CN110846881B - Co3O4Preparation method of/PANI/MXene/PI electromagnetic shielding fabric - Google Patents
Co3O4Preparation method of/PANI/MXene/PI electromagnetic shielding fabric Download PDFInfo
- Publication number
- CN110846881B CN110846881B CN201911174273.7A CN201911174273A CN110846881B CN 110846881 B CN110846881 B CN 110846881B CN 201911174273 A CN201911174273 A CN 201911174273A CN 110846881 B CN110846881 B CN 110846881B
- Authority
- CN
- China
- Prior art keywords
- mxene
- pani
- fabric
- solution
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000767 polyaniline Polymers 0.000 title claims abstract description 80
- 239000004744 fabric Substances 0.000 title claims abstract description 75
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000002131 composite material Substances 0.000 claims abstract description 52
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000002070 nanowire Substances 0.000 claims abstract description 26
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 17
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 16
- 238000005507 spraying Methods 0.000 claims abstract description 14
- 238000009832 plasma treatment Methods 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 9
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract 5
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000004642 Polyimide Substances 0.000 claims description 88
- 229920001721 polyimide Polymers 0.000 claims description 88
- 238000001035 drying Methods 0.000 claims description 14
- 238000005406 washing Methods 0.000 claims description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims 1
- 239000010410 layer Substances 0.000 description 22
- 239000000463 material Substances 0.000 description 18
- 230000000694 effects Effects 0.000 description 12
- 230000005670 electromagnetic radiation Effects 0.000 description 9
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 238000011161 development Methods 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 238000011160 research Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 239000011258 core-shell material Substances 0.000 description 5
- 238000000707 layer-by-layer assembly Methods 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229910021389 graphene Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000005411 Van der Waals force Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000002041 carbon nanotube Substances 0.000 description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010063385 Intellectualisation Diseases 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- -1 Polydimethylsiloxane Polymers 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 241001199012 Usta Species 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000012761 high-performance material Substances 0.000 description 1
- 125000005462 imide group Chemical group 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920013657 polymer matrix composite Polymers 0.000 description 1
- 239000011160 polymer matrix composite Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/06—Inorganic compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
- D06M10/10—Macromolecular compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Laminated Bodies (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention relates to Co3O4A preparation method of/PANI/MXene/PI electromagnetic shielding fabric. The method comprises the following steps: pretreating PI fabric, and then carrying out plasma treatment; spraying MXene solution on the surface of the treated PI fabric for reaction; mixing Co3O4Spraying the PANI nanowire solution on the obtained MXene/PI composite material for reaction; the obtained Co3O4the/PANI/MXene/PI composite material is placed in a PDMS solution for treatment. The method is simple, the conditions are mild, and the obtained electromagnetic shielding fabric has excellent conductivity and electromagnetic shielding performance.
Description
Technical Field
The invention belongs to the field of preparation of flexible electromagnetic shielding materials, and particularly relates to Co3O4A preparation method of/PANI/MXene/PI electromagnetic shielding fabric.
Background
With the rapid development of informatization and intellectualization, electromagnetic waves as important carriers for information transmission have penetrated into the aspects of life, and electronic products have been more and more widely applied to various fields of our national economy and our daily life, such as electronic communication, remote teaching, intelligent equipment and the like, which are closely related to electromagnetic waves. Whether military or civilian, the generation, transmission, reception and processing of information rely on electromagnetic waves as carriers. But electromagnetic waves bring great convenience to us, and electromagnetic radiation also brings a great deal of negative effects to us. Therefore, people have attracted great attention on the electromagnetic interference effect and the harm to the health caused by electromagnetic radiation while pursuing high quality of life.
Electromagnetic shielding is one of effective means for suppressing electromagnetic interference and realizing electromagnetic protection. Electromagnetic shielding generally adopts a good metal conductor with low resistance, when electromagnetic radiation is emitted to the metal conductor from air, reflection and refraction phenomena are generated on the surface of the metal conductor, and the electromagnetic shielding aims to suppress the electromagnetic radiation by utilizing the reflection effect and the absorption effect of the metal conductor on the electromagnetic radiation. Electromagnetic shielding materials are various and have wide application, and various countries have extensive research and exploration on the electromagnetic shielding materials, particularly multifunctional electromagnetic shielding materials. Textile fabric has characteristics such as flexibility, workable, tailorable, wearable and with human direct contact, consequently gives textile fabric electromagnetic shield or other additional functions, can effectively reduce or even eliminate electromagnetic radiation to the harm of human body, can also realize the multi-functionalization of weaving clothing, promotes its in the future to more intelligent orientation development, has fairly long-term meaning to the purification of human health and space electromagnetic environment. Therefore, the development of new textiles with electromagnetic shielding properties is an important task in the current technological development situation.
