CN110820345A - Treatment process of shrink-proof cotton fabric - Google Patents

Treatment process of shrink-proof cotton fabric Download PDF

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Publication number
CN110820345A
CN110820345A CN201911210687.0A CN201911210687A CN110820345A CN 110820345 A CN110820345 A CN 110820345A CN 201911210687 A CN201911210687 A CN 201911210687A CN 110820345 A CN110820345 A CN 110820345A
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China
Prior art keywords
cotton fabric
epoxy resin
mixture
shrink
heating
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CN201911210687.0A
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Chinese (zh)
Inventor
王丽丽
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Anhui Yimin Costume Ltd By Share Ltd
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Anhui Yimin Costume Ltd By Share Ltd
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Priority to CN201911210687.0A priority Critical patent/CN110820345A/en
Publication of CN110820345A publication Critical patent/CN110820345A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55Epoxy resins
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/45Shrinking resistance, anti-felting properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a treatment process of shrink-proof cotton fabric, which relates to the technical field of cotton fabric processing treatment and comprises the following steps: 1) reacting epoxy resin with carboxylic styrene-butadiene rubber to prepare modified epoxy resin emulsion; 2) mixing copper powder and paraffin, heating and extruding, and ball-milling to obtain pretreated copper powder; 3) placing the modified epoxy resin emulsion in a water bath kettle, stirring for 20-30min, adding the pretreated copper powder into the modified epoxy resin emulsion, uniformly dispersing, adding acrylic acid epoxidized soybean oil and glycidyl methacrylate, stirring for dissolving, and then adding isophorone diamine to obtain a cotton fabric impregnation solution; 4) soaking the cotton fabric in the cotton fabric soaking solution, taking out the cotton fabric, and performing hot-pressing solidification to obtain the shrink-proof cotton fabric. The treatment process can improve the shrinkage phenomenon of the cotton fabric, reduce the shrinkage rate of the cotton fabric, and cannot influence the moisture absorption of the cotton fabric and the wearing comfort of the cotton fabric.

Description

Treatment process of shrink-proof cotton fabric
Technical Field
The invention belongs to the technical field of cotton fabric processing, and particularly relates to a treatment process of shrink-proof cotton fabric.
Background
Cotton fabric is also called cotton cloth, and is a fabric woven by using cotton yarn as a raw material. Cotton fabric is one of the most commonly used fabrics with excellent wearability, and is widely used for clothing fabrics, decorative fabrics and industrial fabrics. With the deep development of textile printing and dyeing processing, cotton fabrics are increasingly abundant in variety, and the appearance, the performance and the grade are continuously improved. However, the cotton fabric is easy to shrink and deform, and particularly, the shrinking and deformation of the dyed cotton fabric are more serious, so that the wearing effect of clothes is influenced. In view of this, how to improve the anti-shrinkage capability of cotton fabric is very important. For example, chinese patent CN2012100473379 discloses a treatment method and a treatment liquid for preparing a fluorine-free super-hydrophobic cotton fabric, in which a cotton fabric is padded in a modified silica sol, and a large number of modified silica nanoparticles having water repellency are modified on the surface of the cotton fabric, so that the contact angle between the prepared cotton fabric and water drops exceeds 150 °, and the prepared cotton fabric has super-hydrophobic property, thereby improving the shrinkage phenomenon of the cotton fabric, but the water repellency substance modified on the surface of the cotton fabric can cause the reduction of the moisture absorption property of the cotton fabric, so that the cotton fabric is not prone to sweat absorption, and the wearing comfort of the cotton fabric is reduced in hot summer.
Disclosure of Invention
The invention aims to provide a treatment process of a shrink-proof cotton fabric aiming at the existing problems.
