the mist collides with the chemical washing layer and is attached to the surface of the chemical washing layer due to the inertia effect of rising mist, and the liquid drops are separated from the chemical washing layer and fall down until the gathered liquid drops are large enough that the gravity generated by the liquid drops exceeds the resultant force of the rising force of the gas and the surface tension of the liquid;
low-temperature plasma decomposition: the waste gas firstly passes through a low-temperature plasma excitation area, high-energy electrons are generated under the acceleration action of an electric field, and when the average energy of the electrons exceeds the molecular chemical bond energy of a target treatment substance, the molecular bonds are broken to decompose gaseous pollutants;
performing composite photocatalysis: decomposing organic matters in the waste gas under the irradiation of a lamp of a high-energy ultraviolet lamp beam;
activated carbon adsorption: the active carbon absorbs the undegradable components in the waste gas;
gas distribution and deodorization: deodorizing particles are uniformly distributed on the surface of the deodorizing membrane, deodorizing microparticles can quickly and actively capture odorous gas molecules in the air, the odorous particles are wrapped to generate non-covalent bonding, and sedimentation is generated due to the increase of specific gravity after bonding;
discharging: the height of the flue is increased by more than 15 meters through a chimney for discharging.
Compared with the prior art, the waste gas purification device for the rubber shock pad baking line has the characteristics of waste gas diversity, variability, high pollution concentration, large air volume for treatment and the like, and a treatment process is selected in a targeted manner so as to ensure that the waste gas can be discharged after passing through the device.
1. The waste gas purification device of the rubber shock pad baking line is convenient to install and small in occupied area on site;
2. the operation process of the waste gas purification device of the rubber shock pad baking line is safe, stable and reliable, and the operation and the maintenance are convenient;
3. the multiple treatment processes are combined into integrated equipment, and the borne waste gas concentration and component load are large;
4. the targeted selection treatment process for the components of the waste gas can better control the operation and maintenance cost of the system;
5. the equipment is made of stainless steel, so that the appearance and the service life of the system are guaranteed to the maximum extent;
6. the tail end of the waste gas treatment system is designed with a dry neutralization method (industrial deodorization membrane), which not only ensures the cost index of the discharged waste gas, but also can effectively control the odor concentration of the discharge outlet.
Drawings
FIG. 1 is a perspective view of a waste gas purification device of a baking line of a rubber cushion according to the present invention;
FIG. 2 is a flow chart of the waste gas purification method of the rubber cushion baking line of the present invention.
In the figure: 10. an alkali liquor washing device; 20. an integration device; 30. a gas distribution device; 40. a odor controller; 50. a medium-low pressure centrifugal fan; 60. and (4) a chimney.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It will be understood that when an element is referred to as being "secured to" another element, it can be directly on the other element or intervening elements may also be present, secured by intervening elements. When a component is referred to as being "connected" to another component, it can be directly connected to the other component or intervening components may also be present. When an element is referred to as being "disposed on" another element, it can be directly disposed on the other element or intervening elements may also be present. The terms "vertical," "horizontal," "left," "right," and the like as used herein are for illustrative purposes only.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
Referring to fig. 1 to 2, the waste gas purifying apparatus for a rubber shock pad baking line of the present invention includes an alkali washing device 10, an integrated device 20, a gas distribution device 30, an odor controller 40, a middle and low pressure centrifugal fan 50, a chimney 60, and a plurality of connecting pipes. The alkali liquor washing device 10, the integrated equipment 20, the gas distribution device 30, the odor controller 40, the medium-low pressure centrifugal fan 50 and the chimney 60 are sequentially communicated through a plurality of connecting pipes.
The lye washing apparatus 10 comprises a multistage cross-flow wash tank in which the gas is purified after passing horizontally through one or more packed beds. The filler is cleaned from the top, and the cleaning liquid is sprayed on the top of the filler and flows into the circulating water tank after flowing through the filler. Adding NaOH solution or lime water into circulating water tank to remove NH3、H2S, thiol compounds, and hardly decomposable fatty acids.