Currently, research on electromagnetic shielding materials has been advanced, and the electromagnetic shielding materials can be divided into 3 parts from the mechanism of shielding electromagnetic waves: absorption type, reflection absorption type, and can be classified into coating type and structural composite type according to application forms. For example, the method is characterized in that the layer-by-layer assembly of a graphene oxide multilayer film on cotton fabric and the electromagnetic shielding performance of the graphene oxide multilayer film are researched by Pinsylvan, the graphene oxide is prepared by an improved Hummers method, a dipping layer-by-layer assembly technology is adopted to prepare the graphene oxide/poly dimethyl diallyl ammonium chloride hydrochloride (GO/PDDA) multilayer film on the surface of the cotton fabric, but after 15 times of layer-by-layer assembly, the electromagnetic shielding effect value is only 3.16dB, and the commercial effect cannot be achieved; the chinese patent CN1045428A is an electromagnetic shielding fabric woven from blended yarn of cotton fiber and stainless steel fiber, which belongs to a structural composite electromagnetic shielding material, wherein the metal fiber has a large specific gravity, and the woven fabric is thick and hard in hand feeling, and cannot meet the performance requirements of 'thin, light, wearable' and the like for textile materials; chinese patent CN107988787A discloses a method for preparing a wave-absorbing electromagnetic shielding fabric, which prepares a cotton fabric with a carbon nanotube coating by a dipping-coating method, but after 4 times of coating, the electromagnetic shielding effectiveness is only 9.9dB, and the shielding effect is not ideal.
Disclosure of Invention
The invention aims to provide a Co3O4The preparation method of the/PANI/MXene/PI electromagnetic shielding fabric overcomes the defects of poor shielding effect and the like of an electromagnetic shielding material in the prior art.
The invention provides a Co3O4the/PANI/MXene/PI electromagnetic shielding fabric is prepared by spraying MXene solution on the surface of the treated polyimide fabric for reaction and then spraying Co3O4the/PANI nanowire solution reacts and is placed in the PDMS solution to be processed to obtain the product.
The treated polyimide fabric is: the polyimide fabric is pretreated and then subjected to plasma treatment.
The MXene solution is sprayed on the surface of the treated polyimide fabric for reaction, and then Co is sprayed3O4the/PANI nanowire solution reaction is repeated at least once.
The invention also provides Co3O4Preparation method of/PANI/MXene/PI electromagnetic shielding fabric and bagThe method comprises the following steps:
(1) pretreating a polyimide PI fabric, and then carrying out plasma treatment to obtain a treated PI fabric;
(2) spraying MXene solution on the surface of the PI fabric treated in the step (1), reacting, washing and drying to obtain an MXene/PI composite material, wherein the mass ratio of the treated PI fabric to the MXene solution is 1: 10-20;
(3) mixing Co3O4Spraying the/PANI nanowire solution on the MXene/PI composite material in the step (2), reacting, washing and drying to obtain Co3O4the/PANI/MXene/PI composite material comprises MXene/PI composite material and Co3O4The mass ratio of the PANI nanowire solution is 1: 10-20;
(4) mixing Co in step (3)3O4Putting the/PANI/MXene/PI composite material into PDMS solution, stirring, washing and drying to obtain Co3O4/PANI/MXene/PI electromagnetic shielding fabric, wherein Co3O4The mass ratio of the/PANI/MXene/PI composite material to the PDMS solution is 1: 10-20.
The step (1) of pretreating the polyimide PI fabric comprises the following steps: and (2) soaking the polyimide fabric in acetone for 45-55 h, taking out, washing and drying, wherein the mass ratio of the polyimide fabric to the acetone is 1: 40-60.
The washing adopts distilled water; the drying temperature is 40-60 ℃.
The plasma treatment in the step (1) adopts oxygen plasma, nitrogen plasma or argon plasma bombardment and the like, and the effects of etching the PI surface and improving the hydrophilicity can be achieved.
The technological parameters of the plasma treatment adopting the oxygen plasma for bombardment are as follows: the flow rate of the oxygen is 1.5-2.5L/min, the air pressure is 9-12 Pa, the power is 90-110W, and the bombardment time is 3-6 min.
MXene in the step (2) comprises: ti3C2Tx、Ti2N、Mo3C2、Ti2AlC3Or V2C。
The mass concentration of the MXene solution in the step (2) is 8-12 mg/mL.
