CN110864219A - Liquid hydrogen filling device - Google Patents
Liquid hydrogen filling device Download PDFInfo
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- CN110864219A CN110864219A CN201910983027.XA CN201910983027A CN110864219A CN 110864219 A CN110864219 A CN 110864219A CN 201910983027 A CN201910983027 A CN 201910983027A CN 110864219 A CN110864219 A CN 110864219A
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- hydrogenation gun
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 140
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 140
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 132
- 239000007788 liquid Substances 0.000 title claims abstract description 111
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 557
- 238000000034 method Methods 0.000 claims abstract description 29
- 230000008569 process Effects 0.000 claims abstract description 28
- 238000003860 storage Methods 0.000 claims abstract description 28
- 238000007789 sealing Methods 0.000 claims description 65
- 230000007704 transition Effects 0.000 claims description 12
- 230000007246 mechanism Effects 0.000 claims description 6
- 238000003780 insertion Methods 0.000 claims description 2
- 230000037431 insertion Effects 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 abstract description 8
- 238000002955 isolation Methods 0.000 description 28
- 238000007664 blowing Methods 0.000 description 15
- 238000011084 recovery Methods 0.000 description 11
- 239000003949 liquefied natural gas Substances 0.000 description 8
- 239000011229 interlayer Substances 0.000 description 7
- 238000005192 partition Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
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- 230000000903 blocking effect Effects 0.000 description 2
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- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000005429 filling process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
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- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
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- 238000007726 management method Methods 0.000 description 1
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- 239000000178 monomer Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
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Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C5/00—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
- F17C5/02—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures for filling with liquefied gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/04—Arrangement or mounting of valves
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/12—Arrangements or mounting of devices for preventing or minimising the effect of explosion ; Other safety measures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2260/00—Purposes of gas storage and gas handling
- F17C2260/04—Reducing risks and environmental impact
- F17C2260/042—Reducing risk of explosion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2265/00—Effects achieved by gas storage or gas handling
- F17C2265/06—Fluid distribution
- F17C2265/063—Fluid distribution for supply of refuelling stations
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
The invention discloses a liquid hydrogen filling device, which comprises a hydrogenation gun and a hydrogenation port connected to a liquid hydrogen storage tank, wherein the hydrogenation gun is provided with a first plugging part for plugging an internal filling channel, the hydrogenation port is provided with a second plugging part for plugging the internal filling channel, in the process of inserting the hydrogenation gun into the hydrogenation port, the hydrogenation gun firstly pushes the second plugging part to displace to conduct the filling channel in the hydrogenation port, and then reversely pushes the first plugging part to displace after the hydrogenation port to conduct the filling channel in the hydrogenation gun. In the process of inserting the hydrogenation gun into the hydrogenation port, the filling channel in the hydrogenation port is led through, so that liquid hydrogen in the liquid hydrogen storage tank is gasified into hydrogen to blow off a cavity between the hydrogenation gun and the hydrogenation port, then the filling channel in the hydrogenation gun is conducted to fill the liquid hydrogen, the whole process is automatically completed in the process of inserting the hydrogenation gun into the hydrogenation port, extra operation is not needed, the working efficiency is effectively improved, and the use experience is good.
Description
Technical Field
The invention relates to the technical field of low-temperature liquid filling, in particular to a liquid hydrogen filling device.
Background
The construction of a hydrogenation station is an important factor influencing the development of the hydrogen energy industry, and hydrogenation systems are currently divided into two types, namely a high-pressure normal-temperature hydrogen filling system and a low-pressure liquid hydrogen filling system. Compared with high-pressure hydrogen, the liquid hydrogen has high hydrogen storage density, low storage and transportation cost, low storage pressure and safety, so that the method has a wider prospect.
According to the planning of the national energy-saving and new energy automobile technical route map, with the increase of the hydrogen demand of a fuel cell vehicle, the number of hydrogen stations in China can be gradually increased, so that the domestic hydrogen market is still very large, most of the hydrogen stations operated in China are high-pressure hydrogen storage hydrogen stations, low-temperature liquid hydrogen stations are not put into use in the planning, as the hydrogen stations are just started, the related technology is not mature, liquid hydrogen filling equipment equipped for the liquid hydrogen stations is not available, the development of monomer equipment for liquid hydrogen filling is very important, the realization of the localization of the liquid hydrogen equipment is especially important, and the hydrogen station hydrogen energy management system has an important role in improving the strength of the hydrogen energy development and hydrogen station construction field in China.
Unlike liquefied natural gas, liquid hydrogen is extremely low in temperature, is extremely easy to gasify, and is dangerous when mixed with oxygen, so that a blowing function, a heat insulation function and safety must be considered for a liquid hydrogen filling device. The LNG filling gun is used for the relatively mature low-temperature liquid filling equipment in the current market, however, the functions are not embodied in the structure, and the LNG filling gun is not suitable for liquid hydrogen filling. And heavy weight and poor operability.
Furthermore, when general LNG liquid feeding rifle was the LNG car liquid feeding, operating personnel docked liquid feeding rifle and the gas port of dress on the LNG car, then twist grip forward, along the direction of gas port promptly, locked the liquid feeding rifle on the gas port, and when this process was gone on, liquid feeding rifle passageway and gas port intercommunication begin to annotate LNG liquid to the LNG car through liquid feeding rifle passageway, and it has not blown the air in the chamber between hydrogen feeding rifle and the gas port. Also mention among the prior art to blow the scheme of removing to the cavity between hydrogenation rifle and the hydrogenation mouth, but it often has designed the blowdown pipeline for one's sake, need in the grafting process, and manual control blowdown pipeline switches on, and its structure is complicated to operate also complicacy, is unfavorable for improving production efficiency.
In view of the above, the present invention is particularly proposed.
Disclosure of Invention
The technical problem to be solved by the invention is to overcome the defects of the prior art and provide a liquid hydrogen filling device, wherein the blowing and filling processes are automatically and sequentially executed in the process of inserting a hydrogenation gun into a hydrogenation port.
In order to solve the technical problems, the invention adopts the technical scheme that:
the liquid hydrogen filling device comprises a hydrogenation gun and a hydrogenation port connected to a liquid hydrogen storage tank, wherein the hydrogenation gun is provided with a first plugging part for plugging an internal filling channel, the hydrogenation port is provided with a second plugging part for plugging the internal filling channel, in the process that the hydrogenation gun is inserted into the hydrogenation port, the hydrogenation gun firstly pushes the second plugging part to shift to conduct the filling channel in the hydrogenation port, and then reversely pushes the first plugging part to shift to conduct the filling channel in the hydrogenation gun.
In the scheme, in the process that the hydrogenation gun is inserted into the hydrogenation port, the pilot leads to the filling channel in the hydrogenation port, so that liquid hydrogen in the liquid hydrogen storage tank is gasified into hydrogen to blow off a cavity between the hydrogenation gun and the hydrogenation port, then the filling channel in the hydrogenation gun is conducted to fill the liquid hydrogen, the whole process is automatically completed in the process that the hydrogenation gun is inserted into the hydrogenation port, extra operation is not needed, the working efficiency is effectively improved, and the use experience is good.
Preferably, the first plugging component comprises a first valve plug, a first elastic component and an ejector block, the first elastic component provides acting force of a normally closed hydrogenation gun internal filling channel of the first valve plug, the ejector block is arranged on the first valve plug, the second plugging component comprises a second valve plug, a second elastic component provides acting force of a normally closed hydrogenation gun internal filling channel of the second valve plug, and an ejector rod is arranged on the second valve plug, the ejector rod is abutted to the ejector block in the process that the hydrogenation gun is inserted into the hydrogenation port, and the elastic coefficient of the first elastic component is greater than that of the second elastic component.
In the above scheme, by designing that the elastic coefficient of the first elastic component is greater than that of the second elastic component, the second plugging component is pushed away first to conduct the filling channel in the hydrogenation port when the first plugging component and the second plugging component are abutted, and the first plugging component is pushed away later.
