CN110975138A - Power generation membrane and skin dressing material with same - Google Patents

Power generation membrane and skin dressing material with same Download PDF

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Publication number
CN110975138A
CN110975138A CN201910950882.0A CN201910950882A CN110975138A CN 110975138 A CN110975138 A CN 110975138A CN 201910950882 A CN201910950882 A CN 201910950882A CN 110975138 A CN110975138 A CN 110975138A
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China
Prior art keywords
membrane
water
power generation
soluble material
skin
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CN201910950882.0A
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Chinese (zh)
Inventor
张源炘
沈芳如
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Tuo Jin Creation Ltd By Share Ltd
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Tuo Jin Creation Ltd By Share Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61NELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N1/00Electrotherapy; Circuits therefor
    • A61N1/18Applying electric currents by contact electrodes
    • A61N1/20Applying electric currents by contact electrodes continuous direct currents
    • A61N1/30Apparatus for iontophoresis, i.e. transfer of media in ionic state by an electromotoric force into the body, or cataphoresis
    • A61N1/303Constructional details

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Radiology & Medical Imaging (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Electrotherapy Devices (AREA)
  • Medicinal Preparation (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a power generation membrane, which comprises a membrane body, an electrode material and a water-soluble material. The electrode material is arranged on the membrane body, and the water-soluble material is arranged on the membrane body. The water soluble material comprises an ionic compound. The invention also discloses a skin dressing material.

