CN110888257A - Polaroid assembly, manufacturing method of polaroid assembly and display panel - Google Patents

Polaroid assembly, manufacturing method of polaroid assembly and display panel Download PDF

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Publication number
CN110888257A
CN110888257A CN201911169814.7A CN201911169814A CN110888257A CN 110888257 A CN110888257 A CN 110888257A CN 201911169814 A CN201911169814 A CN 201911169814A CN 110888257 A CN110888257 A CN 110888257A
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China
Prior art keywords
dimensional nano
polarizer
monomer
monomers
film layer
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CN201911169814.7A
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Chinese (zh)
Inventor
宋自航
周淼
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TCL China Star Optoelectronics Technology Co Ltd
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TCL China Star Optoelectronics Technology Co Ltd
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Priority to CN201911169814.7A priority Critical patent/CN110888257A/en
Priority to PCT/CN2019/124241 priority patent/WO2021103134A1/en
Publication of CN110888257A publication Critical patent/CN110888257A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528Polarisers
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Polarising Elements (AREA)

Abstract

The embodiment of the application provides a polaroid subassembly, polaroid subassembly's manufacturing method and display panel, and the polaroid subassembly includes polaroid and thin layer, and the polaroid has relative first face and the second face that sets up, and the thin layer sets up first face, the thin layer includes one-dimensional nanometer monomer, and is a plurality of one-dimensional nanometer monomer's length direction extends towards same direction, one-dimensional nanometer monomer is used for absorbing the polarization blue light the same with one-dimensional nanometer monomer length direction. The polarizer assembly provided by the embodiment of the application can improve the contrast of the polarizer.