Preferably, a limiting structure for limiting the second valve plug to move to a certain position is arranged in the hydrogenation port.
In the above scheme, set up limit structure in the hydrogenation mouth for second valve plug rigidity ensures that second valve plug can reverse action on first shutoff part, makes first shutoff part pushed away, thereby switches on the inside filling passageway of hydrogenation rifle.
Preferably, the limiting structure comprises a limiting convex ring arranged on the inner wall of the filling channel in the hydrogenation port, a limiting convex part arranged in a protruding manner along the radial direction is arranged on the second valve plug, and after the second valve plug is displaced for a certain distance, the limiting convex part abuts against the limiting convex ring.
Preferably, the second valve plug comprises a cylindrical barrel, one end of the cylindrical barrel is open, the other end of the cylindrical barrel is provided with a plug portion in a sealing mode, the cylindrical barrel can slidably penetrate through the limiting convex ring, the second elastic part comprises a spring sleeved on the cylindrical barrel, two ends of the spring are respectively supported between the plug portion and the limiting convex ring in a limiting mode, and the limiting convex portion comprises a limiting convex rib arranged around the outer wall of the cylindrical barrel in a surrounding mode.
Preferably, the cylinder is internally provided with a liquid channel, and the cylinder wall of the cylinder is provided with a through hole communicated with a filling channel at the inner part of the hydrogenation port. The hydrogen sprayed out of the liquid hydrogen storage tank firstly enters the fluid channel, then enters the filling channel in the hydrogenation port through the through hole, then enters the cavity in the hydrogenation gun, and finally carries a small amount of air to be discharged from the splicing gap between the hydrogenation gun and the hydrogenation port after being spliced.
Preferably, the hydrogenation mouth includes hydrogenation mouth interior sleeve pipe, the hydrogenation rifle includes interior sleeve pipe of hydrogenation rifle, the internal diameter of the interior sleeve pipe entrance point of hydrogenation mouth is greater than interior sleeve pipe exit end external diameter of hydrogenation rifle, the interior sheathed tube exit end of hydrogenation rifle inserts the interior sheathed tube entrance point of hydrogenation mouth has the clearance between the interior sleeve pipe of hydrogenation rifle and the interior sleeve pipe of hydrogenation mouth, and the hydrogenation rifle promotes the second shutoff part and shifts and switch on the filling passageway of hydrogenation mouth, liquid hydrogen storage tank to let in the cavity between hydrogenation rifle and the hydrogenation mouth and blow off hydrogen, blow off hydrogen by the clearance is discharged.
Preferably, a sealing part is arranged in the inner sleeve of the hydrogenation port, after the outlet end of the inner sleeve of the hydrogenation gun abuts against the sealing part, the ejector rod on the second valve plug pushes the first valve plug to displace, a filling channel in the hydrogenation gun is conducted, and the liquid hydrogen filling device fills liquid hydrogen into the liquid hydrogen storage tank. In the scheme, the sealing part is designed, so that the gap between the hydrogenation gun and the hydrogenation port can be sealed, and the liquid hydrogen cannot be leaked when the liquid hydrogen is filled.
Preferably, the inner sleeve of the hydrogenation port is sequentially provided with a first pipe body and a second pipe body from the inlet end to the outlet end, the inner diameter of the first pipe body is larger than the inner diameter of the second pipe body and the outer diameter of the outlet end of the inner sleeve of the hydrogenation gun, the first pipe body and the second pipe body are connected through a transition taper pipe, and the sealing part comprises a sealing ring surface arranged on the inner wall of the transition taper pipe or on the inner wall of the second pipe body;
preferably, the outlet end of the inner sleeve of the hydrogenation gun is provided with a sealing ring which is in sealing fit with the sealing ring surface.
Preferably, including handle mechanism, the hydrogenation rifle includes hydrogenation rifle outside pipe and hydrogenation rifle outer tube, and hydrogenation rifle outer tube fixed mounting is in the sleeve pipe outside in the hydrogenation rifle, the cover of hydrogenation rifle outside pipe slidable is established on the hydrogenation rifle outer tube, handle mechanism includes rotatable coupling the push rod of hydrogenation rifle outside pipe, push rod pass through first connecting rod and connect the inside filling passageway of hydrogenation mouthful is switched on in proper order to the inside slip of hydrogenation mouth in hydrogenation rifle outer tube, push rod rotation, drive first connecting rod promotion hydrogenation rifle outer tube and the hydrogenation rifle interior sleeve pipe.
Preferably, the hydrogenation gun comprises a locking sleeve which is sleeved on an external pipe of the hydrogenation gun in a sliding manner, the hydrogenation port comprises a hydrogenation port outer sleeve which is fixedly arranged outside the hydrogenation port inner sleeve, the push rod is connected with the locking sleeve through a second connecting rod, in the rotating process of the push rod, the second connecting rod is firstly driven to push the locking sleeve to slide towards the hydrogenation port outer sleeve and be locked on the hydrogenation port outer sleeve, and then the first connecting rod is driven to drive the hydrogenation gun inner sleeve to slide towards the hydrogenation port inner sleeve;
preferably, a sliding groove is formed in the push rod along the length direction of the push rod, one end of the first connecting rod is installed in the sliding groove in a free sliding mode, the other end of the first connecting rod is rotatably connected to the outer sleeve of the hydrogenation gun, a connecting hole is formed in the push rod between the sliding groove and the outer pipe of the hydrogenation gun, and the second connecting rod is rotatably connected to the connecting hole.
After adopting the technical scheme, compared with the prior art, the invention has the following beneficial effects:
the liquid hydrogen filling device comprises a hydrogenation gun and a hydrogenation port connected to a liquid hydrogen storage tank, wherein the hydrogenation gun is provided with a first plugging part for plugging an internal filling channel, the hydrogenation port is provided with a second plugging part for plugging the internal filling channel, in the process that the hydrogenation gun is inserted into the hydrogenation port, the hydrogenation gun firstly pushes the second plugging part to displace to conduct the filling channel in the hydrogenation port, and then reversely pushes the first plugging part to displace after the hydrogenation port to conduct the filling channel in the hydrogenation gun. In the process of inserting the hydrogenation gun into the hydrogenation port, the filling channel in the hydrogenation port is led through, so that liquid hydrogen in the liquid hydrogen storage tank is gasified into hydrogen to blow off a cavity between the hydrogenation gun and the hydrogenation port, then the filling channel in the hydrogenation gun is conducted to fill the liquid hydrogen, the whole process is automatically completed in the process of inserting the hydrogenation gun into the hydrogenation port, extra operation is not needed, the working efficiency is effectively improved, and the use experience is good.
The following describes embodiments of the present invention in further detail with reference to the accompanying drawings.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention, are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the invention without limiting the invention to the right. It is obvious that the drawings in the following description are only some embodiments, and that for a person skilled in the art, other drawings can be derived from them without inventive effort. In the drawings:
in the drawings:
FIG. 1 is a schematic view of a hydrogenation gun according to the present invention
FIG. 2 is a schematic view of a hydrogenation port structure of the present invention
FIG. 3 is a schematic view of the locking state of the liquid hydrogen filling device according to the present invention;
FIG. 4 is a schematic view of the liquid hydrogen filling apparatus of the present invention in a blow-off state before filling liquid hydrogen;
fig. 5 is a schematic view of a state in which the liquid hydrogen filling apparatus of the present invention fills liquid hydrogen.
Wherein, 1-a hydrogenation gun outer sleeve outer tube, 2-a hydrogenation gun outer sleeve inner tube, 3-a hydrogenation gun inner sleeve inner tube, 4-a first elastic component, 5-a blow-off pipeline, 6-a second connecting rod, 7-a push rod, 8-a first connecting rod, 9-a locking sleeve, 10-a hydrogenation gun outer tube, 11-a limiting ball, 12-an O-ring, 13-a sealing ring, 14-a sealing sleeve, 15-a top block, 16-a first valve plug, 17-a sealing seat, 18-a hydrogenation port outer sleeve outer tube, 19-a hydrogenation port outer sleeve inner tube, 20-a hydrogenation port inner sleeve inner tube, 21-a push rod, 22-an annular sealing sleeve, 23-an elastic supporting component, 24-a first corrugated tube section, 25-a sealing sleeve/limiting part, 26-a pressure relief pipeline, 27-a gasket, 28-a second valve plug, 29-a hydrogen adding port sealing seat, 30-a second elastic component and 31-a fixed ring.