When NaOH solution is used as a detergent, hydrogen sulfide and ammonia gas have good removal effect. Both substances are soluble in water and can react. The hydrosulfuric acid is weak acid, and is ionized in water in a grading way, and the hydrosulfuric acid is an aqueous solution of hydrogen sulfide gas, is a mixture and is volatile binary weak acid; ammonia is very soluble in aqueous solutions. The relevant reaction formula is as follows:
H2S+H2O=HS-+H3O+
HS-+H2O=S2-+H3O+
NH3+H2O=NH3·H2O
the NaOH solution has a good treatment effect on hydrogen sulfide, and the reaction formula is as follows:
H2S+2NaOH=Na2S+H2O(H2s quantity)
H2S+NaOH=NaHS+H2O(H2S excess)
The integrated device 20 includes a low-temperature plasma structure, a composite photocatalytic structure, and an activated carbon adsorption structure.
The low temperature plasma structure includes a molecular energizer and the plasma is a fourth species present. It is composed of electrons, ions, neutral atoms, excited atoms, photons, free radicals, etc. and is a conductive fluid. The main mechanism of the plasma purification technology is as follows: under the action of an external electric field, electrons get energy and then start to move in an accelerated manner to impact odor gas molecules at a speed of 300 to 3000 ten thousand times per second, when the energy of the electrons is the same as or slightly larger than the energy of a certain chemical bond of the odor gas molecules, inelastic collision occurs, and the electrons convert most kinetic energy into the internal energy of pollutant molecules, so that a series of complex physical and chemical reactions such as ionization, cracking or excitation and the like are initiated to the pollutant molecules, and the chemical bonds of the odor-generating groups are broken, thereby achieving the aim of deodorization.
The plasma method uses molecular exciter, high frequency and high voltage, and adopts the principle of molecular resonance to ionize the peculiar smell organic hydrocarbon molecules into H at normal temperature+And C4+Plasma is generated.
H+、C4+The plasma enters a catalyst reaction tank and is oxidized into water and dioxideCarbon.
4H++O2=2H2O
C4++O2+CO2
The composite photocatalysis structure comprises an efficient pretreatment section and a composite photocatalysis section which are usually integrated, so that the occupied area and the installation workload can be effectively reduced. The high-efficiency pretreatment section is mainly formed by combining modularized professional composite fibers and mainly used for treating each component of waste gas so as to adsorb and remove harmful chemical gas in the waste gas, reduce the pressure of rear-end treatment and improve the waste gas treatment efficiency.
Ultraviolet lamp with specific wavelength is used as light energy donor for photocatalytic oxidation, and the photocatalyst nano particle can be excited to generate electron-hole pair and hole decomposing catalyst under the irradiation of ultraviolet light with certain wavelength. TiO22The photocatalytic oxidation is active hydroxyl (OH) and other active oxidation species (O)2-,·OOH,H2O2) The result of the combined action. In TiO2The OH group generated on the surface has high reactivity and reaction energy higher than that of various chemical bond energies in organic matters, and is added with O2 -,·OOH,H2O2The synergistic effect of the active oxidation substances can quickly and effectively decompose the organic substances.
The rough reaction mechanism is:
H2S+O2、O2-、O2+→SO3+H2O
NH3+O2、O2-、O2+→NOx+H2O
VOCs+O2、O2-、O2+→SO3+CO2+H2O
the ultraviolet wavelength of the high-energy ultraviolet lamp is 182nm, 254nm or 365 nm.
The activated carbon adsorption structure is internally filled with activated carbon, and the activated carbon is fine carbon particles, has a large surface area, and has finer holes, namely capillaries. Such a capillary tube has a strong adsorption ability, and can sufficiently contact a gas (impurity) because the surface area of the carbon particle is large. When the gas (impurities) is adsorbed by the capillary tube, the purification effect is achieved (the main effect is to remove most of benzene series, non-methane total hydrocarbon, organic matters such as VOCs and the like, the odor concentration and the like in the waste gas).