Description

Polaroid assembly, manufacturing method of polaroid assembly and display panel
Technical Field
The present disclosure relates to the field of panel manufacturing technologies, and in particular, to a polarizer assembly, a polarizer manufacturing method, and a display panel.
Background
The TFT-LCD (Thin Film Transistor-Liquid Crystal Display) plays an important role in the Display industry at present due to the characteristics of good Display quality, low harmful radiation, large Display area, light weight, thinness and the like, and the polarizer plays an important role in the Display effect of the TFT-LCD (Thin Film Transistor-Liquid Crystal Display).
At present, the polarizer has higher polarization degree in a long wave band, the extinction ratio is generally thousands or even tens of thousands, but in a blue light band of 400 plus 500nm, the extinction ratio of the polarizer is only about hundreds, so that the polarization degree of the blue light band is lower, the transmittance is higher, part of unpolarized blue light penetrates through the polarizer, liquid crystal cannot switch the part of light, and the blue light penetrating through the display panel is higher finally, so that the contrast is reduced when a dark state is displayed, and the display effect is influenced. Therefore, it is important to develop a polarizer with high contrast.
Disclosure of Invention
The embodiment of the application provides a polarizer assembly, a polarizer assembly manufacturing method and a display panel. The contrast ratio of the polarizer may be improved.
A first aspect of an embodiment of the present application provides a polarizer assembly, including:
the polarizer is provided with a first surface and a second surface which are oppositely arranged;
the thin film layer is arranged on the first surface and comprises one-dimensional nano monomers, the length directions of the one-dimensional nano monomers extend towards the same direction, and the one-dimensional nano monomers are used for absorbing polarized blue light the same as the length direction of the one-dimensional nano monomers.
In some embodiments, the length direction of the one-dimensional nano-monomer is perpendicular to the polarization axis direction of the polarizer.
In some embodiments, the thin film layer is formed by one-dimensional nanomonomers attached to a polyvinyl alcohol film.
In some embodiments, the thin film layer has a thickness of between 15 microns and 25 microns.
In some embodiments, the one-dimensional nanomonomer is CdSe, CdS, ZnSe, InP, CsPbCl3、CsPbBr3And any one or more of halogen-doped perovskite structures, wherein the CdSe, CdS, ZnSe and InP comprise cladding structures.
A second aspect of embodiments of the present application provides a method of manufacturing a polarizer assembly, including the steps of:
attaching one-dimensional nano monomers to a polyvinyl alcohol film to form a film layer;
stretching the thin film layer to enable the length direction of the one-dimensional nano monomer to extend towards the same direction, wherein the one-dimensional nano monomer is used for absorbing polarized blue light in the same length direction as the one-dimensional nano monomer;
the stretched film layer is disposed on a polarizer.
In some embodiments, before the attaching the one-dimensional nano-monomer to the polyvinyl alcohol film to form the film layer, the method further comprises: and quenching the one-dimensional nano monomer.
In some embodiments, the attaching the one-dimensional nano-monomers to the polyvinyl alcohol film to form a film layer comprises:
mixing the normal hexane solution of the one-dimensional nano monomer with the pressure-sensitive adhesive to obtain a mixed solution;
coating the mixed solution on a polyvinyl alcohol film to obtain a one-dimensional nano film;
and drying the one-dimensional nano film.
In some embodiments, the length direction of the one-dimensional nano-monomer is perpendicular to the polarization axis direction of the polarizer.
A third aspect of the embodiments of the present application provides a display panel, including an array substrate, a color filter substrate, and a polarizer assembly, where the array substrate and the color filter substrate are arranged oppositely, a thin film transistor is arranged on the array substrate, the polarizer assembly is arranged on the array substrate or the color filter substrate, and the polarizer assembly is the above polarizer assembly.
In this application embodiment, the thin layer includes a plurality of one-dimensional nanometer monomers, and the free length direction of one-dimensional nanometer extends towards same direction, and the thin layer setting is in the one side of polaroid, and one-dimensional nanometer monomer is used for absorbing the polarization blue light the same with one-dimensional nanometer monomer length direction, and this application embodiment adopts this kind of structure can improve the extinction ratio of polaroid blue light wave band, reaches the lower purpose of improvement polaroid blue light wave band polarization degree.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present application, the drawings used in the description of the embodiments will be briefly introduced below.
Fig. 1 is a schematic structural diagram of a display panel in an embodiment of the present application.
Fig. 2 is a schematic structural diagram of a polarizer assembly in an embodiment of the present application.
FIG. 3 is a schematic view of a polarizer assembly according to an embodiment of the present disclosure.
FIG. 4 is a schematic diagram of a structure of a film layer in a polarizer assembly according to an embodiment of the present application.
FIG. 5 is a schematic flow chart illustrating a method for manufacturing a polarizer assembly according to an embodiment of the present application.
Detailed Description
The technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application. It is to be understood that the embodiments described are only a few embodiments of the present application and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.
The embodiment of the application provides a polarizer assembly, a polarizer assembly manufacturing method and a display panel.