The invention is realized by the following technical scheme:
a treatment process of shrink-proof cotton fabric comprises the following specific process steps:
1) preheating bisphenol A epoxy resin in an oven at 50-60 ℃ for 50-80min, adding the epoxy resin into a container, adding carboxylated styrene-butadiene rubber accounting for 3-7% of the weight of the epoxy resin, heating to 140-; according to the invention, the carboxylic styrene-butadiene rubber is used as a raw material, and a chemical copolymerization method is adopted, so that the stability of the epoxy resin emulsion can be improved, and meanwhile, the film-forming strength and the binding power of the epoxy resin emulsion can be improved, and the adhesion film formation on the surface of the cotton fabric is facilitated;
2) mixing copper powder and paraffin according to the mass ratio of 7-10:1, filling the mixture into a copper pipe with the diameter of 5-10cm, heating the copper pipe to 55-60 ℃, applying 30-50KN extrusion force to the mixture in the copper pipe in the heating process to perform extrusion treatment for 40-60min, and naturally cooling to room temperature; according to the invention, copper powder and paraffin are mixed and then subjected to hot extrusion, the paraffin is in a softened state in the hot extrusion process, and the paraffin is wrapped on the surfaces of copper powder particles by using the viscosity of the paraffin, so that the structural properties of the copper powder can be changed, the strength and hardness of the copper particles are reduced, the surface force of the copper particles is reduced, the dispersion depolymerization effect of the copper powder is enhanced, the agglomeration effect is reduced, and the cold welding of the copper powder in the ball milling process is effectively weakened; taking out the mixture, putting the mixture into a ball mill with a ball material ratio of 5-8:1, taking agate balls as grinding balls, and performing high-energy ball milling for 50-80h at the rotating speed of 200-250r/min to obtain pretreated copper powder; through high-energy ball milling, a large amount of plastic deformation is generated in the process of collision of copper particles, dislocation is generated in the interior of crystals in the particles, crystal defects such as dislocation and vacancy are gathered at a crystal boundary along with the prolonging of the ball milling time, the surface energy on the crystal boundary is gradually increased, the copper particles are promoted to break to form new particles, the crystal grains are refined, and the thermal residual stress generated by a copper/epoxy resin interface is increased;
3) placing 50-80 parts of modified epoxy resin emulsion in a water bath kettle at 60-80 ℃, stirring for 20-30min at 250r/min under 150-; according to the invention, the blending solvent composed of acrylic acid epoxidized soybean oil and glycidyl methacrylate is used as the diluent of the modified epoxy resin emulsion, so that the viscosity of the modified epoxy resin emulsion can be reduced, and the infiltration effect of cotton fabrics is improved, thereby enhancing the binding force of the cured resin and the cotton fabrics; by adding copper powder into the modified epoxy resin emulsion, due to the fact that the thermal expansion coefficients of the nano copper and the epoxy resin are different, deformation of the nano copper and the epoxy resin is not coordinated in the thermosetting process, and large thermal residual stress is generated on the interface of the nano copper and the epoxy resin, so that the interface of the nano copper and the epoxy resin has large residual stress, the elastic modulus of the nano copper/the epoxy resin is increased, the nano copper/the epoxy resin is not easy to deform, and the deformation resistance of the nano copper/the epoxy resin is enhanced;
4) soaking the cotton fabric in a cotton fabric soaking solution at room temperature for 15-20s at a pulling speed of 15-25cm/min for 3-4 times by adopting a pulling and soaking method, taking out the cotton fabric, putting the cotton fabric into a hot press, carrying out curing reaction at the pressure of 10-13MPa at 80-100 ℃ for 30-50min, carrying out curing reaction at the temperature of 120-130 ℃ for 1-2h, taking out the cotton fabric, and naturally cooling to room temperature to obtain the shrinkage-proof cotton fabric; by carrying out hot-pressing curing treatment after the cotton fabric is soaked, the nano copper/epoxy resin in the cotton fabric soaking solution can be solidified on the surface of the fibers of the cotton fabric to form a film, so that the swelling of the fibers after the cotton fabric is wetted can be reduced, the shrinkage phenomenon of the cotton fabric is improved, and the shrinkage rate of the cotton fabric is reduced.
Preferably, the process for treating the shrink-proof cotton fabric comprises the following steps in the process step 1): mixing epoxy resin and polyethylene glycol according to a molar ratio of 1:1-1.5, adding the mixture into a heating container, heating the mixture to 110 ℃ for complete dissolution of the polyethylene glycol, adding potassium persulfate accounting for 1.5-3% of the total weight of the reaction system, continuously heating the mixture to 185 ℃ for constant-temperature reaction for 3-4h, and cooling the mixture to room temperature to obtain the required emulsifier.
Compared with the prior art, the invention has the following advantages:
according to the improved cotton fabric treatment process, the cotton fabric is soaked in the soaking solution, so that the nano copper/epoxy resin in the soaking solution can be solidified on the fiber surface of the cotton fabric in a film forming manner, the nano copper/epoxy resin with larger residual stress is formed on the interface of the fiber surface of the cotton fabric, the fibers of the cotton fabric are not easy to deform, the deformation resistance of the cotton fabric is enhanced, the swelling of the fibers after the cotton fabric is wetted is reduced, the shrinkage phenomenon of the cotton fabric is improved, the shrinkage rate of the cotton fabric is reduced, the moisture absorption of the cotton fabric is not influenced, and the wearing comfort of the cotton fabric is not influenced.