In the step (2), the reaction temperature is room temperature, and the reaction time is 10-20 min.
A spray gun is adopted for spraying in the steps (2) and (3); the spraying was carried out at room temperature.
Co in the step (3)3O4The preparation method of the/PANI nanowire comprises the following steps: taking Co3O41.0g of solid powder is added with 50ml of deionized water, 5ml of hydrochloric acid with the concentration of 2mol/L is added, and the mixture is ultrasonically dispersed for 1 hour to obtain Co3O4The suspension of (a); adding 1.6ml of aniline into the suspension, and magnetically stirring for 0.5 h; ammonium Persulfate (APS) solution (4.56g in 50ml deionized water) was added to the mixture and magnetically stirred until Co formation occurred3O4/PANI nanowire solution.
Co in the step (3)3O4The mass concentration of the/PANI nanowire solution is 10-20 mg/mL.
And (4) in the step (3), the reaction temperature is room temperature, and the reaction time is 10-20 min.
Co in the step (3)3O4Repeating the step (2) and the step (3) on the/PANI/MXene/PI composite material to obtain the Co with the multilayer structure3O4the/PANI/MXene/PI composite material is subjected to the step (4), wherein Co3O4Co in/PANI/MXene/PI composite material3O4The total number of the/PANI layer and the MXene layer is 2-20 layers.
The drying temperature in the step (2), the step (3) and the step (4) is 40-60 ℃.
And (3) the mass fraction of the PDMS solution in the step (4) is 3-8%.
And (4) stirring at room temperature for 8-15 s.
The invention also provides Co3O4Application of the/PANI/MXene/PI electromagnetic shielding fabric.
The invention relates to a method for preparing cobaltosic oxide/polyaniline nano-wire (Co) composite nano-material with a two-dimensional layered transition metal carbide (MXene) and one-dimensional linear core-shell structure by coating technology3O4/PANI) is combined with a Polyimide (PI) substrate to prepare the polyimide/polyimide composite materialThe flexible electromagnetic shielding fabric has excellent shielding performance and wide application prospect. The novel electromagnetic shielding composite material meets the requirements on the characteristics of novel electromagnetic shielding materials, such as light weight, good flexibility, high strength, excellent performance and the like, can reduce secondary damage caused by reflection to a certain extent, and is a novel electromagnetic shielding composite material with great development potential.
According to the invention, the Polyimide (PI) is subjected to plasma treatment, so that the surface of the PI is provided with oxygen-containing polar groups and hydroxyl groups, and the hydrophilicity of the surface of the PI fabric is greatly improved; MXene has groups such as-F and-OH on the surface, and can be bonded to PI by intermolecular forces such as hydrogen bond and Van der Waals force to increase the bonding strength between the two to some extent (see Table 2), and MXene and Co3O4The combination of the/PANI nano wire can improve the electromagnetic shielding performance of the composite material. Co3O4the/P ANI nanowire has a core-shell structure, the surface of the PANI layer at the outermost layer is provided with positive charges and-NH, the bonding fastness between the PANI layer and Mxene with negative charges can be improved through electrostatic attraction and hydrogen bonding (shown in Table 2), and MXene oxidation is effectively prevented. In addition, a hydrophobic self-protection layer can be formed on the surface of the composite material through Polydimethylsiloxane (PDMS) after finishing, so that the antifouling property and the scale resistance can be effectively improved, the oxidation in the air can be prevented, and the bonding fastness of the composite material is further improved (as shown in Table 2).
MXene layer and Co in the invention3O4the/PANI nanowire layer is assembled on the surface of the polyimide for multiple times, so that multiple reflection loss of electromagnetic waves in the material is increased, and secondary electromagnetic radiation pollution caused by surface reflection is effectively reduced by coordinating impedance performance.
The invention aims to provide theoretical basis and method for the subsequent electromagnetic shielding research of MXene materials and further research the development of novel electromagnetic shielding fabric with good performance.
Advantageous effects
The invention passes MXene layer and Co3O4the/PANI nanowire layer is assembled on the surface of the PI layer by layer to prepare the electromagnetic shielding fabric. Wherein PI is subjected to plasma pretreatmentThe surface of the PI fabric is provided with oxygen-containing polar groups and hydroxyl groups, so that the hydrophilicity of the surface of the PI fabric is greatly improved; compared with the traditional loading method, the bonding fastness of the MXene layer and the PI substrate is improved through intermolecular forces such as hydrogen bonds, Van der Waals force and the like; second, Co due to core-shell structure3O4The PANI molecules at the outermost layer of the/PANI nanowire have positive charges, so that not only is Co improved3O4The bonding force of the/PANI layer and the MXene layer also provides a good surface for the continuous deposition of the MXene, and the oxidation of the MXene is effectively avoided; in addition, the PDMS is finally adopted for post-finishing, a hydrophobic self-protection layer can be formed on the surface of the PDMS, the antifouling property can be effectively improved, and the oxidation in the air is prevented, so that the shielding effect is influenced.
