CN110771608A - Chlorothalonil smoke agent and using method thereof - Google Patents

Chlorothalonil smoke agent and using method thereof Download PDF

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Publication number
CN110771608A
CN110771608A CN201910991936.8A CN201910991936A CN110771608A CN 110771608 A CN110771608 A CN 110771608A CN 201910991936 A CN201910991936 A CN 201910991936A CN 110771608 A CN110771608 A CN 110771608A
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China
Prior art keywords
parts
chlorothalonil
weight
medicine
smoke agent
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Withdrawn
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CN201910991936.8A
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Chinese (zh)
Inventor
张华伟
王英爽
王佳建
宋显全
卢洪斌
安允龙
卫鑫
安永一
林文华
王春磊
樊殿佐
刘丽颖
葛迎春
韩冰
关丽萍
吴爽
李万龙
于海龙
张少龙
宋久栋
朱遵山
胡明慧
孙黎明
栾媛
高俊峰
闫金
刘世一
孙志权
刘金霞
魏金龙
陈保胜
张鹏
朱遵福
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Pingshan Mountain Heilongjiang Province Forestry Pharmaceutical Factory
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Pingshan Mountain Heilongjiang Province Forestry Pharmaceutical Factory
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Priority to CN201910991936.8A priority Critical patent/CN110771608A/en
Publication of CN110771608A publication Critical patent/CN110771608A/en
Withdrawn legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34Nitriles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18Vapour or smoke emitting compositions with delayed or sustained release
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B29/00Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
    • C06B29/02Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal
    • C06B29/12Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal with carbon or sulfur
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B31/00Compositions containing an inorganic nitrogen-oxygen salt
    • C06B31/02Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate
    • C06B31/04Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate with carbon or sulfur
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B39/00Compositions containing free phosphorus or a binary compound of phosphorus, except with oxygen
    • C06B39/02Compositions containing free phosphorus or a binary compound of phosphorus, except with oxygen with an inorganic oxygen-halogen salt

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to the technical field of pesticide supplies, in particular to a chlorothalonil smoke agent. The utility model provides a chlorothalonil smoke agent, includes the ignition powder pipe at least, draws big gun, former medicine splendid attire pipe, lid, through the diameter of design cross section of acting as go-between, the thickness of length and outer paraffin, delayed the time of drawing big gun ignition, guaranteed the security of personnel of using and the security of smoke agent when storing and using to through add modified magnesium hydroxide in chlorothalonil, adjust diffusion and settlement speed after the gasification of chlorothalonil, improved the utilization ratio of pesticide, reduced environmental pollution.

Description

Chlorothalonil smoke agent and using method thereof
Technical Field
The invention relates to the technical field of pesticide products, in particular to a chlorothalonil smoke agent and a using method thereof.
Background
The chlorothalonil can act with glyceraldehyde triphosphate dehydrogenase in fungal cells and is combined with protein containing cysteine in the enzyme, so that the activity of the enzyme is damaged, the metabolism of the fungal cells is damaged and the vitality of the fungal cells is lost, and therefore, the chlorothalonil can be used as a broad-spectrum protective bactericide and has a prevention effect on various fungal diseases. At present, the medicine is applied to a protected area mostly by adopting a spraying method, the labor intensity is high, and the health of a medicine applying person is influenced.
The smoke agent developed and prepared at present mixes the pesticide for preventing and treating plant diseases and insect pests with combustible substances, and the combustible substances are combusted to ensure that the pesticide is gasified and condensed into smoke particles to quickly and efficiently act on plants, thereby saving labor, time and medicine, and improving the prevention and treatment effect, so the smoke agent is favored. However, the problem exists that the smoke agent needs to be ignited manually, if the application area is too large and the ignition point is too much, the application personnel can not leave in time and can also cause damage to the human body, and in addition, after the chlorothalonil is gasified into smoke, the density is low, the smoke agent is easy to scatter along with the wind, the utilization rate of pesticides is reduced, the environment is polluted, and the health of people is influenced.
Disclosure of Invention
In order to solve the technical problems, the invention provides a chlorothalonil smoke agent, which comprises an ignition powder tube, a pulling gun, a raw medicine containing tube and a box cover; the box cover and the ignition powder tube are connected in a tenon joint mode, and a cavity is formed between the box cover and the ignition powder tube; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes are arranged in the cavity and are uniformly distributed around the pulling cannon;
the pulling gun comprises a pulling wire, a first medicine layer, a second medicine layer and a packaging layer; the outer layer of one end of the stay wire is coated with a first fuel which is used as a fuel twist, and the outer layer of the other end of the stay wire is coated with paraffin; the first medicine layer wraps the medicine twist, the second medicine layer wraps the first medicine layer, the packaging layer wraps the second medicine layer, and the other end of the stay wire is exposed out of the packaging layer;
the raw pesticide containing tube is filled with a chlorothalonil agent and an aerosol regulator.
As a preferable technical scheme of the invention, the diameter of the cross section of the stay wire is 2.3-2.8 mm.
As a preferable technical scheme of the invention, the length of one end of the stay wire exposed out of the packaging layer is 2-4 cm, and the thickness of paraffin on the outer layer of the stay wire is 1-1.2 mm.
As a preferable technical scheme, the weight ratio of the chlorothalonil oil preparation to the aerosol regulator is 1: (0.3-0.5).
In a preferred technical scheme of the invention, the aerosol regulator is modified magnesium hydroxide.
According to a preferable technical scheme, a second fuel is further filled in the ignition tube, and the second fuel is prepared from 45-60 parts by weight of potassium nitrate, 12-18 parts by weight of sulfur, 20-26 parts by weight of kaolin, 23-53 parts by weight of ammonium chloride and 24-36 parts by weight of bagasse powder.
According to a preferable technical scheme, the preparation raw materials of the first fuel comprise, by weight, 75-105 parts of potassium perchlorate, 37-52 parts of sugarcane powder and 12-18 parts of carbon powder.
According to a preferable technical scheme, the first chemical layer contains a third chemical, and the third chemical is prepared from 12-18 parts by weight of red phosphorus, 45-60 parts by weight of potassium perchlorate, 22-37 parts by weight of sugarcane powder, 4.5-10.5 parts by weight of an adhesive and 30-60 parts by weight of water.