Referring to fig. 1, fig. 1 is a schematic structural diagram of a display panel 100 according to an embodiment of the present disclosure. The display panel 100 includes an array substrate 10, a color film substrate 20 and a polarizer assembly 30, wherein the array substrate 10 and the color film substrate 20 are arranged oppositely, the array substrate 10 is provided with a thin film transistor 11, and the polarizer assembly 30 is arranged on the array substrate 10 or the color film substrate 20.
In order to improve the display effect of the display panel 100 when displaying a dark state, it is necessary to increase the polarization degree of the polarizer 31. The embodiment of the present application provides a polarizer assembly 30, which can improve the polarization degree of the polarizer 31 in the low band. The polarizer assembly 30 is described in detail below.
Referring to fig. 2 to 4, fig. 2 is a schematic structural diagram of a polarizer assembly 30 according to an embodiment of the present application. The polarizer assembly 30 includes a polarizer 31 and a thin film layer 32. The polarizer 31 has a first face 31a and a second face 31b disposed oppositely. The thin film layer 32 is disposed on the first surface 31a, the thin film layer 32 includes a plurality of one-dimensional nano monomers 321, length directions of the one-dimensional nano monomers 321 extend in the same direction, the length direction of the one-dimensional nano monomers 321 is perpendicular to a polarization axis 311 direction of the polarizer 31, and the one-dimensional nano monomers 321 are configured to absorb polarized blue light in the same length direction as the one-dimensional nano monomers.
It should be noted that the one-dimensional nano-monomer is a cylinder, and the length direction of the one-dimensional nano-monomer is the direction in which the top of the one-dimensional nano-monomer extends toward the bottom of the one-dimensional nano-monomer.
It should be noted that the first surface 31a may be an upper surface of the polarizer 31, and the second surface 31b may be a lower surface of the polarizer 31. Of course, the first surface 31a may be a lower surface of the polarizer 31, and the second surface 31b may be an upper surface of the polarizer 31. The thin film layer 32 is provided on the first surface 31 a. That is, the thin film layer 32 may be disposed on either the upper surface of the polarizer 31 or the lower surface of the polarizer 31.
When the thin film layer 32 is disposed on the upper surface of the polarizer 31, the backlight firstly passes through the polarizer 31, the polarization degree of the blue light is low, when the light passes through the thin film layer 32 again, the short-wave polarized light parallel to the length direction of the one-dimensional material is absorbed again, and the normal light of the long-wave band is directly transmitted, so that the polarized light with high polarization degree of the visible light full-band is finally obtained.
When the thin film layer 32 is disposed on the lower surface of the polarizer 31, the backlight passes through the thin film layer 32, the polarized light of the blue light part parallel to the length direction of the one-dimensional nano monomer 321 is absorbed, so that the transmitted blue light part is the polarized light perpendicular to the length direction of the one-dimensional nano monomer 321 and the unpolarized light of the long wavelength band, when the light passes through the polarizer 31 again, the polarized light of the blue wavelength band directly passes through the polarizer 31 because the polarization direction is parallel to the polarization axis 311 of the polarizer 31, and the light of the long wavelength band is screened as the polarized light, so that the polarized light of the visible light with higher full-wavelength band polarization degree is obtained.
Wherein, the thin film layer 32 is formed by attaching the one-dimensional nano-monomer 321 to the polyvinyl alcohol thin film. In the embodiment of the application, the one-dimensional nano monomer 321 and the polyvinyl alcohol film are mixed to form the thin film layer 32, and the one-dimensional material nano has the characteristic of selectively absorbing polarized light in the length direction and adjusting and controlling the absorption wave band of incident light, so that the extinction ratio of the blue light wave band of the polarizer 31 is improved, and the purpose of improving the lower polarization degree of the blue light wave band of the polarizer 31 is achieved.
Wherein the thin film layer 32 has a thickness of between 15 and 25 microns.
The thickness of the thin film layer 32 is the thickness of the one-dimensional macromonomer 321 attached to the polyvinyl alcohol film and dried. It is understood that the film layer 32 may be 15 microns, 20 microns, 25 microns, and the like. The thickness of the thin film layer 32 in the present embodiment is related to the concentration of the one-dimensional nano-monomers. The thickness of the thin film layer 32 is set to be between 15 micrometers and 25 micrometers in the embodiment of the present application. This may improve the contrast of the polarizer 31 without increasing the overall thickness of the polarizer assembly 30 too much.
The one-dimensional nano monomer 321 is formed by mixing one or more of CdSe, CdS, ZnSe, InP, CsPbCl3, CsPbBr3 and a halogen-doped perovskite structure, and the CdSe, the CdS, the ZnSe and the InP all comprise cladding structures.
Specifically, the one-dimensional nano-monomer 321 may be a nanorod, a nanowire, or the like. In the embodiment of the present application, the structural form of the one-dimensional nano-monomer 321 is not described in detail. More specifically, the nanorods, nanowires, etc., have a length between 20 nanometers and 200 nanometers. It is understood that the nanorods, nanowires, etc. can have lengths of 20 nm, 100 nm, 150 nm, and 200 nm, etc. In the application, the lengths of the nanorods and the nanowires set to be 20 nm to 200 nm can be set according to the wavelength to be absorbed by the polarizer 31.