The electromagnetic shielding fabric of the invention is made of Co3O4the/PANI nanowire and the MXene are functional particles, and both have excellent conductivity (shown in Table 1) and electromagnetic shielding performance, so that the conductivity and the electromagnetic shielding performance of the material can be further improved. Meanwhile, the strong electrostatic action, hydrogen bond and the like exist between the two components, which is beneficial to Co3O4The high-density deposition of the/PANI layer and the MXene layer further improves the service performance; the PI fabric is a high-performance material with a molecular main chain containing rigid imide rings, and has excellent performances of high and low temperature resistance, high strength and high modulus, radiation resistance, flame retardance, self-extinguishment, chemical corrosion resistance, dielectric property and the like; the invention adopts a layer-by-layer assembly method to prepare the target fabric, increases the multiple reflection loss of electromagnetic waves in the material, and effectively reduces the secondary electromagnetic radiation pollution caused by surface reflection by coordinating impedance performance.
Drawings
FIG. 1 shows Co of the present invention3O4A process flow chart for preparing the/PANI/MXene/PI electromagnetic shielding fabric.
Detailed Description
The invention will be further illustrated with reference to the following specific examples. It should be understood that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention. Further, it should be understood that various changes or modifications of the present invention may be made by those skilled in the art after reading the teaching of the present invention, and such equivalents may fall within the scope of the present invention as defined in the appended claims.
MXene used in the present invention was provided by Beijing Kaifhair Tetao technologies, Inc., polyimide fabrics were obtained from Fusmann technologies, Inc. (Beijing), and other chemical reagents were purchased from national drug group chemical reagents, Inc.
Example 1
(1) According to a polyimide fabric (180 g/m)20.45g) and an acetone solution in a mass ratio of 1:50, soaking the Polyimide (PI) fabric in acetone for 48 hours, taking out, washing with distilled water, and drying at 60 ℃.
(2) And (3) carrying out plasma treatment on the PI fabric pretreated in the step (1) for 4min under the conditions that the oxygen flow rate is 2L/min, the air pressure is 10Pa and the power is 100W, so as to obtain the treated PI fabric.
(3) According to the treated PI fabric (0.42g) with MXene (Ti)3C2Tx, monolayer) solution with the mass ratio of 1:10, spraying 10mg/mL MXene solution on the surface of treated PI by a spray gun, reacting for 10min at room temperature, then washing with distilled water, and drying at 40 ℃ to obtain the MXene/PI composite material.
(4) According to MXene/PI composite (0.45g) with Co3O4The mass ratio of the/PANI nanowire solution is 1:10, and 15mg/mL Co is sprayed by a spray gun3O4Spraying the/PANI nanowire solution (4.5g) on the surface of the MXene/PI composite material, reacting for 10min at room temperature, then washing with distilled water, and drying at 40 ℃ to obtain Co3O4The composite material is/PANI/MXene/PI.
Co3O4The preparation method of the/PANI nanowire comprises the following steps: taking Co3O41.0g of solid powder is added with 50ml of deionized water, 5ml of hydrochloric acid with the concentration of 2mol/L is added, and the mixture is ultrasonically dispersed for 1 hour to obtain Co3O4The suspension of (a); adding 1.6ml of aniline into the suspension, and magnetically stirring for 0.5 h; to the mixture was added Ammonium Persulfate (APS) solution (4.56g in 50ml deionized water) using a glass rodStirring for 20min to generate Co with core-shell structure3O4/PANI nanowire solution.
