CN111053702B - Animal activated carbon collagen mask capable of naturally forming film and preparation method thereof - Google Patents
Animal activated carbon collagen mask capable of naturally forming film and preparation method thereof Download PDFInfo
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- CN111053702B CN111053702B CN201910820575.0A CN201910820575A CN111053702B CN 111053702 B CN111053702 B CN 111053702B CN 201910820575 A CN201910820575 A CN 201910820575A CN 111053702 B CN111053702 B CN 111053702B
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- activated carbon
- crab shell
- shell activated
- collagen
- bone collagen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Gerontology & Geriatric Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Peptides Or Proteins (AREA)
Abstract
An animal activated carbon collagen mask capable of forming a film naturally and a preparation method thereof, relating to the field of biological masks. Comprises the following components: the mass ratio of the crab shell activated carbon to the tuna bone collagen is 0.5: 1. the crab shell activated carbon and the tuna bone collagen used in the invention belong to natural biological materials, and are economical, practical, safe and nontoxic. The crab shell activated carbon can adsorb harmful substances on the surface of a human body and has certain oxidation resistance, and the tuna bone collagen can be adhered to the surface of the skin to form a film and help the skin to moisturize and moisturize, so that the mask has good effects of expelling toxin, moistening the skin and resisting aging.
Description
Technical Field
The invention relates to the field of biological masks, and in particular relates to crab shell activated carbon and application of tuna bone collagen in a mask.
Background
With the gradual improvement of living standard, the idea of self care and maintenance is gradually enhanced, and the facial mask becomes a widely common skin care product. In the using process, the facial mask isolates the skin of a human body from the outside, so that the surface temperature of the skin is raised, pores are expanded, the secretion and metabolism of the skin are accelerated, harmful substances and the like in the skin are more easily discharged, and water, nutrient substances and the like in the facial mask are more easily absorbed by the skin, so that the effects of expelling toxin, moistening the skin and beautifying the skin are realized.
The activated carbon is a black carbon material, is light in weight, has a developed internal pore structure, contains a large number of micropores (less than 2nm), mesopores (2-50nm), macropores (more than 50nm) and the like, has a large specific surface area and very strong physical adsorption capacity, and has very strong chemical adsorption capacity and certain oxidation resistance capacity due to rich nitrogen, sulfur and other heteroatom-containing groups, so that the activated carbon can remove dust, grease, heavy metal ions and the like on the surface of skin and resist oxidation and aging.
The animal bone collagen is formed by winding three polypeptide chains in a supercoiled mode, has good biocompatibility, can be dissolved in hot water, and is convenient to use. Collagen has a close relationship with the growth, aging and the like of a human body, can be absorbed and utilized by the human body, has good trophism, repairability, moisture retention and the like, and is widely applied to the fields of food, medicine, health care and the like.
Disclosure of Invention
In order to better meet the requirements of people on skin care and maintenance and realize the efficient utilization of natural biological resources, the invention provides a preparation method of a naturally film-forming facial mask containing crab shell activated carbon and tuna bone collagen.
The invention adopts the following technical scheme that the composition mask containing the crab shell activated carbon and the tuna bone collagen is prepared from the crab shell activated carbon and the tuna bone collagen in a mass ratio of 0.1-1:1, preferably 0.5: 1.
in a preferred embodiment of the present invention, the commercially available alkaline tuna bone collagen is used.
In a preferred embodiment of the present invention, the mass ratio of the crab shell activated carbon to the tuna bone collagen is 0.5: 1, dissolving collagen with water, and adding crab shell activated carbon, wherein the mass concentration of the collagen water solution is 5%.
The invention also provides a preparation method of the crab shell activated carbon, which comprises the following steps:
(1) cleaning and drying the crab shells;
(2) directly putting the dried crab shells into a tubular furnace for pre-carbonization, heating to 400 ℃ at a heating rate of 2 ℃/min under the nitrogen atmosphere, and preserving heat for 2 hours;
(3) mashing the pre-carbonized crab shell and soaking the crab shell in 1M KOH solution, wherein the mass ratio of the crab shell to KOH is 1:1, standing for one day, and drying the KOH solution;
(4) putting the dried product into a tubular furnace for carbonization, heating to 700 ℃ at the heating rate of 3 ℃/min under the nitrogen atmosphere, and preserving the heat for 1 hour to obtain the crab shell activated carbon;
(5) soaking the crab shell activated carbon in 1M HCl solution for one day and stirring;
(6) and (3) carrying out suction filtration on the solution, boiling and washing the crab shell activated carbon by using deionized water for at least 5 times, and then drying the crab shell activated carbon at 60 ℃.
