CN110861383A - Novel super-matte fingerprint-free board and preparation process thereof - Google Patents
Novel super-matte fingerprint-free board and preparation process thereof Download PDFInfo
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- CN110861383A CN110861383A CN201910889330.3A CN201910889330A CN110861383A CN 110861383 A CN110861383 A CN 110861383A CN 201910889330 A CN201910889330 A CN 201910889330A CN 110861383 A CN110861383 A CN 110861383A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
- B29C63/02—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B29/005—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- B32B38/0008—Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/08—Impregnating
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- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
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- B32B2038/0052—Other operations not otherwise provided for
- B32B2038/0076—Curing, vulcanising, cross-linking
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- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
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- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
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- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
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Abstract
The invention discloses a novel super-matte non-fingerprint plate, which comprises a core plate and decorative papers arranged on two surfaces of the core plate; the core board is made by compounding a plurality of layers of gum dipping paper and then performing hot pressing; the decorative paper is gum dipping paper, the surface of the decorative paper is coated with UV glue, and after the UV glue is cured by UV illumination and is cured by EB energy, a decorative pattern is formed on the surface of the decorative paper; and a protective film is arranged on the outer surface of the decorative paper. The invention also provides a preparation process of the novel super-matte fingerprint-free board, which comprises the following steps: 1) preparing melamine impregnated paper and impregnated core paper; 2) gluing and dual curing of UV glue; 3) hot-press molding; 4) coating a film; 5) and packaging and warehousing. The decorative paper of the invention adopts UV curing and EB (accelerated high-energy electron beam) curing to process various patterns by utilizing electron beams, and also ensures that no residual fingerprints are left, ensures the cleanness of the surface of the decorative paper, and further can greatly reduce the production cost of the decorative paper.
Description
Technical Field
The invention belongs to the field of decorative plates, and particularly relates to a novel super-matte fingerprint-free plate and a preparation process thereof.
Background
The decorative board is used in decoration industry, has the characteristics of high stability, shock resistance, falling resistance, cold resistance, heat resistance, fire resistance, moisture resistance and burning resistance, and has the density of 1.4-1.5g/cm3In the meantime. The decorative board has wide application range, and kitchen ware table boards, wash table boards, dining tables, desks, door leaves in household life, and even bathroom compartments, wash hand tables, reception counters, storage cabinets, ceilings, office tables, office compartments and the like in public places can be made of the decorative board.
When the decorative board is used, fingerprints are printed on the decorative board due to frequent contact of people, so that the fingerprint-free board becomes a trend of decorating the board.
At present, the traditional fingerprint-free board is manufactured by a matte release film, but the matte release film can only be imported, is not produced at home, has high cost, needs an initiator for producing the UV resin required by the fingerprint-free board, is easy to migrate, has certain toxicity, and can cause certain pollution, and the board manufactured by the method cannot be used in the food industry and the pharmaceutical industry.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a novel super-matte fingerprint-free plate and a preparation process thereof, the design is reasonable, different patterns are processed by utilizing a UV processing and EB processing dual curing process, the attractiveness of the surface patterns of the decorative plate is improved, the decorative plate has a natural pattern feeling, good ultraviolet resistance, acid and alkali corrosion resistance, scratch resistance and wear resistance, meanwhile, the surface patterns of the fingerprint-free plate are wavy, super-matte reflection is avoided, light pollution is avoided, the plate is safe and environment-friendly, toxic substances such as an inducer cannot be used in the fingerprint-free plate, food pollution is avoided, and the fingerprint-free plate can be used in the food and medicine industries.
In order to achieve the purpose, the invention provides the following technical scheme:
the utility model provides a novel super inferior light does not have fingerprint board which characterized in that: comprises a core board and decorative paper arranged on two surfaces of the core board; the core board is made by compounding a plurality of layers of gum dipping paper and then performing hot pressing; the decorative paper is gum dipping paper, the surface of the decorative paper is coated with UV glue, and after the UV glue is cured by UV illumination and is cured by EB energy, a decorative pattern is formed on the surface of the decorative paper; and a protective film is arranged on the outer surface of the decorative paper.
The invention also provides a preparation process of the novel super-matte fingerprint-free board, which is characterized by comprising the following steps of: the method comprises the following steps:
1) preparing melamine impregnated paper and impregnated core paper;
2) gluing and dual curing of UV glue;
3) hot-press molding;
4) coating a film;
5) and packaging and warehousing.