(5) According to Co3O4The mass ratio of the/PANI/MXene/PI composite material (0.48g) to the PDMS solution is 1:10, and Co is added3O4Putting the/PANI/MXene/PI composite material into a PDMS solution with the mass fraction of 5%, reacting for 10s at room temperature, taking out the fabric, and drying at 40 ℃ to obtain Co3O4the/PANI/MXene/PI electromagnetic shielding fabric is marked as sample 1#。
Example 2
Co was prepared according to example 13O4the/PANI/MXene/PI composite material is obtained by repeating the step (3) and the step (4) twice in the example 1 and then performing the step (5) in the example 1 to obtain the Co with a multilayer structure3O4the/PANI/MXene/PI electromagnetic shielding fabric is marked as sample 2#。
Example 3
Co was prepared according to example 13O4the/PANI/MXene/PI composite material is then subjected to the step (3) and the step (4) in the example 1 for three times, and then the step (5) in the example 1 is carried out to obtain the Co with a multilayer structure3O4the/PANI/MXene/PI electromagnetic shielding fabric is marked as sample 3#。
Example 4
Co was prepared according to example 13O4the/PANI/MXene/PI composite material is then subjected to the repetition of the step (3) and the step (4) in the example 1 for four times, and then the step (5) in the example 1 is carried out, so that the Co with the multilayer structure is obtained3O4the/PANI/MXene/PI electromagnetic shielding fabric is marked as sample 4#。
Example 5
Co was prepared according to example 13O4the/PANI/MXene/PI composite material is then repeated for five times in the steps (3) and (4) in the example 1 and then is performed in the step (5) in the example 1 to obtain the Co with a multilayer structure3O4the/PANI/MXene/PI electromagnetic shielding fabric is marked as sample 5#。
Example 6
To implementSample 5 in example 5#As a research object, the bending property of the fabric is tested by an SDL-M003A type wrinkle recovery angle tester according to AATCC66-2008 < determination of wrinkle recovery of woven fabrics >3O4the/PANI/MXene/PI composite is noted as sample 6#。
The physical parameters of the samples of inventive examples 1-6 are shown in Table 1.
In the present invention, the MXene/PI composite material and Co of example 1 were tested by 3M tape test3O4/PANI/MXene/PI composite material and Co treated by PDMS3O4The bonding fastness of the/PANI/MXene/PI composite material is tested, and by observing the amount of the particles bonded on the adhesive tape and the mass loss after the test, the mass change before and after the test is not large, the change rate is about 3 percent, and the bonding fastness of each composite material obtained in the example 1 is better. Specific values are shown in table 2.
In the invention, a vector network analyzer is adopted, and a waveguide method is adopted to refer to the standard test sample 1 of GB/T35679-2017 by the vector network analyzer#、2#、3#、4#、5#、6#The specific values of the shielding effectiveness of (1) are shown in Table 3, wherein sample 0#Refers to a Polyimide (PI) fabric that has been plasma treated only. Research shows that 6 kinds of Co prepared by the invention3O4the/PANI/MXene/PI electromagnetic shielding fabric has good shielding performance on electromagnetic waves, and the maximum shielding performance value of all samples is more than 20dB, which shows that the material can shield more than 90% of electromagnetic waves. While accompanying with Co3O4The frequency of assembling the PANI layer and the MXene layer is increased, the microwave shielding performance and the effective shielding bandwidth of the composite material are gradually increased, and the sample 5#The maximum shielding effectiveness value of 52.66 dB.
In the present invention, sample 5 of the example#Sample 6 was found after bending test for the subject#After unloading for 5min, the fold recovery angleUp to 87.2 deg., indicating a better flexibility, the specific values are shown in table 4.
Compared with the traditional magnetic paint such as silver-coated copper, nickel-based and ferrite (for example: CN 105682436A and the like), the product of the invention has light weight (as shown in Table 1), easy processing and better shielding effect on electromagnetic waves; compared with the carbon nano tube and polymer matrix composite electromagnetic shielding material (Like standard, Majiang, Zhang Zhengquan, Machen, Jade, Liuwei, Zhang Jie, Lijing, Wang Dong red, epoxy resin based carbon nano composite electromagnetic shielding material research [ J]Strong laser and particle beams, 2019, (10):27-33, etc.), the preparation of the invention adopts polyimide as a base material, has good flexibility (as shown in example 6 and table 4), good serviceability and more superior market value; compared with the composite material prepared by adding the metal shielding particles with the core-shell structure (for example: CN 109177384A and the like), the composite material has the advantages that MXene and Co with good performance are sprayed by a layer-by-layer assembly spraying process3O4The flexible electromagnetic shielding fabric is prepared by combining the PANI nanowires, the shielding performance of the base fabric is improved, and secondary electromagnetic radiation pollution caused by surface reflection is effectively reduced by coordinating the impedance performance; compared with the conventional coated functional particle-loaded method (ENGINF, USTA I. Development and characterization of polyanilines/polyamides (PANI/PA) fabrics for electronic shielding [ J]Journal of The Textile Institute, 2015, 106(8): 872-879.) The invention treats The functional particles on The fabric by a spraying method, and combines The functional particles with intermolecular force under The action of static electricity, so that The composite material has better bonding fastness and further improves The wave absorbing performance of The composite material while keeping softness and air permeability. Therefore, the electromagnetic shielding fabric prepared by the invention has wider application prospect and huge market value. The performance of the present invention is compared to the prior art as shown in table 5.