It should be noted that the drawings and the description are not intended to limit the scope of the inventive concept in any way, but to illustrate it by a person skilled in the art with reference to specific embodiments.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and the following embodiments are used for illustrating the present invention and are not intended to limit the scope of the present invention.
In the description of the present invention, it should be noted that the terms "upper", "lower", "front", "rear", "left", "right", "vertical", "inner", "outer", etc., indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, and are only for convenience of description and simplicity of description, but do not indicate or imply that the device or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention.
In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; can be mechanically or electrically connected; may be directly connected or indirectly connected through an intermediate. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
Example one
Referring to fig. 1 to 5, the embodiment provides a liquid hydrogen filling device, which includes a hydrogenation gun and a hydrogenation port connected to a liquid hydrogen storage tank, where the hydrogenation gun has a first plugging part for plugging an internal filling channel, the hydrogenation port has a second plugging part for plugging the internal filling channel, and when the hydrogenation gun is inserted into the hydrogenation port, the hydrogenation gun pushes the second plugging part to displace to conduct the filling channel in the hydrogenation port, and pushes the first plugging part to displace in a reverse direction after the hydrogenation port to conduct the filling channel in the hydrogenation gun.
In the process that the hydrogenation gun is inserted into the hydrogenation port, the filling channel in the hydrogenation port is led through in a leading mode, so that liquid hydrogen in the liquid hydrogen storage tank is gasified into hydrogen to blow off a cavity between the hydrogenation gun and the hydrogenation port, then the filling channel in the hydrogenation gun is conducted, the liquid hydrogen is filled, the whole process is automatically completed in the process that the hydrogenation gun is inserted into the hydrogenation port, extra operation is not needed, the working efficiency is effectively improved, and the use experience is good.
The first plugging component comprises a first valve plug 16 and a first elastic component 4 providing acting force of the first valve plug 16 for normally closing the filling channel inside the hydrogenation gun, the second plugging component comprises a second valve plug 28, a second elastic component 30 providing acting force of the second valve plug 28 for normally closing the filling channel inside the hydrogenation port and a push rod 21 arranged on the second valve plug 28, the push rod 21 is abutted against the first valve plug 16 in the process of inserting the hydrogenation gun into the hydrogenation port, and the elastic coefficient of the first elastic component 4 is greater than that of the second elastic component 30.
By designing the elastic coefficient of the first elastic component 4 to be larger than that of the second elastic component 30, the second plugging component is pushed away firstly when the first plugging component and the second plugging component are abutted, a filling channel in the hydrogenation port is communicated, and the first plugging component is pushed away later.
Preferably, a limiting structure for limiting the displacement of the second valve plug 28 to a certain position is arranged in the hydrogenation port.
In the above scheme, a limiting structure is arranged in the hydrogenation port, so that the position of the second valve plug 28 is fixed, the second valve plug 28 can be ensured to act on the first blocking part in a reverse direction, the first blocking part is pushed away, and the filling channel in the hydrogenation gun is communicated.
Referring to fig. 2, the limiting structure includes a limiting convex ring (not labeled in the figure) disposed on an inner wall of the charging passage in the hydrogenation port, a limiting convex portion (not labeled in the figure) disposed to protrude in a radial direction is disposed on the second valve plug 28, and after the second valve plug 28 is displaced by a certain distance, the limiting convex portion abuts against the limiting convex ring.
Preferably, the second valve plug 28 includes a cylindrical tube, one end of the cylindrical tube is open, the other end of the cylindrical tube is provided with a plug portion in a sealing manner, the cylindrical tube slidably penetrates through the limiting convex ring, the second elastic component 30 includes a spring sleeved on the cylindrical tube, two ends of the spring are respectively supported between the plug portion and the limiting convex ring in a limiting manner, and the limiting convex portion includes a limiting convex rib arranged around the outer wall of the cylindrical tube for a circle.
The inner part of the cylindrical barrel is provided with a liquid channel, and the wall of the cylindrical barrel is provided with a through hole communicated with a filling channel at the inner part of the hydrogenation hole. The hydrogen sprayed out of the liquid hydrogen storage tank firstly enters the fluid channel, then enters the filling channel in the hydrogenation port through the through hole, then enters the cavity in the hydrogenation gun, and finally carries a small amount of air to be discharged from the splicing gap between the hydrogenation gun and the hydrogenation port after being spliced.
Referring to fig. 4, the hydrogenation port includes an inner sleeve of the hydrogenation port, the hydrogenation gun includes an inner sleeve of the hydrogenation gun, an inner diameter of an inlet end of the inner sleeve of the hydrogenation port is larger than an outer diameter of an outlet end of the inner sleeve of the hydrogenation gun, an outlet end of the inner sleeve of the hydrogenation gun is inserted into an inlet end of the inner sleeve of the hydrogenation port, a gap is formed between the inner sleeve of the hydrogenation gun and the inner sleeve of the hydrogenation port, the hydrogenation gun pushes a second plugging part to shift to conduct a filling channel of the hydrogenation port, and the liquid hydrogen storage tank introduces blow-off hydrogen into a cavity between the hydrogenation gun and the hydrogenation port, and the blow-off hydrogen is discharged from the.
The inner part of the inner sleeve of the hydrogenation port is provided with a sealing part, the outlet end of the inner sleeve of the hydrogenation gun is abutted against the sealing part, the ejector rod 21 on the second valve plug 28 pushes the first valve plug 16 to shift, a filling channel in the hydrogenation gun is conducted, and the liquid hydrogen filling device fills liquid hydrogen into the liquid hydrogen storage tank. In the scheme, the sealing part is designed, so that the gap between the hydrogenation gun and the hydrogenation port can be sealed, and the liquid hydrogen cannot be leaked when the liquid hydrogen is filled.
Referring to fig. 2, the inner sleeve of the hydrogenation port is sequentially provided with a first tube and a second tube from an inlet end to an outlet end (from left to right), the inner diameter of the first tube is larger than the inner diameter of the second tube and the outer diameter of the outlet end of the inner sleeve of the hydrogenation gun, the first tube and the second tube are connected through a transition taper tube, the sealing part comprises a sealing ring surface arranged on the inner wall of the transition taper tube/the inner wall of the second tube, and the sealing ring surface is a local surface of an annular sealing sleeve 22;
and a sealing ring 13 which is in sealing fit with the sealing ring surface is arranged at the outlet end of the inner sleeve of the hydrogenation gun.
Example two
Referring to fig. 1 to 5, the present embodiment provides a liquid hydrogen filling device, including a hydrogenation gun and a hydrogenation port connected to a liquid hydrogen storage tank, where the hydrogenation gun is provided with a recovery pipeline, the hydrogenation gun and the hydrogenation port are in plug-in fit, the recovery pipeline is communicated with a cavity between the hydrogenation gun and the hydrogenation port, and recovers a small amount of air in the cavity, and blows off hydrogen and/or residual liquid hydrogen.
The recovery pipeline is arranged in the hydrogenation gun, hydrogen and residual liquid hydrogen are blown off in the process of fully recovering the liquid hydrogen filling, so that energy is saved, and safety accidents caused by hydrogen leakage are prevented.
Hydrogenation rifle includes hydrogenation rifle outer tube and sets up at the intraductal hydrogenation rifle of hydrogenation rifle outer tube in, the recovery pipeline is in including the shaping annular passage between the interior sleeve pipe of hydrogenation rifle outer tube and hydrogenation rifle, the hydrogenation mouth includes the interior sleeve pipe of hydrogenation mouth, the interior sleeve pipe of hydrogenation rifle and the interior sleeve pipe cooperation of pegging graft of hydrogenation mouth, annular passage is through the interior sleeve pipe of hydrogenation rifle and the interior sleeve pipe cavity between the interior sleeve pipe of hydrogenation mouth and the interior sleeve pipe of hydrogenation mouth in the grafting gap intercommunication hydrogenation rifle.