The carbon material is prepared by calcining natural crab shells by a natural template method and a chemical activation method. The carbon material is in a cluster-shaped porous carbon fiber structure, and the specific surface area can reach 1500m2More than g. The carbon material is doped with various heteroatoms such as nitrogen, sulfur, phosphorus and the like.
The tuna bone collagen is derived from tuna bone collagen, and the tuna bone collagen is extracted from tuna bones by an alkali-reduction method. The ossein protein is derived from a natural biological material, namely tuna bone, and is low in cost, safe and non-toxic.
The tuna collagen has good film-forming property and adhesiveness. The facial mask does not need a common facial mask base material and can be directly coated.
The invention also protects the cosmetic and medical applications of the composition.
Compared with the prior art, the invention has the following advantages:
(1) the crab shell activated carbon and the tuna bone collagen are both derived from natural biological materials, do not contain chemical substances such as preservatives and the like harmful to human bodies, and are safe and non-toxic.
(2) The preparation method of the crab shell activated carbon has the advantages that the prepared crab shell activated carbon has a unique hierarchical porous fiber cluster structure doped with various heteroatoms, and is high in specific surface area, strong in adsorption capacity and certain in oxidation resistance.
(3) The tuna bone collagen adopted has good film forming property and adhesiveness, so that the mask does not need a common mask base material and can naturally form a film.
(4) The crab shell activated carbon and the tuna bone collagen used in the invention belong to natural biological materials, and are economical, practical, safe and nontoxic. The crab shell activated carbon can adsorb harmful substances on the surface of a human body and has certain oxidation resistance, and the tuna bone collagen can help the skin to moisturize and moisturize, so the mask has good effects of expelling toxin, moisturizing the skin and resisting aging.
Detailed Description
The present invention is further illustrated by the following examples, but the scope of the present invention is not limited thereto. The tuna bone collagen is commonly used in the market.
Example 1
Preparation of facial mask liquid
(1) Preparing a certain amount of crab shell activated carbon according to the preparation method of the crab shell activated carbon;
(2) dissolving a certain amount of tuna bone collagen in water to obtain a collagen aqueous solution, wherein the mass concentration of the collagen aqueous solution is 5%;
(3) adding crab shell activated carbon into the collagen aqueous solution according to a predetermined ratio (the mass ratio of the crab shell activated carbon to the tuna bone collagen is 0.5: 1), and uniformly stirring to obtain the mask liquid.
Example 2
Natural filming test of facial mask liquid
And (3) sucking a proper amount of the facial mask liquid prepared in the example 1 by using a dropper, dripping the facial mask liquid on a horizontally placed clean plastic plate, uniformly coating the facial mask liquid, and observing the state change of the facial mask liquid. The film liquid on the plastic plate is gradually solidified to form a film, and the film can be torn off after a period of time.
Therefore, the tuna collagen has good film-forming property and adhesion. The mask does not require a common mask base material.
Example 3
The method for measuring the antioxidant capacity comprises the following steps:
determination of ABTS free radical scavenging ability
Precisely measuring a material with the volume ratio of 1:1, placing the ABTS solution and a potassium persulfate aqueous solution in a brown volumetric flask, keeping the mixture in the dark and storing the mixture in the brown flask for reaction for 12 hours, diluting the mixture by utilizing a Pbs solution until the ABTS light absorption value (734nm) is about 0.700, respectively placing 1mL of reaction liquid into test tubes, adding a certain amount of crab shell activated carbon into one of the test tubes, using the other test tube as a blank control, placing the two test tubes in a constant-temperature water bath at 37 ℃ for reaction for 10 minutes, filtering the carbon by utilizing a filter membrane, respectively placing 200 mu L of liquid into a 96-well plate from the two test tubes, measuring the light absorption value at 734nm by utilizing an enzyme labeling instrument after the sample application is finished, repeatedly measuring for 3 times, and taking an average value.
The results of measuring the ABTS free radical scavenging ability of the crab shell activated carbon are shown in Table 1.
TABLE 1 determination of the ability of crab Shell charcoal to scavenge ABTS free radicals
Experimental data show that the crab shell charcoal has certain scavenging capacity for ABTS free radicals, and the crab shell charcoal is proved to have certain antioxidant capacity.