TABLE 1 sample 0#、1#、2#、3#、4#、5#、6#Physical parameters of
| Sample (I) | 0# | 1# | 2# | 3# | 4# | 5# | 6# |
| Quality (g) | 0.42 | 0.50 | 0.52 | 0.55 | 0.54 | 0.60 | 0.58 |
| Volume (cm)3) | 7.5 | 9.0 | 10.5 | 11.0 | 11.75 | 12.5 | 12.25 |
| Density (g/cm 3)) | 0.056 | 0.056 | 0.050 | 0.050 | 0.046 | 0.048 | 0.047 |
| Fabric resistor (omega) | - | 865 | 831 | 805 | 819 | 806 | 798 |
Table 2 mass loss before and after 3M tape test for each composite in example 1
| Composite material | MXene/PI | Co3O4/PANI/MXene/PI | Co3O4/PANI/MXene/PI (PDMS treated) |
| Before test (g) | 0.45 | 0.48 | 0.50 |
| After testing (g) | 0.43 | 0.47 | 0.48 |
TABLE 3 sample 0#、1#、2#、3#、4#、5#、6#Electromagnetic shielding performance of
TABLE 4 sample 6#Bending property of
| Sample pressure relief time(s) | 60 | 120 | 180 | 240 | 300 |
| Fold recovery angle (°) | 84.4 | 85.2 | 86.1 | 86.7 | 87.2 |
TABLE 5 comparison of Properties
Claims (9)
1. Co3O4the/PANI/MXene/PI electromagnetic shielding fabric is characterized in that MXene solution is sprayed on the surface of the treated polyimide fabric to react for 10-20min at room temperature, and then Co is sprayed3O4The PANI nanowire solution reacts for 10-20min at room temperature and then is placed in the PDMS solution for treatment to obtain the PANI nanowire;
the treated polyimide fabric is: pretreating the polyimide fabric and then carrying out plasma treatment; MXene solution is sprayed on the surface of the treated polyimide fabric for reaction, and then Co is sprayed3O4the/PANI nanowire solution reaction is repeated at least once.
2. Co3O4The preparation method of the/PANI/MXene/PI electromagnetic shielding fabric comprises the following steps:
(1) pretreating a polyimide PI fabric, and then carrying out plasma treatment to obtain a treated PI fabric;
(2) spraying MXene solution on the surface of the PI fabric treated in the step (1), reacting for 10-20min at room temperature, washing with water, and drying to obtain an MXene/PI composite material, wherein the mass ratio of the treated PI fabric to the MXene solution is 1: 10-20;
(3) mixing Co3O4Spraying the/PANI nanowire solution on the MXene/PI composite material in the step (2), reacting for 10-20min at room temperature, and adding waterWashing and drying to obtain Co3O4the/PANI/MXene/PI composite material comprises MXene/PI composite material and Co3O4The mass ratio of the PANI nanowire solution is 1: 10-20;
(4) mixing Co in step (3)3O4Putting the/PANI/MXene/PI composite material into PDMS solution, stirring, washing and drying to obtain Co3O4/PANI/MXene/PI electromagnetic shielding fabric, wherein Co3O4The mass ratio of the/PANI/MXene/PI composite material to the PDMS solution is 1: 10-20.
3. The method of claim 2, wherein the step (1) of pretreating the polyimide PI fabric comprises: soaking the polyimide fabric in acetone for 45-55 h, taking out, washing and drying; the plasma treatment is bombarded with oxygen plasma, nitrogen plasma or argon plasma.
4. The method of claim 3, wherein the plasma treatment is performed by bombardment with oxygen plasma with the following process parameters: the flow rate of the oxygen is 1.5-2.5L/min, the air pressure is 9-12 Pa, the power is 90-110W, and the bombardment time is 3-6 min.
5. The method of claim 2, wherein MXene in step (2) comprises: ti3C2Tx、Ti2N、Mo3C2、Ti2AlC3Or V2C; the mass concentration of the MXene solution is 8-12 mg/mL.
6. The method of claim 2, wherein the Co is used in step (3)3O4The mass concentration of the/PANI nanowire solution is 10-20 mg/mL.