In the scheme, the blowing hydrogen enters the annular channel through the splicing gap between the inner sleeve of the hydrogenation gun and the inner sleeve of the hydrogenation port to be recycled.
Hydrogenation mouth establishes the outside hydrogenation mouth outer tube of sleeve pipe in the hydrogenation mouth including the cover, and one side that hydrogenation mouth outer tube is located the export of hydrogenation mouth and the interior sleeve pipe sealing connection of hydrogenation mouth, and one side that hydrogenation mouth outer tube is located the import of hydrogenation mouth is the opening end, sleeve pipe in the hydrogenation rifle and the interior sleeve pipe cooperation of pegging graft of hydrogenation mouth, the sealed grafting of opening end of hydrogenation rifle outer tube and hydrogenation mouth outer tube, annular passage is through the interior sleeve pipe of hydrogenation rifle and hydrogenation mouth interior grafting gap intercommunication hydrogenation rifle between the sleeve pipe and the interior cavity of hydrogenation mouth between the sleeve pipe.
In the above scheme, the open ends of the outer sleeve of the hydrogenation gun and the outer sleeve of the hydrogenation port are in sealed insertion, hydrogen/liquid hydrogen cannot be leaked, preferably, the outer wall of the outlet end of the outer sleeve of the hydrogenation gun is provided with the sealing ring, and when the outer sleeve of the hydrogenation gun is inserted into the outer sleeve of the hydrogenation port, the sealing ring is compressed and arranged between the outer sleeve of the hydrogenation gun and the outer sleeve of the hydrogenation port, so that the sealing and isolation effects are achieved.
Preferably, a sealing part is arranged inside the inner sleeve of the hydrogenation port, the outlet end of the inner sleeve of the hydrogenation gun abuts against the sealing part, the cavity between the annular channel and the inner sleeve of the hydrogenation gun and the inner sleeve of the hydrogenation port is isolated, and the outlet end of the inner sleeve of the hydrogenation gun is far away from the sealing part, so that the cavity between the annular channel and the inner sleeve of the hydrogenation gun and the cavity between the inner sleeve of the hydrogenation port is conducted.
In this embodiment, through setting up the sealing, then can realize that the cavity between annular passage and interior sleeve pipe of hydrogenation rifle and the interior sleeve pipe of hydrogenation mouth communicates or ends.
Referring to fig. 2, the inner sleeve of the hydrogenation gun is sequentially provided with a first tube and a second tube from an inlet end to an outlet end, the outer diameter of the first tube is larger than that of the second tube, the first tube and the second tube are connected through a transition taper tube, the sealing part comprises a sealing ring surface arranged on the inner wall of the transition taper tube/the inner wall of the second tube, and the outlet end of the inner sleeve of the hydrogenation gun is inserted into the first tube and contacts with or is far away from the sealing ring surface.
And a sealing ring 13 which is in sealing fit with the sealing ring surface is arranged at the outlet end of the inner sleeve of the hydrogenation gun.
The intraductal first valve plug 16 that is provided with of hydrogenation mouth, be provided with second valve plug 28 in the interior sleeve pipe of hydrogenation rifle, liquid hydrogen filling device has interior sleeve pipe of inserting of hydrogenation mouth in the hydrogenation rifle, and first valve plug 16 opens, and second valve plug 28 ends, and the intraductal exit end is kept away from in the hydrogenation rifle the first operating mode of blowing off of sealed anchor the first in the operating mode of blowing off, behind the interior hydrogen blow off of hydrogenation rifle in the liquid hydrogen storage tank and the interior cavity between the sleeve pipe of hydrogenation mouth, the warp annular channel discharges and retrieves.
In the scheme, before the liquid hydrogen is filled, the liquid hydrogen in the liquid hydrogen storage tank is gasified, and a small amount of air in the space between the hydrogenation gun and the hydrogenation port is blown out reversely. The invention does not use special blowing equipment for blowing, but uses the reverse blowing of the vehicle-mounted liquid hydrogen storage tank, and the scheme is simpler. The liquid hydrogen filling device further comprises a recovery tank, and the recovery tank is communicated with the annular channel and used for containing recovered hydrogen or liquid hydrogen.
Hydrogenation mouth is including pressure release pipeline 26, pressure release pipeline 26 runs through hydrogenation mouth outer tube, and the end extends to the interior sleeve pipe of hydrogenation mouth and adds the annular channel between the hydrogen mouth outer tube, the gas vent on the liquid hydrogen storage box is passed through the pipe connection to the relief valve.
In the actual process of filling liquid hydrogen, an exhaust port on the liquid hydrogen storage tank needs to be connected with a pressure relief pipeline 26 on the hydrogenation port through a pipeline, so that smooth liquid hydrogen filling is facilitated.
Preferably, as shown in fig. 1, a blowing pipeline 5 is included, and the blowing pipeline 5 is communicated to a filling channel in an inner sleeve of the hydrogenation gun.
Liquid hydrogen filling device has hydrogenation rifle interior sleeve pipe and pegs graft on the interior sleeve pipe of hydrogenation mouth, and first valve plug and second valve plug all end, and the sleeve pipe exit end is kept away from in the hydrogenation rifle the second blowdown operating mode of sealed anchor face, in the second blowdown operating mode, blow off pipeline 5 and inject hydrogen in the cavity between interior sleeve pipe of sleeve pipe and hydrogenation mouth in to the hydrogenation rifle for remaining liquid hydrogen is by the annular channel discharge recovery in the hydrogenation rifle.
The inner sleeve of the hydrogenation gun is internally provided with an interlayer, the inner sleeve of the hydrogenation gun is provided with a blowing port communicated with the interlayer and a hydrogenation channel inside the hydrogenation gun, and the blowing pipeline 5 is arranged in the interlayer and communicated with the blowing port. The interlayer is designed for thermal insulation purposes and will be described in detail below.
Preferably, the inner sleeve of the hydrogenation gun comprises an inner sleeve 3 of the hydrogenation gun and an outer sleeve of the hydrogenation gun, the inner sleeve 3 of the hydrogenation gun and the outer sleeve of the hydrogenation gun are connected at one side of an outlet of the hydrogenation gun, a first partition plate and a second partition plate (shown in fig. 1 and not labeled) are sequentially arranged in an interlayer between the inner sleeve 3 of the hydrogenation gun and the outer sleeve of the hydrogenation gun at intervals along the direction from the inlet to the outlet of the hydrogenation gun, a first cavity is formed between the first partition plate and the second partition plate in the interlayer, a second cavity is formed between the second partition plate and the outlet end of the inner sleeve of the hydrogenation gun, a blow-off port (shown in fig. 1 and not labeled) for communicating the second cavity and a filling channel of the hydrogenation gun is arranged on the inner sleeve 3 of the hydrogenation gun, the blow-off pipe sequentially and hermetically penetrates through the first partition plate and the second partition plate, and the tail end of the blow-off pipe is, wherein the first chamber is a vacuum isolation chamber.
EXAMPLE III
Referring to fig. 1 to 5, the present embodiment provides a liquid hydrogen filling apparatus, including a hydrogenation gun, a hydrogenation port, and a handle mechanism, where the hydrogenation gun includes a hydrogenation gun outer tube 10, a hydrogenation gun inner tube slidably disposed inside the hydrogenation gun outer tube 10, and a locking sleeve 9 slidably disposed outside the hydrogenation gun outer tube 10, where it should be noted that the defined hydrogenation gun inner tube includes a hydrogenation gun inner tube and a hydrogenation gun outer tube, and the hydrogenation gun inner tube and the hydrogenation gun outer tube are fixedly connected into a whole through a connecting rib.
Handle mechanism includes rotatable coupling hydrogenation rifle outside pipe 10's push rod 7, and push rod 7 connects through first connecting rod 8 locking sleeve 9 connects through second connecting rod 6 hydrogenation rifle inside pipe, push rod 7 rotate, drive first connecting rod 8 and promote locking sleeve 9 is to hydrogenation mouthful slip locking on the hydrogenation mouth, drive second connecting rod 6 and promote hydrogenation rifle inside pipe and slide to the hydrogenation mouth, switch on the interior notes passageway that adds of hydrogenation rifle and hydrogenation mouth.
Preferably, as shown in fig. 1, the inner tube of the hydrogenation gun has a first connecting seat, the outer tube 10 of the hydrogenation gun has a second connecting seat, the locking sleeve 9 has a third connecting seat, the first connecting seat, the second connecting seat and the third connecting seat are sequentially arranged along the extension direction of the hydrogenation gun, the push rod 7 is rotatably connected to the second connecting seat, one end of each of the first connecting rod 8 and the second connecting rod 6 is rotatably connected to the push rod 7, and the other end of each of the first connecting rod 8 and the second connecting rod 6 extends to the third connecting seat and the first connecting seat respectively and is rotatably connected to the third connecting seat and the first connecting seat.
When the push rod 7 rotates, the locking sleeve 9 is pushed to slide out of the hydrogenation cavity through the first connecting rod 8 respectively, the hydrogenation gun inner pipe is pushed to slide towards the hydrogenation port through the second connecting rod 6, and the handle driving structure is simple and practical and is not prone to failure.
In the rotating process of the push rod 7, the push rod 7 firstly drives the first connecting rod 8 to push the locking sleeve 9 to slide towards the hydrogenation port, the hydrogenation gun is locked on the hydrogenation port, and then drives the second connecting rod 6 to push the hydrogenation gun inner pipe to slide towards the hydrogenation port to conduct the hydrogenation gun inner pipe and a filling channel in the hydrogenation port.
In the embodiment, in the rotating process of the push rod 7, the first connecting rod 8 firstly pushes the locking sleeve 9 to slide towards the hydrogenation port, and then drives the second connecting rod 6 to drive the inner tube of the hydrogenation gun to slide towards the hydrogenation port after the hydrogenation gun and the hydrogenation port are locked, so that the hydrogenation port and the filling channel inside the hydrogenation gun are communicated for filling liquid hydrogen, the hydrogenation gun and the hydrogenation port are sealed and locked, and then filling is performed, and safety is ensured.
In order to realize the process, a sliding groove is formed in the push rod 7 along the length direction of the push rod 7, the second connecting rod 6 is freely and slidably mounted in the sliding groove, a connecting hole is formed in the push rod 7 and located between the sliding groove and the second connecting seat, and the first connecting rod 8 is rotatably connected to the connecting hole. The second connecting rod 6 is slidably mounted in the chute, so that in the rotating process of the push rod 7, when the end part of the second connecting rod 6 does not slide to the tail end of the chute, even if the push rod 7 rotates, the second connecting rod 6 can not apply thrust to the inner tube of the hydrogenation gun, and when the end part of the second connecting rod 6 slides to the lower end part of the chute, the inner tube of the hydrogenation gun can be driven to slide to the hydrogenation port along with the rotation of the push rod 7.
Preferably, second connecting rod 6 includes two support arms that the interval set up, and two support arms are located the both sides of spout on push rod 7 respectively, and through running through the connecting axle of spout, the one end that push rod 7 was kept away from to two support arms is connected, and rotatable the installation on the first connection pad.
Specifically, the push rod 7 is connected with the outer sleeve of the hydrogenation gun through the second connecting rod 6, the push rod 7 rotates to drive the second connecting rod 6 to push the outer sleeve of the hydrogenation gun and the inner sleeve of the hydrogenation gun to slide towards the inner part of the hydrogenation port, and the internal filling channel of the hydrogenation port and the internal filling channel of the hydrogenation gun are sequentially communicated so as to sequentially execute a blowing-off working condition and a filling working condition. For example, referring to fig. 3, a hydrogenation gun is inserted into a hydrogenation port, a folded handle is perpendicular to the hydrogenation gun, the hydrogenation gun is locked on the hydrogenation port, then the handle is pushed forward continuously as shown in fig. 4, and is rotated by a certain angle, for example, 8 °, a first plugging component in the hydrogenation gun pushes a second plugging component in the hydrogenation port to displace, liquid hydrogen in the liquid hydrogen storage tank flows out and gasifies to blow off air in the hydrogenation port and the hydrogenation gun, and the blown off air is discharged to a recovery pipeline in the hydrogenation gun through a gap between an inner sleeve of the hydrogenation gun and an inner sleeve of the hydrogenation port. After the blowing is finished, as shown in fig. 5, after the temperature sensor receives a signal, the temperature sensor controls to close the blowing pipeline 5, the pressure relief pipeline 26 on the filling port is opened, the handle is continuously rotated (about 13 °), the hydrogenation gun continuously moves towards the hydrogenation port, the end part of the inner sleeve of the hydrogenation gun is abutted against the sealing ring surface at the inner part of the hydrogenation port, the gap between the inner sleeve of the hydrogenation gun and the inner sleeve of the hydrogenation port is closed, meanwhile, the push rod 21 reversely pushes the first plugging part to shift and conduct due to the elastic force of the second elastic part 30 in the hydrogenation port and the action of the limiting structure, so that the filling channel in the hydrogenation port and the hydrogenation gun is conducted, high-pressure liquid hydrogen in the hydrogenation station flows out to fill the liquid hydrogen, after the filling is finished, as shown in fig. 3, the handle returns to the vertical state with the hydrogenation gun, at the moment, a gap is formed between the inner sleeve, and plugging the plugging parts in the hydrogenation gun and the hydrogenation port, and disconnecting the filling. And opening a valve switch (which is supposed to be arranged on a pipeline between the hydrogenation station and the hydrogenation gun) on a blow-off pipeline 5 in the hydrogenation gun, introducing normal-temperature hydrogen to complete blowing-off, and recovering residual liquid hydrogen generated in the filling process through a recovery pipe part in the hydrogenation gun. In addition, normal temperature hydrogen raises the temperature of the gun body, and has a quick defrosting function. The liquid hydrogen in the filling device is recovered, a recovery pipeline is disconnected after recovery is finished, the pressure value in the hydrogenation gun is detected to be lower than a certain value, when the temperature value is recovered to normal temperature, the handle is rotated reversely, the hydrogenation gun is pulled out, and the hydrogenation port is protected in a self-sealing mode.
As shown in fig. 2, the hydrogenation port includes a hydrogenation port outer sleeve, a limiting groove (see a groove at the upper left corner in fig. 2) is formed in the outer wall of the hydrogenation port outer sleeve, a limiting hole is formed in the hydrogenation gun outer tube 10, a limiting ball 11 is movably arranged in the limiting hole, the limiting ball 11 can float in the limiting hole for a certain distance up and down, the hydrogenation gun outer tube 10 is sleeved outside the hydrogenation port outer sleeve, the limiting ball 11 on the hydrogenation gun outer tube 10 is clamped in the limiting groove, and as shown in fig. 3, the locking sleeve 9 slides to cover and extrude the limiting ball 11, so that the hydrogenation gun outer tube 10 and the hydrogenation port outer sleeve are locked.
Locking sleeve 9 includes first sleeve pipe and second sleeve pipe from inside to outside in proper order, first lantern ring and second sleeve pipe smooth connection, second sheathed tube internal diameter is greater than first sleeve pipe, and locking sleeve pipe 9 is to hydrogenation mouthful roll-off, first sleeve pipe covers and extrudees spacing ball 11, locking sleeve pipe 9 slides and resets, the second sleeve pipe slides extremely spacing ball 11's top has the clearance with hydrogenation rifle outside pipe 10 surface, the restriction spacing ball 11 breaks away from spacing hole, hydrogenation rifle outside pipe 10 with hydrogenation mouthful outer tube unblock.
Preferably, the hydrogenation port comprises a hydrogenation port inner sleeve with a filling channel, the hydrogenation port inner sleeve comprises a first corrugated pipe section 24, and an elastic support part 23 is arranged on the hydrogenation port inner sleeve at the first corrugated pipe section.
In the above scheme, the corrugated pipe section is arranged on the inner sleeve of the hydrogenation port, and the elastic support part 23 is arranged on the corrugated pipe section, so that the structural design has many effective effects. At first, the stress transition of the inner sleeve of the hydrogenation port is effectively prevented, the buffering effect is achieved, in addition, through the design of the elastic supporting part 23, a certain pretightening force is achieved, the sealing of liquid hydrogen can be guaranteed when filling is carried out, and the compensation problem caused by abrasion can be solved.
Preferably, the inner tube of the hydrogenation gun comprises an inner tube of the hydrogenation gun with a filling channel, an annular sealing sleeve 22 and a limiting part arranged at an interval with the annular sealing sleeve 22 are arranged on the inner wall of the inner tube of the hydrogenation port, a sealing ring surface in contact fit with the outlet end of the inner tube of the hydrogenation gun is arranged on one side of the annular sealing sleeve 22 close to the inlet end of the hydrogenation port, a mounting seat is arranged on the other side of the annular sealing sleeve 22, the inner tube of the hydrogenation port is located between the annular sealing sleeve 22 and the limiting part, a first corrugated tube section 24 is arranged between the annular sealing sleeve 22 and the limiting part, and the elastic support part 23 comprises a spring arranged between the mounting seat and the limiting part.
When the inner sleeve of the hydrogenation gun is inserted into the inner sleeve of the hydrogenation port, the inner sleeve is abutted against the sealing ring surface of the annular sealing sleeve 22 or has a gap.
Preferably, referring to fig. 2, the edge of the inlet end of the inner sleeve of the hydrogenation port is provided with a second bellows section and a protective structure for preventing the second bellows from being compressed excessively. When the hydrogenation gun is in splicing fit with the hydrogenation port, the inlet end of the sleeve in the hydrogenation port is directly contacted with the hydrogenation gun and is easily stressed and damaged, so that the second corrugated pipe section is arranged at the inlet end of the sleeve in the hydrogenation port, and the inlet end of the sleeve in the hydrogenation port is effectively prevented from being stressed and damaged.
Preferably, the inner sleeve of the hydrogenation port is sequentially provided with a first pipe body and a second pipe body from an inlet end to an outlet end, the inner diameter of the first pipe body is larger than that of the second pipe body, the first pipe body is connected with the second pipe body through a transition taper pipe, the first corrugated pipe is arranged on the second pipe body, the second corrugated pipe is arranged on the first pipe body, the protection structure comprises a return pipe which is folded from the outer end part of the second corrugated pipe to one side inside the inner sleeve of the hydrogenation port, and a supporting surface which is matched with the end part of the return pipe in a supporting manner is arranged on the transition taper pipe.
In the above scheme, the outer end of the second corrugated pipe is bent back to form a return pipe, the end of the return pipe is in a clearance with the support surface on the transition conical pipe in a natural state, and when the inlet end of the hydrogenation port is extruded by the hydrogenation gun, the end of the return pipe is stopped on the support surface to prevent the inlet end of the inner sleeve pipe of the hydrogenation port from seriously deforming.
Example four
Referring to fig. 1 to 4, in the fourth embodiment, a liquid hydrogen filling apparatus is provided, which includes a hydrogenation gun and a hydrogenation port, and at least a vacuum isolation cavity is disposed on the hydrogenation port. This embodiment is through the design through vacuum isolation chamber, and reduction that can be very big leaks heat, prevents that the outer wall from frosting, improve equipment's heat preservation effect.
The hydrogenation port comprises a hydrogenation port outer sleeve and a hydrogenation port inner sleeve arranged in the hydrogenation port outer sleeve, the hydrogenation port inner sleeve is provided with a filling channel, and a vacuum isolation cavity is arranged in the tube wall of the hydrogenation port outer sleeve.
In the scheme, the outer sleeve of the hydrogenation port and the inner sleeve of the hydrogenation port are fixedly connected into a whole, and the hydrogenation port is designed by an inner layer and an outer layer, so that the heat insulation performance is further improved.
Preferably, the hydrogenation mouth outer tube includes hydrogenation mouth outer tube inner tube 19 and the hydrogenation mouth outer tube 18 that set gradually from inside to outside, the open end border of hydrogenation mouth outer tube 18 is provided with the face of buckling to the inboard buckling, the outer surface sealing laminating of hydrogenation mouth outer tube inner tube 19 the terminal surface of the face of buckling has formed the vacuum isolation chamber between hydrogenation mouth outer tube 18 and hydrogenation mouth outer tube inner tube 19.
Preferably, the hydrogenation port inner sleeve is also provided with a vacuum isolation cavity.
In the scheme, the vacuum isolation cavity is also arranged on the inner sleeve of the hydrogenation port, and two layers of vacuum isolation cavities are arranged outside the hydrogenation port, so that the heat insulation performance is further improved.
Preferably, the hydrogenation port inner sleeve comprises a hydrogenation port inner sleeve tube 20 with a filling channel and a hydrogenation port inner sleeve tube outer tube from inside to outside in sequence, the opening end of the hydrogenation port inner sleeve tube outer tube is bent inwards and is in sealing connection with the hydrogenation port inner sleeve tube 20, and a vacuum isolation cavity is formed between the hydrogenation port inner sleeve tube outer tube and the hydrogenation port inner sleeve tube 20.
The hydrogenation port is provided with a first evacuating nozzle which is communicated with two vacuum isolation cavities in the hydrogenation port;
preferably, the first evacuating nozzle sequentially penetrates through the outer tube of the hydrogenation port and the tail end of the outer tube of the inner tube of the hydrogenation port from outside to inside and is positioned in a vacuum isolation cavity in the inner tube of the hydrogenation port, and a pipe section of the first evacuating nozzle positioned in the outer tube of the hydrogenation port is provided with a communication port communicated with the vacuum isolation cavity in the outer tube of the hydrogenation port;
or, referring to the lower part of fig. 2, the inner sleeve of the hydrogenation port is communicated with the vacuum isolation chamber in the outer sleeve of the hydrogenation port, a bending part for plugging an interlayer between the inner sleeve of the hydrogenation port and the outer sleeve of the hydrogenation port is arranged on the inner sleeve of the outer sleeve of the hydrogenation port, a through port is arranged on one side of the inner sleeve of the outer sleeve of the hydrogenation port, which is close to the outlet end, and the through port is communicated with two vacuum isolation chambers, and a first evacuating nozzle is arranged on the outer sleeve of the hydrogenation port and is communicated with the two vacuum isolation chambers in the hydrogenation port.
In the scheme, two vacuum isolation cavities in the hydrogenation port are simultaneously vacuumized through the first vacuumizing nozzle. The structure is simple, and an exhaust pipe is not required to be respectively arranged for the two vacuum chambers.
Preferably, a vacuum isolation cavity is arranged on the hydrogenation gun.
Preferably, the hydrogenation gun comprises a hydrogenation gun outer sleeve and a hydrogenation gun inner sleeve arranged inside the hydrogenation gun outer sleeve, the hydrogenation gun inner sleeve is provided with a filling channel, and a vacuum isolation cavity is arranged in the hydrogenation gun outer sleeve.
In the scheme, the outer sleeve of the hydrogenation gun and the inner sleeve of the hydrogenation gun are fixedly connected into a whole through the connecting rib.
Preferably, the vacuum isolation cavity in the hydrogenation gun outer sleeve extends to the outlet end of the hydrogenation gun outer sleeve, the vacuum isolation cavity in the hydrogenation port outer sleeve extends to the inlet end of the hydrogenation port outer sleeve, and when the hydrogenation gun inner sleeve is communicated with the hydrogenation port inner sleeve, the outlet end of the hydrogenation gun outer sleeve is close to the inlet end of the hydrogenation port outer sleeve to be contacted with the inlet end of the hydrogenation port outer sleeve, so that the joint of the hydrogenation port inner sleeve and the hydrogenation gun inner sleeve is coated.