In the embodiment of the present application, thin layer 32 includes a plurality of one-dimensional nanometer monomer 321, it is a plurality of one-dimensional nanometer monomer 321's length direction extends towards same direction, thin layer 32 sets up the one side at polaroid 31, and one-dimensional nanometer monomer 321 is used for absorbing the polarization blue light the same with one-dimensional nanometer monomer length direction, when being shaded like this and passing thin layer 32, the polarization light that the blue light part is on a parallel with thin layer 32 length direction is absorbed, when light permeates polaroid 31 again, the polarization light of blue light wave band directly passes through polaroid 31, the light of long wave band is then screened as polarization light, thereby the higher polarization light of visible light full wave band polarization degree has been obtained, thereby improve the extinction ratio of 31 blue light wave bands of polaroid, reach the lower purpose of improvement polaroid 31 blue light.
Referring to fig. 5, fig. 5 is a flowchart illustrating a method for manufacturing a polarizer assembly according to an embodiment of the present disclosure. The embodiment of the application provides a method for manufacturing a polarizer assembly, which comprises the following steps:
101. and attaching the one-dimensional nano monomer to the polyvinyl alcohol film to form the film layer.
The one-dimensional nano-monomer can be formed by mixing any one or more of CdSe, CdS, ZnSe, InP, CsPbCl3, CsPbBr3 and halogen-doped perovskite structures, and the CdSe, the CdS, the ZnSe and the InP all comprise cladding structures. In the embodiment of the present application, which component is specifically used for the one-dimensional nano-monomer is not specifically limited. Specifically, the length of the one-dimensional nano-monomer is between 20 nanometers and 200 nanometers.
Before the one-dimensional nano monomer is attached to the polyvinyl alcohol film to form the film layer, the one-dimensional nano monomer is subjected to quenching treatment. The luminescent one-dimensional nano monomer material can be quenched so that the luminescent one-dimensional nano monomer material does not emit light any more. Therefore, the polarization degree of the whole visible light wave band of the polarizer is further improved.
Specifically, the step of mixing the one-dimensional nano monomer with the polyvinyl alcohol film to form the film layer further comprises the following steps:
1011. and mixing the normal hexane solution of the one-dimensional nano monomer with the pressure-sensitive adhesive to obtain a mixed solution.
The mass concentration of the one-dimensional nano monomer is between 2.5 and 5 percent, so that the one-dimensional nano monomer can not agglomerate and can be smoothly bonded with the polyvinyl alcohol film. And the method is simple and convenient to operate and low in cost.
1012. And coating the mixed solution on a polyvinyl alcohol film to obtain the one-dimensional nano film.
In this way, the one-dimensional nano-monomer can be formed into a film adhered to the polarizer. The one-dimensional nano monomer is conveniently arranged on the polaroid, and the length direction of the one-dimensional nano monomer and the polarization axis direction of the polaroid keep a stable angle. The extinction ratio can be improved after light penetrates through the thin film layer with the one-dimensional nano monomer, and therefore the polarization degree of the whole visible wave band of the polarizer is improved.
1013. And drying the one-dimensional nano film.
And drying the one-dimensional nano film by using drying equipment so that the one-dimensional nano film can be stretched and the one-dimensional nano monomers are arranged at the same angle.
102. And stretching the film layer to enable the length direction of the one-dimensional nano monomer to extend towards the same direction, wherein the one-dimensional nano monomer is used for absorbing the polarized blue light in the same length direction as the one-dimensional nano monomer.
The one-dimensional nano film is stretched by the stretching tool at a stretch ratio of 6 to 8 times, so that the one-dimensional nano film becomes a film layer, specifically, the film layer may be 15 micrometers, 20 micrometers, 25 micrometers, and the like. The thickness of the thin film layer in the embodiment of the application is related to the concentration of the one-dimensional nano monomer.
The thickness of the thin film layer is set to be between 15 micrometers and 25 micrometers in the embodiment of the present application. Therefore, the contrast of the polarizer can be improved, and the whole thickness of the polarizer assembly is not increased too much.
Specifically, in the stretching process, the length direction of the one-dimensional nano monomer is perpendicular to the length direction of the polarizing axis of the polarizer. Because the polarized light of the blue light part parallel to the length direction of the one-dimensional nano monomer is absorbed, the transmitted blue light part is the polarized light vertical to the length direction of the one-dimensional nano monomer and the unpolarized light of the long wave band, when the light transmits through the polarizer, the polarized light of the blue light wave band directly passes through the polarizer because the polarization direction is parallel to the polarization axis of the polarizer, and the light of the long wave band is screened into the polarized light, thereby obtaining the polarized light with higher polarization degree of the visible light full wave band.
In this application embodiment, the thin layer includes a plurality of one-dimensional nanometer monomers, and the free length direction of one-dimensional nanometer extends towards same direction, and the thin layer setting is in the one side of polaroid, and one-dimensional nanometer monomer is used for absorbing the blue light, and this application embodiment adopts this kind of structure can improve the extinction ratio of polaroid blue light wave band, reaches the lower purpose of improvement polaroid blue light wave band polarization degree.
The polarizer assembly, the method of manufacturing the polarizer assembly, and the display panel according to the embodiments of the present application are described in detail above. The principles and implementations of the present application are described herein using specific examples, which are presented only to aid in understanding the present application. Meanwhile, for those skilled in the art, according to the idea of the present application, there may be variations in the specific embodiments and the application scope, and in summary, the content of the present specification should not be construed as a limitation to the present application.