The gas distribution device 30 distributes gas to the odor controller 40, the Vaportek odor controller 40 is a core device, and the Vaportek deodorization membrane is a main deodorization unit. Odor removing particles are uniformly distributed on the surface of the membrane through VP, and the odor is rapidly removed by utilizing the air convection power, and meanwhile, other external substances cannot be sucked, so that the naturalness of the plant extracting solution is kept forever. The deodorizing particles in the waste gas can quickly and actively capture the odor gas molecules in the air and wrap the odor particles. The common odor molecules are mostly small molecular organic matters (esters, alcohols, aromatic hydrocarbons and the like), and also comprise part of inorganic small molecules such as ozone, ammonia, hydrogen sulfide, hydrocarbons and the like, and the odor molecules have high activity on the surface of olfactory cells and strong irritation, and still have strong olfactory pollution capacity even under the premise that the concentration of each odor component reaches the standard and is discharged, namely the odor molecules have the characteristics of low pollution concentration and high odor intensity. Vaportek particles are natural oily deodorized molecules, and the particles are in non-covalent combination with odor molecules through intermolecular nonpolar interaction, so that the molecules are greatly stabilized, and the activity and the irritation of the molecules are reduced. Further, the increase in specific gravity after the binding is solved by the sedimentation effect. The process is different from chemical reaction process to generate a third substance and masking effect, does not cause secondary pollution, and can thoroughly remove odor.
When the rubber shock pad is used for baking the waste gas purifying device of the line, the collected waste gas is sent to the alkali liquor washing device 10 under the action of the suction port, the conveying air pipe and the fan for treatment, sodium hydroxide is selected as circulating liquid in the treatment section and is used for washing odor molecules in spraying solution and gas to generate gas and liquid contact, SO that odor components in the gas phase are transferred to the liquid phase, odor substances are removed by neutralization, oxidation or other chemical reactions of chemical agents and the odor components, and SO in the waste gas is removed2、NOxMethyl mercaptan, methyl sulfideRemoving waste gas components dissolved in the alkali liquor, such as methyl disulfide and the like.
The waste gas washed by the alkali liquor washing device 10 belongs to a gas-liquid mixed state, and most of water vapor in the gas needs to be removed through the treatment of a high-efficiency dehydration and dehumidification layer in order to avoid influencing the next treatment section. Due to the inertia effect of the rising of the waste gas, the water vapor collides with the dehydration layer and is attached to the surface, so that the liquid drops are larger and larger, and the gravity sedimentation is achieved. (the main function is to intercept floccules in the gas and remove most of water vapor in the gas)
The dehydrated waste gas is pumped to the low-temperature plasma structure of the integrated equipment 20, the waste gas firstly passes through the low-temperature plasma excitation area, high-energy electrons are generated under the acceleration action of an electric field, and when the average energy of the electrons exceeds the molecular chemical bond energy of a target treatment object, the molecular bonds are broken, so that the aim of eliminating gaseous pollutants is fulfilled. (mainly used for removing benzene, toluene, xylene, non-methane total hydrocarbons, VOCs and other organic matters in a part of waste gas).