In the above scheme, when the hydrogenation gun is in splicing fit with the hydrogenation port, the end parts of the outer sleeve of the hydrogenation port and the outer sleeve of the hydrogenation gun are contacted, a temporary vacuum environment is formed at the joint of the outer sleeve and the outer sleeve of the hydrogenation gun, the heat leakage can be greatly reduced by adopting a double-vacuum mode, and the heat preservation effect of the equipment is improved.
Preferably, the hydrogenation rifle outer tube includes hydrogenation rifle outer tube inner tube 2 and the hydrogenation rifle outer tube 1 that sets gradually from inside to outside, the tip that hydrogenation rifle outer tube 1 is located the hydrogenation rifle exit end is equipped with the first face of buckling to the inboard perpendicular buckle, the terminal surface and the 2 sealing connection in hydrogenation rifle outer tube of first face of buckling, the tip that hydrogenation mouth outer tube 18 is located the hydrogenation mouth entrance point is equipped with the second face of buckling to the inboard perpendicular buckle, this second the face of buckling with the surface sealing connection of hydrogenation mouth outer tube inner tube 19, during sleeve pipe and the interior sleeve pipe intercommunication of hydrogenation mouth in the hydrogenation rifle, first face of buckling and second are close to the laminating.
Preferably, the hydrogenation gun inner sleeve is provided with a vacuum isolation cavity.
Preferably, the sleeve pipe is in the hydrogenation rifle from inside to outside including in the hydrogenation rifle that has the filling passageway sleeve pipe inner tube 3 and the outer tube in the hydrogenation rifle in proper order, the open end of the sleeve pipe outer tube is buckled to the inboard in the hydrogenation rifle to with sleeve pipe inner tube 3 sealing connection in the hydrogenation rifle, sleeve pipe outer tube and hydrogenation rifle in the hydrogenation rifle between sleeve pipe inner tube 3 has formed the vacuum isolation chamber.
In the scheme, the hydrogenation gun is also provided with an inner layer vacuum isolation cavity and an outer layer vacuum isolation cavity, so that the heat preservation effect of the equipment is ensured. And the multilayer structure design in the hydrogenation rifle has further strengthened the heat preservation effect, prevents that the external structure from frosting, influences liquid hydrogen filling device's use.
Preferably, the hydrogenation gun is provided with a second evacuating nozzle which is respectively communicated with the two vacuum isolation cavities in the hydrogenation gun.
Preferably, the exhaust pipe penetrates through the outer sleeve of the hydrogenation gun from outside to inside and extends to a vacuum isolation cavity inside the inner sleeve of the hydrogenation gun, and the pipe section of the second evacuation nozzle in the outer sleeve of the hydrogenation gun is provided with a communication port communicated with the vacuum isolation cavity inside the outer sleeve of the hydrogenation gun.
It should be noted that the above embodiments of the present invention can be combined with each other to obtain various technical solutions.
Although the present invention has been described with reference to a preferred embodiment, it should be understood that various changes, substitutions and alterations can be made herein without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (10)
1. The liquid hydrogen filling device is characterized by comprising a hydrogenation gun and a hydrogenation port connected to a liquid hydrogen storage tank, wherein the hydrogenation gun is provided with a first plugging part for plugging an internal filling channel, the hydrogenation port is provided with a second plugging part for plugging the internal filling channel, in the process that the hydrogenation gun is inserted into the hydrogenation port, the hydrogenation gun firstly pushes the second plugging part to displace to conduct the filling channel in the hydrogenation port, and reversely pushes the first plugging part to displace after the hydrogenation port to conduct the filling channel in the hydrogenation gun.
2. The liquid hydrogen filling apparatus according to claim 1, wherein the first plugging member includes a first valve plug, a first elastic member providing an acting force for normally closing the filling passage inside the hydrogenation gun with the first valve plug, and an ejector block disposed on the first valve plug, the second plugging member includes a second valve plug, a second elastic member providing an acting force for normally closing the filling passage inside the hydrogenation port with the second valve plug, and an ejector rod disposed on the second valve plug, the ejector rod abuts against the ejector block during insertion of the hydrogenation gun into the hydrogenation port, and an elastic coefficient of the first elastic member is greater than an elastic coefficient of the second elastic member.
3. The liquid hydrogen filling apparatus according to claim 2, wherein a limiting structure is provided in the hydrogen inlet to limit the second valve plug from being displaced to a certain position.
4. The liquid hydrogen filling apparatus according to claim 3, wherein the limiting structure comprises a limiting convex ring disposed on an inner wall of the filling passage in the hydrogenation port, the second valve plug is provided with a limiting convex portion protruding in a radial direction, and after the second valve plug is displaced by a certain distance, the limiting convex portion abuts against the limiting convex ring.
5. The liquid hydrogen filling apparatus according to claim 4, wherein the second valve plug comprises a cylindrical tube, one end of the cylindrical tube is open, the other end of the cylindrical tube is provided with a plug portion in a sealing manner, the cylindrical tube is slidably disposed through the limit convex ring, the second elastic member comprises a spring sleeved on the cylindrical tube, two ends of the spring are respectively limited and supported between the plug portion and the limit convex ring, and the limit convex portion comprises a limit convex rib disposed around the outer wall of the cylindrical tube;
preferably, the cylinder is internally provided with a liquid channel, and the cylinder wall of the cylinder is provided with a through hole communicated with a filling channel at the inner part of the hydrogenation port.
6. The liquid hydrogen filling device according to claim 5, wherein the hydrogenation port includes an inner sleeve of the hydrogenation gun, the hydrogenation gun includes an inner sleeve of the hydrogenation gun, the inner diameter of the inlet end of the inner sleeve of the hydrogenation port is larger than the outer diameter of the outlet end of the inner sleeve of the hydrogenation gun, the outlet end of the inner sleeve of the hydrogenation gun is inserted into the inlet end of the inner sleeve of the hydrogenation port, a gap is formed between the inner sleeve of the hydrogenation gun and the inner sleeve of the hydrogenation port, the hydrogenation gun pushes the second plugging member to displace to conduct the filling channel of the hydrogenation port, and the liquid hydrogen storage tank introduces blowing-off hydrogen into a cavity between the hydrogenation gun and the hydrogenation port, and the blowing-off hydrogen is discharged from.
7. The liquid hydrogen filling device according to claim 6, wherein a sealing portion is disposed inside the inner sleeve of the hydrogenation port, the outlet end of the inner sleeve of the hydrogenation gun abuts against the sealing portion, the ejector rod on the second valve plug pushes the first valve plug to displace, the filling channel in the hydrogenation gun is conducted, and the liquid hydrogen filling device fills liquid hydrogen into the liquid hydrogen storage tank.
8. The liquid hydrogen filling device according to claim 7, wherein the inner sleeve of the hydrogenation port is provided with a first tube and a second tube in sequence from the inlet end to the outlet end, the inner diameter of the first tube is larger than the inner diameter of the second tube and the outer diameter of the outlet end of the inner sleeve of the hydrogenation gun, the first tube and the second tube are connected through a transition taper tube, and the sealing part comprises a sealing ring surface arranged on the inner wall of the transition taper tube/the inner wall of the second tube;
preferably, the outlet end of the inner sleeve of the hydrogenation gun is provided with a sealing ring which is in sealing fit with the sealing ring surface.
9. The liquid hydrogen filling device according to claim 6, comprising a handle mechanism, wherein the hydrogenation gun comprises a hydrogenation gun outer tube and a hydrogenation gun outer tube, the hydrogenation gun outer tube is fixedly mounted outside the hydrogenation gun inner tube, the hydrogenation gun outer tube is slidably sleeved on the hydrogenation gun outer tube, the handle mechanism comprises a push rod rotatably connected with the hydrogenation gun outer tube, the push rod is connected with the hydrogenation gun outer tube through a second connecting rod, the push rod rotates to drive the second connecting rod to push the hydrogenation gun outer tube and the hydrogenation gun inner tube to slide towards the inside of the hydrogenation port, and the hydrogenation port inner filling channel and the hydrogenation gun inner filling channel are sequentially communicated.
