CN111003758A - High-performance proton conductor ceramic membrane reactor - Google Patents
High-performance proton conductor ceramic membrane reactor Download PDFInfo
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- CN111003758A CN111003758A CN201911149429.6A CN201911149429A CN111003758A CN 111003758 A CN111003758 A CN 111003758A CN 201911149429 A CN201911149429 A CN 201911149429A CN 111003758 A CN111003758 A CN 111003758A
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- ceramic membrane
- conductor ceramic
- reactor
- fixed frame
- water
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/46115—Electrolytic cell with membranes or diaphragms
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The invention discloses a high-performance proton conductor ceramic membrane reactor, which structurally comprises a reactor, a support frame, a drain pipe, a bidirectional water pipe and a water inlet pipe, wherein the reactor consists of a shell, a conductor ceramic membrane module, a partition plate, a back pressure mechanism and a reaction chamber, the reactor utilizes a fixed frame to fixedly install and bind a conductor ceramic membrane so as to prevent the conductor ceramic membrane from shaking and damaging the conductor ceramic membrane, the back pressure mechanism injects a water source into the conductor ceramic membrane through a guide pipe, and the back pressure mechanism is matched with the water inlet mechanism to extrude water in the conductor ceramic membrane from the inside of the conductor ceramic membrane so that foreign matters on the surface of the conductor ceramic membrane are driven by the water source to be discharged from a permeation hole in the fixed frame to be cleaned conveniently.
Description
Technical Field
The invention relates to the field of conductor ceramics, in particular to a high-performance proton conductor ceramic membrane reactor.
Background
The problems of water environment deterioration and water resource shortage are increasingly serious in the world, the membrane water treatment technology becomes the leading technology of a novel water treatment technology by the outstanding advantages of high efficiency, energy conservation, good selectivity and wide application, a high-temperature proton conductor ceramic membrane can carry out electrolytic decontamination and filtration on sewage, but the characteristics of a ceramic material provide a hotbed for scaling, the backwashing effect is low, the scaling phenomenon is serious and becomes a main factor influencing the service life of the ceramic membrane, and the ceramic material causes the ceramic plate type membrane component to have serious room temperature brittleness, so that the plate type membrane component has the characteristics of poor thermal shock resistance, no machining, no welding connection and the like.
Disclosure of Invention
Aiming at the defects of the prior art, the invention is realized by the following technical scheme: a high-performance proton conductor ceramic membrane reactor structurally comprises a reactor, a support frame, drain pipes, a bidirectional water pipe and a water inlet pipe, wherein the support frame is installed below the bottom end of the reactor;
the reactor comprises a shell, a conductor ceramic membrane module, a partition plate, a back pressure mechanism and a reaction chamber, wherein the partition plate is arranged in the shell, the partition plate is arranged at the upper part and the lower part of the shell, the conductor ceramic membrane module is arranged between the partition plate and the partition plate, the partition plate is movably connected with the conductor ceramic membrane module, the reaction chamber is arranged between the partition plate and the partition plate, the back pressure mechanism is arranged at the top end of the conductor ceramic membrane module, and the conductor ceramic membrane module is matched with the back pressure mechanism.
As a further optimization of the technical scheme, the conductor ceramic membrane module comprises a fixed frame, mounting holes, conductor ceramic membranes, permeation holes and water outlet pipes, wherein the mounting holes are formed in the surface of the fixed frame, the conductor ceramic membranes are arranged in the fixed frame, the fixed frame is movably connected with the conductor ceramic membranes, the water outlet pipes are arranged below the middle positions of the bottom ends of the fixed frame, the fixed frame is connected with the water outlet pipes in an adhesive mode, and the permeation holes are formed in the left side and the right side of the fixed frame.
As a further optimization of the technical scheme, the back pressure mechanism comprises a supporting plate, a pressing rod, a sliding rod, an ejector rod and a water inlet mechanism, the sliding rod is arranged at each of the left end and the right end of the supporting plate, the supporting plate is fixedly connected with the sliding rod, the pressing rod is arranged at the middle position of the top end of the supporting plate, the supporting plate is connected with the pressing rod in a gluing mode, more than two ejector rods are arranged below the bottom end of the supporting plate, one ends of the supporting plate and the ejector rods are connected, and the water inlet mechanism is arranged at the other end of each ejector rod.