Claims (10)

1. A polarizer assembly, comprising:
the polarizer is provided with a first surface and a second surface which are oppositely arranged;
the thin film layer is arranged on the first surface and comprises a plurality of one-dimensional nano monomers, the length directions of the one-dimensional nano monomers extend towards the same direction, and the one-dimensional nano monomers are used for absorbing polarized blue light the same as the length direction of the one-dimensional nano monomers.
2. The polarizer assembly of claim 1, wherein the one-dimensional nano-monomers have a length direction perpendicular to a polarizing axis direction of the polarizer.
3. The polarizer assembly of claim 1, wherein the film layer is formed by one-dimensional nanomonomers attached to a polyvinyl alcohol film.
4. A polarizer assembly according to claim 3, wherein the film layer has a thickness of between 15 and 25 microns.
5. A polarizer assembly according to any of claims 1 to 4, wherein the one-dimensional nano-monomer is CdSe, CdS, ZnSe, InP, CsPbCl3、CsPbBr3And any one or more of halogen-doped perovskite structures, wherein the CdSe, CdS, ZnSe and InP comprise cladding structures.
6. A method of manufacturing a polarizer assembly, comprising the steps of:
attaching one-dimensional nano monomers to a polyvinyl alcohol film to form a film layer;
stretching the thin film layer to enable the length direction of the one-dimensional nano monomer to extend towards the same direction, wherein the one-dimensional nano monomer is used for absorbing polarized blue light in the same length direction as the one-dimensional nano monomer;
the stretched film layer is disposed on a polarizer.
7. The method of manufacturing a polarizer assembly according to claim 6, wherein the attaching the one-dimensional nano-monomers to the polyvinyl alcohol film to form the film layer further comprises:
and quenching the one-dimensional nano monomer.
8. The method of manufacturing a polarizer assembly according to claim 6, wherein the attaching the one-dimensional nano-monomers to the polyvinyl alcohol film to form a film layer comprises:
mixing the normal hexane solution of the one-dimensional nano monomer with the pressure-sensitive adhesive to obtain a mixed solution;
coating the mixed solution on a polyvinyl alcohol film to obtain a one-dimensional nano film;
and drying the one-dimensional nano film.
9. The method of any of claims 6 to 8, wherein the one-dimensional nano-monomers have a length direction perpendicular to a polarizing axis direction of the polarizer.
10. A display panel is characterized by comprising an array substrate, a color film substrate and a polarizer assembly, wherein the array substrate and the color film substrate are oppositely arranged, a thin film transistor is arranged on the array substrate, the polarizer assembly is arranged on the array substrate or the color film substrate, and the polarizer assembly is the polarizer assembly in any one of claims 1 to 5.
CN201911169814.7A 2019-11-26 2019-11-26 Polaroid assembly, manufacturing method of polaroid assembly and display panel Pending CN110888257A (en)

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CN201911169814.7A CN110888257A (en) 2019-11-26 2019-11-26 Polaroid assembly, manufacturing method of polaroid assembly and display panel
PCT/CN2019/124241 WO2021103134A1 (en) 2019-11-26 2019-12-10 Polarizer assembly, manufacturing method for polarizer assembly, and display panel

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Application publication date: 20200317