As an optimized technical scheme, the preparation steps of the melamine impregnated paper are as follows: processing by adopting a coating and drying integrated machine, adding purchased melamine glue into a glue dipping tank, automatically feeding purchased decorative paper, and enabling the decorative paper to pass through the glue dipping tank; the glue roller stained with the melamine glue is uniformly contacted with the surface of the decorative paper, and a glue layer is formed on the surface of the decorative paper; then, the decorative paper with the surface adhered with the glue layer enters an oven to be dried, the temperature of the oven is changed from low to high to low, and the heat source of the oven is provided by pipeline steam or natural gas boiler steam; and after drying the impregnated decorative paper, cutting off redundant raw paper leftover materials to obtain the finished melamine impregnated paper.
As an optimized technical scheme, the preparation steps of the gum dipping core paper are as follows: processing by adopting a coating and drying integrated machine, adding purchased fireproof core paper into a glue dipping tank, automatically feeding the purchased fireproof core paper, and enabling the fireproof core paper to pass through the glue dipping tank; the rubber roller stained with the melamine glue is uniformly contacted with the surface of the fireproof core paper, and a glue layer is formed on the surface of the fireproof core paper; then, the fireproof core paper with the surface adhered with the glue layer enters an oven to be dried, the temperature of the oven is reduced from low to high to low, and the heat source of the oven is provided by pipeline steam or natural gas boiler steam; and after the impregnated fireproof core paper is dried, cutting off redundant leftover materials of the base paper to obtain the finished impregnated fireproof core paper.
As an optimized technical scheme, the steps of gluing and curing the UV glue are as follows: adding UV glue into a glue tank of a decorative board production line, and gluing the binding surface of the melamine impregnated paper by a glue spreader; then, under the protection of nitrogen, irradiating by an excimer lamp of 180nm, then realizing secondary curing by an accelerated high-energy electron beam process, and finally preparing the double-cured decorative paper.
As an optimized technical scheme, the hot-press forming method comprises the following steps: matching the gum dipping fireproof core paper and the decorative paper, conveying the paper to a full-automatic intelligent high-temperature high-pressure large-scale vacuum press, controlling the temperature of the vacuum press to be 120-160 ℃, rolling the matched paper roll up and down, and mutually bonding and curing glue covered on the paper by utilizing high temperature to prepare a semi-finished decorative plate.
As an optimized technical scheme, the film covering steps are as follows: covering a layer of protective film made of a PVC film on the surface of the semi-finished dual-curing EBC plate by a film covering machine to prepare a finished decorative plate; the softening temperature of the PVC film is 80 ℃.
EB curing is a form of radiation curing. It is a process of inducing specially prepared one hundred percent reactive liquid to be quickly converted into solid by taking electron beams as radiation sources. The principle is as follows: firstly, high-energy electrons interact with paint or ink molecules to decompose the paint or ink molecules into free radicals; then, the free radical reacts with the C ═ C double bond to form a propagating chain; finally, the chain-extending chain reacts with the rest of the components of the coating or ink, so that the cured coating is crosslinked and the crosslinking density is increased. Due to the high energy of the irradiated electrons, the above reaction is often accompanied by negative reactions such as molecular degradation and molecular ion rearrangement. The EB cured coating thus produces a greater degree of branching and a higher crosslink density.
EB curing requires dedicated curing equipment. The working principle is as follows: after the electrons are emitted from a group of linear cathode plates, the electrons are accelerated by a vertical uniform electric field, and curtain-shaped electron beams are obtained under an accelerator irradiation box. The acceleration voltage is not high (less than 500kV) because the irradiated article is closer to the electric field, but the power is higher because of the large output current. The linear cathode gun is far more compact than scanning type equipment, is easier to install on a production line and is easier to shield.
Due to the adoption of the technical scheme, compared with the prior art, the invention has the beneficial effects that:
1. the decorative paper of the invention adopts UV curing and EB (accelerated high-energy electron beam) curing to process various patterns by utilizing electron beams, and also ensures that no residual fingerprints are left, ensures the cleanness of the surface of the decorative paper, and further can greatly reduce the production cost of the decorative paper.
2. In the present invention, the excimer lamp treatment is used, the depth of penetration of the excimer lamp photons can reach 0.3 μm, the lower surface is still wet and not cured, and the surface free radicals are directly crosslinked, thus increasing the crosslinked area, which is expected to increase the area by 25%.
3. The invention uses the excimer lamp and the accelerating high-energy electron beam process, the surface has no shrinkage, and the finally formed pattern structure is very stable. In addition, a set of equipment is used for processing various patterns, a production mode that the texture of the traditional decorative plate needs to be pressed by a steel plate with prefabricated texture at high temperature is abandoned, the die making cost of the steel plate is reduced, the production cost of the decorative plate is further reduced, and the processing efficiency is improved.