Description

Power generation membrane and skin dressing material with same
Technical Field
The invention relates to a power generation membrane, in particular to a power generation membrane containing a water-soluble material and a skin dressing containing the power generation membrane.
Background
Skin care products on the market seal local skin and prevent the evaporation of skin moisture, thereby increasing the water content of the skin and improving the skin hydration degree; meanwhile, the temperature of the skin rises, which is beneficial to the penetration of molecules and promotes the absorption of active ingredients to a certain extent. Therefore, some doctors believe that the dressing is equivalent to the package treatment of dermatology, and the absorption of skin care products by the skin can be increased. In addition, some chemicals with ions or charges are absorbed into the human body through the skin, and an ion introduction method (Iontophoresis) can be used for assistance.
In recent years, paper batteries (printed batteries) have been developed rapidly, and are very environmentally friendly due to low contamination of materials used therein, and the simple production process is advantageous for reducing the cost and making it economically competitive with the light and thin profile. The paper battery has the characteristics of a capacitor like a lithium ion battery, and can provide a long-term and stable power output. Therefore, the development of paper batteries (printed batteries) provides another approach to the application of iontophoresis technology.
However, when a paper battery is used to deliver skin care products into the skin by iontophoresis, the energy that can be stored in the paper battery is limited due to its light and thin characteristics, so that the skin care components in the aqueous solution are difficult to move by electrical repulsive force.
In addition, generally, the dressing is soaked in an aqueous solution containing a skin care product during the sale of the dressing, and the dressing is set to have a short shelf life because of the fear of deterioration of the skin care product, which is disadvantageous in terms of improvement of economic competitiveness.
Disclosure of Invention
In view of the above problems, the present invention discloses a power generation membrane and a skin dressing comprising the power generation membrane, which are useful for solving the problems that skin care ingredients are difficult to enter deep layers of skin by an iontophoresis method and the shelf life of products is short.
The invention discloses a power generation membrane, which comprises a membrane body, an electrode material and a water-soluble material. The electrode material is arranged on the membrane body, and the water-soluble material is arranged on the membrane body. The water soluble material comprises an ionic compound.
The skin dressing material disclosed by the invention comprises the power generation membrane.
According to the power generation membrane and the skin dressing material disclosed by the invention, the water-soluble material containing the ionic compound is arranged on the membrane body. When the power generation membrane is soaked by liquid, the water-soluble material is dissolved to increase the conductivity of the liquid, and the water-soluble material of the functional material is favorably fed into the deep layer of the skin together with the functional material through an iontophoresis method. Because the dissolved water-soluble material and the porous channel formed in the membrane body after the water-soluble material is dissolved can improve the conductivity, the power generation membrane does not need to additionally contain a substance for improving the conductivity.
Further, the skin dressing disclosed in the present invention is not soaked in an aqueous solution containing an ionic compound, but is provided with a water-soluble material containing an ionic compound on the film body when the product is sold commercially, and therefore, there is no concern about deterioration of the aqueous solution, which contributes to extension of the shelf life of the skin dressing.
The above description of the present invention and the following description of the embodiments are provided to illustrate and explain the spirit and principles of the present invention and to provide further explanation of the invention as claimed in the appended claims.
Drawings
Fig. 1 is a schematic view of a power generation diaphragm according to a first embodiment of the present invention.
Fig. 2 is a schematic view of a power generation diaphragm according to a second embodiment of the present invention.
Fig. 3 is a schematic view of a power generation diaphragm according to a third embodiment of the present invention.
Fig. 4 is a schematic view of a power generation diaphragm according to a fourth embodiment of the present invention.
Fig. 5 is a schematic view of a power generation diaphragm according to a fifth embodiment of the present invention.
Fig. 6 is a schematic view of a power generation diaphragm according to a sixth embodiment of the present invention.
Fig. 7 is a schematic view of a skin dressing according to a seventh embodiment of the invention.
Fig. 8 is a schematic view of the skin dressing of fig. 7 attached to human skin.
FIG. 9 is a fluorescent image showing the ion introduction effect of the examples and comparative examples of the present invention.
Wherein, the reference numbers:
power generation membranes 1a, 1b, 1c, 1d, 1e, 1f
Skin dressing 2
Liquid 3
Diaphragm bodies 10a, 10b, 10c
First film layer 110
Second film layer 120
Interlayer 130
Porous channel 140
Electrode materials 20a, 20b
The anode particles 210a
Cathode particles 220a
Anode pad 210b
Cathode pad 220b
Water- soluble materials 30a, 30b
Water-soluble material particles 310a
Water-soluble material unit 310b
Functional material 320
Detailed Description
The detailed features and advantages of the present invention are described in detail in the embodiments below, which are sufficient for anyone skilled in the art to understand the technical contents of the present invention and to implement the present invention, and the related objects and advantages of the present invention can be easily understood by anyone skilled in the art according to the disclosure of the present specification, the protection scope of the claims and the attached drawings. The following examples further illustrate aspects of the present invention in detail, but are not intended to limit the scope of the invention in any way.
According to an embodiment of the present invention, a power generation membrane is provided, which includes a membrane body, an electrode material, and a water-soluble material. Fig. 1 is a schematic diagram of a power generation diaphragm according to a first embodiment of the invention. In the present embodiment, the power generating membrane 1a includes a membrane body 10a, an electrode material 20a and a water-soluble material 30 a. The electrode material 20a and the water-soluble material 30a are both disposed on the membrane body 10 a.