As a further optimization of the technical scheme, the pressure rod and the supporting plate are internally provided with flow guide pipes.
As the further optimization of this technical scheme, the mechanism of intaking constitute by ring body, valve water piece, dead lever, torsional spring, the inboard intermediate position of ring body on install the dead lever, the ring body inboard on be equipped with the valve water piece, ring body and valve water piece swing joint, the valve water piece be connected through the torsional spring with the dead lever.
As a further optimization of the technical scheme, a rubber sealing ring is arranged below the bottom end of the ring body, and the ring body is connected with the rubber sealing ring in an adhesive mode.
As a further optimization of the technical scheme, the conductor ceramic membrane is in sliding fit with the ejector rod.
As a further optimization of the technical scheme, the supporting plate and the partition plate are parallel to each other.
As a further optimization of the technical scheme, the diameter of the ring body is the same as the diameter of the hole in the conductor ceramic film.
Advantageous effects
The invention relates to a high-performance proton conductor ceramic membrane reactor, which is characterized in that sewage is fed into a bidirectional water pipe from a water inlet pipe, the sewage enters a reaction chamber from the bidirectional water pipe for electrolytic reaction, the sewage enters a conductor ceramic membrane from a permeation hole for filtration after being subjected to electrolytic decontamination, filtered clean water is discharged to the bottom end of a shell from a water outlet pipe, the conductor ceramic membrane is bound and protected by a fixed frame to avoid shaking of the conductor ceramic membrane, after the reactor finishes filtration, the water outlet pipe is blocked, a small amount of clean water is injected from a hole on a pressure rod, the clean water is extruded and injected, so that the water pressure flows onto a valve water sheet in a ring body from a diversion pipe, the valve water sheet is extruded by the water pressure to drive a torsion spring to open, the clean water enters a ceramic membrane filter element in the conductor ceramic membrane from the ring body, then the pressure rod is pushed downwards forcefully, the ejector rod utilizes the fixed rod to pull back the valve water sheet through the torsional spring and seals for the ejector rod drives the valve water sheet and extrudes the clear water, makes the clear water clear away the foreign matter on the conductor ceramic membrane surface.
Compared with the prior art, the invention has the beneficial effects that: the reactor utilizes fixed frame to carry out the fixed mounting constraint to conductor ceramic membrane, avoid conductor ceramic membrane to appear rocking, cause conductor ceramic membrane to damage, back pressure mechanism pours the water source into conductor ceramic membrane into through the honeycomb duct, back pressure mechanism cooperation is intake the water of mechanism in with conductor ceramic membrane and is gone out from its inside extrusion, make the water source drive the infiltration hole discharge on conductor ceramic membrane surface's foreign matter from fixed frame, so that clear up, the condition that conductor ceramic membrane scale deposit can be clear away to this design appears, the cleaning efficiency is improved, conductor ceramic membrane's life has also been increased.
Drawings
Other features, objects and advantages of the invention will become more apparent upon reading of the detailed description of non-limiting embodiments with reference to the following drawings:
FIG. 1 is a schematic structural diagram of a high performance proton conductor ceramic membrane reactor of the present invention.
FIG. 2 is a schematic diagram of a front cross-sectional structure of a high performance proton conductor ceramic membrane reactor of the present invention.
FIG. 3 is a schematic top view cross-sectional structure of a high performance proton conductor ceramic membrane reactor of the present invention.
Fig. 4 is a schematic structural view of the conductor ceramic membrane module according to the present invention.
Fig. 5 is a schematic structural view of the back pressure mechanism of the present invention.
Fig. 6 is a schematic structural view of the water inlet mechanism of the present invention.
