CN110903571A - Composite material for constant-temperature fabric and preparation method thereof - Google Patents
Composite material for constant-temperature fabric and preparation method thereof Download PDFInfo
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- CN110903571A CN110903571A CN201911152614.0A CN201911152614A CN110903571A CN 110903571 A CN110903571 A CN 110903571A CN 201911152614 A CN201911152614 A CN 201911152614A CN 110903571 A CN110903571 A CN 110903571A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to the field of ground mat materials, and discloses a composite material for constant-temperature fabric, which is prepared from the following raw materials in parts by weight: 5-10 parts of nano silicon dioxide, 40-60 parts of PVC resin, 7-9 parts of chlorinated paraffin, 10-15 parts of polyethylene, 40-100 parts of tributyl citrate, 25-40 parts of polyurethane, 20-30 parts of polyether ether ketone, 5-10 parts of nano titanium dioxide, 20-30 parts of calcium carbonate, 3-10 parts of epoxidized soybean oil, 1-2 parts of polyoxyethylene polyoxypropylene polyether, 2-5 parts of calcium zinc stabilizer, 6-12 parts of plasticizer and 2-6 parts of stabilizer. Also discloses a preparation method of the composite material for the constant-temperature fabric. The composite material has the advantages of good antibacterial property, good constant temperature property, good bending property and good tensile property.
Description
Technical Field
The invention relates to the field of ground mat materials, in particular to a composite material for constant-temperature fabric and a preparation method thereof.
Background
With the popularization of automobiles, automobile foot mats have become indispensable consumer goods for people. The invention patent of application No. CN201510612783.3 discloses a multilayer composite anti-skid breathable flame-retardant material for an automobile foot pad, and the foot pad made of the material has the advantages of good anti-skid breathable flame retardance. However, in addition to the characteristics of comfort, air permeability, skid resistance, flame retardance and the like, the foot pad is also expected to have the functions of good antibacterial performance, good bending performance, good tensile performance and the like, so that research and development of composite materials for the foot pad are hot spots in the industry.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides a composite material for a constant-temperature fabric and a preparation method thereof.
In order to solve the technical problem, the invention is solved by the following technical scheme:
the composite material for the constant-temperature fabric is prepared from the following raw materials in parts by weight:
preferably, the calcium zinc stabilizer comprises stearic acid, calcium hydroxide, zinc oxide, an auxiliary stabilizer and water, and the weight ratio of the stearic acid, the calcium hydroxide, the zinc oxide, the auxiliary stabilizer and the water is 15:1:3: 6.
Preferably, the plasticizer comprises polyvinyl chloride, ethylene glycol, methyl methacrylate and trioctyl trimellitate, and the weight ratio of the polyvinyl chloride to the ethylene glycol to the methyl methacrylate to the trioctyl trimellitate is 1:6:3: 7.
Preferably, the composition is prepared from the following raw materials in parts by weight:
preferably, the composition is prepared from the following raw materials in parts by weight:
preferably, the composition is prepared from the following raw materials in parts by weight:
a preparation method of a composite material for a constant-temperature fabric comprises the following steps: weighing 5-10 parts of nano silicon dioxide, 40-60 parts of PVC resin, 7-9 parts of chlorinated paraffin, 10-15 parts of polyethylene, 40-100 parts of tributyl citrate, 25-40 parts of polyurethane, 20-30 parts of polyether ether ketone, 5-10 parts of nano titanium dioxide, 20-30 parts of calcium carbonate, 3-10 parts of epoxidized soybean oil and 1-2 parts of polyoxyethylene polyoxypropylene polyether according to the weight parts of the raw materials, adding the raw materials into a stirring kettle, and stirring for 25-40 minutes at the temperature of 100 ℃ and the rotating speed of 2000 ℃ and 3000 r/min.
Preferably, the method further comprises the following steps: weighing 2-5 parts of calcium zinc stabilizer, 6-12 parts of plasticizer and 2-6 parts of stabilizer according to the weight parts of the raw materials, adding into a stirring kettle, and stirring for 10-20 minutes at the temperature of 110-.
Due to the adoption of the technical scheme, the invention has the remarkable technical effects that: the foot pad made of the composite material has better antibacterial property, the antibacterial rate reaches 87%, and the antibacterial time is long compared with the existing product. Meanwhile, the floor mat has good bending property and tensile property, so that the floor mat made of the composite material has better mechanical property and long service life. The composite material has the advantages of good antibacterial property, good constant temperature property, good bending property and good tensile property.
Detailed Description
The present invention will be described in further detail with reference to examples.
Example 1
The composite material for the constant-temperature fabric is prepared from the following raw materials in parts by weight:
the calcium-zinc stabilizer comprises stearic acid, calcium hydroxide, zinc oxide, an auxiliary stabilizer and water, wherein the weight ratio of the stearic acid, the calcium hydroxide, the zinc oxide, the auxiliary stabilizer and the water is 15:1:3: 6.
The plasticizer comprises polyvinyl chloride, ethylene glycol, methyl methacrylate and trioctyl trimellitate, and the weight ratio of the polyvinyl chloride to the ethylene glycol to the methyl methacrylate to the trioctyl trimellitate is 1:6:3: 7.
A preparation method of a composite material for a constant-temperature fabric comprises the following steps: weighing 7 parts of nano silicon dioxide, 50 parts of PVC resin, 8 parts of chlorinated paraffin, 13 parts of polyethylene, 70 parts of tributyl citrate, 30 parts of polyurethane, 25 parts of polyether-ether-ketone, 8 parts of nano titanium dioxide, 25 parts of calcium carbonate, 6 parts of epoxidized soybean oil and 1.5 parts of polyoxyethylene polyoxypropylene polyether according to the parts by weight of the raw materials, adding the raw materials into a stirring kettle, and stirring the mixture for 35 minutes at the temperature of 115 ℃ and the rotating speed of 2500 r/min.
Further comprising the steps of: weighing 4 parts of calcium-zinc stabilizer, 9 parts of plasticizer and 4 parts of stabilizer according to the weight parts of the raw materials, adding into a stirring kettle, and stirring for 15 minutes at the temperature of 120 ℃ and the rotating speed of 3500 r/min.
Example 2
The embodiment 1 is different from the embodiment in that the preparation method of the composite material for the constant-temperature fabric comprises the following steps: weighing 7 parts of nano silicon dioxide, 50 parts of PVC resin, 8 parts of chlorinated paraffin, 13 parts of polyethylene, 70 parts of tributyl citrate, 30 parts of polyurethane, 25 parts of polyether-ether-ketone, 8 parts of nano titanium dioxide, 25 parts of calcium carbonate, 6 parts of epoxidized soybean oil and 1.5 parts of polyoxyethylene polyoxypropylene polyether according to the parts by weight of the raw materials, adding the raw materials into a stirring kettle, and stirring the mixture for 25 minutes at the temperature of 100 ℃ and the rotating speed of 2000 r/min.
Further comprising the steps of: weighing 4 parts of calcium zinc stabilizer, 9 parts of plasticizer and 4 parts of stabilizer according to the weight parts of the raw materials, adding into a stirring kettle, and stirring for 10 minutes at the temperature of 110 ℃ and the rotating speed of 3500 r/min.
Example 3
The embodiment 1 is different from the embodiment in that the preparation method of the composite material for the constant-temperature fabric comprises the following steps: weighing 7 parts of nano silicon dioxide, 50 parts of PVC resin, 8 parts of chlorinated paraffin, 13 parts of polyethylene, 70 parts of tributyl citrate, 30 parts of polyurethane, 25 parts of polyether-ether-ketone, 8 parts of nano titanium dioxide, 25 parts of calcium carbonate, 6 parts of epoxidized soybean oil and 1.5 parts of polyoxyethylene polyoxypropylene polyether according to the weight parts of the raw materials, adding the raw materials into a stirring kettle, and stirring the mixture for 40 minutes at the temperature of 130 ℃ and the rotating speed of 3000 r/min.
Further comprising the steps of: weighing 4 parts of calcium zinc stabilizer, 9 parts of plasticizer and 4 parts of stabilizer according to the weight parts of the raw materials, adding into a stirring kettle, and stirring for 20 minutes at the temperature of 130 ℃ and the rotating speed of 3500 r/min.
Example 4
The composite material for the constant-temperature fabric is prepared from the following raw materials in parts by weight:
the calcium-zinc stabilizer comprises stearic acid, calcium hydroxide, zinc oxide, an auxiliary stabilizer and water, wherein the weight ratio of the stearic acid, the calcium hydroxide, the zinc oxide, the auxiliary stabilizer and the water is 15:1:3: 6.
The plasticizer comprises polyvinyl chloride, ethylene glycol, methyl methacrylate and trioctyl trimellitate, and the weight ratio of the polyvinyl chloride to the ethylene glycol to the methyl methacrylate to the trioctyl trimellitate is 1:6:3: 7.
A preparation method of a composite material for a constant-temperature fabric comprises the following steps: weighing 5 parts of nano silicon dioxide, 40 parts of PVC resin, 7 parts of chlorinated paraffin, 10 parts of polyethylene, 40 parts of tributyl citrate, 25 parts of polyurethane, 20 parts of polyether-ether-ketone, 5 parts of nano titanium dioxide, 20 parts of calcium carbonate, 3 parts of epoxidized soybean oil and 1 part of polyoxyethylene polyoxypropylene polyether according to the weight parts of the raw materials, adding the raw materials into a stirring kettle, and stirring the mixture for 35 minutes at the temperature of 115 ℃ and the rotating speed of 2500 r/min.
Further comprising the steps of: weighing 2 parts of calcium-zinc stabilizer, 6 parts of plasticizer and 2 parts of stabilizer according to the weight parts of the raw materials, adding the raw materials into a stirring kettle, and stirring for 15 minutes at the temperature of 120 ℃ and the rotating speed of 3500 r/min.
Example 5
The composite material for the constant-temperature fabric is prepared from the following raw materials in parts by weight:
the calcium-zinc stabilizer comprises stearic acid, calcium hydroxide, zinc oxide, an auxiliary stabilizer and water, wherein the weight ratio of the stearic acid, the calcium hydroxide, the zinc oxide, the auxiliary stabilizer and the water is 15:1:3: 6.
The plasticizer comprises polyvinyl chloride, ethylene glycol, methyl methacrylate and trioctyl trimellitate, and the weight ratio of the polyvinyl chloride to the ethylene glycol to the methyl methacrylate to the trioctyl trimellitate is 1:6:3: 7.
A preparation method of a composite material for a constant-temperature fabric comprises the following steps: weighing 10 parts of nano silicon dioxide, 60 parts of PVC resin, 9 parts of chlorinated paraffin, 15 parts of polyethylene, 100 parts of tributyl citrate, 40 parts of polyurethane, 30 parts of polyether-ether-ketone, 10 parts of nano titanium dioxide, 30 parts of calcium carbonate, 10 parts of epoxidized soybean oil and 2 parts of polyoxyethylene polyoxypropylene polyether according to the weight parts of the raw materials, adding the raw materials into a stirring kettle, and stirring for 35 minutes at the temperature of 115 ℃ and the rotating speed of 2500 r/min.
Further comprising the steps of: weighing 5 parts of calcium-zinc stabilizer, 12 parts of plasticizer and 6 parts of stabilizer according to the weight parts of the raw materials, adding the raw materials into a stirring kettle, and stirring for 15 minutes at the temperature of 120 ℃ and the rotating speed of 3500 r/min.
Example 6
Mats made from the composites of examples 1-5 were tested for various properties and the results are shown in the following table.
The product performance test conditions were as follows:
bending property: the test speed was 2 mm/min according to ISO 178.
Tensile property: the drawing speed was 50 mm/min according to ISO 527.
| Test items | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Existing products |
| Antibacterial rate | 83％ | 81％ | 81％ | 80％ | 87％ | 60％ |
| Bending properties | 9.0 | 8.9 | 9.1 | 7.9 | 11.2 | 7.6 |
| Tensile Properties | 8.3 | 8.4 | 8.4 | 7.5 | 9.8 | 7.5 |
The data in the table show that the foot pad made of the composite material has better antibacterial property and good bending property and tensile property compared with the existing products.
In summary, the above-mentioned embodiments are only preferred embodiments of the present invention, and all equivalent changes and modifications made in the claims of the present invention should be covered by the claims of the present invention.
Claims (8)
1. The composite material for the constant-temperature fabric is characterized by being prepared from the following raw materials in parts by weight:
2. the composite material for the constant-temperature fabric as claimed in claim 1, wherein the calcium-zinc stabilizer comprises stearic acid, calcium hydroxide, zinc oxide, an auxiliary stabilizer and water, and the weight ratio of the stearic acid, the calcium hydroxide, the zinc oxide, the auxiliary stabilizer and the water is 15:1:3: 6.
3. The composite material for a constant temperature fabric as claimed in claim 1, wherein the plasticizer comprises polyvinyl chloride, ethylene glycol alcohol, methyl methacrylate and trioctyl trimellitate, and the weight ratio of the polyvinyl chloride to the ethylene glycol alcohol to the methyl methacrylate to the trioctyl trimellitate is 1:6:3: 7.
4. The composite material for the constant-temperature fabric as claimed in claim 1, which is prepared from the following raw materials in parts by weight:
5. the composite material for the constant-temperature fabric as claimed in claim 1, which is prepared from the following raw materials in parts by weight:
6. the composite material for the constant-temperature fabric as claimed in claim 1, which is prepared from the following raw materials in parts by weight:
7. the preparation method of the composite material for the constant-temperature fabric is characterized by comprising the following steps of: weighing 5-10 parts of nano silicon dioxide, 40-60 parts of PVC resin, 7-9 parts of chlorinated paraffin, 10-15 parts of polyethylene, 40-100 parts of tributyl citrate, 25-40 parts of polyurethane, 20-30 parts of polyether ether ketone, 5-10 parts of nano titanium dioxide, 20-30 parts of calcium carbonate, 3-10 parts of epoxidized soybean oil and 1-2 parts of polyoxyethylene polyoxypropylene polyether according to the weight parts of the raw materials, adding the raw materials into a stirring kettle, and stirring for 25-40 minutes at the temperature of 100 ℃ and the rotating speed of 2000 ℃ and 3000 r/min.
8. The preparation method of the composite material for the constant-temperature fabric according to claim 7, characterized by further comprising the following steps of: weighing 2-5 parts of calcium zinc stabilizer, 6-12 parts of plasticizer and 2-6 parts of stabilizer according to the weight parts of the raw materials, adding into a stirring kettle, and stirring for 10-20 minutes at the temperature of 110-.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911152614.0A CN110903571A (en) | 2019-11-22 | 2019-11-22 | Composite material for constant-temperature fabric and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201911152614.0A CN110903571A (en) | 2019-11-22 | 2019-11-22 | Composite material for constant-temperature fabric and preparation method thereof |
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| CN110903571A true CN110903571A (en) | 2020-03-24 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110885531A (en) * | 2019-11-22 | 2020-03-17 | 浙江海啊汽车用品有限公司 | Composite material for odor-resistant adsorption fabric and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104098855A (en) * | 2014-06-18 | 2014-10-15 | 三门永鼎橡塑有限公司 | High-performance rubber composite material for automobile floor mat and preparation method |
| CN109553883A (en) * | 2018-10-30 | 2019-04-02 | 浙江海啊汽车用品有限公司 | A kind of composite material and preparation method of high-performance foot pad |
-
2019
- 2019-11-22 CN CN201911152614.0A patent/CN110903571A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104098855A (en) * | 2014-06-18 | 2014-10-15 | 三门永鼎橡塑有限公司 | High-performance rubber composite material for automobile floor mat and preparation method |
| CN109553883A (en) * | 2018-10-30 | 2019-04-02 | 浙江海啊汽车用品有限公司 | A kind of composite material and preparation method of high-performance foot pad |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110885531A (en) * | 2019-11-22 | 2020-03-17 | 浙江海啊汽车用品有限公司 | Composite material for odor-resistant adsorption fabric and preparation method thereof |
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Application publication date: 20200324 |
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