The electrode material 20a includes a plurality of electrode material particles, and the electrode material particles include a plurality of anode particles 210a and a plurality of cathode particles 220 a. The anode particles 210a and the cathode particles 220a are dispersed in the membrane body 10 a.
The water-soluble material 30a includes a plurality of water-soluble material particles 310a, and the water-soluble material particles 310a are dispersed in the film body 10 a.
Fig. 2 is a schematic view of a power generation diaphragm according to a second embodiment of the present invention. In the present embodiment, the power generation membrane 1b includes a membrane body 10a, an electrode material 20b, and a water-soluble material 30 a. The electrode material 20b and the water-soluble material 30a are both disposed on the membrane body 10 a. The electrode material 20b includes a plurality of anode pads 210b and a plurality of cathode pads 220 b. The anode pad 210b and the cathode pad 220b are attached to the outer surface of one side of the diaphragm body 10 a.
Fig. 3 is a schematic view of a power generation diaphragm according to a third embodiment of the present invention. In the present embodiment, the power generation membrane 1c includes a membrane body 10a, an electrode material 20a and a water-soluble material 30 b. The electrode material 20a and the water-soluble material 30b are both disposed on the membrane body 10 a. The water-soluble material 30b includes a plurality of sheet-shaped or block-shaped water-soluble material units 310b attached to the outer surface of one side of the film body 10 a.
According to an embodiment of the present invention, the diaphragm body includes a first film layer and a second film layer. Fig. 4 is a schematic view of a power generation diaphragm according to a fourth embodiment of the invention. In the present embodiment, the power generation membrane 1d includes a membrane body 10b, an electrode material 20a and a water-soluble material 30 b. The electrode material 20a and the water-soluble material 30b are both disposed on the membrane body 10 b.
The film body 10b includes a first film 110 and a second film 120.
The electrode material 20a includes a plurality of anode particles 210a and a plurality of cathode particles 220 a. A portion of the anode particles 210a and a portion of the cathode particles 220a are dispersed in the first film 110, and another portion of the anode particles 210a and another portion of the cathode particles 220a are dispersed in the second film 120.
The water-soluble material 30b includes a plurality of sheet-shaped or block-shaped water-soluble material units 310b disposed between the first film 110 and the second film 120. More specifically, the first film 110 and the second film 120 sandwich the water-soluble material unit 310 b.
Fig. 5 is a schematic view of a power generation diaphragm according to a fifth embodiment of the present invention. In the present embodiment, the power generation membrane 1e includes a membrane body 10c, an electrode material 20a, and a water-soluble material 30 b. The electrode material 20a and the water-soluble material 30b are both disposed on the membrane body 10 c. The membrane body 10c further includes an interlayer 130 in addition to the first film layer 110 and the second film layer 120. The interlayer 130 is disposed between the first film layer 110 and the second film layer 120, and the water-soluble material unit 310b of the water-soluble material 30b is disposed in the interlayer 130.
Fig. 6 is a schematic view of a skin dressing according to a sixth embodiment of the invention. In the present embodiment, the power generation membrane 1f includes a membrane body 10c, an electrode material 20a, and a water-soluble material 30 a. The electrode material 20a and the water-soluble material 30a are both disposed on the membrane body 10 c. The membrane body 10c further includes an interlayer 130 disposed between the first film layer 110 and the second film layer 120, in addition to the first film layer 110 and the second film layer 120. The water-soluble material particles 310a of the water-soluble material 30a are dispersed in the interlayer 130.
In the above embodiments, the membrane body is, for example, but not limited to, a sheet-like hydrogel, a nonwoven fabric, a hydrophobic adhesive, or an acrylic adhesive. Examples of hydrophobic binders include, but are not limited to, silicones, polyisobutylene and its derivatives, acrylics, natural rubbers, and combinations thereof. Examples of acrylic binders include, but are not limited to, vinyl (D acetate-acrylate) copolymers. The electrode material is a pure metal or a metal alloy such as, but not limited to, zinc, aluminum, copper, magnesium, manganese, silver, titanium, tin, iron, or alloys of the above metals. The water soluble material comprises ionic compounds such as, but not limited to, hydrochlorides (exemplified by sodium chloride, potassium chloride, lithium chloride, calcium chloride, strontium chloride, magnesium chloride or other hydrochlorides), sodium salts, potassium salts, lithium salts, calcium salts, magnesium salts, strontium salts, hydrofluorides, hydroiodides, hydrobromides, phosphates, citrates, acetates, lactates and borates. In some embodiments, the water-soluble material may contain more than two mutually reactive compositions. For example, the water-soluble material 30a may include carbonate in a solid state as well as carbon dioxide. Further, in the case where the membrane body includes a plurality of film layers, these film layers may be stacked or further bonded to each other by an adhesive.
The power generation membrane disclosed by the invention can be applied to skin dressing materials. Referring to fig. 7 and 8, wherein fig. 7 is a schematic view of a skin dressing according to a seventh embodiment of the invention, and fig. 8 is a schematic view of the skin dressing of fig. 7 attached to human skin. In this embodiment, the skin dressing 2 comprises the power generation membrane 1a described in the first embodiment, and the water-soluble material 30a therein further comprises the functional material 320. The functional material 320 contains an ingredient having a cosmetic or medical effect. In the embodiment, the facial mask is taken as an example of the skin dressing 2, but the invention is not limited thereto. In other embodiments, the skin dressing may be a neck membrane, elbow membrane, leg membrane, or wound dressing.
When the skin dressing 2 is used, the skin dressing 2 is attached to the skin of a human body, and the skin dressing 2 is soaked with a liquid (e.g., water). When the skin dressing 2 is immersed in the liquid, the water-soluble material particles 310a are dissolved in the liquid 3, and the originally non-ionized ionic compound in the water-soluble material particles 310a contacts the liquid 3 to form positively charged ions and negatively charged ions. Due to the potential difference between the power generation membrane 1a and the human skin, the charged ions are driven by the current between the anode particles 210a and the cathode particles 220a to move towards the inside of the human skin, so that the water-soluble material particles 310a and the functional material 320 are effectively transported to the deep layer of the skin by the iontophoresis method.
In addition, after the water-soluble material particles 310a are dissolved in the liquid, the porous channel 140 is formed in the position originally occupied by the water-soluble material particles 310a inside the membrane body 10a, so that the total contact area of the power generation membrane 1a and the liquid is increased, which contributes to increase of conductivity.
The non-ionized ionic compound in the water-soluble material particles may be an ionic compound in a dry state or a gel state. For example, in the embodiment of fig. 1, the water-soluble material particles may be a dry powder; in the embodiment of fig. 3, the water-soluble material unit may be a dry sheet-like body aggregated from powder; in the embodiment of fig. 5, the water-soluble material unit may be a gel sheet.
The functional material may contain a skin care product having a cosmetic effect on human skin or may contain a pharmaceutical ingredient having a therapeutic effect on human skin, for example, the functional material may contain anti-wrinkle agents such as carotenoids, ascorbic acid (vitamin C) and vitamin E and other vitamin preparations, in another embodiment, the water-soluble material may further contain a moisturizer of the type such as vitamin A (retinol), α hydroxy acids, β hydroxy acids (salicylic acid), combination hydroxy acids and polyhydroxy acids, in yet another embodiment, the functional material may further contain hydrolyzed and soluble collagen and other hyaluronic acids, in yet another embodiment, the functional material may further contain an anti-cellulite agent such as aminophylline and others, in yet another embodiment, the functional material may further contain a skin bleaching agent such as retinoic acid, hydroquinone and peroxide and others, in yet another embodiment, the functional material may further contain a skin bleaching agent such as retinoids, phytoalexin, such as retinoids, renin-dependent vasopressive hormone releasing hormone(s), vasopressive hormone releasing hormone, vasopressin, and other active antagonists, vasopressin, and other active antagonists, vasopressin, and other active antagonists, vasopressin, and other active antagonists, vasopressin, E, vasopressin, and other active antagonists, vasopressin, E, and other active antagonists, vasopressin, E, and other active, E, and other active.
In an embodiment, the functional material may further comprise a superabsorbent polymer. Superabsorbent polymers refer to materials that are capable of absorbing and retaining at least about 10 times their weight in body fluids under a pressure of 0.5 psi. The superabsorbent polymer particles may be inorganic or organic cross-linked hydrophilic polymers such as polyvinyl alcohol, polyethylene oxide, cross-linked starch, guar gum, xanthan gum, and other materials known in the art of absorbent article manufacture.
Hereinafter, specific examples of the present invention and comparative examples are provided to further illustrate the efficacy of the present invention.
[ example ]
There is provided a mask (i.e., skin dressing) comprising a power generation membrane having the structure as shown in fig. 1 and a functional material. In the power generation diaphragm, the diaphragm body is a non-woven fabric, the electrode material comprises zinc particles and copper particles, and the water-soluble material comprises sodium chloride. The functional material is vitamin C. When in use, the facial mask is soaked in pure water and then attached to the skin of a human face.
[ comparative example ]
A mask is provided, comprising a power generating membrane and a functional material. The power generation membrane comprises a membrane body and an electrode material, but does not comprise a water-soluble material. The membrane body is non-woven fabric, the electrode material comprises zinc particles and copper particles, and the functional material is vitamin C. When in use, the facial mask is soaked by aqueous solution containing sodium chloride and then is attached to the skin of a human face.
[ Effect of iontophoresis ]
FIG. 9 is a fluorescent image showing the ion implantation effect of the examples and comparative examples of the present invention. The functional materials in the examples and comparative examples were modified with green fluorescent molecules in advance. The masks of the example and comparative examples after being soaked were attached to artificial skin, respectively, and then the depth of vitamin C entering the artificial skin was observed. Referring to fig. 9, fluorescence (white area) can be detected in the deeper skin area by using the wet mask containing water-soluble material, which indicates that the functional material of the embodiment can enter the deeper skin area by the iontophoresis method. Since the water-soluble material dissolved in water is accumulated in the vicinity of the electrode material, resulting in high conductivity of the liquid around the electrode material, the power generation membrane can effectively deliver the water-soluble material together with the functional material into the skin. In addition, the porous channel formed in the membrane body after the water-soluble material is dissolved can enlarge the contact total area of the power generation membrane and the liquid, and also contributes to increasing the conductivity.
In summary, in the power generation membrane and the skin dressing disclosed in the present invention, the water-soluble material containing the ionic compound is disposed on the membrane body. When the power generation membrane is soaked by liquid, the water-soluble material is dissolved to increase the conductivity of the liquid, and the water-soluble material of the functional material is favorably fed into the deep layer of the skin together with the functional material through an iontophoresis method. Because the dissolved water-soluble material and the porous channel formed in the membrane body after the water-soluble material is dissolved can improve the conductivity, the power generation membrane does not need to additionally contain a substance for improving the conductivity.
Further, the skin dressing disclosed in the present invention is not soaked in an aqueous solution containing an ionic compound, but is provided with a water-soluble material containing an ionic compound on the film body when the product is sold commercially, and therefore, there is no concern about deterioration of the aqueous solution, which contributes to extension of the shelf life of the skin dressing.