In the figure: the device comprises a reactor-1, a support frame-2, a water discharge pipe-3, a bidirectional water pipe-4, a water inlet pipe-5, a shell-1 a, a conductor ceramic membrane module-1 b, a partition plate-1 c, a back pressure mechanism-1 d, a reaction chamber-1 e, a fixed frame-1 b1, a mounting hole-1 b2, a conductor ceramic membrane-1 b3, a permeation hole-1 b4, a water outlet pipe-1 b5, a support plate-1 d1, a pressure lever-1 d2, a sliding lever-1 d3, a push rod-1 d4, a water inlet mechanism-1 d5, a flow guide pipe-1 d21, a ring body-1 d51, a valve water sheet-1 d52, a fixed rod-1 d53, a torsion spring-1 d54 and a rubber sealing ring-d 1.
Detailed Description
In order to make the technical means, the original characteristics, the achieved purposes and the effects of the invention easy to understand, the following description and the accompanying drawings further illustrate the preferred embodiments of the invention.
Examples
Referring to fig. 1-6, the present invention provides a high performance proton conductor ceramic membrane reactor, which comprises a reactor 1, a support frame 2, a water discharge pipe 3, a bidirectional water pipe 4, and a water inlet pipe 5, wherein the support frame 2 is installed below the bottom end of the reactor 1, the water discharge pipe 3 is installed at both left and right ends of the reactor 1, the reactor 1 is connected with the water discharge pipe 3 by glue, the bidirectional water pipe 4 is installed on the surface of the reactor 1, the reactor 1 is connected with the bidirectional water pipe 4, the water inlet pipe 5 is installed on the surface of the bidirectional water pipe 4, the bidirectional water pipe 4 and the water inlet pipe 5 are integrated, the reactor 1 is composed of a shell 1a, a conductor ceramic membrane module 1b, a partition board 1c, a back pressure mechanism 1d, and a reaction chamber 1e, partition boards 1c are installed at both upper and lower portions inside the shell 1a, and a conductor ceramic membrane module 1b is installed between the partition board 1c and, the conductor ceramic membrane module is characterized in that the partition plate 1c is movably connected with the conductor ceramic membrane module 1b, a reaction chamber 1e is arranged between the partition plate 1c and the partition plate 1c, a back pressure mechanism 1d is arranged at the top end of the conductor ceramic membrane module 1b, and the conductor ceramic membrane module 1b is matched with the back pressure mechanism 1 d.
The conductor ceramic membrane module 1b comprises a fixed frame 1b1, mounting holes 1b2, conductor ceramic membranes 1b3, permeation holes 1b4 and a water outlet pipe 1b5, wherein the surface of the fixed frame 1b1 is provided with the mounting holes 1b2, the conductor ceramic membranes 1b3 are arranged in the fixed frame 1b1, the fixed frame 1b1 is movably connected with the conductor ceramic membranes 1b3, the water outlet pipe 1b5 is arranged in the middle of the bottom end of the fixed frame 1b1, the fixed frame 1b1 is connected with the water outlet pipe 1b5 through glue, and the permeation holes 1b4 are arranged on the left side and the right side of the fixed frame 1b 1.
The mounting holes 1b2 are used to position and mount the conductor ceramic membrane 1b3 in the fixing frame 1b 1.
The back pressure mechanism 1d comprises a supporting plate 1d1, a pressure lever 1d2, a sliding rod 1d3, a push rod 1d4 and a water inlet mechanism 1d5, sliding rods 1d3 are arranged at the left end and the right end of the supporting plate 1d1, the supporting plate 1d1 is fixedly connected with the sliding rod 1d3, the pressure lever 1d2 is arranged at the middle position of the top end of the supporting plate 1d1, the supporting plate 1d1 is connected with the pressure lever 1d2 through glue, more than two push rods 1d4 are arranged below the bottom end of the supporting plate 1d1, one ends of the supporting plate 1d1 and the push rod 1d4 are connected, and the water inlet mechanism 1d5 is arranged at the other end of the push rod 1d 4.
The sliding bar 1d3 is used to prevent the support plate 1d1 from shaking when moving up and down.
The pressure lever 1d2 and the support plate 1d1 are both internally provided with a draft tube 1d 21.
The water inlet mechanism 1d5 comprises ring body 1d51, valve water piece 1d52, dead lever 1d53, torsional spring 1d54, ring body 1d51 inboard intermediate position on install dead lever 1d53, ring body 1d51 inboard on be equipped with valve water piece 1d52, ring body 1d51 and valve water piece 1d52 swing joint, valve water piece 1d52 be connected through torsional spring 1d54 with dead lever 1d 53.
The bottom end of the ring body 1d51 is provided with a rubber sealing ring d1, and the ring body 1d51 is connected with the rubber sealing ring d1 through glue.
The rubber seal d1 is used to prevent water from leaking upward when the ring body 1d51 slides in the conductor ceramic membrane 1b 3.
The conductor ceramic membrane 1b3 is in sliding fit with the ejector rod 1d4, the supporting plate 1d1 and the partition plate 1c are parallel to each other, and the diameter of the ring body 1d51 is the same as that of the hole in the conductor ceramic membrane 1b 3.
The principle of the invention is as follows: sewage is sent into a bidirectional water pipe 4 from a water inlet pipe 5, the sewage enters a reaction chamber 1e from the bidirectional water pipe 4 for electrolytic reaction, the sewage is subjected to electrolytic decontamination and then enters a conductor ceramic membrane 1b3 from a permeation hole 1b4 for filtration, filtered clean water is discharged to the bottom end of a shell 1a from a water outlet pipe 1b5, the conductor ceramic membrane 1b3 is restrained and protected by a fixed frame 1b1 to avoid shaking of the conductor ceramic membrane 1b3, after the reactor 1 finishes filtration, the water outlet pipe 1b5 is blocked, a small amount of clean water is injected from a hole on a pressure lever 1d2, the clean water is extruded and injected, so that the water pressure flows onto a valve water sheet 1d52 in a ring body 1d51 from a guide pipe 1d21, the valve water sheet 1d52 is extruded by the water pressure to drive a torsion spring 1d54 to be opened, the clean water enters a ceramic membrane filter core in the conductor ceramic membrane 1b3 from the ring body 1d51, and then the pressure lever 1d2 is pushed, so that the pressure lever 1d2 drives the ejector rod 1d4 to move towards the conductor ceramic membrane 1b3 through the supporting frame 2, the ejector rod 1d4 utilizes the fixed lever 1d53 to pull back and seal the valve water sheet 1d52 through the torsion spring 1d54, so that the ejector rod 1d4 drives the valve water sheet 1d52 to extrude clear water, and the clear water removes the foreign matters on the surface of the conductor ceramic membrane 1b 3.
The method for solving the problems comprises the following steps: the reactor 1 utilizes the fixed frame 1b1 to fixedly install and restrain the conductor ceramic membrane 1b3, so that the phenomenon that the conductor ceramic membrane 1b3 shakes is avoided, the conductor ceramic membrane 1b3 is damaged, the back pressure mechanism 1d injects a water source into the conductor ceramic membrane 1b3 through the draft tube 1d21, the back pressure mechanism 1d is matched with the water inlet mechanism 1d5 to extrude water in the conductor ceramic membrane 1b3 out of the reactor, so that the water source drives foreign matters on the surface of the conductor ceramic membrane 1b3 to be discharged from the permeation holes 1b4 on the fixed frame 1b1, and the cleaning is convenient.
While there have been shown and described what are at present considered the fundamental principles of the invention, the essential features and advantages thereof, it will be understood by those skilled in the art that the present invention is not limited by the embodiments described above, which are merely illustrative of the principles of the invention, but rather, is capable of numerous changes and modifications in various forms without departing from the spirit or essential characteristics thereof, and it is intended that the invention be limited not by the foregoing descriptions, but rather by the appended claims and their equivalents.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.