According to a preferable technical scheme, the second chemical layer contains a fourth chemical, and the fourth chemical is prepared from 45-75 parts by weight of potassium nitrate, 12-18 parts by weight of sulfur, 20-34 parts by weight of sugarcane powder, 4-8 parts by weight of a binder and 30-60 parts by weight of water.
As a preferable technical scheme, the application method of the chlorothalonil smoke agent comprises the following steps:
s1: uniformly placing at least one chlorothalonil smoke agent at a burning point in an application range, fixing the position, and removing paraffin at a stay wire end to expose the stay wire by 2-4 mm;
s2: the operator, after igniting the aerosol with the ignition tool, leaves the aerosol application zone.
Has the advantages that: the invention provides a chlorothalonil smoke agent, which is prepared by placing chlorothalonil in a raw medicine containing pipe, wherein the smoke agent at least comprises an ignition powder pipe, a pulling gun, a raw medicine containing pipe and a box cover, and the smoke agent can be ignited by igniting a pulling wire, so that the chlorothalonil is gasified and condensed into smoke particles. In addition, the modified magnesium hydroxide is added into the chlorothalonil, so that the diffusion and sedimentation speed of smoke generated after the chlorothalonil is gasified is effectively adjusted, the utilization rate of pesticides is ensured, and the environmental pollution is reduced.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without creative efforts.
FIG. 1 is a diagram of the construction of the chlorothalonil smoke agent of the present invention;
wherein, 1-outer package damp-proof device, 3-box cover, 4-igniting powder tube, 5-raw medicine containing tube, and 6-pulling gun.
FIG. 2 is a structural diagram of the present invention;
wherein, 2-stay wire, 8-medical twist, 9-first medical layer, 10-second medical layer and 11-packaging layer.
Detailed Description
The disclosure may be understood more readily by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, including definitions, will control.
The terms "comprises," "comprising," "includes," "including," "has," "having," "contains," "containing," or any other variation thereof, as used herein, are intended to cover a non-exclusive inclusion. For example, a composition, process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, process, method, article, or apparatus.
When an amount, concentration, or other value or parameter is expressed as a range, preferred range, or as a range of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when a range of "1 to 5" is disclosed, the described range should be interpreted to include the ranges "1 to 4", "1 to 3", "1 to 2 and 4 to 5", "1 to 3 and 5", and the like. When a range of values is described herein, unless otherwise stated, the range is intended to include the endpoints thereof and all integers and fractions within the range.
In addition, the indefinite articles "a" and "an" preceding an element or component of the invention are not intended to limit the number requirement (i.e., the number of occurrences) of the element or component. Thus, "a" or "an" should be read to include one or at least one, and the singular form of an element or component also includes the plural unless the stated number clearly indicates that the singular form is intended.
The meaning of "first, second, third and fourth" in the present invention is to distinguish the same structural or compositional features in the product, and not to limit the order of the structures of the product of the present invention.
The chlorothalonil smoke agent of the present invention will be described in detail with reference to the accompanying drawings.
As shown in fig. 1, the invention provides a chlorothalonil smoke agent on one hand, and the smoke agent comprises an ignition powder pipe 4, a pulling gun 6, a raw medicine containing pipe 5 and a box cover 3; the box cover 3 and the ignition charge pipe 4 are connected in a joggle mode, and a cavity is formed between the box cover and the ignition charge pipe; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes 5 are arranged in the cavity and are uniformly distributed around the pulling cannon 6;
as shown in fig. 2, the pulling gun 6 comprises a pulling wire 2, a first medicine layer 9, a second medicine layer 10 and a packaging layer 11; the outer layer of one end of the stay wire 2 is coated with a first fuel, which is used as a fuel twist 8, and the outer layer of the other end of the stay wire is coated with paraffin; the first medicine layer 9 wraps the medicine twist 8, the second medicine layer 10 wraps the first medicine layer 9, the packaging layer 11 wraps the second medicine layer 10, and the other end of the stay wire 2 is exposed out of the packaging layer 11;
the raw pesticide containing pipe 5 is filled with a chlorothalonil agent and an aerosol regulator.
Chlorothalonil, also known as tetrachloroisophthalonitrile, can act on glyceraldehyde triphosphate dehydrogenase in fungal cells and combine with protein containing cysteine in the enzyme to destroy the activity of the enzyme, so that the metabolism of the fungal cells is destroyed and the vitality of the fungal cells is lost, thereby being capable of being used as a broad-spectrum protective bactericide and having a preventive effect on various fungal diseases. In the present invention, the content of chlorothalonil in the chlorothalonil oil agent is not limited, and a chlorothalonil crude drug can be prepared into the chlorothalonil oil agent according to a preparation method conventionally used by a person skilled in the art, and the chlorothalonil crude drug can be obtained commercially, for example, the commercially available chlorothalonil crude drug includes but is not limited to a product purchased from zheng zhou south chemical product sales limited.
In a preferred embodiment, the chlorothalonil smoke agent further comprises an overwrap moisture barrier 1. The outer moisture-proof packaging device 1 is not limited in the invention and can be a bag or a box, and the function of the outer moisture-proof packaging device is to ensure that the smoke agent can not absorb moisture when stored in humid climates.
In some embodiments, the diameter of the cross section of the pull wire is 2.3-2.8 mm; preferably, the diameter of the cross section of the pull wire is 2.5 mm.
In some embodiments, the length of the end of the stay wire exposed out of the packaging layer is 2-4 cm, and the thickness of paraffin on the outer layer of the stay wire is 1-1.2 mm; preferably, the length of the stay wire is 3cm, and the thickness of the outer paraffin is 1 mm.
