CN111054531A - Electrostatic spraying atomization device for nano material - Google Patents
Electrostatic spraying atomization device for nano material Download PDFInfo
- Publication number
- CN111054531A CN111054531A CN201911325790.XA CN201911325790A CN111054531A CN 111054531 A CN111054531 A CN 111054531A CN 201911325790 A CN201911325790 A CN 201911325790A CN 111054531 A CN111054531 A CN 111054531A
- Authority
- CN
- China
- Prior art keywords
- electrode
- nano
- solution tank
- electrostatic spraying
- atomizing device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
- B05B5/08—Plant for applying liquids or other fluent materials to objects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
- B05B5/08—Plant for applying liquids or other fluent materials to objects
- B05B5/087—Arrangements of electrodes, e.g. of charging, shielding, collecting electrodes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
Abstract
The invention relates to an electrostatic spraying atomization device for nano materials, which comprises a first solution tank, a first electrode and a second electrode, wherein the first electrode and the second electrode are arranged in the first solution tank; the first solution tank is connected with a spraying part, and the spraying part comprises an electrode support part and a nozzle; an opposite electrode is arranged above the ejecting piece, a plurality of through holes are formed in the opposite electrode, and the through holes are matched with the nozzles; the first electrode and the opposite electrode are connected through a first voltage applying part, and the first electrode and the second electrode are connected through a second voltage applying part; the beneficial effects are that: the charged liquid is broken to form charged liquid drops, and after the charged liquid drops leave the nozzle, secondary breaking is carried out under the action of charge repulsion, so that particles with smaller particle size and more uniformity can be obtained.
Description
Technical Field
The invention belongs to the technical field of spraying equipment, and particularly relates to an electronic spraying atomization device.
Background
The electrostatic spraying device mainly comprises a high-voltage generating device, a solution supplying device, a spraying device and a collecting device. The principle is that a static electric field is established between the jet liquid and the receiving device in the high-voltage generator, and when the intensity of the static electric field exceeds a critical value, the polymer solution or melt overcomes the surface tension thereof under the action of the electric field force to form a charged jet flow at the spinneret orifice. The charged stream is bent or whiped at a high speed due to electrostatic repulsion, and is cooled to obtain particles or fibers with diameters ranging from tens of nanometers to several micrometers along with solvent volatilization or melt cooling, and finally falls on a collecting device to form a compact particle cluster or fiber membrane material.
The electrostatic spraying technology can be used for preparing fibers with uniform thickness or particles with uniform particle size. The method has great advantages that the method can directly obtain particles with uniform particle size without an emulsifier on the preparation of micron or nanometer sized particles. However, the biggest limitation is in the preparation speed, the typical capillary tube is used as the spray head, the liquid supply speed is required to be consistent with the speed of the liquid flying to the corresponding electrode overcoming the surface tension, and the typical speed is dozens of microliters to a plurality of milliliters per hour, so that the application of the capillary tube in industrial production is greatly limited.
Disclosure of Invention
In order to solve the problems, the invention adopts the following technical scheme:
an electrostatic spraying atomizer for nano material is composed of the first solution tank,
a first electrode and a second electrode provided in the first solution tank;
the first solution tank is connected with a spraying piece,
the ejection member includes an electrode support member and a nozzle;
an opposite electrode is arranged above the ejecting piece, a plurality of through holes are arranged on the opposite electrode,
the through hole is matched with the nozzle;
the first electrode and the opposite electrode are connected through a first voltage applying part, and the first electrode and the second electrode are connected through a second voltage applying part;
a nano composite coating is attached outside the counter electrode; the nano composite coating is of a gradient nano structure, and a metal nano layer, a nano metal-ceramic layer and a nano ceramic layer are sequentially arranged inside and outside the nano composite coating.
In one mode, an ion permeable membrane is provided between the first electrode and the second electrode.
In one form, the first electrode is located within a first chamber and the second electrode is located within a second chamber.
In one form, the first and second chambers are separated by an ion permeable membrane.
In one mode, the apparatus is further provided with a second solution tank, and the second solution tank and the first solution tank are communicated through a circulation unit.
In one form, the nozzle tip is provided with an opening;
the opening is arranged opposite to the through hole.
In one mode, the counter electrode is disposed on the support.
In one mode, a solution is disposed in both the first solution tank and the second solution tank.
In one mode, the metal particles and the ceramic particles in the metal nanolayers and the nanoceramic layers are nanocrystalline particles.
The invention has the beneficial effects that:
the charged liquid is broken to form charged liquid drops, and after the charged liquid drops leave the nozzle, secondary breaking is carried out under the action of charge repulsion, so that particles with smaller particle size and more uniformity can be obtained.
Drawings
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 is another schematic structural view of the present invention;
fig. 3 is a schematic structural diagram of an implementation state of the present invention.
