CN110759435A - Pollution treatment system and method based on star-structure friction nano generator - Google Patents

Pollution treatment system and method based on star-structure friction nano generator Download PDF

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Publication number
CN110759435A
CN110759435A CN201911167430.1A CN201911167430A CN110759435A CN 110759435 A CN110759435 A CN 110759435A CN 201911167430 A CN201911167430 A CN 201911167430A CN 110759435 A CN110759435 A CN 110759435A
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China
Prior art keywords
star
generator
module
degradation
gas
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CN201911167430.1A
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Chinese (zh)
Inventor
唐伟
王中林
韩凯
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Beijing Zhongke Qilin Technology Co Ltd
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Beijing Zhongke Qilin Technology Co Ltd
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Priority to CN201911167430.1A priority Critical patent/CN110759435A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • C02F2101/163Nitrates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • C02F2101/166Nitrites
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/009Apparatus with independent power supply, e.g. solar cells, windpower, fuel cells

Abstract

The embodiment of the invention provides a pollution treatment system and method based on a star-structure friction nano generator, wherein the system comprises the following components: the system comprises a star-shaped engine, and a contact separation type nano generator, a one-way gas circuit control module, a circuit management module and an electrochemical degradation module which are arranged in each cavity of the star-shaped engine; the star-shaped engine rotates along with the pushing of external mechanical energy to drive the piston of each chamber to move; the one-way gas circuit control module is used for driving gas in an open environment to be introduced into the electrochemical degradation module by utilizing the movement of the piston so as to dissolve water-soluble pollutants in the gas into a degradation pool of the electrochemical degradation module; the circuit management module is used for managing the electric energy generated by the contact separation type nanometer generator and providing the electric energy for the electrochemical degradation module so as to degrade the water-soluble pollutants in the degradation pool.