The carbon material has adsorption and oxidation resistance, and the tuna bone collagen has oxidation resistance, water replenishing and moisture preserving capabilities.
The carbon material is derived from a natural biological material, namely crab shell, and has low cost, safety and no toxicity. The carbon material is prepared by calcining natural crab shells by a natural template method and a chemical activation method. The carbon material is in a cluster-shaped porous carbon fiber structure, and the specific surface area can reach 1500m2The content of the compound is more than that of the compound (see the contents of the preparation method); the carbon material is doped with various heteroatoms such as nitrogen, sulfur, phosphorus and the like.
Those skilled in the art will recognize that a wide variety of modifications, alterations, and combinations can be made with respect to the above described embodiments without departing from the scope of the invention, and that such modifications, alterations, and combinations are to be viewed as being within the ambit of the inventive concept.
Claims (2)
1. A composition facial mask containing crab shell activated carbon and tuna bone collagen is characterized in that the facial mask contains the crab shell activated carbon and the tuna bone collagen; the facial mask comprises crab shell activated carbon, tuna bone collagen and water; wherein the mass ratio of the crab shell activated carbon to the tuna bone collagen is 0.1-1:1, wherein the collagen is firstly dissolved by water and then added with the crab shell activated carbon, and the concentration of the collagen aqueous solution is 5 percent;
the preparation method of the crab shell activated carbon comprises the following steps:
cleaning and drying the crab shells;
directly putting the dried crab shells into a tubular furnace for pre-carbonization, heating to 400 ℃ at a heating rate of 2 ℃/min under the nitrogen atmosphere, and preserving heat for 2 hours;
mashing the pre-carbonized crab shell and soaking the crab shell in 1M KOH solution, wherein the mass ratio of the crab shell to KOH is 1:1, standing for one day, and drying the KOH solution;
putting the dried product into a tubular furnace for carbonization, heating to 700 ℃ at the heating rate of 3 ℃/min under the nitrogen atmosphere, and preserving the heat for 1 hour to obtain the crab shell activated carbon;
soaking the crab shell activated carbon in 1M HCl solution for one day and stirring;
and (3) carrying out suction filtration on the solution, boiling and washing the crab shell activated carbon by using deionized water for at least 5 times, and then drying the crab shell activated carbon at 60 ℃.
2. The facial mask containing the composition of the crab shell activated carbon and the tuna bone collagen according to claim 1, wherein the mass ratio of the crab shell activated carbon to the tuna bone collagen is 0.5: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910820575.0A CN111053702B (en) | 2019-08-29 | 2019-08-29 | Animal activated carbon collagen mask capable of naturally forming film and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910820575.0A CN111053702B (en) | 2019-08-29 | 2019-08-29 | Animal activated carbon collagen mask capable of naturally forming film and preparation method thereof |
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| CN111053702A CN111053702A (en) | 2020-04-24 |
| CN111053702B true CN111053702B (en) | 2021-06-29 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012041297A (en) * | 2010-08-19 | 2012-03-01 | Tekunooburu:Kk | Skin care preparation for external use |
| CN103420353A (en) * | 2012-05-15 | 2013-12-04 | 北京化工大学 | Porous carbon material and preparation method and application thereof |
| CN108078869A (en) * | 2018-02-02 | 2018-05-29 | 广州市聚吉科绿色化学共性技术研究院有限公司 | A kind of adsorbing composition |
| CN108578266A (en) * | 2018-07-27 | 2018-09-28 | 北京化工大学 | A kind of antioxidant composition and its application in facial mask liquid |
-
2019
- 2019-08-29 CN CN201910820575.0A patent/CN111053702B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012041297A (en) * | 2010-08-19 | 2012-03-01 | Tekunooburu:Kk | Skin care preparation for external use |
| CN103420353A (en) * | 2012-05-15 | 2013-12-04 | 北京化工大学 | Porous carbon material and preparation method and application thereof |
| CN108078869A (en) * | 2018-02-02 | 2018-05-29 | 广州市聚吉科绿色化学共性技术研究院有限公司 | A kind of adsorbing composition |
| CN108578266A (en) * | 2018-07-27 | 2018-09-28 | 北京化工大学 | A kind of antioxidant composition and its application in facial mask liquid |
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| CN111053702A (en) | 2020-04-24 |
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