The photocatalytic oxidation of TiO2 formed in the exhaust gas after low-temperature plasma decomposition under the lamp irradiation of high-energy ultraviolet lamp beams is the result of the combined action of active hydroxyl groups (. OH) and other active oxidation substances (. O2-,. OOH, H2O 2). OH groups generated on the surface of TiO2 have high reactivity and higher reaction energy than various chemical bond energies in organic matters, and can quickly and effectively decompose the organic matters by the synergistic effect of O2-,. OOH and H2O2 active oxidation substances. (main function: removal of easily decomposed and oxidized exhaust gas components (benzene, toluene, xylene, non-methane total hydrocarbons, VOCs, etc., and only good disinfection and deodorization effects) from a part of exhaust gas)
The waste gas after the composite photocatalysis is pumped to an activated carbon adsorption structure, the activated carbon has a large surface area, and the carbon granules also have finer holes, namely capillaries. Such a capillary tube has a strong adsorption ability, and can sufficiently contact a gas (impurity) because the surface area of the carbon particle is large. When the gas (impurities) is adsorbed by the capillary, the components which have stable molecular structure and cannot be biodegraded are removed.
The odor gas pretreated by the previous stages still has the biggest odor pollution problem. At this time, the Vaportek odor controller 40 is adopted, and a medium-low pressure centrifugal fan 50 is used for blowing air (realizing variable frequency control), so that the deodorizing particles in the odor controller 40 are taken away, odor gas molecules in the air are rapidly and actively captured, and the odor particles are wrapped. Vaportek particles are natural oily deodorizing molecules, and the particles are in non-covalent combination with odor molecules through intermolecular nonpolar interaction, so that the molecules are greatly stabilized, the activity and the irritation of the molecules are reduced, and the odor is thoroughly removed. (main function: removal of malodors in exhaust gas to the point of emission).
The treated waste gas reaching the standard is discharged by being led to a height of more than 15 meters through a chimney 60.
The invention also relates to a waste gas purification method for the baking line of the rubber shock pad, which comprises the following steps:
a waste gas purification method for a rubber shock pad baking line comprises the following steps:
washing with alkali liquor: collecting and conveying the waste gas to a multi-stage cross-flow washing tank, wherein in the cross-flow washing tank, the gas is purified after horizontally passing through one or more packing beds, the packing is cleaned from the top, cleaning liquid is sprayed on the top of the packing, the cleaning liquid flows through the packing and enters a circulating water tank, NaOH solution or lime water is added into the circulating water tank, and substances such as NH3, H2S, thiol and fatty acid which is difficult to decompose are removed;
and (3) dehydration treatment: when the gas with mist rises through the spraying washing layer at a certain speed, the mist collides with the chemical washing layer and is attached to the surface of the chemical washing layer due to the inertia effect of rising mist, and the liquid drops are separated from the chemical washing layer and fall down until the gathered liquid drops are large enough that the gravity generated by the liquid drops exceeds the resultant force of the rising force of the gas and the surface tension of the liquid;
low-temperature plasma decomposition: the waste gas firstly passes through a low-temperature plasma excitation area, high-energy electrons are generated under the acceleration action of an electric field, and when the average energy of the electrons exceeds the molecular chemical bond energy of a target treatment substance, the molecular bonds are broken to decompose gaseous pollutants;
performing composite photocatalysis: decomposing organic matters in the waste gas under the irradiation of a lamp of a high-energy ultraviolet lamp beam;
activated carbon adsorption: the active carbon absorbs the undegradable components in the waste gas;
gas distribution and deodorization: deodorizing particles are uniformly distributed on the surface of the deodorizing membrane, deodorizing microparticles can quickly and actively capture odorous gas molecules in the air, the odorous particles are wrapped to generate non-covalent bonding, and sedimentation is generated due to the increase of specific gravity after bonding;
discharging: the height is increased by more than 15 meters through a chimney 60 for discharging.
Compared with the prior art, the waste gas purification device for the rubber shock pad baking line has the characteristics of waste gas diversity, variability, high pollution concentration, large air volume for treatment and the like, and a treatment process is selected in a targeted manner so as to ensure that the waste gas can be discharged after passing through the device.
1. The waste gas purification device of the rubber shock pad baking line is convenient to install and small in occupied area on site;
2. the operation process of the waste gas purification device of the rubber shock pad baking line is safe, stable and reliable, and the operation and the maintenance are convenient;
3. the multiple treatment processes are combined into integrated equipment, and the borne waste gas concentration and component load are large;
4. the targeted selection treatment process for the components of the waste gas can better control the operation and maintenance cost of the system;
5. the equipment is made of stainless steel, so that the appearance and the service life of the system are guaranteed to the maximum extent;
6. the tail end of the waste gas treatment system is designed with a dry neutralization method (industrial deodorization membrane), which not only ensures the cost index of the discharged waste gas, but also can effectively control the odor concentration of the discharge outlet.
Various other modifications and changes may be made by those skilled in the art based on the above-described technical solutions and concepts, and all such modifications and changes should fall within the scope of the claims of the present invention.

Claims (10)

1. The utility model provides a rubber shock pad toasts line exhaust gas purification device, includes a plurality of connecting pipes, its characterized in that: rubber shock pad toasts line exhaust gas purification device and still includes alkali lye washing device, integration equipment, cloth gas device and peculiar smell controller, alkali lye washing device integration equipment cloth gas device reaches the peculiar smell controller communicates through the connecting pipe in proper order, inside low temperature plasma structure, compound photocatalysis structure, the active carbon adsorption structure of including of integration equipment, waste gas warp alkali lye washing device washing and dewatering at the washing in-process, the waste gas after the dehydration gets into gaseous pollutant is eliminated to low temperature plasma structure, later gets into compound photocatalysis structure decomposes the organic matter, the active carbon adsorption structure adsorbs the composition of unable degradation in with waste gas, later waste gas gets into cloth gas device reaches peculiar smell controller deodorization.
2. The rubber cushion baking line exhaust gas purification device of claim 1, characterized in that: the alkali liquor washing device comprises a cross-flow washing tank, a packed bed positioned in the cross-flow washing tank, a spraying structure positioned at the top of the packed bed and a circulating water tank, wherein in the cross-flow washing tank, waste gas horizontally passes through one or more packed beds to be purified, the packed bed is cleaned from the top, cleaning liquid is sprayed on the top of the packed bed and flows through the packed bed to enter the circulating water tank, and the cleaning liquid is NaOH solution or lime water.
3. The rubber cushion baking line exhaust gas purification device of claim 1, characterized in that: the low-temperature plasma structure comprises a molecular exciter, waste gas passes through a low-temperature plasma excitation area, high-energy electrons are generated under the acceleration action of an electric field, and when the average energy of the electrons exceeds the molecular chemical bond energy of a target treatment object, the molecular bonds are broken, so that the aim of eliminating gaseous pollutants is fulfilled.
4. The rubber cushion baking line exhaust gas purification device of claim 1, characterized in that: the composite photocatalytic structure comprises a pretreatment section, wherein the pretreatment section comprises a plurality of modularized composite fibers, and the composite fibers adsorb harmful chemical gases in waste gases.
5. The rubber cushion baking line exhaust gas purification device of claim 4, characterized in that: the composite photocatalytic structure also comprises a composite photocatalytic section, the composite photocatalytic section comprises a high-energy ultraviolet lamp, and waste gas is irradiated by a high-energy ultraviolet lamp beam to decompose organic matters.
6. The rubber cushion baking line exhaust gas purification device of claim 5, characterized in that: the ultraviolet wavelength of the high-energy ultraviolet lamp is 182nm, 254nm or 365 nm.
7. The rubber cushion baking line exhaust gas purification device of claim 1, characterized in that: the activated carbon adsorption structure comprises filled activated carbon, and the activated carbon adsorbs undegradable components in the exhaust gas.
8. The rubber cushion baking line exhaust gas purification device of claim 1, characterized in that: the odor distribution device distributes odor to the odor controller, the odor controller comprises a deodorization membrane, odor removing particles are uniformly distributed on the surface of the deodorization membrane, odor removing particles can rapidly and actively capture odor gas molecules in the air and wrap the odor particles to generate non-covalent bonding, and the odor particles are settled due to the increase of specific gravity after bonding.
9. The rubber cushion baking line exhaust gas purification device of claim 1, characterized in that: the waste gas purification device of the rubber shock pad baking line further comprises a medium-low pressure centrifugal fan and a chimney, and waste gas deodorized by the peculiar smell controller flows into the chimney through the medium-low pressure centrifugal fan to be discharged.
10. The waste gas purification method for the rubber shock pad baking line is characterized by comprising the following steps of:
washing with alkali liquor: collecting and conveying the waste gas to a multi-stage cross-flow washing tank, wherein in the cross-flow washing tank, the gas is purified after horizontally passing through one or more packing beds, the packing is cleaned from the top, cleaning liquid is sprayed on the top of the packing, the cleaning liquid flows through the packing and enters a circulating water tank, NaOH solution or lime water is added into the circulating water tank, and substances such as NH3, H2S, thiol and fatty acid which is difficult to decompose are removed;
and (3) dehydration treatment: when the gas with mist rises through the spraying washing layer at a certain speed, the mist collides with the chemical washing layer and is attached to the surface of the chemical washing layer due to the inertia effect of rising mist, and the liquid drops are separated from the chemical washing layer and fall down until the gathered liquid drops are large enough that the gravity generated by the liquid drops exceeds the resultant force of the rising force of the gas and the surface tension of the liquid;
low-temperature plasma decomposition: the waste gas firstly passes through a low-temperature plasma excitation area, high-energy electrons are generated under the acceleration action of an electric field, and when the average energy of the electrons exceeds the molecular chemical bond energy of a target treatment substance, the molecular bonds are broken to decompose gaseous pollutants;
performing composite photocatalysis: decomposing organic matters in the waste gas under the irradiation of a lamp of a high-energy ultraviolet lamp beam;
activated carbon adsorption: the active carbon absorbs the undegradable components in the waste gas;
gas distribution and deodorization: deodorizing particles are uniformly distributed on the surface of the deodorizing membrane, deodorizing microparticles can quickly and actively capture odorous gas molecules in the air, the odorous particles are wrapped to generate non-covalent bonding, and sedimentation is generated due to the increase of specific gravity after bonding;
discharging: the height of the flue is increased by more than 15 meters through a chimney for discharging.
CN202010052781.4A 2020-01-17 2020-01-17 Waste gas purification device and method for baking line of rubber shock pad Withdrawn CN111068487A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113198317A (en) * 2021-04-22 2021-08-03 上海玉朗科技有限公司 Wire and cable fire behaviour test waste gas treatment system
CN113877411A (en) * 2020-07-02 2022-01-04 大连爱德摩设备制造有限公司 Distributed air purifying device for industrial sewage gathering and transportation system
CN113877410A (en) * 2020-07-02 2022-01-04 大连爱德摩设备制造有限公司 VOCs (volatile organic compounds) and odor treatment method for industrial sewage gathering and transportation system

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113877411A (en) * 2020-07-02 2022-01-04 大连爱德摩设备制造有限公司 Distributed air purifying device for industrial sewage gathering and transportation system
CN113877410A (en) * 2020-07-02 2022-01-04 大连爱德摩设备制造有限公司 VOCs (volatile organic compounds) and odor treatment method for industrial sewage gathering and transportation system
CN113877410B (en) * 2020-07-02 2024-05-07 大连爱德摩设备制造有限公司 VOCs (volatile organic compounds) and odor treatment method for industrial sewage collection and transportation system
CN113877411B (en) * 2020-07-02 2024-05-07 大连爱德摩设备制造有限公司 Distributed air purifying device for industrial sewage collecting and conveying system
CN113198317A (en) * 2021-04-22 2021-08-03 上海玉朗科技有限公司 Wire and cable fire behaviour test waste gas treatment system

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Application publication date: 20200428