10. The liquid hydrogen filling apparatus according to claim 9, wherein the hydrogenation gun includes a locking sleeve slidably fitted over an outer tube of the hydrogenation gun, the hydrogenation port includes a hydrogenation port outer tube fixedly disposed outside the hydrogenation port inner tube, the push rod is connected to the locking sleeve through a first connecting rod, during rotation of the push rod, the first connecting rod is first driven to push the locking sleeve to slide towards the hydrogenation port outer tube, and to be locked on the hydrogenation port outer tube, and then the second connecting rod is driven to drive the hydrogenation gun inner tube to slide towards the hydrogenation port inner tube;
preferably, a sliding groove is formed in the push rod along the length direction of the push rod, one end of the second connecting rod is installed in the sliding groove in a free sliding mode, the other end of the second connecting rod is rotatably connected to the outer sleeve of the hydrogenation gun, a connecting hole is formed in the push rod between the sliding groove and the outer pipe of the hydrogenation gun, and the first connecting rod is rotatably connected to the connecting hole.
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| CN201910983027.XA CN110864219B (en) | 2019-10-16 | 2019-10-16 | Liquid hydrogen filling device |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113148938A (en) * | 2021-05-07 | 2021-07-23 | 苏州赛智达智能科技有限公司 | Ultra-low temperature liquid filling device |
| CN115164094A (en) * | 2022-07-01 | 2022-10-11 | 成都安迪生测量有限公司 | Liquid hydrogen filling device and filling method |
| CN115596994A (en) * | 2022-09-07 | 2023-01-13 | 南通大学（Cn） | Active hydrogenation device of hydrogen energy |
Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2146641Y (en) * | 1992-07-30 | 1993-11-17 | 王克龙 | Gun for filling with liquefied petroleum gases |
| US5301723A (en) * | 1992-11-06 | 1994-04-12 | Hydra Rig, Inc. | Apparatus and method of preventing ice accumulation on coupling valves for cryogenic fluids |
| EP1437543A1 (en) * | 2002-12-18 | 2004-07-14 | Witt-Gasetechnik GmbH & Co. KG | Quick-connect coupling with actuating device for the transfer of a gaseous and/or liquid medium |
| JP2006162033A (en) * | 2004-12-10 | 2006-06-22 | Meiko Sangyo Kk | High-pressure gas filling device |
| CN201228852Y (en) * | 2008-06-03 | 2009-04-29 | 北京航天发射技术研究所 | Fast connecting device for charging liquid at low-temperature |
| CN104390128A (en) * | 2014-11-20 | 2015-03-04 | 四川兴良川深冷科技有限公司 | LNG form type pneumatic liquid adding gun |
| CN205065283U (en) * | 2015-07-27 | 2016-03-02 | 成都安迪生测量有限公司 | Liquid feeding rifle |
| CN206018268U (en) * | 2016-08-30 | 2017-03-15 | 成都安迪生测量有限公司 | A kind of intelligent filling gun |
| US20170101304A1 (en) * | 2015-04-15 | 2017-04-13 | Acd, Llc | Liquid natural gas gun-style nozzle |
| US20180134148A1 (en) * | 2016-11-16 | 2018-05-17 | Tatsuno Corporation | Filling device |
| CN108050385A (en) * | 2018-01-15 | 2018-05-18 | 四川兴良川深冷科技有限公司 | LNG ship filling apparatus |
| JP2018080745A (en) * | 2016-11-16 | 2018-05-24 | 株式会社タツノ | Filling device |
| CN109654370A (en) * | 2019-01-29 | 2019-04-19 | 成都瑞恒达机电设备有限公司 | A kind of pneumatic liquid feeding rifle |
| CN109931499A (en) * | 2019-02-21 | 2019-06-25 | 北京航天试验技术研究所 | A kind of internal pressure balanced type adds hydrogen rifle and the internal pressure balanced type to add the application method of hydrogen rifle |
| CN109931498A (en) * | 2019-02-21 | 2019-06-25 | 北京航天试验技术研究所 | A kind of application method of long-range hydrogenation plant and the long-range hydrogenation plant |
| CN211289557U (en) * | 2019-10-16 | 2020-08-18 | 北京航天试验技术研究所 | Liquid hydrogen filling device |
-
2019
- 2019-10-16 CN CN201910983027.XA patent/CN110864219B/en active Active
Patent Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2146641Y (en) * | 1992-07-30 | 1993-11-17 | 王克龙 | Gun for filling with liquefied petroleum gases |
| US5301723A (en) * | 1992-11-06 | 1994-04-12 | Hydra Rig, Inc. | Apparatus and method of preventing ice accumulation on coupling valves for cryogenic fluids |
| EP1437543A1 (en) * | 2002-12-18 | 2004-07-14 | Witt-Gasetechnik GmbH & Co. KG | Quick-connect coupling with actuating device for the transfer of a gaseous and/or liquid medium |
| JP2006162033A (en) * | 2004-12-10 | 2006-06-22 | Meiko Sangyo Kk | High-pressure gas filling device |
| CN201228852Y (en) * | 2008-06-03 | 2009-04-29 | 北京航天发射技术研究所 | Fast connecting device for charging liquid at low-temperature |
| CN104390128A (en) * | 2014-11-20 | 2015-03-04 | 四川兴良川深冷科技有限公司 | LNG form type pneumatic liquid adding gun |
| US20170101304A1 (en) * | 2015-04-15 | 2017-04-13 | Acd, Llc | Liquid natural gas gun-style nozzle |
| CN205065283U (en) * | 2015-07-27 | 2016-03-02 | 成都安迪生测量有限公司 | Liquid feeding rifle |
| CN206018268U (en) * | 2016-08-30 | 2017-03-15 | 成都安迪生测量有限公司 | A kind of intelligent filling gun |
| US20180134148A1 (en) * | 2016-11-16 | 2018-05-17 | Tatsuno Corporation | Filling device |
| JP2018080745A (en) * | 2016-11-16 | 2018-05-24 | 株式会社タツノ | Filling device |
| CN108050385A (en) * | 2018-01-15 | 2018-05-18 | 四川兴良川深冷科技有限公司 | LNG ship filling apparatus |
| CN109654370A (en) * | 2019-01-29 | 2019-04-19 | 成都瑞恒达机电设备有限公司 | A kind of pneumatic liquid feeding rifle |
| CN109931499A (en) * | 2019-02-21 | 2019-06-25 | 北京航天试验技术研究所 | A kind of internal pressure balanced type adds hydrogen rifle and the internal pressure balanced type to add the application method of hydrogen rifle |
| CN109931498A (en) * | 2019-02-21 | 2019-06-25 | 北京航天试验技术研究所 | A kind of application method of long-range hydrogenation plant and the long-range hydrogenation plant |
| CN211289557U (en) * | 2019-10-16 | 2020-08-18 | 北京航天试验技术研究所 | Liquid hydrogen filling device |
Non-Patent Citations (2)
| Title |
|---|
| 梁月华;: "浅谈冷媒加注枪的原理及结构", 装备制造技术, no. 11, 15 November 2009 (2009-11-15) * |
| 路兰卿;郁焕礼;: "大口径液氢真空截止阀的结构设计", 机电产品开发与创新, no. 05, 28 September 2010 (2010-09-28) * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113148938A (en) * | 2021-05-07 | 2021-07-23 | 苏州赛智达智能科技有限公司 | Ultra-low temperature liquid filling device |
| CN115164094A (en) * | 2022-07-01 | 2022-10-11 | 成都安迪生测量有限公司 | Liquid hydrogen filling device and filling method |
| CN115164094B (en) * | 2022-07-01 | 2023-10-27 | 成都安迪生测量有限公司 | Liquid hydrogen filling device and filling method |
| CN115596994A (en) * | 2022-09-07 | 2023-01-13 | 南通大学（Cn） | Active hydrogenation device of hydrogen energy |
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