4. The invention is environment-friendly and pollution-free, and does not use toxic substances such as an inducer, thereby avoiding the pollution of food and ensuring the edible health.
5. The decorative plate has good ultraviolet resistance, acid and alkali corrosion resistance, scraping resistance and wear resistance, and meanwhile, the surface patterns are wavy, super-matte and non-reflective, so that light pollution is avoided, and the decorative plate is safe and environment-friendly.
Detailed Description
Examples
A novel super-matte non-fingerprint board comprises a core board and decorative paper arranged on two surfaces of the core board; the core board is made by compounding a plurality of layers of gum dipping paper and then performing hot pressing; the decorative paper is gum dipping paper, the surface of the decorative paper is coated with UV glue, and after the UV glue is cured by UV illumination and is cured by EB energy, a decorative pattern is formed on the surface of the decorative paper; and a protective film is arranged on the outer surface of the decorative paper.
The invention also provides a novel super-matte fingerprint-free board, which comprises the following steps:
1) and preparing the melamine impregnated paper and the impregnated core paper.
The preparation method of the melamine impregnated paper comprises the following steps: processing by adopting a coating and drying integrated machine, adding purchased melamine glue into a glue dipping tank, automatically feeding purchased decorative paper, and enabling the decorative paper to pass through the glue dipping tank; the glue roller stained with the melamine glue is uniformly contacted with the surface of the decorative paper, and a glue layer is formed on the surface of the decorative paper; then, the decorative paper with the surface adhered with the glue layer enters an oven to be dried, the temperature of the oven is changed from low to high to low, and the heat source of the oven is provided by pipeline steam or natural gas boiler steam; and after drying the impregnated decorative paper, cutting off redundant raw paper leftover materials to obtain the finished melamine impregnated paper.
The preparation steps of the gum dipping core paper are as follows: processing by adopting a coating and drying integrated machine, adding purchased fireproof core paper into a glue dipping tank, automatically feeding the purchased fireproof core paper, and enabling the fireproof core paper to pass through the glue dipping tank; the rubber roller stained with the melamine glue is uniformly contacted with the surface of the fireproof core paper, and a glue layer is formed on the surface of the fireproof core paper; then, the fireproof core paper with the surface adhered with the glue layer enters an oven to be dried, the temperature of the oven is reduced from low to high to low, and the heat source of the oven is provided by pipeline steam or natural gas boiler steam; and after the impregnated fireproof core paper is dried, cutting off redundant leftover materials of the base paper to obtain the finished impregnated fireproof core paper.
2) And gluing and curing the UV glue.
The steps of gluing and curing the UV glue are as follows:
adding UV glue into a glue tank of a decorative board production line, and gluing the binding surface of the melamine impregnated paper by a glue spreader; then, under the protection of nitrogen, irradiating by an excimer lamp of 180nm, then realizing secondary curing by an accelerated high-energy electron beam process, and finally preparing the double-cured decorative paper.
3) And hot-press forming.
The hot-press forming method comprises the following steps: matching the gum dipping fireproof core paper and the decorative paper, conveying the paper to a full-automatic intelligent high-temperature high-pressure large-scale vacuum press, controlling the temperature of the vacuum press to be 120-160 ℃, rolling the matched paper roll up and down, and mutually bonding and curing glue covered on the paper by utilizing high temperature to prepare a semi-finished decorative plate.
4) And coating the film.
The film coating steps are as follows: covering a layer of protective film made of a PVC film on the surface of the semi-finished dual-curing EBC plate by a film covering machine to prepare a finished decorative plate; the softening temperature of the PVC film is 80 ℃.
5) And packaging and warehousing.
The decorative paper of the invention adopts UV curing and EB curing to process various patterns by utilizing electron beams, and also ensures no fingerprint residue, ensures the cleanness of the board surface, and further can greatly reduce the production cost of the decorative board.
In the present invention, the excimer lamp treatment is used, the depth of penetration of the excimer lamp photons can reach 0.3 μm, the lower surface is still wet and not cured, and the surface free radicals are directly crosslinked, thus increasing the crosslinked area, which is expected to increase the area by 25%.
The invention uses the excimer lamp and the accelerating high-energy electron beam process, the surface has no shrinkage, and the finally formed pattern structure is very stable. In addition, a set of equipment is used for processing various patterns, a production mode that the texture of the traditional decorative plate needs to be pressed by a steel plate with prefabricated texture at high temperature is abandoned, the die making cost of the steel plate is reduced, the production cost of the decorative plate is further reduced, and the processing efficiency is improved.