10 first solution tank, 10a first chamber, 10b second chamber, 11 second solution tank, 20 ejection plate, 21 electrode support, 26 nozzle, 30 counter electrode, 80 circulation portion, 110 first electrode, 120 second electrode, 140 ion transmission membrane, 200 solution, 27 opening, 31 support.
Detailed Description
The invention is further illustrated with reference to the accompanying drawings:
as shown in fig. 1, an electrostatic spraying and atomizing device for nano-materials is characterized in that: comprising a first solution tank (10) in which,
a first electrode 110 and a second electrode 120 provided in the first solution tank 10;
the first solution tank 10 is connected with a spouting member 20,
the ejection member 20 includes an electrode support 21 and a nozzle 26;
a counter electrode 30 is arranged above the ejection member 20, the counter electrode 30 is provided with a plurality of through holes 32,
the through hole 32 is matched with the nozzle 26;
the first electrode 110 and the counter electrode 30 are connected to each other by a first voltage applying unit 40, and a potential is applied so that a predetermined potential difference is applied between the counter electrode 30 and the first electrode 110;
the first electrode 110 and the second electrode 120 are connected by a second voltage applying unit 41; the second electrode 120 is an electrode which is provided in the first solution tank 10, which is paired with the 1 st electrode 110, and which electrolyzes the solution 200 by applying a voltage between the first electrode 110 and the second electrode. Specifically, the first electrode 110 and the second electrode 120 are an electrode pair that applies a potential to the second voltage applying section 41 to cause the solution 200 to apply a voltage and electrolyze the solution 200.
A nano composite coating is attached to the outside of the counter electrode 30; the nano composite coating is of a gradient nano structure, and a metal nano layer, a nano metal-ceramic layer and a nano ceramic layer are sequentially arranged inside and outside the nano composite coating; the metal particles and the ceramic particles in the metal nano layer and the nano ceramic layer are nano crystal grains.
As shown in fig. 2, an ion-transmissive film 140 is provided in a spaced relationship between the first electrode 110 and the second electrode 120.
The first electrode 110 is located in the first chamber 10a and the second electrode 120 is located in the second chamber 10 b.
The first chamber 10a and the second chamber 10b are separated by an ion-transmissive membrane 140.
One way of the ion-transmissive membrane 140 is a porous membrane or an ion-exchange membrane. The material of the porous membrane is, for example, a ceramic material or a resin material, but is not particularly limited; cation exchange membranes or anion exchange membranes can be used, and double ion exchange membranes can also be used.
The first electrode 110 is disposed in the first chamber 10a, the first chamber 10a being one side of the first solution tank 10 partitioned by the ion-transmissive film 140, the second electrode 120 is disposed in the second chamber 10b, and the second chamber 10b is located on the opposite side of the first electrode 110.
The ion-permeable membrane 140 separates a 1 st chamber 10a, which is a side where the solution 200 can directly move, from a 2 nd chamber 10b, which is a side where the solution 200 cannot directly move, and is not connected to the inside of the nozzle 26, by connecting the inside of the 1 st solution tank 10 to the inside of the nozzle 26. The first electrode 110 is disposed in a first chamber 10a, and the first chamber 10a is located on the side of the nozzle 26 in the first solution tank 10 partitioned by the ion-permeable membrane 140
As shown in fig. 3, a second solution tank 11 is further provided, and the second solution tank 11 and the first solution tank 10 are communicated through a circulation portion 80.
The end of the nozzle 26 is provided with an opening 27;
the opening 27 is disposed opposite to the through hole 32 so that the substance ejected from the opening 27 can pass through the through hole 32.
The counter electrode 30 is provided on the holder 31.
The first solution tank 10 and the second solution tank 11 are both provided with a solution 200.
It will be apparent to those skilled in the art that various modifications may be made to the above embodiments without departing from the general spirit and concept of the invention. All falling within the scope of protection of the present invention. The protection scheme of the invention is subject to the appended claims.
Claims (9)
1. The electrostatic spraying and atomizing device for the nano material is characterized in that: comprises a first solution tank (10),
a first electrode (110) and a second electrode (120) provided in the first solution tank (10);
the first solution tank (10) is connected with a spraying piece (20),
the ejection member (20) comprises an electrode support (21) and a nozzle (26);
a counter electrode (30) is arranged above the ejection piece (20), a plurality of through holes (32) are arranged on the counter electrode (30),
the through hole (32) is matched with the nozzle (26);
the first electrode (110) and the counter electrode (30) are connected by a first voltage applying unit (40), and the first electrode (110) and the second electrode (120) are connected by a second voltage applying unit (41);
a nano composite coating is attached to the outside of the counter electrode (30); the nano composite coating is of a gradient nano structure, and a metal nano layer, a nano metal-ceramic layer and a nano ceramic layer are sequentially arranged inside and outside the nano composite coating.
2. The electrostatic spraying and atomizing device for nano-materials as claimed in claim 1, wherein: an ion transmission film (140) is arranged between the first electrode (110) and the second electrode (120) in a separating way.
3. The electrostatic spraying and atomizing device for nano-materials as claimed in claim 2, wherein: the first electrode (110) is located within a first chamber (10a) and the second electrode (120) is located within a second chamber (10 b).
4. The electrostatic spraying and atomizing device for nano-materials as claimed in claim 3, wherein: the first chamber (10a) and the second chamber (10b) are separated by an ion-transmissive membrane (140).
5. The electrostatic spraying and atomizing device for nano-materials according to any one of claims 1 to 4, wherein: a second solution tank (11) is also arranged, and the second solution tank (11) is communicated with the first solution tank (10) through a circulating part (80).
6. The electrostatic spraying and atomizing device for nano-materials as claimed in claim 1, wherein: the end part of the nozzle (26) is provided with an opening (27);
the opening (27) is arranged opposite to the through hole (32).
7. The electrostatic spraying and atomizing device for nano-materials as claimed in claim 1, wherein: the counter electrode (30) is provided on the holder (31).
8. The electrostatic spraying and atomizing device for nano-materials as claimed in claim 5, wherein: the first solution tank (10) and the second solution tank (11) are both provided with a solution (200).
9. The electrostatic spraying and atomizing device for nano-materials as claimed in claim 1, wherein: the metal particles and the ceramic particles in the metal nano layer and the nano ceramic layer are nano crystal grains.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911325790.XA CN111054531A (en) | 2019-12-20 | 2019-12-20 | Electrostatic spraying atomization device for nano material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911325790.XA CN111054531A (en) | 2019-12-20 | 2019-12-20 | Electrostatic spraying atomization device for nano material |
Publications (1)
Publication Number | Publication Date |
---|---|
CN111054531A true CN111054531A (en) | 2020-04-24 |
Family
ID=70301367
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201911325790.XA Pending CN111054531A (en) | 2019-12-20 | 2019-12-20 | Electrostatic spraying atomization device for nano material |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111054531A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112121578A (en) * | 2020-09-21 | 2020-12-25 | 郑妍 | High-efficient type waste gas sprays purifying column for refuse treatment |
-
2019
- 2019-12-20 CN CN201911325790.XA patent/CN111054531A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112121578A (en) * | 2020-09-21 | 2020-12-25 | 郑妍 | High-efficient type waste gas sprays purifying column for refuse treatment |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1948854B1 (en) | Electrohydrodynamic printing and manufacturing | |
US7629030B2 (en) | Electrospraying/electrospinning array utilizing a replacement array of individual tip flow restriction | |
JP4598083B2 (en) | Electrostatic spraying apparatus and electrostatic spraying method | |
KR102267119B1 (en) | Spray charging and discharging system for polymer spray deposition device | |
CN103170416B (en) | A kind of static nozzle and using method thereof | |
JP5382637B2 (en) | Spinneret for electrospinning equipment | |
García-López et al. | 3D printed multiplexed electrospinning sources for large-scale production of aligned nanofiber mats with small diameter spread | |
CN112122614B (en) | Self-excitation electrostatic field-driven spray deposition-based 3D printing device, working method and application thereof | |
CN111054531A (en) | Electrostatic spraying atomization device for nano material | |
JP6112873B2 (en) | Composite spinning nozzle for producing nanofiber materials and microfiber materials | |
KR100947028B1 (en) | Nonconductor Electrostatic Spray Apparatus and Method Thereof | |
CN114475015A (en) | Electrostatic spraying direct writing system and method with focusing electric field structure | |
CN211887485U (en) | Electrostatic spraying atomization device for nano material | |
CN205344115U (en) | Array electrofluid spouts seal shower nozzle | |
KR20090104404A (en) | Multiplexed Grooved Nozzles Electrospray Apparatus Having Extractor of Insulated Electric Potential and Method Thereof | |
CN110681505B (en) | Electric spraying device | |
US20230063889A1 (en) | Method for manufacturing secondary battery, or secondary battery | |
CN115210906A (en) | Method for manufacturing secondary battery, or secondary battery | |
US20220090298A1 (en) | Capillary type multi-jet nozzle for fabricating high throughput nanofibers | |
CN110735192B (en) | Electrode-assisted disc type porous electrostatic spinning spray head assembly | |
KR20050112044A (en) | Valve type electrospray apparatus for preparing materials having nano-structure | |
US20240059060A1 (en) | Electrohydrodynamic printer with fluidic extractor | |
CN117358948A (en) | Metal nano-structure 3D printing device and method integrated with annular electrode spray head | |
Zhao et al. | Field induced jet micro-EDM | |
Aksay et al. | Electrohydrodynamic printing and manufacturing |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |