CN110981446A - Volume-stable high-temperature bedplate and manufacturing method thereof - Google Patents

Volume-stable high-temperature bedplate and manufacturing method thereof Download PDF

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Publication number
CN110981446A
CN110981446A CN201911274596.3A CN201911274596A CN110981446A CN 110981446 A CN110981446 A CN 110981446A CN 201911274596 A CN201911274596 A CN 201911274596A CN 110981446 A CN110981446 A CN 110981446A
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temperature
micropowder
equal
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bedplate
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CN110981446B (en
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王立平
王理达
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Jiangsu Sanheng Hi Tech Kiln Funiture Co ltd
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Jiangsu Sanheng Hi Tech Kiln Funiture Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C04B35/101Refractories from grain sized mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232Titanium oxides or titanates, e.g. rutile or anatase
    • C04B2235/3234Titanates, not containing zirconia
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite

Abstract

A volume stable high temperature platen, in the field of refractory kiln furniture preparation, use sintered corundum, electrofused mullite granule as aggregate, introduce the aluminium titanate composite phase material in the substrate and fire and get final product through high temperature, the platen made can guarantee the high temperature strength and good thermal shock property requirement used of the platen, can obviously improve the volume stability of the platen in addition, through testing after long-time circulation under the service environment, the dimensional change of the propulsion direction is less than or equal to 0.5%.

Description

Volume-stable high-temperature bedplate and manufacturing method thereof
Technical Field
The invention belongs to the field of refractory kiln furniture preparation, and particularly relates to a volume-stable high-temperature bedplate and a manufacturing method thereof.
Background
The bedplate, also called push plate or moving plate, is a key part for carrying the propelling operation of products in the push plate kiln, not only needs to meet the high-temperature atmosphere condition of sintering, but also needs a thin bedplate (generally with the thickness of only 30mm) to bear the pressure of 20-30 kg/plate and transmit the propelling extrusion force of the burnt products for a long distance (about 30M), and the bedplate can bear the constantly changing impact of high and low temperature (once circulating in the furnace every 20-30 h) caused by long-term circulation from room temperature → high temperature → room temperature), and has long service life. When the push plate is used, if only one push plate is broken, falls off and climbs the plate, is bonded or deforms, the push plate can cause a serious accident that the push plate cannot be continuously pushed and is forced to be stopped for carrying out the top turning treatment, and great economic loss is caused to a user. Therefore, the bedplate not only needs to have excellent high-temperature resistance and wear resistance, and better thermal shock resistance stability and volume stability, but also needs not to pollute a fired product, ensures the consistency of the bedplate, and has extremely high requirements on the comprehensive performance of the bedplate.
At present, mullite platens are usually used in the market, platens made of other materials such as cordierite and corundum are not suitable for expansion due to low refractoriness, and silicon carbide is not suitable for expansion due to oxidation resistance in an oxidizing atmosphere, for example, a push plate for a nitrogen kiln sintered by soft magnetic ferrite of Chinese patent CN1796465 comprises, by weight, 0.5-3mm 40-45% of electrofused mullite, 0.06-0.5mm 5-8%, less than 0.04mm 18-22%, 0.5-3mm 8-12% of tabular corundum, 0.06-0.5mm 1-3% of electrofused white corundum, α -alumina less than 0.045mm 10-14%, less than 4um 4-6%, 2-4% of silica powder and 8-9% of silica-alumina gel, and the soft magnetic ferrite sintered nitrogen kiln is suitable for being used in a nitrogen kiln below 1450 ℃, and the temperature and the requirements of the push plate are different from those of the present patent, and the present invention is greatly different from that of the present patent.
Chinese patent CN201410809937.3 is a high-performance modified mullite high-temperature platen and a preparation process thereof, wherein the weight percentages of the modified mullite high-temperature platen are that fused mullite is less than or equal to 3mm and 40-50%, tabular corundum is less than or equal to 3mm and less than or equal to 3-35%, α -alumina is less than or equal to 320 meshes and 12-20%, spinel is less than or equal to 200 meshes and 3-5%, kaolin is less than or equal to 200 meshes and 7-10%, and a lanthanum oxide and yttrium oxide composite rare earth additive is less than or equal to 1um and 0.5-1%, and the mass ratio of yttrium oxide to lanthanum oxide in the lanthanum oxide and yttrium oxide composite rare earth additive is 1: 0.05-0.3.
Disclosure of Invention
The invention aims to provide a volume-stable high-temperature bedplate, which is a key part for pushing and operating various electronic materials and special ceramic products with the temperature below 1600 ℃ to be sintered in a push-plate kiln as a bearing product, and is mainly characterized in that an aluminum titanate material with low expansion coefficient, high thermal shock resistance and excellent thermal shock resistance is introduced into the field of bedplate kiln furniture, and the introduced aluminum titanate material is subjected to composite second phase doping modification, so that the problem of high temperature instability of the aluminum titanate material at 800-1300 ℃ is effectively solved, namely, a small amount of silicon oxide and mullite micropowder is added into the composite refractory material system, a stable solid solution is formed under high-temperature firing, the crystalline phase of the formed solid solution has a decisive effect on inhibiting the high-temperature decomposition of the main crystalline phase of aluminum titanate, the volume stability of a composite material product can be ensured, meanwhile, the mullite composite second phase formed by the reaction in the solid solution can improve the high-temperature strength and the high-temperature thermal shock resistance of the composite material.
The bedplate which is made by using sintered corundum and fused mullite particles as aggregates and introducing an aluminum titanate composite phase material into a matrix and firing at high temperature can meet the requirements of high-temperature strength and good thermal shock property in use, and can also obviously improve the volume stability of the bedplate, and the size change in the pushing direction is less than or equal to 0.5 percent after long-time circulation in a use environment.
The method is implemented specifically as follows: a volume-stable high-temperature bedplate is characterized by comprising the following raw materials in percentage by mass:
30-40% of sintered corundum with the thickness of 1-3 mm
0.3-1 mm 10-20% of electrically-fused mullite particles
α -alumina micropowder is less than or equal to 0.045mm and 15-25%
The content of the electrically fused mullite micro powder is less than or equal to 0.045mm and is 10-20%
The aluminum titanate micro powder is less than or equal to 0.063mm and is 10-20%
The content of the silicon dioxide micro powder is less than or equal to 0.045mm < 2 > -6%
5-10% of kaolin with the diameter less than or equal to 0.063 mm.
The manufacturing method of the volume stable type high temperature bedplate comprises the steps of firstly, adding 0.1% of polyvinyl alcohol organic binder aqueous solution on the electric melting mullite micro powder, the aluminum titanate micro powder and the silicon dioxide micro powder on a ball mill according to the proportion, performing ball milling to prepare slurry, performing dry powder granulation, adding the sintered corundum, the electric melting mullite particles, the α -alumina micro powder and the kaolin into a V-shaped mixer according to the mass percentage, adding the granulated material into the mixer, uniformly mixing, sealing and ageing for 30-48 hours, performing pressure molding on a large-tonnage press, drying, and then performing high temperature sintering to prepare the volume stable type high temperature bedplate.
The main reason for causing the damage of the high-temperature bedplate is the contradiction between the thermal shock resistance and the mechanical strength, and the bad thermal shock resistance can cause the bedplate to crack or break and damage due to the cold and hot cyclic impact which cannot start cold and hot sudden change; the mechanical strength is not enough, delamination, chipping and stripping can be generated under the alternate firing environment, and the bedplate can be cracked or broken seriously; in addition, poor volume stability of the high-temperature bedplate is also a main reason for short service life of the high-temperature bedplate; on the basis of fully mastering the main reasons of the bedplate, such as the use environment requirement, the damage and the short service life, the invention introduces the aluminum titanate material and critically introduces the doping modification of the composite second phase of the aluminum titanate material to form a stable solid solution under high-temperature sintering, so that the volume stability of a composite material product can be ensured, and simultaneously, the high-temperature strength and the high-temperature thermal shock resistance of the composite material can be improved by the mullite composite second phase formed by the reaction in the solid solution.
Detailed Description
Example 1
A volume stable high temperature bedplate is composed of, by mass, 1-3 mm 40% of sintered corundum, 0.3-1 mm 14% of fused mullite particles, α -less than or equal to 0.045mm15% of alumina micropowder, less than or equal to 0.045mm10% of fused mullite micropowder, less than or equal to 0.063mm 14% of aluminum titanate micropowder, less than or equal to 0.045mm 2% of silica micropowder, less than or equal to 0.063mm 5%, the fused mullite micropowder, the aluminum titanate micropowder and the silica micropowder are firstly added to a ball mill according to a ratio, 0.1% of polyvinyl alcohol aqueous solution is added for ball milling for about 8 hours to prepare slurry, then dry powder granulation is carried out for standby, then the sintered corundum, the fused mullite particles, α -alumina micropowder and kaolin are added to a V-type high temperature kiln according to mass percent, the granulated material is added to the mixer for about 24 hours, the confined ageing is carried out for 30-48 hours, the sintered corundum, the pushed to a 152 times of a track in a kiln is used, the track can be pushed in a high temperature kiln, the push plate can be used, the push plate is pushed, the slab can not be cracked, and the slab has the requirements of long service life and the slab is controlled within a long service life and the slab is not to be peeled off.
Example 2
A volume-stable high-temperature bedplate is composed of, by mass, 1-3 mm 30% of sintered corundum, 0.3-1 mm10% of fused mullite particles, α -less than or equal to 0.045mm 17% of alumina micropowder, less than or equal to 0.045mm15% of fused mullite micropowder, less than or equal to 0.063mm 12% of aluminum titanate micropowder, less than or equal to 0.045mm 6% of silica micropowder, less than or equal to 0.063mm 10%, the fused mullite micropowder, the aluminum titanate micropowder and the silica micropowder are firstly added into a ball mill according to a ratio, 0.1% of polyvinyl alcohol aqueous solution is added for ball milling for about 8 hours to prepare slurry, then dry powder granulation is carried out, and then dry powder granulation is carried out for standby application, the sintered corundum, the fused mullite particles, α -alumina micropowder and kaolin are added into a V-type high-temperature kiln, the granulated material is added into a mixer according to a mass percentage, uniformly mixed for about 24 hours, the confined ageing is carried out for 30-shaping on a large-tonnage press, drying is carried out, the high-temperature kiln is used, 145 times of the push plate is pushed into a mixing kiln, the contact track is pushed, the high-temperature-resistant cracking, the service life is controlled within a long service life and the range of the small-resistant thermal shock.
Example 3
A volume-stable high-temperature bedplate is composed of, by mass, 1-3 mm 32% of sintered corundum, 0.3-1 mm12% of fused mullite particles, α -16% of alumina micropowder not more than 0.045mm, 20% of fused mullite micropowder not more than 0.045mm, 10% of aluminum titanate micropowder not more than 0.063mm, 4% of silica micropowder not more than 0.045mm and 6% of kaolin not more than 0.063mm, the fused mullite micropowder, the aluminum titanate micropowder and the silica micropowder are firstly added into a ball mill according to a ratio, 0.1% of polyvinyl alcohol aqueous solution is added for ball milling for about 8 hours to prepare slurry, then dry powder granulation is carried out for standby application, the sintered corundum, the fused mullite particles, α -alumina micropowder and the kaolin are added into a V-type high-temperature kiln according to mass percent, then the granulated material is added into a mixer for about 24 hours, the confined ageing is carried out for 30-48 hours, the sintered corundum, the push plate is tested in a high-temperature kiln at 1600 ℃, the track can be pushed for about 158 times, the track can be used in a good contact direction, the high-temperature-resistant cracking and the thermal shock-resistant cracking, and the service life of the slab is controlled by a long service life.
Example 4
A volume-stable high-temperature bedplate is composed of, by mass, 1-3 mm 31% of sintered corundum, 0.3-1 mm20% of fused mullite particles, α -16% of alumina micropowder not more than 0.045mm 16%, 12% of fused mullite micropowder not more than 0.045mm, 13% of aluminum titanate micropowder not more than 0.063mm 13%, less than 0.045mm 3% and less than 0.063mm 5% of kaolin, the fused mullite micropowder, the aluminum titanate micropowder and the silicon dioxide micropowder are firstly added into a ball mill according to a ratio, 0.1% of polyvinyl alcohol aqueous solution is added for ball milling for about 8 hours to prepare slurry, then dry powder granulation is carried out for standby application, the sintered corundum, the fused mullite particles, α -alumina micropowder and kaolin are added into a V-type high-temperature kiln according to mass percent, the granulated material is added into a mixer for about 24 hours, the confined ageing is carried out for 30-48 hours, drying is carried out, and sintering is carried out by a high-tonnage press, 165-time kiln, the push plate can be used in a kiln, the push plate can be pushed into a mixing kiln, the direction, the kiln, the track can not fall in a good-resistant and the cracking and the long-resistant cracking and the thermal shock-cracking can not fall within the range of the requirement of 0.5% of the.
Example 5
A volume-stable high-temperature bedplate is composed of, by mass, 1-3 mm 31% of sintered corundum, 0.3-1 mm12% of fused mullite particles, α -less than or equal to 0.045mm 25% of alumina micropowder, less than or equal to 0.045mm13% of fused mullite micropowder, less than or equal to 0.063mm 10% of aluminum titanate micropowder, less than or equal to 0.045mm 3% of silica micropowder, less than or equal to 0.063mm 6%, the fused mullite micropowder, the aluminum titanate micropowder and the silica micropowder are firstly added into a ball mill according to a ratio, 0.1% of polyvinyl alcohol aqueous solution is added for ball milling for about 8 hours to prepare slurry, then dry powder granulation is carried out, and then dry powder granulation is carried out for standby application, the sintered corundum, the fused mullite particles, α -alumina micropowder and kaolin are added into a V-type high-temperature kiln according to mass percentage, the granulated material is added into a mixer for about 24 hours, the closed ageing is carried out for 30-molding on a large-tonnage press, drying is carried out, and sintering is carried out in a high-temperature kiln, 166 times of the push plate can be used, the push plate can be pushed into a mixing kiln, the direction, the kiln, the size of the track can be pushed, the track can not fall within the range of the stable.
Example 6
A volume-stable high-temperature bedplate is composed of, by mass, 1-3 mm 34% of sintered corundum, 0.3-1 mm12% of fused mullite particles, α -less than or equal to 0.045mm15% of alumina micropowder, less than or equal to 0.045mm11% of fused mullite micropowder, less than or equal to 0.063mm 20% of aluminum titanate micropowder, less than or equal to 0.045mm 3% of silica micropowder, less than or equal to 0.063mm 5% of kaolin, the fused mullite micropowder, the aluminum titanate micropowder and the silica micropowder are firstly added into a ball mill according to a ratio, 0.1% of polyvinyl alcohol aqueous solution is added for ball milling for about 8 hours to prepare slurry, then dry powder granulation is carried out, and then the slurry is prepared for standby after dry powder granulation, the sintered corundum, the fused mullite particles, α -alumina micropowder and the kaolin are added into a V-type high-temperature kiln, the granulated material is added into a mixer according to be uniformly mixed for about 24 hours, the confined ageing is carried out, the slab can be used in a kiln with a high-temperature, a track can be pushed for 162 times, the slab can not be used in a kiln with good contact and the requirements of long service life and no spalling or thermal shock can be generated, and the slab is not be peeled off.

Claims (2)

1. A volume-stable high-temperature bedplate is characterized by comprising the following raw materials in percentage by mass:
30-40% of sintered corundum with the thickness of 1-3 mm
0.3-1 mm 10-20% of electrically-fused mullite particles
α -alumina micropowder is less than or equal to 0.045mm and 15-25%
The content of the electrically fused mullite micro powder is less than or equal to 0.045mm and is 10-20%
The aluminum titanate micro powder is less than or equal to 0.063mm and is 10-20%
The content of the silicon dioxide micro powder is less than or equal to 0.045mm < 2 > -6%
5-10% of kaolin with the diameter less than or equal to 0.063 mm.
2. The method for manufacturing a volume-stable high-temperature bedplate according to claim 1, wherein the method comprises the steps of ball-milling the electrofused mullite micropowder, the aluminum titanate micropowder and the silica micropowder on a ball mill in proportion and adding 0.1% of polyvinyl alcohol organic binder aqueous solution to prepare slurry, performing dry powder granulation, adding the sintered corundum, the electrofused mullite particles, α -alumina micropowder and kaolin into a V-shaped mixer according to mass percentage, adding the granulated material into the mixer, uniformly mixing, sealing and ageing for 30-48 hours, performing pressure molding on a large-tonnage press, drying, and then performing high-temperature firing to obtain the volume-stable high-temperature bedplate.
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CN114380580A (en) * 2021-12-29 2022-04-22 北京金隅通达耐火技术有限公司 Corundum heat-resistant concrete with low ablation rate and preparation method and application thereof
CN114380607A (en) * 2022-01-26 2022-04-22 郑州金河源耐火材料有限公司 Corundum-mullite gel composite wear-resistant castable and preparation method thereof
CN116496079A (en) * 2023-03-21 2023-07-28 河南竹林庆州耐火材料有限公司 Preparation method of low-carbon production refined mullite corundum high-temperature material

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CN114133227A (en) * 2021-12-08 2022-03-04 湖南仁海科技材料发展有限公司 Long-life wire laying plate and preparation method thereof
CN114380580A (en) * 2021-12-29 2022-04-22 北京金隅通达耐火技术有限公司 Corundum heat-resistant concrete with low ablation rate and preparation method and application thereof
CN114380607A (en) * 2022-01-26 2022-04-22 郑州金河源耐火材料有限公司 Corundum-mullite gel composite wear-resistant castable and preparation method thereof
CN116496079A (en) * 2023-03-21 2023-07-28 河南竹林庆州耐火材料有限公司 Preparation method of low-carbon production refined mullite corundum high-temperature material

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