7. The method of claim 2, wherein the Co is used in step (3)3O4Repeating the step (2) and the step (3) on the/PANI/MXene/PI composite material to obtain the Co with the multilayer structure3O4/PANI/MXene/PI composite, then to step (4) where Co3O4Co in/PANI/MXene/PI composite material3O4The total number of the/PANI layer and the MXene layer is 2-20 layers.
8. The method according to claim 2, wherein the mass fraction of the PDMS solution in the step (4) is 3-8%; the stirring treatment temperature is room temperature, and the stirring treatment time is 8-15 s.
9. Use of the fabric of claim 1 in the preparation of an electromagnetic protective composite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911174273.7A CN110846881B (en) | 2019-11-26 | 2019-11-26 | Co3O4Preparation method of/PANI/MXene/PI electromagnetic shielding fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911174273.7A CN110846881B (en) | 2019-11-26 | 2019-11-26 | Co3O4Preparation method of/PANI/MXene/PI electromagnetic shielding fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110846881A CN110846881A (en) | 2020-02-28 |
| CN110846881B true CN110846881B (en) | 2022-03-04 |
Family
ID=69604611
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911174273.7A Active CN110846881B (en) | 2019-11-26 | 2019-11-26 | Co3O4Preparation method of/PANI/MXene/PI electromagnetic shielding fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110846881B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111286252A (en) * | 2020-03-09 | 2020-06-16 | 长沙而道新能源科技有限公司 | Radiation-resistant anticorrosive paint and preparation method thereof |
| CN111501326A (en) * | 2020-05-13 | 2020-08-07 | 郑州大学 | Multifunctional wearable polymer/MXene composite fabric heater and preparation method thereof |
| CN111678425B (en) * | 2020-05-22 | 2022-02-15 | 扬州大学 | Breathable and waterproof multi-response fabric sensor |
| CN112127159A (en) * | 2020-08-21 | 2020-12-25 | 盐城工学院 | Silver nanowire anti-electromagnetic fabric and preparation method thereof |
| CN112366034B (en) * | 2020-11-04 | 2022-04-08 | 湖南华菱线缆股份有限公司 | Anti-electromagnetic interference flexible tensile medical cable |
| CN112663323B (en) * | 2020-12-03 | 2022-11-04 | 东华大学 | MXene electromagnetic shielding fabric and preparation method and application thereof |
| CN113303767A (en) * | 2021-05-26 | 2021-08-27 | 东南大学 | Large-deformation sensing fabric sensor in two-dimensional global range and preparation method |
| CN116446177B (en) * | 2023-03-15 | 2024-05-28 | 天津工业大学 | Preparation method of MXene/metal nanoparticle multifunctional coating composite material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106835712A (en) * | 2017-02-28 | 2017-06-13 | 东华大学 | A kind of preparation method of ferrite/polyaniline Electromagnetically shielding fabrics |
| CN108893070A (en) * | 2018-07-16 | 2018-11-27 | 梧州市兴能农业科技有限公司 | A kind of ice-covering-proof pad pasting of photo-thermal type low temperature |
| CN109439188A (en) * | 2018-11-15 | 2019-03-08 | 北京林业大学 | A kind of super-hydrophobic photo-thermal coating and preparation method thereof |
| CN109527680A (en) * | 2018-12-03 | 2019-03-29 | 武汉市银莱制衣有限公司 | Have antibacterial, antistatic, monitoring poisonous gas and mine protective garment fabric of toxic dust filtering synergistic function and preparation method thereof |
| CN109881493A (en) * | 2019-02-27 | 2019-06-14 | 温州优巴信息技术有限公司 | A kind of MXene base flexible translucent electromagnetic shielding fabric of LBL self-assembly and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109295732A (en) * | 2018-09-27 | 2019-02-01 | 天津工业大学 | A kind of preparation method of polypyrrole/polyaniline electromagnetic shielding composite material |
| CN109868648A (en) * | 2019-01-17 | 2019-06-11 | 菏泽学院 | A kind of black Electromagnetically shielding fabrics and preparation method thereof |
| CN109868646A (en) * | 2019-03-22 | 2019-06-11 | 青岛大学 | The method and product of Electromagnetically shielding fabrics are prepared based on two-dimensional layer MXene nanometer sheet |
-
2019
- 2019-11-26 CN CN201911174273.7A patent/CN110846881B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106835712A (en) * | 2017-02-28 | 2017-06-13 | 东华大学 | A kind of preparation method of ferrite/polyaniline Electromagnetically shielding fabrics |
| CN108893070A (en) * | 2018-07-16 | 2018-11-27 | 梧州市兴能农业科技有限公司 | A kind of ice-covering-proof pad pasting of photo-thermal type low temperature |