Detailed Description
The present invention will be further described with reference to specific embodiments.
Example 1
A treatment process of shrink-proof cotton fabric comprises the following specific process steps:
1) mixing epoxy resin and polyethylene glycol according to a molar ratio of 1:1-1.5, adding the mixture into a heating container, heating to 100 ℃, adding potassium persulfate accounting for 1.5 percent of the total weight of the reaction system after the polyethylene glycol is completely dissolved, continuously heating to 170 ℃, reacting at constant temperature for 4 hours, and cooling to room temperature to obtain the required emulsifier;
2) placing bisphenol A epoxy resin in a 50 ℃ drying oven for preheating treatment for 80min, then adding the bisphenol A epoxy resin into a container, adding carboxylated styrene-butadiene rubber accounting for 3% of the weight of the epoxy resin, heating to 140 ℃ for constant-temperature reaction for 4h, then adding the obtained product into a container containing an emulsifier accounting for 15% of the weight of the epoxy resin, heating and stirring the mixture for 40min at 100r/min in a 60 ℃ water bath kettle, then adding a proper amount of water according to the mass-volume ratio of the epoxy resin to the water of 1.2:1g/ml, and continuously stirring the mixture for 70min until the solution is uniform to obtain a modified epoxy resin emulsion;
3) mixing copper powder and paraffin according to a mass ratio of 7:1, then filling the mixture into a copper pipe with the diameter of 5cm, heating the copper pipe to 55 ℃, applying 30KN extrusion force to the mixture in the copper pipe in the heating process to perform extrusion treatment for 60min, naturally cooling to room temperature, taking out the mixture, then putting the mixture into a ball mill with a ball-to-material ratio of 5:1, using agate balls as grinding balls, and performing high-energy ball milling for 80h at a rotating speed of 200r/min to obtain pretreated copper powder;
4) placing 50 parts of modified epoxy resin emulsion in a 60 ℃ water bath, stirring for 30min at the speed of 150r/min, then adding 0.5 part of pretreated copper powder, oscillating and dispersing for 40min under 300W ultrasonic waves, after uniform dispersion, adding 150 parts of acrylic acid epoxy soybean oil and 40 parts of glycidyl methacrylate, stirring for dissolution, then adding 0.2 part of isophorone diamine, and continuing stirring for 2h to obtain a cotton fabric impregnation solution;
5) soaking the cotton fabric in a cotton fabric soaking solution at room temperature for 15s each time at a pulling and soaking speed of 15cm/min for 3 times by adopting a pulling and soaking method, taking out the cotton fabric, putting the cotton fabric into a hot press, carrying out curing reaction at the pressure of 10MPa at 80 ℃ for 50min, carrying out curing reaction at the temperature of 120 ℃ for 2h, taking out the cotton fabric, and naturally cooling to room temperature to obtain the shrink-proof cotton fabric.
The shrink-proof cotton fabric provided by the embodiment is cut into woven belts with the width of 50mm and the length of 200mm, then a washing test is carried out according to ISO6330A and AATCC135 standards, the length of the woven belts after washing is 200mm, the untreated cotton fabric with the same size is subjected to the washing test, and the length of the woven belts after washing is 195 mm.