The chlorothalonil smoke agent can ignite the smoke agent by pulling the pull wire, also can ignite the smoke agent by igniting the pull wire, and preferably adopts a mode of igniting the pull wire to ignite the smoke agent. Chlorothalonil belongs to a class 2B carcinogen and is harmful to eyes and skin of people, and when the chlorothalonil is used for preparing a smoke agent, a plurality of ignition points are usually set for ensuring the uniformity of a medicament, so that if the ignition speed of the smoke agent is too high, and particularly when the ignition points are too high, the smoke of the chlorothalonil can be released when people do not leave in time, and the harm to the human body is easily caused. According to the invention, the surface of one end of the stay wire exposed out of the packaging layer is coated with a layer of paraffin, on one hand, the paraffin needs to be melted into paraffin oil at high temperature, and then the paraffin oil is vaporized into steam at high temperature to be combusted, so that the safety of the smoke agent in the storage and transportation processes can be ensured, on the other hand, when the smoke agent is used, the paraffin at the stay wire end is firstly removed by 2-4 mm, the stay wire is ignited, the paraffin at the outer layer is melted into liquid state by using the heat released by the combustion of the stay wire, and the paraffin oil runs upwards along the stay wire due to the capillary action of the stay wire and is vaporized into paraffin steam to be combusted when running below the flame, so that the time before the fire gun is ignited is prolonged, and people have sufficient time to ignite all smoke. Meanwhile, in order to ensure the ignition rate of the smoke agent and properly delay the ignition time to ensure that the flame can be extinguished in time, strict requirements are imposed on the length of the stay wire and the thickness of the outer layer paraffin.
In some embodiments, the weight ratio of the chlorothalonil agent to the aerosol regulator is 1: (0.3 to 0.5); preferably, the weight ratio of the chlorothalonil agent to the aerosol regulator is 1: 0.4.
in some embodiments, the aerosol conditioner is a modified magnesium hydroxide.
The modified magnesium hydroxide can be obtained commercially, and for example, the commercially available modified magnesium hydroxide includes but is not limited to products (CAS number: 105-11-3, active substance content 99%, particle size 1.5-2 μm) obtained from flame retardant materials of City of Dongguan.
The chlorothalonil is gasified to form smoke which is diffused in the space, and the smoke is easy to blow away along with wind if the air leakage position exists in the application space due to the low density of the chlorothalonil, so that the utilization rate of pesticides is reduced, the environment is easy to pollute, and the health of human bodies is easily injured. According to the invention, the modified magnesium hydroxide is added into the raw pesticide containing pipe at the same time, and is heated and decomposed to generate magnesium oxide and water vapor, so that on one hand, the released water vapor can quickly diffuse and condense the gasified pesticide smoke and plays a role in extinguishing combustion, and on the other hand, the modified magnesium hydroxide or magnesium oxide with smaller particle size forms a nucleation center in the smoke, so that the settling speed of the pesticide smoke can be accelerated, the modified magnesium hydroxide or magnesium oxide can effectively act on the surface of a plant, and the utilization rate of the pesticide is improved.
In some embodiments, a second propellant is also filled in the ignition charge pipe 4, and the second propellant is prepared from 45-60 parts by weight of potassium nitrate, 12-18 parts by weight of sulfur, 20-26 parts by weight of kaolin, 23-53 parts by weight of ammonium chloride and 24-36 parts by weight of bagasse powder; preferably, the raw materials for preparing the second fuel comprise 53 parts of potassium nitrate, 15 parts of sulfur, 23 parts of kaolin, 38 parts of ammonium chloride and 30 parts of bagasse powder.
In some embodiments, the preparation raw materials of the first fuel comprise, by weight, 75-105 parts of potassium perchlorate, 37-52 parts of sugarcane powder and 12-18 parts of carbon powder; preferably, the preparation raw materials of the first fuel comprise 90 parts of potassium perchlorate, 45 parts of sugarcane powder and 15 parts of carbon powder.
In some embodiments, the first chemical layer contains a third chemical, and the third chemical is prepared from 12-18 parts by weight of red phosphorus, 45-60 parts by weight of potassium perchlorate, 22-37 parts by weight of sugarcane powder, 4.5-10.5 parts by weight of a binder and 30-60 parts by weight of water; preferably, the raw materials for preparing the third fuel comprise 15 parts of red phosphorus, 52 parts of potassium perchlorate, 30 parts of sugarcane powder, 7.5 parts of adhesive and 45 parts of water.
In some embodiments, the second chemical layer contains a fourth chemical, and the fourth chemical is prepared from 45-75 parts by weight of potassium nitrate, 12-18 parts by weight of sulfur, 20-34 parts by weight of sugarcane powder, 4-8 parts by weight of a binder and 30-60 parts by weight of water; preferably, the preparation raw materials of the fourth fuel comprise 60 parts of potassium nitrate, 15 parts of sulfur, 25 parts of sugarcane powder, 6 parts of adhesive and 45 parts of water.
Kaolin is a non-metal mineral product, is clay and claystone which mainly comprises kaolinite clay minerals, is in a white, fine and soft clay shape, and has good physical and chemical properties such as plasticity, fire resistance and the like. The kaolin clay used as the flame retardant in the present invention can be obtained commercially, for example, commercially available kaolin clay includes but is not limited to those having a product number XY-15 (fineness 1250 mesh) which are obtained from mineral powder processing plants in the Piaoning county.
Sugarcane contains abundant sugar and water, and also contains substances such as vitamins, fat, protein, organic acid, calcium, iron and the like, the sugarcane powder is obtained by peeling stems of the sugarcane, crushing the stems by using a crusher, and sieving the stems, and can be obtained by commercial products, such as the commercially available sugarcane powder including but not limited to products purchased from Xian Qingzhi biotechnology limited.
Bagasse is a main byproduct in sugar industry, is a main part left after mechanical pressing of sugarcane, belongs to agricultural solid waste, mainly contains lignin, cellulose, hemicellulose, protein, coarse ash, pectin, fat and sugar, and has a spongy structure, a large water absorption capacity and a strong water retention capacity. The bagasse powder in the present invention is a powder having a particle size of less than 400 mesh obtained by pulverizing bagasse by a pulverizer and sieving, and the bagasse can be obtained commercially, for example, commercially available bagasse includes, but is not limited to, a product (water absorption of 60% and pH of 5) purchased from the ministry of agricultural and sideline products purchased from agriculture and love of nanning.
The pesticide smoke agent is easy to absorb moisture during storage and use, and further influences the ignition rate of the smoke agent. According to the invention, the bagasse powder is added into the ignition powder pipe as the fuel, so that on one hand, the bagasse powder has high carbon-hydrogen content and large negative oxygen balance, and can improve the smoke generation rate of the smoke agent, on the other hand, the bagasse powder has a sponge-shaped internal structure, can absorb and store moisture in air, and prevents the moisture in the air from entering the pull cannon to influence the ignition rate of the smoke agent, and the stored moisture is gasified into water mist after the smoke agent is ignited, so that the effect of extinguishing the fire is achieved, and the safety of the use of the smoke agent is ensured.
The preparation method of the first fuel, the second fuel, the third fuel and the fourth fuel adopts a method which is conventionally used by a person skilled in the art, and the preparation raw materials are put into a container according to the weight ratio and are mixed and stirred.
In another aspect of the invention, the method for using the chlorothalonil smoke agent comprises the following steps:
s1: uniformly placing at least one chlorothalonil smoke agent at a burning point in an application range, fixing the position, and removing paraffin at a stay wire end to expose the stay wire by 2-4 mm;
s2: the operator, after igniting the aerosol with the ignition tool, leaves the aerosol application zone.
In practical application, a proper amount of chlorothalonil smoke agent is determined according to the type, application range and application period of plants, when in use, a plurality of chlorothalonil smoke agents are uniformly placed at a burning point and fixed in position to ensure that the smoke agents cannot easily fall down obliquely, then an outer package moisture-proof device on the outer layer of the smoke agents is opened, paraffin at the end of a stay wire is removed to expose a small section of the stay wire, an operator ignites the stay wire part which is not wrapped by the paraffin by using an ignition tool such as a lighter or a cigarette and the like, the stay wire is ignited, the paraffin at the lower part is melted into paraffin oil, the paraffin oil runs upwards along the stay wire due to the capillary action of the stay wire, the paraffin oil is vaporized into paraffin steam at high temperature and then is combusted, after the stay wire is exposed outside a package layer and wrapped by the paraffin, a pulling gun is ignited, a raw medicine containing pipe in the ignition pipe is melted and decomposed by heat, wherein the chlorothalonil is gasified and diffused, then condensing into smoke particles, and acting on the surface of the plant through drift and sedimentation.
Examples
Example 1
Referring to the attached drawing 1, embodiment 1 provides a chlorothalonil smoke agent, which comprises an ignition powder tube 4, a pulling gun 6, a raw medicine containing tube 5, a box cover 3 and an outer package moisture-proof device 1; the box cover 3 and the ignition charge pipe 4 are connected in a joggle mode, and a cavity is formed between the box cover and the ignition charge pipe; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes 5 are arranged in the cavity and are uniformly distributed around the pulling cannon 6; as shown in fig. 2, the pulling gun 6 comprises a pulling wire 2, a first medicine layer 9, a second medicine layer 10 and a packaging layer 11; the diameter of the cross section of the stay wire 2 is 2.5mm, the outer layer of one end of the stay wire is coated with a first fuel which is used as a fuel twist 8, the length of the other end of the stay wire is 3cm, and the outer layer of the stay wire is coated with paraffin with the thickness of 1 mm; the first medicine layer 9 wraps the medicine twist 8, the second medicine layer 10 wraps the first medicine layer 9, the packaging layer 11 wraps the second medicine layer 10, and the other end of the stay wire 2 is exposed out of the packaging layer 11; the raw medicine containing pipe 5 is internally provided with a raw medicine material according to the weight ratio of 1: 0.4 of a chlorothalonil agent and modified magnesium hydroxide.
The ignition charge pipe 4 is also internally provided with a second fuel, and the preparation raw materials of the second fuel comprise 53 parts of potassium nitrate, 15 parts of sulfur, 23 parts of kaolin, 38 parts of ammonium chloride and 30 parts of bagasse powder according to parts by weight.
According to parts by weight, the preparation raw materials of the first fuel comprise 90 parts of potassium perchlorate, 45 parts of sugarcane powder and 15 parts of carbon powder.
The first chemical layer contains a third chemical, and the preparation raw materials of the third chemical comprise, by weight, 15 parts of red phosphorus, 52 parts of potassium perchlorate, 30 parts of sugarcane powder, 7.5 parts of an adhesive and 45 parts of water.
The second medicine layer contains a fourth medicine, and the preparation raw materials of the fourth medicine comprise, by weight, 60 parts of potassium nitrate, 15 parts of sulfur, 25 parts of sugarcane powder, 6 parts of an adhesive and 45 parts of water.
The chlorothalonil original drug is purchased from Zhengzhou Minghua chemical product sales Limited company, and the content of chlorothalonil in the prepared chlorothalonil oil agent is 10 wt%; the modified magnesium hydroxide is purchased from flame retardant materials, Inc. sourced from Dongguan city; the sugarcane powder is purchased from Xian Qingzhi biotechnology limited; the bagasse powder is powder with a particle size of less than 400 meshes, which is obtained by crushing bagasse purchased from the Ministry of agricultural and sideline products purchased from Nanning City with a crusher and sieving.
Example 2
Referring to the attached drawing 1, embodiment 2 provides a chlorothalonil smoke agent, which comprises an ignition powder tube 4, a pulling gun 6, a raw medicine containing tube 5, a box cover 3 and an outer package moisture-proof device 1; the box cover 3 and the ignition charge pipe 4 are connected in a joggle mode, and a cavity is formed between the box cover and the ignition charge pipe; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes 5 are arranged in the cavity and are uniformly distributed around the pulling cannon 6; as shown in fig. 2, the pulling gun 6 comprises a pulling wire 2, a first medicine layer 9, a second medicine layer 10 and a packaging layer 11; the diameter of the cross section of the stay wire 2 is 2.3mm, the outer layer of one end of the stay wire is coated with a first fuel which is used as a fuel twist 8, the length of the other end of the stay wire is 4cm, and the outer layer of the stay wire is coated with paraffin with the thickness of 1.2 mm; the first medicine layer 9 wraps the medicine twist 8, the second medicine layer 10 wraps the first medicine layer 9, the packaging layer 11 wraps the second medicine layer 10, and the other end of the stay wire 2 is exposed out of the packaging layer 11; the raw medicine containing pipe 5 is internally provided with a raw medicine material according to the weight ratio of 1: 0.3 of a chlorothalonil agent and modified magnesium hydroxide.
The ignition charge pipe 4 is also internally provided with a second fuel, and the preparation raw materials of the second fuel comprise, by weight, 45 parts of potassium nitrate, 12 parts of sulfur, 20 parts of kaolin, 23 parts of ammonium chloride and 24 parts of bagasse powder.
According to parts by weight, the preparation raw materials of the first fuel comprise 75 parts of potassium perchlorate, 37 parts of sugarcane powder and 12 parts of carbon powder.
The first chemical layer contains a third chemical, and the preparation raw materials of the third chemical comprise, by weight, 12 parts of red phosphorus, 45 parts of potassium perchlorate, 22 parts of sugarcane powder, 4.5 parts of an adhesive and 30 parts of water.
The second medicine layer contains a fourth medicine, and the preparation raw materials of the fourth medicine comprise, by weight, 45 parts of potassium nitrate, 12 parts of sulfur, 20 parts of sugarcane powder, 4 parts of an adhesive and 30 parts of water.
The chlorothalonil original drug is purchased from Zhengzhou Minghua chemical product sales Limited company, and the content of chlorothalonil in the prepared chlorothalonil oil agent is 10 wt%; the modified magnesium hydroxide is purchased from flame retardant materials, Inc. sourced from Dongguan city; the sugarcane powder is purchased from Xian Qingzhi biotechnology limited; the bagasse powder is powder with a particle size of less than 400 meshes, which is obtained by crushing bagasse purchased from the Ministry of agricultural and sideline products purchased from Nanning City with a crusher and sieving.
Examples3
Referring to the attached figure 1, embodiment 3 provides a chlorothalonil smoke agent, which comprises an ignition powder tube 4, a pulling gun 6, a raw medicine containing tube 5, a box cover 3 and an outer package moisture-proof device 1; the box cover 3 and the ignition charge pipe 4 are connected in a joggle mode, and a cavity is formed between the box cover and the ignition charge pipe; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes 5 are arranged in the cavity and are uniformly distributed around the pulling cannon 6; as shown in fig. 2, the pulling gun 6 comprises a pulling wire 2, a first medicine layer 9, a second medicine layer 10 and a packaging layer 11; the diameter of the cross section of the stay wire 2 is 2.8mm, the outer layer of one end of the stay wire is coated with a first fuel which is used as a fuel twist 8, the length of the other end of the stay wire is 4cm, and the outer layer of the stay wire is coated with paraffin with the thickness of 1 mm; the first medicine layer 9 wraps the medicine twist 8, the second medicine layer 10 wraps the first medicine layer 9, the packaging layer 11 wraps the second medicine layer 10, and the other end of the stay wire 2 is exposed out of the packaging layer 11; the raw medicine containing pipe 5 is internally provided with a raw medicine material according to the weight ratio of 1: 0.5 of a chlorothalonil agent and modified magnesium hydroxide.
The ignition charge pipe 4 is also internally provided with a second fuel, and the preparation raw materials of the second fuel comprise, by weight, 60 parts of potassium nitrate, 18 parts of sulfur, 26 parts of kaolin, 53 parts of ammonium chloride and 36 parts of bagasse powder.
The preparation raw materials of the first fuel comprise 105 parts of potassium perchlorate, 52 parts of sugarcane powder and 18 parts of carbon powder by weight.
The first chemical layer contains a third chemical, and the preparation raw materials of the third chemical comprise, by weight, 18 parts of red phosphorus, 60 parts of potassium perchlorate, 37 parts of sugarcane powder, 10.5 parts of an adhesive and 60 parts of water.
The second medicine layer contains a fourth medicine, and the preparation raw materials of the fourth medicine comprise, by weight, 75 parts of potassium nitrate, 18 parts of sulfur, 34 parts of sugarcane powder, 8 parts of an adhesive and 60 parts of water.
The chlorothalonil original drug is purchased from Zhengzhou Minghua chemical product sales Limited company, and the content of chlorothalonil in the prepared chlorothalonil oil agent is 10 wt%; the modified magnesium hydroxide is purchased from flame retardant materials, Inc. sourced from Dongguan city; the sugarcane powder is purchased from Xian Qingzhi biotechnology limited; the bagasse powder is powder with a particle size of less than 400 meshes, which is obtained by crushing bagasse purchased from the Ministry of agricultural and sideline products purchased from Nanning City with a crusher and sieving.
Example 4
Referring to the attached drawing 1, embodiment 4 provides a chlorothalonil smoke agent, which comprises an ignition powder tube 4, a pulling gun 6, a raw medicine containing tube 5, a box cover 3 and an outer package moisture-proof device 1; the box cover 3 and the ignition charge pipe 4 are connected in a joggle mode, and a cavity is formed between the box cover and the ignition charge pipe; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes 5 are arranged in the cavity and are uniformly distributed around the pulling cannon 6; as shown in fig. 2, the pulling gun 6 comprises a pulling wire 2, a first medicine layer 9, a second medicine layer 10 and a packaging layer 11; the diameter of the cross section of the stay wire 2 is 2.5mm, the outer layer of one end is coated with a first fuel, which is used as a fuel twist 8, and the length of the other end is 3 cm; the first medicine layer 9 wraps the medicine twist 8, the second medicine layer 10 wraps the first medicine layer 9, the packaging layer 11 wraps the second medicine layer 10, and the other end of the stay wire 2 is exposed out of the packaging layer 11; the raw medicine containing pipe 5 is internally provided with a raw medicine material according to the weight ratio of 1: 0.4 of a chlorothalonil agent and modified magnesium hydroxide.
The ignition charge pipe 4 is also internally provided with a second fuel, and the preparation raw materials of the second fuel comprise 53 parts of potassium nitrate, 15 parts of sulfur, 23 parts of kaolin, 38 parts of ammonium chloride and 30 parts of bagasse powder according to parts by weight.
According to parts by weight, the preparation raw materials of the first fuel comprise 90 parts of potassium perchlorate, 45 parts of sugarcane powder and 15 parts of carbon powder.
The first chemical layer contains a third chemical, and the preparation raw materials of the third chemical comprise, by weight, 15 parts of red phosphorus, 52 parts of potassium perchlorate, 30 parts of sugarcane powder, 7.5 parts of an adhesive and 45 parts of water.
The second medicine layer contains a fourth medicine, and the preparation raw materials of the fourth medicine comprise, by weight, 60 parts of potassium nitrate, 15 parts of sulfur, 25 parts of sugarcane powder, 6 parts of an adhesive and 45 parts of water.
The chlorothalonil original drug is purchased from Zhengzhou Minghua chemical product sales Limited company, and the content of chlorothalonil in the prepared chlorothalonil oil agent is 10 wt%; the modified magnesium hydroxide is purchased from flame retardant materials, Inc. sourced from Dongguan city; the sugarcane powder is purchased from Xian Qingzhi biotechnology limited; the bagasse powder is powder with a particle size of less than 400 meshes, which is obtained by crushing bagasse purchased from the Ministry of agricultural and sideline products purchased from Nanning City with a crusher and sieving.
Example 5
Referring to the attached drawing 1, embodiment 5 provides a chlorothalonil smoke agent, which comprises an ignition powder tube 4, a pulling gun 6, a raw medicine containing tube 5, a box cover 3 and an outer package moisture-proof device 1; the box cover 3 and the ignition charge pipe 4 are connected in a joggle mode, and a cavity is formed between the box cover and the ignition charge pipe; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes 5 are arranged in the cavity and are uniformly distributed around the pulling cannon 6; as shown in fig. 2, the pulling gun 6 comprises a pulling wire 2, a first medicine layer 9, a second medicine layer 10 and a packaging layer 11; the diameter of the cross section of the stay wire 2 is 2.5mm, the outer layer of one end of the stay wire is coated with a first fuel which is used as a fuel twist 8, the length of the other end of the stay wire is 3cm, and the outer layer of the stay wire is coated with paraffin with the thickness of 3 mm; the first medicine layer 9 wraps the medicine twist 8, the second medicine layer 10 wraps the first medicine layer 9, the packaging layer 11 wraps the second medicine layer 10, and the other end of the stay wire 2 is exposed out of the packaging layer 11; the raw medicine containing pipe 5 is internally provided with a raw medicine material according to the weight ratio of 1: 0.4 of a chlorothalonil agent and modified magnesium hydroxide.
The ignition charge pipe 4 is also internally provided with a second fuel, and the preparation raw materials of the second fuel comprise 53 parts of potassium nitrate, 15 parts of sulfur, 23 parts of kaolin, 38 parts of ammonium chloride and 30 parts of bagasse powder according to parts by weight.
According to parts by weight, the preparation raw materials of the first fuel comprise 90 parts of potassium perchlorate, 45 parts of sugarcane powder and 15 parts of carbon powder.
The first chemical layer contains a third chemical, and the preparation raw materials of the third chemical comprise, by weight, 15 parts of red phosphorus, 52 parts of potassium perchlorate, 30 parts of sugarcane powder, 7.5 parts of an adhesive and 45 parts of water.
The second medicine layer contains a fourth medicine, and the preparation raw materials of the fourth medicine comprise, by weight, 60 parts of potassium nitrate, 15 parts of sulfur, 25 parts of sugarcane powder, 6 parts of an adhesive and 45 parts of water.
The chlorothalonil original drug is purchased from Zhengzhou Minghua chemical product sales Limited company, and the content of chlorothalonil in the prepared chlorothalonil oil agent is 10 wt%; the modified magnesium hydroxide is purchased from flame retardant materials, Inc. sourced from Dongguan city; the sugarcane powder is purchased from Xian Qingzhi biotechnology limited; the bagasse powder is powder with a particle size of less than 400 meshes, which is obtained by crushing bagasse purchased from the Ministry of agricultural and sideline products purchased from Nanning City with a crusher and sieving.
Example 6
Referring to the attached drawing 1, embodiment 6 provides a chlorothalonil smoke agent, which comprises an ignition powder tube 4, a pulling gun 6, a raw medicine containing tube 5, a box cover 3 and an outer package moisture-proof device 1; the box cover 3 and the ignition charge pipe 4 are connected in a joggle mode, and a cavity is formed between the box cover and the ignition charge pipe; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes 5 are arranged in the cavity and are uniformly distributed around the pulling cannon 6; as shown in fig. 2, the pulling gun 6 comprises a pulling wire 2, a first medicine layer 9, a second medicine layer 10 and a packaging layer 11; the diameter of the cross section of the stay wire 2 is 2.5mm, the outer layer of one end of the stay wire is coated with a first fuel which is used as a fuel twist 8, the length of the other end of the stay wire is 3cm, and the outer layer of the stay wire is coated with paraffin with the thickness of 1 mm; the first medicine layer 9 wraps the medicine twist 8, the second medicine layer 10 wraps the first medicine layer 9, the packaging layer 11 wraps the second medicine layer 10, and the other end of the stay wire 2 is exposed out of the packaging layer 11; the technical product containing tube 5 is filled with a chlorothalonil oil agent.
The ignition charge pipe 4 is also internally provided with a second fuel, and the preparation raw materials of the second fuel comprise 53 parts of potassium nitrate, 15 parts of sulfur, 23 parts of kaolin, 38 parts of ammonium chloride and 30 parts of bagasse powder according to parts by weight.
According to parts by weight, the preparation raw materials of the first fuel comprise 90 parts of potassium perchlorate, 45 parts of sugarcane powder and 15 parts of carbon powder.
The first chemical layer contains a third chemical, and the preparation raw materials of the third chemical comprise, by weight, 15 parts of red phosphorus, 52 parts of potassium perchlorate, 30 parts of sugarcane powder, 7.5 parts of an adhesive and 45 parts of water.
The second medicine layer contains a fourth medicine, and the preparation raw materials of the fourth medicine comprise, by weight, 60 parts of potassium nitrate, 15 parts of sulfur, 25 parts of sugarcane powder, 6 parts of an adhesive and 45 parts of water.
The chlorothalonil original drug is purchased from Zhengzhou Minghua chemical product sales Limited company, and the content of chlorothalonil in the prepared chlorothalonil oil agent is 10 wt%; the bagasse powder is powder with a particle size of less than 400 meshes, which is obtained by crushing bagasse purchased from the Ministry of agricultural and sideline products purchased from Nanning City with a crusher and sieving.
Example 7
Referring to the attached drawing 1, embodiment 7 provides a chlorothalonil smoke agent, which comprises an ignition powder tube 4, a pulling gun 6, a raw medicine containing tube 5, a box cover 3 and an outer package moisture-proof device 1; the box cover 3 and the ignition charge pipe 4 are connected in a joggle mode, and a cavity is formed between the box cover and the ignition charge pipe; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes 5 are arranged in the cavity and are uniformly distributed around the pulling cannon 6; as shown in fig. 2, the pulling gun 6 comprises a pulling wire 2, a first medicine layer 9, a second medicine layer 10 and a packaging layer 11; the diameter of the cross section of the stay wire 2 is 2.5mm, the outer layer of one end of the stay wire is coated with a first fuel which is used as a fuel twist 8, the length of the other end of the stay wire is 3cm, and the outer layer of the stay wire is coated with paraffin with the thickness of 1 mm; the first medicine layer 9 wraps the medicine twist 8, the second medicine layer 10 wraps the first medicine layer 9, the packaging layer 11 wraps the second medicine layer 10, and the other end of the stay wire 2 is exposed out of the packaging layer 11; the raw medicine containing pipe 5 is internally provided with a raw medicine material according to the weight ratio of 1: 1 and modified magnesium hydroxide.
The ignition charge pipe 4 is also internally provided with a second fuel, and the preparation raw materials of the second fuel comprise 53 parts of potassium nitrate, 15 parts of sulfur, 23 parts of kaolin, 38 parts of ammonium chloride and 30 parts of bagasse powder according to parts by weight.
According to parts by weight, the preparation raw materials of the first fuel comprise 90 parts of potassium perchlorate, 45 parts of sugarcane powder and 15 parts of carbon powder.
The first chemical layer contains a third chemical, and the preparation raw materials of the third chemical comprise, by weight, 15 parts of red phosphorus, 52 parts of potassium perchlorate, 30 parts of sugarcane powder, 7.5 parts of an adhesive and 45 parts of water.
The second medicine layer contains a fourth medicine, and the preparation raw materials of the fourth medicine comprise, by weight, 60 parts of potassium nitrate, 15 parts of sulfur, 25 parts of sugarcane powder, 6 parts of an adhesive and 45 parts of water.
The chlorothalonil original drug is purchased from Zhengzhou Minghua chemical product sales Limited company, and the content of chlorothalonil in the prepared chlorothalonil oil agent is 10 wt%; the modified magnesium hydroxide is purchased from flame retardant materials, Inc. sourced from Dongguan city; the sugarcane powder is purchased from Xian Qingzhi biotechnology limited; the bagasse powder is powder with a particle size of less than 400 meshes, which is obtained by crushing bagasse purchased from the Ministry of agricultural and sideline products purchased from Nanning City with a crusher and sieving.
Example 8
Referring to the attached drawing 1, embodiment 8 provides a chlorothalonil smoke agent, which comprises an ignition powder tube 4, a pulling gun 6, a raw medicine containing tube 5, a box cover 3 and an outer package moisture-proof device 1; the box cover 3 and the ignition charge pipe 4 are connected in a joggle mode, and a cavity is formed between the box cover and the ignition charge pipe; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes 5 are arranged in the cavity and are uniformly distributed around the pulling cannon 6; as shown in fig. 2, the pulling gun 6 comprises a pulling wire 2, a first medicine layer 9, a second medicine layer 10 and a packaging layer 11; the diameter of the cross section of the stay wire 2 is 2.5mm, the outer layer of one end of the stay wire is coated with a first fuel which is used as a fuel twist 8, the length of the other end of the stay wire is 3cm, and the outer layer of the stay wire is coated with paraffin with the thickness of 1 mm; the first medicine layer 9 wraps the medicine twist 8, the second medicine layer 10 wraps the first medicine layer 9, the packaging layer 11 wraps the second medicine layer 10, and the other end of the stay wire 2 is exposed out of the packaging layer 11; the raw medicine containing pipe 5 is internally provided with a raw medicine material according to the weight ratio of 1: 0.4 of a chlorothalonil agent and modified magnesium hydroxide.
The ignition powder tube 4 is also internally provided with a second fuel, and the preparation raw materials of the second fuel comprise 53 parts of potassium nitrate, 15 parts of sulfur, 23 parts of kaolin, 38 parts of ammonium chloride and 30 parts of rice husk powder according to parts by weight.
According to parts by weight, the preparation raw materials of the first fuel comprise 90 parts of potassium perchlorate, 45 parts of sugarcane powder and 15 parts of carbon powder.
The first chemical layer contains a third chemical, and the preparation raw materials of the third chemical comprise, by weight, 15 parts of red phosphorus, 52 parts of potassium perchlorate, 30 parts of sugarcane powder, 7.5 parts of an adhesive and 45 parts of water.
The second medicine layer contains a fourth medicine, and the preparation raw materials of the fourth medicine comprise, by weight, 60 parts of potassium nitrate, 15 parts of sulfur, 25 parts of sugarcane powder, 6 parts of an adhesive and 45 parts of water.
The chlorothalonil original drug is purchased from Zhengzhou Minghua chemical product sales Limited company, and the content of chlorothalonil in the prepared chlorothalonil oil agent is 10 wt%; the modified magnesium hydroxide is purchased from flame retardant materials, Inc. sourced from Dongguan city; the sugarcane powder is purchased from Xian Qingzhi biotechnology limited; the rice hull powder is purchased from Ming's department of agriculture and sideline products.
In the above embodiment, the content of chlorothalonil in the raw medicament containing tube and the number of the raw medicament containing tubes in the smoking agent are kept consistent.
Performance evaluation:
1. quality evaluation of smoking agent
The smoke agent prepared in the embodiment 1-8 is put into a constant temperature oven (80 +/-2) DEG C, and observed for 1 time every 2 hours within 72 hours, if the smoke agent is found to be self-ignited, the quality is unqualified, and if the smoke agent is not self-ignited, the smoke agent is qualified.
2. Safety testing of smoke agents
The smoke agents prepared in examples 1-8 were simultaneously ignited by 8 persons wearing protective equipment in the same manner, the time for starting smoking the smoke agent and the time for extinguishing the flame were observed, and the safety of the smoke agent was classified into three grades, i.e., high, medium and low, according to whether sufficient time was left before smoking and whether the flame could be extinguished in time.
3. Moisture resistance and ignition Rate testing of the smoking agent
50 chlorothalonil smoke agents were prepared according to each of examples 1-8, and divided into A, B groups of 25, wherein group A was subjected to an ignition test on the day of preparation and recorded as w1, and group B was placed in the same temperature and humidity environment and subjected to an ignition test 30 days later and recorded as w 2.
