CN110923041A - Method for preparing biomass RNA (ribonucleic acid) isomerase semi-hydrocarbonated rice hull boiler fuel - Google Patents

Method for preparing biomass RNA (ribonucleic acid) isomerase semi-hydrocarbonated rice hull boiler fuel Download PDF

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Publication number
CN110923041A
CN110923041A CN201911297466.1A CN201911297466A CN110923041A CN 110923041 A CN110923041 A CN 110923041A CN 201911297466 A CN201911297466 A CN 201911297466A CN 110923041 A CN110923041 A CN 110923041A
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CN
China
Prior art keywords
biomass
rna
isomerase
semi
boiler fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911297466.1A
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Chinese (zh)
Inventor
刘宏伟
姜国有
姜钧奇
王丽华
姜钧元
李晓峰
王宇峥
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SHENYANG ZHONGKE CORROSION CONTROL ENGINEERING TECHNOLOGY CENTER
Institute of Metal Research of CAS
Original Assignee
SHENYANG ZHONGKE CORROSION CONTROL ENGINEERING TECHNOLOGY CENTER
Institute of Metal Research of CAS
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Application filed by SHENYANG ZHONGKE CORROSION CONTROL ENGINEERING TECHNOLOGY CENTER, Institute of Metal Research of CAS filed Critical SHENYANG ZHONGKE CORROSION CONTROL ENGINEERING TECHNOLOGY CENTER
Priority to CN201911297466.1A priority Critical patent/CN110923041A/en
Publication of CN110923041A publication Critical patent/CN110923041A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/445Agricultural waste, e.g. corn crops, grass clippings, nut shells or oil pressing residues
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

The invention belongs to the field of biomass boiler fuel, and particularly relates to a method for preparing biomass RNA (ribonucleic acid) isomerase semi-hydrocarbonated rice hull boiler fuel, which comprises the following steps: (1) processing, crushing and grinding biomass into 125-186 meshes; adding an auxiliary material biomass of 134-168 meshes and 2-9 wt%; fermenting at the temperature of 30-71 ℃ for 39-75 h; (2) spraying 1-3 wt% of isohydrogenase peptidyl-amine on the product obtained in the step (1); (3) adding calcium oxide into the product obtained in the step (2) to obtain a target product; the weight ratio of the biomass to the isomerohydrogenase pepstatin is 78-98: 5-11. The invention has strong heat radiation capability, low water content and high energy conversion rate.

Description

Method for preparing biomass RNA (ribonucleic acid) isomerase semi-hydrocarbonated rice hull boiler fuel
Technical Field
The invention belongs to the field of biomass boiler fuel, and particularly relates to a method for preparing biomass RNA (ribonucleic acid) isomerase semi-hydrocarbonated rice hull boiler fuel.
Background
With the increasing demand for energy from society, fossil fuels, which are major energy sources, are rapidly decreasing. Therefore, the search for a renewable alternative energy source becomes a focus of general social attention. Biomass energy is an ideal renewable energy source, and has wide sources, and a large amount of industrial, agricultural and forest waste is produced every year. Among the energy consumption in the world at present, biomass energy consumption accounts for 14% of the total energy consumption in the world. The renewable resources such as corn stalks in our country, particularly in northern areas, and rice husks in south are very rich, and the renewable resources are used for replacing or partially replacing fire coal, so that not only is a huge economic return brought to enterprises, but also the income of vast farmers is increased. In another aspect, the biomass energy is a clean renewable energy source, SO2The discharge is close to zero, so the utilization of biomass energy has important effects on protecting the environment and improving the ecology. The existing biomass fuel generally has the problems of weak heat-assisted radiation capability, high water content, low energy conversion rate and the like.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides the method for preparing the biomass RNA isomerase semi-hydrocarbonated rice hull boiler fuel with strong heat-assisted radiation capability, low water content and high energy conversion rate.
In order to solve the technical problem, the invention is realized as follows:
the method for preparing the biomass RNA isomerase semi-hydrocarbonized rice hull boiler fuel comprises the following steps:
(1) processing, crushing and grinding biomass into 125-186 meshes;
(2) spraying 1-3 wt% of isohydrogenase peptidyl-amine on the product obtained in the step (1);
(3) and (3) adding calcium oxide into the product obtained in the step (2) to obtain the target product.
Preferably, the weight ratio of the biomass to the isomerohydrogenase peptidoglycan is 78-98: 5-11.
Further, in the invention, auxiliary material biomass of 134-168 meshes with the weight percentage of 2-9% is added in the step (1); fermenting at the temperature of 30-71 ℃ for 39-75 h.
Further, the biomass is agricultural rice hulls, hay or straw; the auxiliary material biomass is crop straw.
According to the invention, a delay agent calcium oxide (compatible with enzyme element) activator is added into a mixed dispersion body of an isohydrogenase enzyme catalysis substrate agricultural crop rice hull fuel, so that the rice hulls are decomposed into a hydrogen-rich state under the enzyme catalysis action to participate in the middle temperature section combustion of a boiler, the hydrogen-rich index is in direct proportion to combustion energy, and therefore, the hydrogen-containing saturation degree of the biomass agricultural crop rice hulls in essence is improved, and the biomass agricultural crop rice hulls are called as hydrogen-rich organic matters, and the same is true; the heat radiation strength in the rice hull combustion process is enhanced, agricultural straws, rice hulls and the like are used for replacing non-renewable energy sources of coal and used as power generation and supply fuel, a coal-fired power boiler can be replaced, and the environmental pollution is reduced.
Detailed Description
The present invention will be described in further detail with reference to specific examples. The scope of the present invention is not limited to the following expressions.
Example 1
The method for preparing the biomass RNA isomerase semi-hydrocarbonized rice hull boiler fuel is characterized by comprising the following steps of:
(1) processing, crushing and grinding the agricultural rice hulls into 125 meshes;
(2) spraying 1 weight percent of isohydrogenase peptide to the product obtained in the step (1);
(3) and (3) adding calcium oxide into the product obtained in the step (2) to obtain the target product.
The weight ratio of the agricultural crop rice hull to the isomerohydrogenase peptide is 78: 5.
In the invention, crop straws of 134 meshes and 2 percent by weight can be added in the step (1); fermentation was carried out at 30 ℃ for 39 h.
Example 2
The method for preparing the biomass RNA isomerase semi-hydrocarbonized rice hull boiler fuel comprises the following steps:
(1) processing, crushing and grinding the hay into 186 meshes;
(2) spraying 3 wt% of isohydrogenase peptide to the product obtained in the step (1);
(3) and (3) adding calcium oxide into the product obtained in the step (2) to obtain the target product.
The weight ratio of the hay to the isomerohydrogenase pepstatin is 98: 11.
In the invention, 168-mesh crop straws with the weight percentage of 9 percent can be added in the step (1); the fermentation was carried out at a temperature of 71 ℃ for a period of 75 h.
Example 3
The method for preparing the biomass RNA isomerase semi-hydrocarbonized rice hull boiler fuel comprises the following steps:
(1) processing, crushing and grinding biomass into 145 meshes;
(2) spraying 1.5 wt% of isohydrogenase peptidyl-amine to the product obtained in the step (1);
(3) and (3) adding calcium oxide into the product obtained in the step (2) to obtain the target product.
The weight ratio of the biomass to the isomerohydrogenase peptin is 89: 7.
In the invention, crop straws of 145 meshes and 5 percent by weight can be added in the step (1); fermentation was carried out at 45 ℃ for 65 h.
The invention sprays 1.5% RNA isomerization hydrogenase peptide on the fuel of 'agricultural rice hull', thus obtaining the fuel which improves the thermal efficiency of the fuel by 30%.
The peptide of the isohydrogenase is a product which is circulated in the existing market and is sold in Liaohe oil field area. A burning rice husk power boiler power station, the main fuel is remained agricultural rice husk, hay, straw carbohydrate after grain deep processing, because this kind of substance and grain itself have the nature hygroscopicity and the moisture content of the same sex, therefore, add in the leading technology of burning rice husk: the 1.5 percent RNA isomerase peptide modified various shell half-alkylation (alkylation) is beneficial to the wetting and moisture prevention of the fuel, and is beneficial to the low consumption and efficiency improvement, energy conservation and emission reduction of the fuel of the crop gramineous crops.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (4)

1. A method for preparing biomass RNA (ribonucleic acid) isomerase semi-hydrocarbonized rice hull boiler fuel is characterized by comprising the following steps:
(1) processing, crushing and grinding biomass into 125-186 meshes;
(2) spraying 1-3 wt% of isohydrogenase peptidyl-amine on the product obtained in the step (1);
(3) and (3) adding calcium oxide into the product obtained in the step (2) to obtain the target product.
2. The method for preparing the biomass RNA isomerase semi-hydrocarbonated rice hull boiler fuel according to claim 1, is characterized in that: the weight ratio of the biomass to the isomerohydrogenase pepstatin is 78-98: 5-11.
3. The method for preparing the biomass RNA isomerase semi-hydrocarbonated rice hull boiler fuel according to claim 2, is characterized in that: adding an auxiliary material biomass of 134-168 meshes in a weight percentage of 2-9% in the step (1); fermenting at the temperature of 30-71 ℃ for 39-75 h.
4. The method for preparing the biomass RNA isomerase semi-hydrocarbonated rice hull boiler fuel according to claim 3, is characterized in that: the biomass is agricultural rice hulls, hay or straws; the auxiliary material biomass is crop straw.
CN201911297466.1A 2019-12-17 2019-12-17 Method for preparing biomass RNA (ribonucleic acid) isomerase semi-hydrocarbonated rice hull boiler fuel Pending CN110923041A (en)

Priority Applications (1)

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CN201911297466.1A CN110923041A (en) 2019-12-17 2019-12-17 Method for preparing biomass RNA (ribonucleic acid) isomerase semi-hydrocarbonated rice hull boiler fuel

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CN201911297466.1A CN110923041A (en) 2019-12-17 2019-12-17 Method for preparing biomass RNA (ribonucleic acid) isomerase semi-hydrocarbonated rice hull boiler fuel

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5358869A (en) * 1990-01-05 1994-10-25 Institute Of Gas Technology Microbial cleavage of organic C-S bonds
CN101544922A (en) * 2009-04-30 2009-09-30 陈胜保 Biomass/microbial biomass composite fuel and production method thereof
EP2195440A2 (en) * 2007-10-04 2010-06-16 Bio Architecture Lab, Inc. Biofuel production
CN111208244A (en) * 2018-11-22 2020-05-29 中国科学院大连化学物理研究所 Antibody-independent protein methylation modification enrichment analysis method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5358869A (en) * 1990-01-05 1994-10-25 Institute Of Gas Technology Microbial cleavage of organic C-S bonds
EP2195440A2 (en) * 2007-10-04 2010-06-16 Bio Architecture Lab, Inc. Biofuel production
CN101544922A (en) * 2009-04-30 2009-09-30 陈胜保 Biomass/microbial biomass composite fuel and production method thereof
CN111208244A (en) * 2018-11-22 2020-05-29 中国科学院大连化学物理研究所 Antibody-independent protein methylation modification enrichment analysis method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
农业部厌氧微生物重点开放实验室: "《产甲烷细菌及其研究方法》", 30 September 1997, 成都科技大学出版社出版发行 *

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Application publication date: 20200327