Example 2
A treatment process of shrink-proof cotton fabric comprises the following specific process steps:
1) mixing epoxy resin and polyethylene glycol according to a molar ratio of 1:1.2, adding the mixture into a heating container, heating to 105 ℃, adding potassium persulfate accounting for 2.3 percent of the total weight of the reaction system after the polyethylene glycol is completely dissolved, continuously heating to 175 ℃, reacting at constant temperature for 3.2 hours, and cooling to room temperature to obtain the required emulsifier;
2) preheating bisphenol A epoxy resin in a 55 ℃ drying oven for 70min, adding the bisphenol A epoxy resin into a container, adding carboxylic styrene-butadiene rubber accounting for 5% of the weight of the epoxy resin, heating to 150 ℃ for constant-temperature reaction for 3.5h, adding the obtained product into a container containing an emulsifier accounting for 17% of the weight of the epoxy resin, heating and stirring the mixture for 35min at a speed of 120r/min in a 65 ℃ water bath kettle, adding a proper amount of water according to the mass-volume ratio of the epoxy resin to the water of 1.5:1g/ml, and continuously stirring the mixture for 75min until the solution is uniform to obtain a modified epoxy resin emulsion;
3) mixing copper powder and paraffin according to a mass ratio of 8:1, then filling the mixture into a copper pipe with the diameter of 7cm, heating the copper pipe to 58 ℃, applying 40KN extrusion force to the mixture in the copper pipe in the heating process to perform extrusion treatment for 50min, naturally cooling to room temperature, taking out the mixture, then putting the mixture into a ball mill with a ball-to-material ratio of 6:1, using agate balls as grinding balls, and performing high-energy ball milling for 55h at a rotating speed of 210r/min to obtain pretreated copper powder;
4) placing 65 parts of modified epoxy resin emulsion in a 70 ℃ water bath, stirring for 25min at 200r/min, then adding 1 part of pretreated copper powder, oscillating and dispersing for 35min under 400W ultrasonic waves, adding 180 parts of acrylic acid epoxy soybean oil and 50 parts of glycidyl methacrylate after uniform dispersion, adding 0.5 part of isophorone diamine after stirring and dissolving, and continuing stirring for 1.5h to obtain a cotton fabric impregnation solution;
5) soaking the cotton fabric in a cotton fabric soaking solution at room temperature for 18s each time at a pulling speed of 20cm/min for 3 times by adopting a pulling and soaking method, taking out the cotton fabric, putting the cotton fabric into a hot press, carrying out curing reaction at the pressure of 12MPa at 90 ℃ for 40min, carrying out curing reaction at the temperature of 125 ℃ for 1.5h, taking out the cotton fabric, and naturally cooling to room temperature to obtain the shrink-proof cotton fabric.
Example 3
A treatment process of shrink-proof cotton fabric comprises the following specific process steps:
1) mixing epoxy resin and polyethylene glycol according to a molar ratio of 1:1.5, adding the mixture into a heating container, heating the mixture to 110 ℃, adding potassium persulfate accounting for 3 percent of the total weight of the reaction system after the polyethylene glycol is completely dissolved, continuously heating the mixture to 185 ℃, reacting the mixture at a constant temperature for 3 hours, and cooling the mixture to room temperature to obtain the required emulsifier;
2) placing bisphenol A epoxy resin in a 60 ℃ drying oven for preheating treatment for 50min, then adding the bisphenol A epoxy resin into a container, adding 7 wt% of carboxylic styrene-butadiene rubber of the epoxy resin, heating to 160 ℃ for constant-temperature reaction for 3h, then adding the obtained product into a container filled with 20 wt% of the epoxy resin, heating and stirring the mixture for 30min at a speed of 150r/min in a 70 ℃ water bath kettle, then adding a proper amount of water according to the mass-volume ratio of the epoxy resin to the water of 1.8:1g/ml, and continuously stirring the mixture for 80min until the solution is uniform to obtain a modified epoxy resin emulsion;
3) mixing copper powder and paraffin according to a mass ratio of 10:1, then loading the mixture into a copper pipe with the diameter of 10cm, heating the copper pipe to 60 ℃, applying 50KN extrusion force to the mixture in the copper pipe in the heating process to perform extrusion treatment for 40min, naturally cooling to room temperature, taking out the mixture, then placing the mixture into a ball mill with a ball-to-material ratio of 8:1, using agate balls as grinding balls, and performing high-energy ball milling for 50h at a rotating speed of 250r/min to obtain pretreated copper powder;
4) placing 80 parts of modified epoxy resin emulsion in a water bath kettle at 80 ℃, stirring for 20min at 250r/min, then adding 1.5 parts of pretreated copper powder, oscillating and dispersing for 30min under 500W ultrasonic waves, after uniform dispersion, adding 200 parts of acrylic acid epoxy soybean oil and 60 parts of glycidyl methacrylate, stirring for dissolution, then adding 0.7 part of isophorone diamine, and continuing stirring for 1h to obtain the cotton fabric impregnation liquid
5) Soaking the cotton fabric in a cotton fabric soaking solution at room temperature for 20s each time at a pulling and soaking speed of 25cm/min for 4 times by adopting a pulling and soaking method, taking out the cotton fabric, putting the cotton fabric into a hot press, carrying out curing reaction at the pressure of 13MPa at 100 ℃ for 30min, carrying out curing reaction at the temperature of 130 ℃ for 1h, taking out the cotton fabric, and naturally cooling to room temperature to obtain the shrink-proof cotton fabric.
The above description is only an embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that are not thought of through the inventive work should be included in the scope of the present invention.

Claims (6)

1. A treatment process of shrink-proof cotton fabric is characterized by comprising the following specific process steps:
1) placing epoxy resin in an oven at 50-60 ℃ for preheating for 50-80min, then adding the epoxy resin into a container, adding a proper amount of carboxylic styrene-butadiene rubber, heating to 140-;
2) mixing copper powder and paraffin according to a certain proportion, then loading the mixture into a copper pipe, heating the copper pipe to 55-60 ℃, extruding the mixture in the copper pipe for 40-60min in the heating process, naturally cooling to room temperature, taking out the mixture, then placing the mixture into a ball mill, and performing high-energy ball milling for 50-80h to obtain pretreated copper powder;
3) placing the modified epoxy resin emulsion in a water bath kettle, stirring for 20-30min, adding a proper amount of pretreated copper powder, oscillating and dispersing for 30-40min under 300-500W ultrasonic wave, adding a proper amount of acrylic acid epoxidized soybean oil and glycidyl methacrylate after uniform dispersion, adding isophorone diamine after stirring and dissolving, and continuously stirring for 1-2h to obtain a cotton fabric impregnation solution;
4) adopting a pulling impregnation method, impregnating the cotton fabric in a cotton fabric impregnation solution at room temperature, taking out the cotton fabric, putting the cotton fabric into a hot press, carrying out a curing reaction at the temperature of 80-100 ℃ for 30-50min under the pressure of 10-13MPa, carrying out a curing reaction at the temperature of 120-130 ℃ for 1-2h, taking out the cotton fabric, and naturally cooling to room temperature to obtain the shrinkage-resistant cotton fabric.
2. The process for treating a shrink-resistant cotton fabric according to claim 1, wherein in the process step 1), the epoxy resin is bisphenol a type epoxy resin; the addition amount of the carboxylic styrene-butadiene rubber is 3-7% of the weight of the epoxy resin, and the addition amount of the emulsifier is 15-20% of the weight of the epoxy resin; the mass volume ratio of the epoxy resin to the water is 1.2-1.8:1 g/ml; the stirring time after adding water is 70-80 min.
3. The process for treating a shrink-resistant cotton fabric according to claim 1, wherein in process step 1), the emulsifier is prepared by the following method: mixing epoxy resin and polyethylene glycol according to a molar ratio of 1:1-1.5, adding the mixture into a heating container, heating the mixture to 110 ℃ for complete dissolution of the polyethylene glycol, adding potassium persulfate accounting for 1.5-3% of the total weight of the reaction system, continuously heating the mixture to 185 ℃ for constant-temperature reaction for 3-4h, and cooling the mixture to room temperature to obtain the required emulsifier.
4. The process for treating the shrink-proof cotton fabric as claimed in claim 1, wherein in the process step 1), the mass ratio of the copper powder to the paraffin wax is 7-10: 1; the diameter of the copper pipe is 10-15cm, and the extrusion pressure is 30-50 KN; the rotation speed of the ball mill is 200-250r/min, the grinding balls are agate balls, and the ball-material ratio is 5-8: 1.
5. The process for treating shrink-resistant cotton fabric as claimed in claim 1, wherein in the process step 3), the weight ratio of the modified epoxy resin emulsion, the copper powder, the acrylic acid epoxidized soybean oil, the glycidyl methacrylate and the isophorone diamine is 50-80:0.5-1.5: 150-; the temperature of the water bath is 60-80 ℃; the stirring rotating speed is 150-250 r/min.
6. The process for treating a shrink-resistant cotton fabric as claimed in claim 1, wherein in the process step 4), the dipping time is 15-20s per time, the pulling speed is 15-25cm/min, and the dipping is performed 3-4 times.
CN201911210687.0A 2019-12-02 2019-12-02 Treatment process of shrink-proof cotton fabric Pending CN110820345A (en)

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CN112981942A (en) * 2021-02-18 2021-06-18 邱德澳 Ultrahigh-hardness fabric and preparation method thereof
CN114591669A (en) * 2022-03-03 2022-06-07 广东台实实业有限公司 Waterproof coating with cracking resistance and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112981942A (en) * 2021-02-18 2021-06-18 邱德澳 Ultrahigh-hardness fabric and preparation method thereof
CN114591669A (en) * 2022-03-03 2022-06-07 广东台实实业有限公司 Waterproof coating with cracking resistance and preparation method thereof
CN114591669B (en) * 2022-03-03 2023-01-24 广东台实实业有限公司 Waterproof coating with cracking resistance and preparation method thereof

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Application publication date: 20200221