4. Test of field drug effect
The test is carried out in a greenhouse, six rows of greenhouses are used for the test, each row of greenhouses is treated for three times, the growth of the cucumbers is basically consistent, and the field management is carried out according to a conventional management method.
The test survey of each greenhouse adopts a five-point sampling method, 10 plants are planted at each point, about 50 leaves are surveyed at each point, the leaves are arranged above, in the middle and below each plant, the grade of the diseased leaves is recorded according to downy mildew grading treatment, the first pesticide application is started at the initial stage of disease attack, the disease condition is surveyed at intervals of 10 days and three times in total at the later stage, and the disease prevention effect is calculated on the fourth day after the third pesticide application.
Prevention and treatment effect calculation mode: relative control effect (%) (control disease means increment-prevention disease means increment)/X100% disease means increment-prevention after disease means prevention before disease means increment
Grading standard of cucumber downy mildew conditions:
grade Disease condition
Level 0 No scab
Level 1 1/10 with sporadic incidence and disease spots with area not exceeding leaf area
Stage
2 The area of the lesion is 1/10-1/5
Grade 3 The area of the lesion spots is 1/5-1/3
4 stage The area of the lesion spots is 1/3-2/3
Grade 5 The area of the lesion spots is more than 2/3
Table 1 results of performance testing
Figure BDA0002238568260000151
As can be seen from the table 1, the chlorothalonil smoke agent provided by the invention has the advantages that the smoking time is delayed, the operator has enough time to leave after igniting the smoke agent pull wire, and the flame can be extinguished in time, so the safety in the use process is higher; in addition, the sugarcane residue powder is added into the ignition powder tube, so that the moisture resistance of the smoke agent is effectively improved, and the ignition rate of the smoke agent is still 100% after the smoke agent is stored for a long time; in addition, the modified magnesium hydroxide is added into the chlorothalonil, so that the diffusion and sedimentation speed of the gasified chlorothalonil are increased, and the pesticide effect of the gasified chlorothalonil on plant disease control is enhanced.
The foregoing examples are merely illustrative and serve to explain some of the features of the method of the present invention. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. Also, where numerical ranges are used in the claims, subranges therein are included, and variations in these ranges are also to be construed as possible being covered by the appended claims.

Claims (10)

1. A chlorothalonil smoke agent is characterized in that the smoke agent comprises an ignition powder tube, a pulling gun, a raw medicine containing tube and a box cover; the box cover and the ignition powder tube are connected in a tenon joint mode, and a cavity is formed between the box cover and the ignition powder tube; the pulling cannon is arranged at the center of the cavity, and the raw medicine containing pipes are arranged in the cavity and are uniformly distributed around the pulling cannon;
the pulling gun comprises a pulling wire, a first medicine layer, a second medicine layer and a packaging layer; the outer layer of one end of the stay wire is coated with a first fuel which is used as a fuel twist, and the outer layer of the other end of the stay wire is coated with paraffin; the first medicine layer wraps the medicine twist, the second medicine layer wraps the first medicine layer, the packaging layer wraps the second medicine layer, and the other end of the stay wire is exposed out of the packaging layer;
the raw pesticide containing tube is filled with a chlorothalonil agent and an aerosol regulator.
2. The chlorothalonil smoke agent of claim 1, wherein a diameter of a cross section of said pull wire is between 2.3mm and 2.8 mm.
3. The chlorothalonil smoke agent according to claim 1, wherein the length of the end of the pulling wire exposed out of the packaging layer is 2-4 cm, and the thickness of the outer layer paraffin is 1-1.2 mm.
4. The chlorothalonil smoke agent of claim 1, wherein the weight ratio of the chlorothalonil oil agent to the aerosol regulator is 1: (0.3-0.5).
5. A chlorothalonil smoke agent according to claim 1, wherein said aerosol regulator is a modified magnesium hydroxide.
6. The chlorothalonil smoke agent as defined in claim 1, wherein a second fuel is further filled in the priming powder tube, and the preparation raw materials of the second fuel comprise, by weight, 45-60 parts of potassium nitrate, 12-18 parts of sulfur, 20-26 parts of kaolin, 23-53 parts of ammonium chloride and 24-36 parts of bagasse powder.
7. The chlorothalonil smoke agent according to claim 1, wherein the preparation raw materials of the first fuel comprise, by weight, 75-105 parts of potassium perchlorate, 37-52 parts of sugarcane powder and 12-18 parts of carbon powder.
8. The chlorothalonil smoke agent according to claim 1, wherein the first medicine layer contains a third fuel, and the third fuel is prepared from 12-18 parts by weight of red phosphorus, 45-60 parts by weight of potassium perchlorate, 22-37 parts by weight of sugarcane flour, 4.5-10.5 parts by weight of adhesive and 30-60 parts by weight of water.
9. The chlorothalonil smoke agent according to claim 1, wherein the second drug layer contains a fourth fuel, and the fourth fuel is prepared from 45-75 parts by weight of potassium nitrate, 12-18 parts by weight of sulfur, 20-34 parts by weight of sugarcane powder, 4-8 parts by weight of a binder and 30-60 parts by weight of water.
10. A chlorothalonil smoke agent according to any one of claims 1 to 9, wherein the method of use of the chlorothalonil smoke agent comprises the steps of:
s1: uniformly placing at least one chlorothalonil smoke agent at a burning point in an application range, fixing the position, and removing paraffin at a stay wire end to expose the stay wire by 2-4 mm;
s2: the operator, after igniting the aerosol with the ignition tool, leaves the aerosol application zone.
CN201910991936.8A 2019-10-18 2019-10-18 Chlorothalonil smoke agent and using method thereof Withdrawn CN110771608A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114711236A (en) * 2021-07-30 2022-07-08 黑龙江森工农化有限公司 Persistent and safe chlorothalonil smoke agent and application thereof
CN114711246A (en) * 2021-07-30 2022-07-08 黑龙江森工农化有限公司 Efficient and stable dichlorvos smoke agent and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114711236A (en) * 2021-07-30 2022-07-08 黑龙江森工农化有限公司 Persistent and safe chlorothalonil smoke agent and application thereof
CN114711246A (en) * 2021-07-30 2022-07-08 黑龙江森工农化有限公司 Efficient and stable dichlorvos smoke agent and application thereof

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Application publication date: 20200211