| CN109439188A (en) * | 2018-11-15 | 2019-03-08 | 北京林业大学 | A kind of super-hydrophobic photo-thermal coating and preparation method thereof |
| CN109527680A (en) * | 2018-12-03 | 2019-03-29 | 武汉市银莱制衣有限公司 | Have antibacterial, antistatic, monitoring poisonous gas and mine protective garment fabric of toxic dust filtering synergistic function and preparation method thereof |
| CN109881493A (en) * | 2019-02-27 | 2019-06-14 | 温州优巴信息技术有限公司 | A kind of MXene base flexible translucent electromagnetic shielding fabric of LBL self-assembly and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| Flexible and Multifunctional Silk Textiles with Biomimetic Leaf-Like MXene/Silver Nanowire Nanostructures for Electromagnetic Interference Shielding, Humidity Monitoring, and Self-Derived Hydrophobicity;Liu-Xin Liu等;《Multifunctional Textiles》;20190901;第1-10页 * |
| Synthesis and Microwave Absorption Properties of Core-Shell Structured Co3O4-PANI Nanocomposites;Hongyan Xu等;《Journal of Nanomaterials》;20151231;第1-8页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110846881A (en) | 2020-02-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110846881B (en) | Co3O4Preparation method of/PANI/MXene/PI electromagnetic shielding fabric | |
| CN110845844B (en) | Preparation method of PANI/MXene/carbon cloth composite wave-absorbing material | |
| EP3723465B1 (en) | Electromagnetic shielding filler, electromagnetic shielding coating comprising same, preparation method and application thereof | |
| CN108251053B (en) | Graphene ferrite polymer ternary nano composite wave-absorbing material and preparation method thereof | |
| Wang et al. | Preparation of silver/reduced graphene oxide coated polyester fabric for electromagnetic interference shielding | |
| Zhang et al. | Flexible polyaniline-coated poplar fiber composite membranes with effective electromagnetic shielding performance | |
| Wang et al. | Layer-by-layer assembly of low-temperature in-situ polymerized pyrrole coated nanofiber membrane for high-efficiency electromagnetic interference shielding | |
| CN108976820B (en) | Ferroferric oxide/polypyrrole composite material and preparation method thereof | |
| CN114657775B (en) | Flame-retardant cold-resistant cut-resistant shielding multispectral fabric and preparation method thereof | |
| CN113638239A (en) | Polyimide/silver composite film with electromagnetic shielding function and preparation method thereof | |
| CN110195351B (en) | Preparation method of carbon nanotube/copper sulfide composite electromagnetic shielding fabric | |
| Liu et al. | Highly flexible electromagnetic interference shielding films based on ultrathin Ni/Ag composites on paper substrates | |
| CN105153678B (en) | The preparation of carbon nanotube conducting high polymer material/ferrite composite polyurethane | |
| Kim et al. | Direct coating of copper nanoparticles on flexible substrates from copper precursors using underwater plasma and their EMI performance | |
| CN114835932A (en) | Copper nanowire/aramid nanofiber composite conductive film and preparation method thereof | |
| Yang et al. | Stretchable textile with ultra-high electromagnetic interference shielding performance based on porous wrinkled conductive network | |
| CN114150496A (en) | Flexible nanofiber membrane with electromagnetic shielding and piezoresistive sensing performances and preparation method thereof | |
| Zhang et al. | Fabrication of acanthosphere-like SiO2@ Ag with designed angular tip silver shape for construction of superhydrophobic-electromagnetic shielding surface by imitating lotus leaf structure | |
| Tang et al. | Flexible metalized polyimide nonwoven fabrics for efficient electromagnetic interference shielding | |
| CN110776658B (en) | Cotton fiber-based flexible carbon composite film and preparation method thereof | |
| CN114351445A (en) | Method for preparing electromagnetic shielding composite coating on surface of non-woven fabric | |
| CN111793435A (en) | EMI shielding optimized coating and preparation method thereof | |
| CN113604133A (en) | Light carbon-based electromagnetic shielding coating and preparation method thereof | |
| CN113930051B (en) | Carbon-based composite material and preparation method and application thereof | |
| KR20170123404A (en) | METAL-PLATED GLASS FIBER SMC(Sheet Moldings Compound) FOR EMI SHIELDING AND MANUFACTURING METHOD THEREBY |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |