CN110788332A - Powder metallurgy eccentric wheel for atomizer compression pump and preparation method thereof - Google Patents

Powder metallurgy eccentric wheel for atomizer compression pump and preparation method thereof Download PDF

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Publication number
CN110788332A
CN110788332A CN201911196067.6A CN201911196067A CN110788332A CN 110788332 A CN110788332 A CN 110788332A CN 201911196067 A CN201911196067 A CN 201911196067A CN 110788332 A CN110788332 A CN 110788332A
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China
Prior art keywords
powder
eccentric wheel
preparation
compression pump
atomizer
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CN201911196067.6A
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Chinese (zh)
Inventor
王昌举
鹿振
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Jinan Bohan Precision Machinery Co Ltd
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Jinan Bohan Precision Machinery Co Ltd
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Priority to CN201911196067.6A priority Critical patent/CN110788332A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F1/0003
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/14Treatment of metallic powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/02Compacting only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • B22F3/1003Use of special medium during sintering, e.g. sintering aid
    • B22F3/1007Atmosphere
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • B22F3/1017Multiple heating or additional steps
    • B22F3/1021Removal of binder or filler
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention provides a powder metallurgy eccentric wheel for an atomizer compression pump and a preparation method thereof, wherein the powder metallurgy eccentric wheel comprises the following raw materials: 92-93.4% of atomized iron powder, 0.8-1% of graphite, 2-2.3% of copper powder, 3-3.2% of nickel powder, 0.6-0.8% of molybdenum powder and 0.2-0.3% of manganese sulfide powder.

Description

Powder metallurgy eccentric wheel for atomizer compression pump and preparation method thereof
Technical Field
The invention relates to the field of manufacturing of eccentric wheels of compression pumps of atomizers, in particular to a powder metallurgy eccentric wheel for the compression pump of the atomizers and a preparation method thereof.
Background
The eccentric wheel is the most important component in the compression pump of the atomizer, gas compression is carried out through the rotation of the eccentric wheel, and high-speed airflow is formed through the small pipe orifice, so that liquid drops are changed into mist-shaped particles to be sprayed out. The eccentric wheel of the compression pump of the conventional atomizer is composed of a convex handle (1), an eccentric wheel body (2) and a positioning groove (3) as shown in figure 1. Under the general condition, the convex handle (1), the eccentric wheel body (2) and the positioning groove (3) are all required to be processed respectively and independently, but the convex handle (1), the eccentric wheel body (2) and the positioning groove (3) are all processed independently, the processing process is complex, uncontrollable factors are more, the production efficiency is lower, and the production cost is very high.
CN101769370A provides a powder metallurgy eccentric helical gear and a method for manufacturing the same, in which a gear body and an eccentric cam are separately molded and pre-sintered, and then welded to form an integral through a welding point and then integrally tempered, so as to manufacture the powder metallurgy eccentric helical gear, but the gear body and the eccentric cam still need to be separately processed, and then are welded, and the like, which is complicated in manufacturing process, prone to cause center distance deviation, and low in production efficiency. The existing preparation method is to firstly carry out rough machining on round steel, then carry out finish machining through a machining center, and obtain a product after multiple positioning machining, and the preparation process is complex, the deviation of the center distance is easy to generate, and the production efficiency is not high.
CN103223489B provides a preparation method of eccentric wheel powder metallurgy, which is characterized in that a modification auxiliary agent is added into raw materials, ultrafine powder is provided in mixed raw materials, and a phosphating treatment process is matched, so that one-step forming can be realized, and the apparent density of the mixed materials is improved.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a metallurgical powder eccentric wheel for an atomizer compression pump and a preparation method thereof, and aims to improve the mechanical strength of the eccentric wheel, improve the density of a product and improve the production efficiency of the eccentric wheel.
In order to solve the technical problems, the invention adopts the following technical scheme:
the utility model provides a powder metallurgy eccentric wheel for atomizer compression pump which characterized in that, powder metallurgy eccentric wheel, by weight percent, its raw and other materials constitution includes: 92-93.4% of atomized iron powder, 0.8-1% of graphite, 2-2.3% of copper powder, 3-3.2% of nickel powder, 0.6-0.8% of molybdenum powder and 0.2-0.3% of manganese sulfide powder;
the atomized iron powder is a powder material produced by Swedish Hegners Limited, and the product model is ASC 100.29;
the preparation method of the powder metallurgy eccentric wheel for the atomizer compression pump comprises the steps of mixing, cooling, press forming and sintering;
mixing materials, wherein the stirring speed is 18-20rad/min, and the stirring time is 45-60 minutes;
cooling, namely cooling the mixed powder at room temperature, and standing for 20-24h at 25 ℃;
performing press forming, wherein the density difference between the eccentric wheel convex handle and the eccentric wheel body is less than 0.05 g/cm, the pressure is 14-15 tons, and the weight of the powder is 20-20.5 grams;
the forming rate can reach 8-10 pieces/minute;
sintering, wherein the temperature of a dewaxing section is 650-850 ℃, the dewaxing time is 1.5-2 hours, the temperature of a high temperature section is 1120-1130 ℃, and the heat preservation time is 30-50 minutes;
the invention applies ASC100.29 atomized iron powder to the manufacturing process of the powder metallurgy eccentric wheel in a breakthrough manner, in the iron-based powder metallurgy material, through the reasonable collocation of carbon, copper, nickel, molybdenum and manganese, the material not only has very strong compressibility, but also has excellent mechanical strength, only needs one-time pressing and one-time sintering during preparation to meet the requirement of the eccentric wheel product on service performance, simplifies the manufacturing process, and greatly improves the production efficiency.
By adopting the technical scheme, the invention has the beneficial effects that:
1. by adopting the preparation method of the metallurgical powder eccentric wheel for the atomizer compression pump, the test is carried out through a pressure feed testing machine, the crushing value of the eccentric wheel can be improved to 2300 plus 2500N, the material strength is higher, and the product performance requirement is met;
2. by adopting the preparation method of the metallurgical powder eccentric wheel for the atomizer compression pump, the product density can reach 7.2-7.3g/cm through high-speed dry-rolling and sintering, and the higher material density can be reached through one-time pressing and sintering;
3. by adopting the powder metallurgy material, the convex handle, the eccentric wheel body and the positioning groove are molded at one time by pressing, so that the processing process that a plurality of parts are respectively independent is omitted, the manufacturing is easy, the press molding speed can reach 8-10 pieces/minute, and the production efficiency is obviously improved;
4. by adopting the preparation method of the metallurgical powder eccentric wheel for the atomizer compression pump, the problem of unstable center distance generated in the processing process of eccentric wheel products can be solved, the powder metallurgical material is formed in one step, the deviation existing in the process of multiple clamping is avoided, and the center distance is very stable;
5. by adopting the preparation method of the metallurgical powder eccentric wheel for the atomizer compression pump, the powder metallurgy material is formed at one time, the pressed product is very smooth, the phenomenon that burrs are generated on the product after a cutter is worn when the product is machined and cut is avoided, and the yield is high.
Description of the drawings:
FIG. 1 is a schematic view of an eccentric wheel for a compression pump of an atomizer
Wherein, (1) shows the convex handle, (2) shows the eccentric wheel body, (3) shows the locating slot
The specific implementation mode is as follows:
the invention is further illustrated below with reference to specific examples.
Embodiment 1 atomizer compression pump powder metallurgy eccentric wheel and preparation method thereof
The powder metallurgy eccentric wheel for the atomizer compression pump comprises the following raw materials in percentage by weight:
93 percent of atomized iron powder, 1 percent of graphite, 2 percent of copper powder, 3 percent of nickel powder, 0.7 percent of molybdenum powder and 0.3 percent of manganese sulfide powder
The atomized iron powder is a powder material produced by Swedish Hegners Limited, and the product model is ASC 100.29;
the preparation method of the powder metallurgy eccentric wheel for the atomizer compression pump comprises the following steps:
1. mixing material
Stirring atomized iron powder, graphite, copper powder, nickel powder, molybdenum powder and manganese sulfide by a powder mixer at a stirring speed of 18rad/min for 45 minutes;
2. cooling down
After the powder materials are uniformly mixed, cooling is carried out at room temperature, and the mixture is placed for 20 hours at 25 ℃ for use;
3. and (3) pressing and forming:
adding the mixed powder into a hopper, performing compression molding by a press, wherein the middle die is made of hard alloy, other punches are made of high-speed steel, and the density difference between the eccentric wheel convex handle and the eccentric wheel body is controlled not to exceed 0.05 g/cm for carrying out thin-film forging to obtain a molding blank;
the press forming is carried out, the pressure is 14 tons, the powder weight is 20 grams, and the press forming speed is 8 per minute;
4. and (3) sintering:
placing the formed blank in a sintering furnace for sintering, and changing the formed blank into a high-strength sintered blank after sintering;
and (3) sintering: the dewaxing time is 2 hours at 650 ℃ in the dewaxing section, the heat preservation time is 30 minutes at 1130 ℃ in the high temperature section, and the furnace protective atmosphere is 90 percent of nitrogen and 10 percent of hydrogen.
The metallurgical powder eccentric wheel for the atomizer compression pump, which is prepared by adopting the technical scheme of embodiment 1 of the invention, has the density of 7.215 g/cm, the pressure-fed value of 2350N and higher material strength.
Embodiment 2 atomizer compression pump powder metallurgy eccentric wheel and preparation method thereof
The powder metallurgy eccentric wheel for the atomizer compression pump comprises the following raw materials in percentage by weight:
93.15 percent of atomized iron powder, 0.8 percent of graphite, 2.2 percent of copper powder, 3 percent of nickel powder, 0.6 percent of molybdenum powder and 0.25 percent of manganese sulfide powder
The atomized iron powder is a powder material produced by Swedish Hegners Limited, and the product model is ASC 100.29;
the preparation method of the powder metallurgy eccentric wheel for the atomizer compression pump comprises the following steps:
1. mixing material
Stirring atomized iron powder, graphite, copper powder, nickel powder, molybdenum powder and manganese sulfide by a powder mixer at a stirring speed of 18rad/min for 50 minutes;
2. cooling down
After the powder materials are uniformly mixed, cooling is carried out at room temperature, and then the mixture is placed for 24 hours at 25 ℃ for use;
3. and (3) pressing and forming:
adding the mixed powder into a hopper, performing compression molding by a press, wherein the middle die is made of hard alloy, other punches are made of high-speed steel, and the density difference between the eccentric wheel convex handle and the eccentric wheel body is controlled not to exceed 0.03 g/cm for carrying out thin film forging to obtain a molding blank;
the pressure of the compression molding is 14.5 tons, the weight of the powder is 20 grams, and the compression molding speed is 10 per minute;
4. and (3) sintering:
placing the formed blank in a sintering furnace for sintering, and changing the formed blank into a high-strength sintered blank after sintering;
and (3) sintering: the dewaxing period is 750 ℃, the dewaxing time is 1.5 hours, the high temperature period is 1120 ℃, the heat preservation time is 50 minutes, and the furnace protective atmosphere is 90 percent of nitrogen and 10 percent of hydrogen.
The metallurgical powder eccentric wheel for the atomizer compression pump, which is prepared by adopting the technical scheme of the embodiment 2, has the density of 7.278 g/cm and the pressure-fed value of 2412N, and is high in material strength.
Embodiment 3 atomizer compression pump powder metallurgy eccentric wheel and preparation method thereof
The powder metallurgy eccentric wheel for the atomizer compression pump comprises the following raw materials in percentage by weight:
92.9 percent of atomized iron powder, 0.8 percent of graphite, 2 percent of copper powder, 3.2 percent of nickel powder, 0.8 percent of molybdenum powder and 0.3 percent of manganese sulfide powder
The atomized iron powder is a powder material produced by Swedish Hegners Limited, and the product model is ASC 100.29;
the preparation method of the powder metallurgy eccentric wheel for the atomizer compression pump comprises the following steps:
1. mixing material
Stirring atomized iron powder, graphite, copper powder, nickel powder, molybdenum powder and manganese sulfide by a powder mixer at a stirring speed of 20rad/min for 60 minutes;
2. cooling down
After the powder materials are uniformly mixed, cooling is carried out at room temperature, and the mixture is placed for 20 hours at 25 ℃ for use;
3. and (3) pressing and forming:
adding the mixed powder into a hopper, performing compression molding by a press, wherein the middle die is made of hard alloy, other punches are made of high-speed steel, and the density difference between the eccentric wheel convex handle and the eccentric wheel body is controlled not to exceed 0.05 g/cm for carrying out thin-film forging to obtain a molding blank;
the pressure of the pressing forming is 15 tons, the powder weight is 20.5 grams, and the pressing forming speed is 10 per minute;
4. and (3) sintering:
placing the formed blank in a sintering furnace for sintering, and changing the formed blank into a high-strength sintered blank after sintering;
and (3) sintering: the dewaxing time is 1.5 hours at 850 ℃ in the dewaxing section, the heat preservation time is 40 minutes at 1130 ℃ in the high temperature section, and the furnace protective atmosphere is 90 percent of nitrogen and 10 percent of hydrogen.
The metallurgical powder eccentric wheel for the atomizer compression pump, which is prepared by adopting the technical scheme of embodiment 3 of the invention, has the density of 7.305 g/cm, the pressure-fed value of 2495N and higher material strength.
Embodiment 4 atomizer compression pump powder metallurgy eccentric wheel and preparation method thereof
The powder metallurgy eccentric wheel for the atomizer compression pump comprises the following raw materials in percentage by weight:
92.4 percent of atomized iron powder, 1 percent of graphite, 2.3 percent of copper powder, 3.2 percent of nickel powder, 0.8 percent of molybdenum powder and 0.3 percent of manganese sulfide powder
The atomized iron powder is a powder material produced by Swedish Hegners Limited, and the product model is ASC 100.29;
the preparation method of the powder metallurgy eccentric wheel for the atomizer compression pump comprises the following steps:
1. mixing material
Stirring atomized iron powder, graphite, copper powder, nickel powder, molybdenum powder and manganese sulfide by a powder mixer at a stirring speed of 20rad/min for 60 minutes;
2. cooling down
After the powder materials are uniformly mixed, cooling is carried out at room temperature, and the mixture is placed for 22 hours at 25 ℃ for use;
3. and (3) pressing and forming:
adding the mixed powder into a hopper, performing compression molding by a press, wherein the middle die is made of hard alloy, other punches are made of high-speed steel, and the density difference between the eccentric wheel convex handle and the eccentric wheel body is controlled not to exceed 0.02 g/cm for carrying out thin film forging to obtain a molding blank;
the pressure of the pressing forming is 15 tons, the powder weight is 20.3 grams, and the pressing forming speed is 10 per minute;
4. and (3) sintering:
placing the formed blank in a sintering furnace for sintering, and changing the formed blank into a high-strength sintered blank after sintering;
and (3) sintering: the dewaxing period is 750 ℃, the dewaxing time is 1.5 hours, the high temperature period is 1120 ℃, the heat preservation time is 30 minutes, and the furnace protective atmosphere is 90 percent of nitrogen and 10 percent of hydrogen.
The metallurgical powder eccentric wheel for the atomizer compression pump, which is prepared by adopting the technical scheme of embodiment 4 of the invention, has the density of 7.255 g/cm, the pressure-feed value of 2453N and high material strength.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art will understand that various changes, modifications and substitutions can be made without departing from the spirit and scope of the present invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (9)

1. The utility model provides a powder metallurgy eccentric wheel for atomizer compression pump which characterized in that, powder metallurgy eccentric wheel, by weight percent, its raw and other materials constitution includes: 92-93.4% of atomized iron powder, 0.8-1% of graphite, 2-2.3% of copper powder, 3-3.2% of nickel powder, 0.6-0.8% of molybdenum powder and 0.2-0.3% of manganese sulfide powder.
2. The eccentric wheel of claim 1, wherein the atomized iron powder is a powder manufactured by Hegners Limited, Sweden, and its product model is ASC 100.29.
3. The preparation method of the powder metallurgy eccentric wheel for the atomizer compression pump is characterized by comprising the steps of mixing, cooling, press forming and sintering.
4. The preparation method according to claim 3, wherein the pressing forming is carried out by carrying out high speed carrying on the eccentric wheel convex handle and the eccentric wheel body according to the density difference of less than 0.05 g/cm under the pressure of 14-15 tons and the powder weight of 20-20.5 grams.
5. The method as claimed in claim 3, wherein the sintering temperature is 650-850 ℃ and the dewaxing time is 1.5-2 hours, the temperature is 1120-1130 ℃ and the holding time is 30-50 minutes.
6. The method according to claim 3, wherein the powder after cooling and mixing is cooled at room temperature and left at 25 ℃ for 20 to 24 hours.
7. The preparation method according to claim 3, wherein the mixing is performed at a stirring speed of 18 to 20rad/min for 45 to 60 minutes.
8. The method according to claim 3, wherein the press molding is carried out at a molding rate of 8 to 10 pieces/minute.
9. The preparation method as claimed in claims 1 to 8, wherein the crushing value of the prepared eccentric wheel is 2300-2500N, and the density can reach 7.2-7.3 g/cm.
CN201911196067.6A 2019-11-29 2019-11-29 Powder metallurgy eccentric wheel for atomizer compression pump and preparation method thereof Pending CN110788332A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5659873A (en) * 1995-02-16 1997-08-19 Miba Sintermetall Aktiengesellschaft Method of producing a cam for a jointed camshaft
CN1946500A (en) * 2004-04-21 2007-04-11 霍加纳斯股份有限公司 Sintered metal parts and method for the manufacturing thereof
CN101251112A (en) * 2008-03-26 2008-08-27 陈惠莲 Medical air pump offset cam as well as manufacturing process thereof
DE102011109473A1 (en) * 2011-08-04 2012-03-15 Daimler Ag Sintered component e.g. cam for assembled camshaft of internal combustion engine, comprises surface portion of sintered component, boundary layer compaction, and hardened region, where compression layer is produced in surface portion
CN103223489A (en) * 2013-04-09 2013-07-31 吴建平 Method for manufacturing eccentric wheel through powder metallurgy
CN103244400A (en) * 2012-02-14 2013-08-14 无锡格兰登福托玛斯气动系统有限公司 Eccentric wheel for medical pump and process for manufacturing eccentric wheel
CN106363179A (en) * 2016-08-30 2017-02-01 宁波拓发汽车零部件有限公司 Bottom valve

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5659873A (en) * 1995-02-16 1997-08-19 Miba Sintermetall Aktiengesellschaft Method of producing a cam for a jointed camshaft
CN1946500A (en) * 2004-04-21 2007-04-11 霍加纳斯股份有限公司 Sintered metal parts and method for the manufacturing thereof
CN101251112A (en) * 2008-03-26 2008-08-27 陈惠莲 Medical air pump offset cam as well as manufacturing process thereof
DE102011109473A1 (en) * 2011-08-04 2012-03-15 Daimler Ag Sintered component e.g. cam for assembled camshaft of internal combustion engine, comprises surface portion of sintered component, boundary layer compaction, and hardened region, where compression layer is produced in surface portion
CN103244400A (en) * 2012-02-14 2013-08-14 无锡格兰登福托玛斯气动系统有限公司 Eccentric wheel for medical pump and process for manufacturing eccentric wheel
CN103223489A (en) * 2013-04-09 2013-07-31 吴建平 Method for manufacturing eccentric wheel through powder metallurgy
CN106363179A (en) * 2016-08-30 2017-02-01 宁波拓发汽车零部件有限公司 Bottom valve

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张华诚: "《粉末冶金实用工艺学》", 30 September 2004, 冶金工业出版社 *

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Application publication date: 20200214