CN110994078B - Magnesium tourmaline ion hair battery - Google Patents
Magnesium tourmaline ion hair battery Download PDFInfo
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- CN110994078B CN110994078B CN201911154182.7A CN201911154182A CN110994078B CN 110994078 B CN110994078 B CN 110994078B CN 201911154182 A CN201911154182 A CN 201911154182A CN 110994078 B CN110994078 B CN 110994078B
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- 239000011777 magnesium Substances 0.000 title claims abstract description 54
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 48
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 229910052613 tourmaline Inorganic materials 0.000 title claims abstract description 36
- 239000011032 tourmaline Substances 0.000 title claims abstract description 36
- 229940070527 tourmaline Drugs 0.000 title claims abstract description 36
- 238000010248 power generation Methods 0.000 claims abstract description 34
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 18
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 18
- 239000011707 mineral Substances 0.000 claims abstract description 18
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 5
- 239000010439 graphite Substances 0.000 claims abstract description 5
- 229920000642 polymer Polymers 0.000 claims abstract description 4
- 230000005611 electricity Effects 0.000 claims description 12
- 229910000245 dravite Inorganic materials 0.000 claims description 8
- 229910000861 Mg alloy Inorganic materials 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229940037003 alum Drugs 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 238000013473 artificial intelligence Methods 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 229910021389 graphene Inorganic materials 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 210000002768 hair cell Anatomy 0.000 claims 7
- 210000004027 cell Anatomy 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 150000002500 ions Chemical class 0.000 abstract description 17
- 229910052751 metal Inorganic materials 0.000 abstract description 9
- 239000002184 metal Substances 0.000 abstract description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 abstract description 7
- 239000001301 oxygen Substances 0.000 abstract description 7
- 238000006479 redox reaction Methods 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- 239000011149 active material Substances 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000002360 explosive Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009440 infrastructure construction Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910006016 Si6O18 Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000009429 distress Effects 0.000 description 1
- 230000009189 diving Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000010437 gem Substances 0.000 description 1
- 229910001751 gemstone Inorganic materials 0.000 description 1
- IDIJOAIHTRIPRC-UHFFFAOYSA-J hexaaluminum;sodium;2,2,4,4,6,6,8,8,10,10,12,12-dodecaoxido-1,3,5,7,9,11-hexaoxa-2,4,6,8,10,12-hexasilacyclododecane;iron(2+);triborate;tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Fe+2].[Fe+2].[Fe+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-][Si]1([O-])O[Si]([O-])([O-])O[Si]([O-])([O-])O[Si]([O-])([O-])O[Si]([O-])([O-])O[Si]([O-])([O-])O1 IDIJOAIHTRIPRC-UHFFFAOYSA-J 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 229910000246 schorl Inorganic materials 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
- H01M12/065—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode with plate-like electrodes or stacks of plate-like electrodes
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
Abstract
The invention relates to the technical field of metal power generation, in particular to a magnesium tourmaline ion power generation battery. Comprises a carbon layer, a mineral layer (tourmaline) and a magnesium layer which are integrally connected in the form of a high polymer battery. The cathode (namely a magnesium plate) for releasing and absorbing ions and the anode (graphite) for taking oxygen existing in the air as active materials are subjected to oxidation-reduction reaction at the cathode, and chemical energy generated by the oxidation-reduction reaction is converted into electric energy and output, so that the problems of wind energy, water energy and solar energy of the existing renewable energy sources are solved, and the solar energy generating device has the advantages of environmental protection, high-performance generating efficiency, non-explosive stability and economy, and is a new generation of future energy.
Description
Technical Field
The invention relates to the technical field of metal power generation, in particular to a magnesium tourmaline ion power generation battery.
Background
Electrical energy refers to the ability to use electricity to perform work in various forms (i.e., produce energy). The electric energy is an economic, practical, clean and easily controlled and converted energy form, and is a special product (which also has a plurality of characteristics of the product, such as measurable, estimated, guaranteed or improved) which is provided by three parties to guarantee the quality to the power users by the power department.
The electric energy is widely applied to various fields such as power, illumination, chemistry, spinning, communication, broadcasting and the like, and is the main power for scientific and technical development and people's economic leap. Electrical energy plays a significant role in our lives.
The electric energy used in daily life mainly comes from conversion of other forms of energy, including water energy (hydroelectric power generation), heat energy (thermal power generation), atomic energy (nuclear power generation), wind energy (wind power generation), chemical energy (battery), light energy (photovoltaic cell, solar cell, etc.), and the like. However, most of the energy conversion modes are large-scale equipment, a large amount of manpower and material resources are consumed for infrastructure construction, power grid construction is also needed for centralized power supply, and many severe places are limited by resources, environments and funds and cannot be electrified, so that the local development is hindered.
Disclosure of Invention
The invention aims to solve the technical problems that most of the existing power generation modes are large-scale equipment, a large amount of manpower and material resources are consumed for infrastructure construction, power grid construction is also needed for centralized power supply, and many severe places are limited by resources, environments and funds and cannot be electrified, so that the local development is hindered.
In order to solve the problems, the magnesium tourmaline ion power generation cell is provided, a negative electrode (namely a magnesium plate) for releasing and absorbing ions and an anode (graphite) which takes oxygen existing in the air as an active material are utilized, oxidation-reduction reaction is carried out at the negative electrode, chemical energy generated by the oxidation-reduction reaction is converted into electric energy and is output, the problems of wind energy, water energy and solar energy of the existing renewable energy sources are solved, and the magnesium tourmaline ion power generation cell has the advantages of environmental protection, high performance power generation efficiency, non-explosion stability and economy and is a new generation of future energy.
There are three materials with their own energy in the matter present on the earth. The first is "uranium ore" from which radiation is emitted, the second is "magnetite", and the third is Tourmaline (Tourmaline). The "uranium ore" emits very strong radioactive rays and cannot use the raw stone any more, but the "magnetite" has the magnetite property, namely magnetic force, and can be reasonably used, for example, permanent electric energy is possessed, while the third tourmaline which has weak energy and is a gem tending to be absorbed is used in the invention. The chemical general formula of the tourmaline is as follows: XY3Z6[Si6O18](BO3)3(OH)4(ii) a Wherein the position of X is mainly occupied by Na, Ca and K; the Y position is mainly occupied by Mg, Fe, A1 and Li; the position of Z is predominantly occupied by a 1; due to the replacement of the X, Y, Z position and the difference of the forming environment, a plurality of tourmaline species are formed. When Y is mainly Mg, it is called dravite, when Fe is mainly, it is called ferrotourmaline or schorl, and when Mn enters this position, it is called nathmenite. When the tourmaline is mainly Li + Al, the tourmaline is called lithium tourmaline. In lithium tourmaline, part of the OH is often replaced by F.
In order to achieve the purpose, the invention is realized by the following technical scheme: a magnesium tourmaline ion power generation battery is characterized in that a metal negative electrode and a mineral crystal film layer are subjected to oxidation reaction to generate electrons, oxygen is supplied from the outside in an air anode, and reduction reaction is generated, so that electric energy is generated. The composite power generation device comprises a carbon layer, a mineral layer and a magnesium layer which are integrally connected in a high polymer battery (namely, the layers are sequentially overlapped and combined), so that the composite power generation and the replacement of the fault leakage are facilitated. Wherein, the magnesium layer is used as a negative electrode and is used for providing a metal material for reaction; the mineral layer is used for slowly providing oxygen, so that a low-speed oxidation-reduction reaction is realized, and long-term power generation is ensured; the carbon layer is used as the anode, so that the size of the electrode plate can be reduced, and the power generation efficiency is improved.
The voltage generated by reacting several metals with oxygen under the same conditions is as follows (in terms of average generated 0.04A current):
Li≥3.04V，Mg＝2.37V，Al≥1.66V，Zn≥0.76V，Fe≥0.44V，H≥0V，Hg≥-0.24V，Cu≥0.34V，Ag≥1.69V。
from the above data, it can be seen that Mg or Al alloys are ideal metal fuels in terms of the magnitude of the voltage produced, and cost. And the specific voltage and current values can be adjusted by adjusting the size and the number of the metal of the electrode plate, the area of the contact surface and the like.
Furthermore, each electrode plate in the magnesium tourmaline ion hair battery has the size of 5 cm in width multiplied by 10 cm in length, the thickness of a magnesium layer of 0.3 cm, a mineral layer of 0.5 cm and a carbon layer of 0.3 cm in water layer.
Further, the magnesium layer is made of magnesium or a magnesium alloy.
Further, the magnesium layer is made of magnesium alloy, and the ratio of the Mg to the Cr to the Ni is 100-61: 10-0: 7.
Further, the carbon layer is made of graphite plates or graphene.
Further, the mineral layer mainly comprises tourmaline and borax (Na)2B4O7·10H2O) and alum (KAL (SO)4)2·12H2O); wherein tourmaline is XY9B3Si6O27(O,OH,F)4X is Ca, Na, K and Mn, and Y is Mg, Fe, Al, Cr, Mn, Ti and Li.
Further, the manufacturing method of the mineral layer comprises the following steps: mixing the above materials, heating at 30-2300 deg.C, and sandwiching between carbon layer and magnesium layer.
Furthermore, the electrode plates of the magnesium tourmaline ion power generation cell are connected in series through a series layer, the series layer is made of stainless steel or copper, and voltage and current are combined together.
Further, the magnesium tourmaline ion power generation battery is stored and used in a variable voltage mode through a charging system.
Furthermore, the power generation device utilizing the magnesium tourmaline ion power generation battery is controlled by an artificial intelligence prediction control system, and when the charged electricity is consumed, the power can be recharged by automatic prediction so as to realize sustainable electricity utilization.
The invention has the beneficial effects that:
(1) the electric energy generated in the process of potential difference ionization for producing hydrogen by using oxidation-reduction reaction does not need to supplement an input power supply, can be used in areas without electric energy, has wide application range, and can be used for emergency situations such as mobile phone chargers (power generation packs), notebook computer batteries, natural disasters and the like, situations such as distress in remote areas (water and electricity are supplied simultaneously), small-sized generators, marine generators/diving equipment, generators for electric vehicles/motorcycles, household generators, industrial generators and the like.
(2) The metal loss of the reaction is slow, the metal can be continuously used for more than 2 to 30 years, the cost is low, and the efficiency is high.
(3) When in use, the device can be used without starting and switching on, and is more convenient and fast.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below. It is obvious that the drawings in the following description are some embodiments of the invention, and that for a person skilled in the art, other drawings can be derived from them without inventive effort.
FIG. 1 is a schematic diagram of the electrode plate structure of the present invention;
FIG. 2 is a schematic diagram of a series configuration of electrode plates of the present invention;
in the figure, a carbon layer 1, a mineral layer 2, a magnesium layer 3 and a series layer 4.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
a magnesium tourmaline ion power generation battery is characterized in that a metal negative electrode and a mineral crystal film layer are subjected to oxidation reaction to generate electrons, oxygen is supplied from the outside in an air anode, and reduction reaction is generated, so that electric energy is generated. The combined power generation device comprises a carbon layer 1, a mineral layer 2 and a magnesium layer 3 which are integrally connected in a high polymer battery (namely, the layers are sequentially overlapped and combined), so that combined power generation and replacement of fault and leakage are facilitated. Wherein, the magnesium layer is used as a negative electrode and is used for providing a metal material for reaction; the mineral layer is used for slowly providing oxygen, so that a low-speed oxidation-reduction reaction is realized, and long-term power generation is ensured; the carbon layer is used as the anode, so that the size of the electrode plate can be reduced, and the power generation efficiency is improved.
Each electrode plate in the magnesium tourmaline ion hair battery has the size of 5 cm in width multiplied by 10 cm in length, the thickness of 0.3 cm of a magnesium layer, 0.5 cm of a mineral layer and 0.3 cm of a carbon layer water layer.
The magnesium layer is made of magnesium.
The carbon layer is made of graphite plates.
The mineral layer mainly comprises tourmaline and borax (Na)2B4O7·10H2O) and alum (KAL (SO)4)2·12H2O); wherein tourmaline is XY9B3Si6O27(O,OH,F)4X is Ca, Na, K and Mn, and Y is Mg, Fe, Al, Cr, Mn, Ti and Li.
The manufacturing method of the mineral layer comprises the following steps: mixing the above materials, heating at 30-2300 deg.C, and sandwiching between carbon layer and magnesium layer.
Example 2:
the magnesium layer is made of magnesium alloy, and the ratio of Mg to Cr to Ni is 100-61: 10-0: 7.
The rest is the same as in example 1.
Example 3:
the carbon layer is made of graphene, so that the volume and the weight of the battery can be reduced, and the application range is expanded (for example, the carbon layer can be made into a chip form, and is more convenient and faster).
The rest is the same as in example 1.
Example 4:
the electrode plates of the magnesium tourmaline ion hair battery are connected in series through a series layer 4, the series layer is made of stainless steel or copper, and voltage and current are combined together.
The rest is the same as in example 1.
Wherein, a group of electrode plates can generate electricity of 1.8V and 0.02A, and 130 series-connected groups of 234V and 2.6A, which are about 600W in total, and by analogy, 2000 series-connected groups can realize the electricity generation of about 72 KW.
Example 5:
the magnesium tourmaline ion power generation battery is stored and used in a variable voltage mode through a charging system.
The rest is the same as in example 1.
Example 6:
the power generation device utilizing the magnesium tourmaline ion power generation cell is controlled by an artificial intelligence prediction control system, and when the charged electricity is consumed, the electricity can be recharged by automatic prediction so as to realize sustainable electricity utilization.
The rest is the same as in example 1.
Claims (8)
1. A magnesium tourmaline ion hair battery is characterized in that: comprises a carbon layer, a mineral layer and a magnesium layer which are integrally connected in the form of a high polymer battery; the electrode plates of the magnesium tourmaline ion power generation cell are connected in series through a series layer 4, and the series layer is made of stainless steel or copper;
the mineral layer mainly comprises tourmaline, borax and alum; wherein tourmaline is XY9B 3Si 6O27(O, OH, F)4, X is Ca, Na, K, Mn, Y is Mg, Fe, Al, Cr, Mn, Ti, Li.
2. The dravite ion hair cell of claim 1, characterized in that: each electrode plate has a width of 5 cm x a length of 10 cm, a thickness of 0.3 cm for the magnesium layer, 0.5 cm for the mineral layer, and 0.3 cm for the carbon layer.
3. The dravite ion hair cell of claim 1, characterized in that: the magnesium layer is made of magnesium or a magnesium alloy.
4. The dravite ion hair cell of claim 1 or 3, characterized in that: the magnesium layer is made of magnesium alloy, and the ratio of Mg to Cr to Ni is 100-61: 10-0: 7.
5. The dravite ion hair cell of claim 1, characterized in that: the carbon layer is made of graphite plates or graphene.
6. The dravite ion hair cell of claim 1, characterized in that: the preparation method of the mineral layer comprises the following steps: mixing the raw materials, heating at 30-2300 deg.C, and sandwiching between carbon layer and magnesium layer.
7. The dravite ion hair cell of claim 1, characterized in that: the magnesium tourmaline ion power generation battery is stored and used in a variable voltage mode through a charging system.
8. The dravite ion hair cell of claim 1, characterized in that: the power generation device utilizing the magnesium tourmaline ion power generation cell is controlled by an artificial intelligence prediction control system, and when the charged electricity is consumed, the electricity can be recharged by automatic prediction so as to realize sustainable electricity utilization.
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| CN103715433A (en) * | 2013-12-12 | 2014-04-09 | 大连理工大学 | Preparation method and application of tourmaline-polyaniline combined electrode |
| CN105874642A (en) * | 2013-12-27 | 2016-08-17 | 索尼公司 | Battery, electrolyte, battery pack, electronic device, electric vehicle, electricity-storage device, and power system |
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| TW200532977A (en) * | 2004-03-29 | 2005-10-01 | Chien-Kuo Liu | A battery with high activity |
| KR101535051B1 (en) * | 2015-01-08 | 2015-07-08 | 임형진 | Process for recycling waste battery |
| CN106981674A (en) * | 2016-01-18 | 2017-07-25 | 李坚 | A kind of water fuel cell Hydrogen Energy generator and its method for generating |
| CN108808174A (en) * | 2018-06-29 | 2018-11-13 | 潘仁忠 | A kind of magnesium metal-air battery |
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| CN103715433A (en) * | 2013-12-12 | 2014-04-09 | 大连理工大学 | Preparation method and application of tourmaline-polyaniline combined electrode |
| CN105874642A (en) * | 2013-12-27 | 2016-08-17 | 索尼公司 | Battery, electrolyte, battery pack, electronic device, electric vehicle, electricity-storage device, and power system |
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