Claims (10)

1. A power generating diaphragm, comprising:
a diaphragm body;
an electrode material disposed on the membrane body; and
the water-soluble material is arranged on the membrane body and contains ionic compounds.
2. The power generating membrane of claim 1, wherein the electrode material comprises a plurality of electrode material particles, and the electrode material particles are dispersed within the membrane body.
3. The power generation membrane of claim 2, wherein the electrode material particles comprise a plurality of anode particles and a plurality of cathode particles.
4. The power generation membrane of claim 1, wherein the water-soluble material comprises a plurality of water-soluble material particles, and the water-soluble material particles are dispersed in the membrane body.
5. The power generation membrane of claim 1, wherein the membrane body comprises a first layer and a second layer, the electrode material is disposed between the first layer and the second layer, and the water-soluble material is disposed between the first layer and the second layer.
6. The power generation membrane of claim 5, wherein the active material comprises a plurality of electrode material particles, and the electrode material particles are dispersed in the first and second membrane layers.
7. The power generation membrane of claim 5, wherein the membrane body further comprises an interlayer disposed between the first membrane layer and the second membrane layer, and the water-soluble material is disposed within the interlayer.
8. The power generating membrane of claim 1 wherein the water soluble material comprises an unionized ionic compound.
9. A skin dressing comprising the power generating membrane of any one of claims 1-8.
10. The skin dressing of claim 9, wherein the water-soluble material further comprises an ingredient having a cosmetic or medical effect.
CN201910950882.0A 2018-10-03 2019-10-08 Power generation membrane and skin dressing material with same Pending CN110975138A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201862740497P 2018-10-03 2018-10-03
US62/740,497 2018-10-03

Publications (1)

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TW (1) TW202014215A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1282263A (en) * 1997-12-22 2001-01-31 阿尔扎有限公司 Anhydrous drug reservoir for electrolytic transdermal delivery device
TWI617327B (en) * 2016-09-26 2018-03-11 Self-generating material and method of manufacturing same
TWM564452U (en) * 2018-05-25 2018-08-01 正美企業股份有限公司 Dressing material capable of generating power

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1282263A (en) * 1997-12-22 2001-01-31 阿尔扎有限公司 Anhydrous drug reservoir for electrolytic transdermal delivery device
TWI617327B (en) * 2016-09-26 2018-03-11 Self-generating material and method of manufacturing same
TWM564452U (en) * 2018-05-25 2018-08-01 正美企業股份有限公司 Dressing material capable of generating power

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