Claims (6)
1. The utility model provides a high performance proton conductor ceramic membrane reactor, its structure includes reactor (1), support frame (2), drain pipe (3), two-way water pipe (4), inlet tube (5), reactor (1) bottom under install support frame (2), reactor (1) about both ends all be equipped with drain pipe (3), reactor (1) and drain pipe (3) glue and connect, reactor (1) be equipped with two-way water pipe (4) on the surface, reactor (1) be connected with two-way water pipe (4), two-way water pipe (4) on the surface inlet tube (5) are equipped with, two-way water pipe (4) and inlet tube (5) structure as an organic whole, its characterized in that:
reactor (1) constitute by casing (1a), conductor ceramic membrane module (1b), baffle (1c), backpressure mechanism (1d), reacting chamber (1e), casing (1a) inside all install baffle (1c) from top to bottom, baffle (1c) and baffle (1c) between be equipped with conductor ceramic membrane module (1b), baffle (1c) and conductor ceramic membrane module (1b) swing joint, baffle (1c) and baffle (1c) between be equipped with reacting chamber (1e), conductor ceramic membrane module (1b) top on be equipped with backpressure mechanism (1d), conductor ceramic membrane module (1b) and backpressure mechanism (1d) cooperate.
2. The high performance proton conductor ceramic membrane reactor of claim 1 wherein: conductor ceramic membrane module (1b) constitute by fixed frame (1b1), mounting hole (1b2), conductor ceramic membrane (1b3), infiltration hole (1b4), outlet pipe (1b5), fixed frame (1b1) be equipped with mounting hole (1b2) on the surface, fixed frame (1b1) inside be equipped with conductor ceramic membrane (1b3), fixed frame (1b1) and conductor ceramic membrane (1b3) swing joint, fixed frame (1b1) bottom intermediate position have outlet pipe (1b5), fixed frame (1b1) and outlet pipe (1b5) glue connection, fixed frame (1b1) the left and right sides all be equipped with infiltration hole (1b 4).
3. The high performance proton conductor ceramic membrane reactor of claim 1 wherein: backpressure mechanism (1d) constitute by backup pad (1d1), depression bar (1d2), slide bar (1d3), ejector pin (1d4), mechanism of intaking (1d5), backup pad (1d1) both ends all be equipped with slide bar (1d3) about, backup pad (1d1) and slide bar (1d3) fixed connection, backup pad (1d1) top intermediate position on be equipped with depression bar (1d2), backup pad (1d1) and depression bar (1d2) gluey connection, backup pad (1d1) bottom have ejector pin (1d4) more than two, backup pad (1d1) and ejector pin (1d4) one end be connected, ejector pin (1d4) other end on install mechanism of intaking (1d 5).
4. The high performance proton conductor ceramic membrane reactor of claim 3 wherein: the pressure lever (1d2) and the support plate (1d1) are both internally provided with a draft tube (1d 21).
5. The high performance proton conductor ceramic membrane reactor of claim 3 wherein: intake mechanism (1d5) constitute by ring body (1d51), valve water piece (1d52), dead lever (1d53), torsional spring (1d54), ring body (1d51) inboard intermediate position on install dead lever (1d53), ring body (1d51) inboard on be equipped with valve water piece (1d52), ring body (1d51) and valve water piece (1d52) swing joint, valve water piece (1d52) be connected through torsional spring (1d54) with dead lever (1d 53).
6. The high performance proton conductor ceramic membrane reactor of claim 5 wherein: the rubber sealing ring (d1) is arranged below the bottom end of the ring body (1d51), and the ring body (1d51) is connected with the rubber sealing ring (d1) in a gluing mode.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911149429.6A CN111003758A (en) | 2019-11-21 | 2019-11-21 | High-performance proton conductor ceramic membrane reactor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911149429.6A CN111003758A (en) | 2019-11-21 | 2019-11-21 | High-performance proton conductor ceramic membrane reactor |
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| Publication Number | Publication Date |
|---|---|
| CN111003758A true CN111003758A (en) | 2020-04-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911149429.6A Withdrawn CN111003758A (en) | 2019-11-21 | 2019-11-21 | High-performance proton conductor ceramic membrane reactor |
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| Country | Link |
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| CN (1) | CN111003758A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113415858A (en) * | 2021-07-23 | 2021-09-21 | 广西碧清源环保投资有限公司 | Ceramic membrane and filtration system with electrolysis function |
-
2019
- 2019-11-21 CN CN201911149429.6A patent/CN111003758A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113415858A (en) * | 2021-07-23 | 2021-09-21 | 广西碧清源环保投资有限公司 | Ceramic membrane and filtration system with electrolysis function |
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Application publication date: 20200414 |