The invention is environment-friendly and pollution-free, and does not use toxic substances such as an inducer, thereby avoiding the pollution of food and ensuring the edible health.
The decorative plate has good ultraviolet resistance, acid and alkali corrosion resistance, scraping resistance and wear resistance, and meanwhile, the surface patterns are wavy, super-matte and non-reflective, so that light pollution is avoided, and the decorative plate is safe and environment-friendly.
The protection scope of the present invention is not limited to the above embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention. It should be noted that modifications and embellishments within the scope of the invention may occur to those skilled in the art without departing from the principle of the invention, and are considered to be within the scope of the invention.
Claims (6)
1. A novel preparation process of a super-matte non-fingerprint board is characterized by comprising the following steps:
the novel super-matte non-fingerprint board comprises a core board and decorative paper arranged on two surfaces of the core board;
the core board is made by compounding a plurality of layers of gum dipping paper and then performing hot pressing;
the decorative paper is gum dipping paper, the surface of the decorative paper is coated with UV glue, and after the UV glue is cured by UV illumination and is cured by EB energy, a decorative pattern is formed on the surface of the decorative paper; a protective film is arranged on the outer surface of the decorative paper;
the preparation process comprises the following steps:
1) preparing melamine impregnated paper and impregnated core paper;
2) gluing and dual curing of UV glue;
3) hot-press molding;
4) coating a film;
5) and packaging and warehousing.
2. The preparation process of the novel super matte non-fingerprint board as claimed in claim 1, wherein the preparation process comprises the following steps:
the preparation steps of the melamine impregnated paper are as follows:
processing by adopting a coating and drying integrated machine, adding purchased melamine glue into a glue dipping tank, automatically feeding purchased decorative paper, and enabling the decorative paper to pass through the glue dipping tank; the glue roller stained with the melamine glue is uniformly contacted with the surface of the decorative paper, and a glue layer is formed on the surface of the decorative paper; then, the decorative paper with the surface adhered with the glue layer enters an oven to be dried, the temperature of the oven is changed from low to high to low, and the heat source of the oven is provided by pipeline steam or natural gas boiler steam; and after drying the impregnated decorative paper, cutting off redundant raw paper leftover materials to obtain the finished melamine impregnated paper.
3. The preparation process of the novel super matte non-fingerprint board as claimed in claim 2, wherein:
the preparation steps of the gum dipping core paper are as follows: processing by adopting a coating and drying integrated machine, adding purchased fireproof core paper into a glue dipping tank, automatically feeding the purchased fireproof core paper, and enabling the fireproof core paper to pass through the glue dipping tank; the rubber roller stained with the melamine glue is uniformly contacted with the surface of the fireproof core paper, and a glue layer is formed on the surface of the fireproof core paper; then, the fireproof core paper with the surface adhered with the glue layer enters an oven to be dried, the temperature of the oven is reduced from low to high to low, and the heat source of the oven is provided by pipeline steam or natural gas boiler steam; and after the impregnated fireproof core paper is dried, cutting off redundant leftover materials of the base paper to obtain the finished impregnated fireproof core paper.
4. The novel preparation process of the super matte non-fingerprint plate as claimed in claim 3, wherein:
the steps of gluing and curing the UV glue are as follows:
adding UV glue into a glue tank of a decorative board production line, and gluing the binding surface of the melamine impregnated paper by a glue spreader; then, under the protection of nitrogen, irradiating by an excimer lamp of 180nm, then realizing secondary curing by an accelerated high-energy electron beam process, and finally preparing the double-cured decorative paper.
5. The novel preparation process of the super-matte non-fingerprint plate as claimed in claim 4, wherein the preparation process comprises the following steps: the hot-press forming method comprises the following steps:
matching the gum dipping fireproof core paper with the decorative paper, conveying the paper to a full-automatic intelligent high-temperature high-pressure large-scale vacuum press, controlling the temperature of the vacuum press to be 120-160 ℃, rolling the matched paper roll up and down, and bonding the glue coated on the paper by using high temperature to obtain a semi-finished decorative plate.
6. The preparation process of the novel super matte non-fingerprint board according to claim 5, wherein the preparation process comprises the following steps:
the film coating steps are as follows:
covering a layer of protective film made of a PVC film on the surface of the semi-finished dual-curing EBC plate by a film covering machine to prepare a finished decorative plate; the softening temperature of the PVC film is 80 ℃.
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