Description

Pollution treatment system and method based on star-structure friction nano generator
Technical Field
The embodiment of the invention relates to the technical field of environmental protection, in particular to a pollution treatment system and method based on a star-structure friction nano generator.
Background
With the increasing worldwide demand for energy, fossil fuels have been at a significant position. However, various toxic and harmful gases generated along with the combustion of the fuel are also discharged into the atmosphere along with the exhaust gas. These harmful gases have various harmful effects on human beings and the environment, such as severe damage to crops and plant growth caused by acid rain, and harm to human beings caused by heavy metals and the like accumulated along with a biological chain.
At present, the main treatment modes of the harmful gases are filtration, electrostatic adsorption, chemical reduction, catalytic degradation and the like from a source. These are very powerful treatments, but lack effective control of gaseous pollutants entering the open environment. Particularly, the number of urban fuel automobiles is increased year by year, so that the problem is further exacerbated.
Therefore, how to provide a pollution treatment scheme capable of effectively controlling and degrading the gas pollutants in the open environment is a technical problem to be solved by those skilled in the art.
Disclosure of Invention
Therefore, the embodiment of the invention provides a pollution treatment system and method based on a star-structure friction nano generator, which can effectively control and degrade gas pollutants in an open environment.
In order to achieve the above object, the embodiments of the present invention provide the following technical solutions:
in a first aspect, an embodiment of the present invention provides a pollution treatment system based on a star-structured friction nanogenerator, including: the system comprises a star-shaped engine, and a contact separation type nano generator, a one-way gas circuit control module, a circuit management module and an electrochemical degradation module which are arranged in each cavity of the star-shaped engine;
the star-shaped engine rotates along with the pushing of external mechanical energy to drive the piston of each chamber to move;
the contact separation type nano generator generates electricity along with the movement of the piston;
the unidirectional gas circuit control module is used for driving gas in an open environment to be introduced into the electrochemical degradation module by utilizing the movement of the piston so as to dissolve water-soluble pollutants in the gas into a degradation pool of the electrochemical degradation module;
the circuit management module is used for managing the electric energy generated by the contact separation type nanometer generator and providing the electric energy for the electrochemical degradation module so as to degrade the water-soluble pollutants in the degradation pool.
Preferably, the water-soluble contaminants include, but are not limited to: sulfur oxides, nitrogen oxides.
Preferably, the star engine is connected with a power driving device, including but not limited to: wind power and water flow;
when wind blows or water flow drives the power driving device, the star-shaped engine is driven to rotate.
Preferably, the contact separation type nano-generator includes: the stacked friction nano-generator is formed by connecting more than one contact separation type nano-generator in series;
the stacked friction nano-generator is connected end to end and is folded and placed in the cavity;
when the piston in the chamber moves, the stacked friction nano-generator is in contact separation to generate a potential difference.
Preferably, the circuit management module includes: and the rectification modules correspond to the chambers one by one and are used for converting electric energy generated by the contact separation type nano generator into direct current and connecting the direct current to the electrochemical degradation module.
Preferably, the electrochemical degradation module comprises: the electrolytic cell is provided with a working electrode and a counter electrode in the electrolytic cell;
when the circuit management module accesses direct current to the working electrode and the counter electrode, water-soluble pollutants in the electrolytic cell are degraded.
Preferably, the method further comprises the following steps: and the rainwater collector is used for collecting rainwater into the degradation tank so as to realize the enrichment of water-soluble pollutants.
Preferably, the rain water collector is a rain cover;
the rain cover includes: a rain collecting surface and a water outlet; the peripheral part of the rain collecting surface is higher than the middle part of the rain collecting surface; the water outlet is communicated with the middle part of the rain collecting surface and leads rainwater to the degradation pool.
Preferably, the one-way air channel control module includes: the first air inlet pipeline is communicated with the cavity, and the second air outlet pipeline is communicated with the cavity;
the first air inlet pipeline is provided with an air inlet one-way valve, and the other end of the first air inlet pipeline is communicated with an open atmosphere environment;
the second gas outlet pipeline is provided with a gas outlet one-way valve, and the other end of the second gas outlet pipeline is communicated with the degradation tank;
when the piston in the cavity moves, the gas in the open atmosphere is led to the degradation pool through the first gas inlet pipeline and the second gas outlet pipeline.
In a second aspect, an embodiment of the present invention provides a pollution treatment method based on a star-structured friction nano-generator, which is applied to a pollution treatment system based on a star-structured friction nano-generator as described in any one of the above first aspects, and includes:
when the star-shaped engine rotates along with the pushing of external mechanical energy, the pistons of all the chambers are driven to move;
the contact separation type nano generator generates electricity along with the movement of the piston;
the unidirectional gas circuit control module drives gas in an open environment to be introduced into the electrochemical degradation module by utilizing the movement of the piston so that water-soluble pollutants in the gas are dissolved into a degradation pool of the electrochemical degradation module;
the circuit management module manages the electric energy generated by the contact separation type nanometer generator and provides electric energy for the electrochemical degradation module so as to degrade water-soluble pollutants in the degradation pool.
The embodiment of the invention provides a pollution treatment system based on a star-structure friction nano generator, which comprises: the system comprises a star-shaped engine, and a contact separation type nano generator, a one-way gas circuit control module, a circuit management module and an electrochemical degradation module which are arranged in each cavity of the star-shaped engine; the star-shaped engine rotates along with the pushing of external mechanical energy to drive the piston of each chamber to move; the one-way gas circuit control module is used for driving gas in an open environment to be introduced into the electrochemical degradation module by utilizing the movement of the piston so as to dissolve water-soluble pollutants in the gas into a degradation pool of the electrochemical degradation module; the circuit management module is used for managing the electric energy generated by the contact separation type nanometer generator and providing the electric energy for the electrochemical degradation module so as to degrade the water-soluble pollutants in the degradation tank and effectively control and degrade the gas pollutants in the open environment.
The pollution treatment method based on the friction nano-generator with the star-shaped structure provided by the embodiment of the invention is applied to the pollution treatment system based on the friction nano-generator with the star-shaped structure in any one of the first aspect, and has the beneficial effects, and details are not repeated herein.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below. It should be apparent that the drawings in the following description are merely exemplary, and that other embodiments can be derived from the drawings provided by those of ordinary skill in the art without inventive effort.
The structures, ratios, sizes, and the like shown in the present specification are only used for matching with the contents disclosed in the specification, so as to be understood and read by those skilled in the art, and are not used to limit the conditions that the present invention can be implemented, so that the present invention has no technical significance, and any structural modifications, changes in the ratio relationship, or adjustments of the sizes, without affecting the effects and the achievable by the present invention, should still fall within the range that the technical contents disclosed in the present invention can cover.
FIG. 1 is a block diagram of a pollution treatment system based on a star-structured friction nanogenerator according to an embodiment of the invention;
FIG. 2 is a schematic structural diagram of a friction nanogenerator of a pollution treatment system based on a star-structured friction nanogenerator according to an embodiment of the invention;
FIG. 3 is a schematic plan view of a star-type engine structure friction nano-generator and a one-way gas circuit module of a pollution treatment system based on a star-type structure friction nano-generator according to an embodiment of the present invention;
FIG. 4 is a schematic structural diagram of a pollution treatment system based on a star-structured friction nanogenerator according to an embodiment of the invention;
FIG. 5 is a schematic view of the water solution absorption in the environment with simulated NOx contamination of the contamination treatment system based on the star-structured friction nanogenerator according to the embodiment of the invention;
FIG. 6 is a schematic diagram of the detection of the degradation simulation absorption solution product of the pollution treatment system based on the star-structured friction nano-generator according to the embodiment of the present invention;
fig. 7 is a flowchart of a pollution treatment method based on a star-structured friction nanogenerator according to an embodiment of the invention.
Detailed Description
The present invention is described in terms of particular embodiments, other advantages and features of the invention will become apparent to those skilled in the art from the following disclosure, and it is to be understood that the described embodiments are merely exemplary of the invention and that it is not intended to limit the invention to the particular embodiments disclosed. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1, fig. 2, fig. 3 and fig. 4, fig. 1 is a block diagram of a pollution treatment system based on a star-structured friction nano-generator according to an embodiment of the present invention; FIG. 2 is a schematic structural diagram of a friction nanogenerator of a pollution treatment system based on a star-structured friction nanogenerator according to an embodiment of the invention; FIG. 3 is a schematic plan view of a star-type engine structure friction nano-generator and a one-way gas circuit module of a pollution treatment system based on a star-type structure friction nano-generator according to an embodiment of the present invention; fig. 4 is a schematic structural diagram of a pollution treatment system based on a star-structured friction nano-generator according to an embodiment of the present invention.
The embodiment of the invention provides a pollution treatment system based on a star-structure friction nano generator, which comprises: the system comprises a star-shaped engine 110, a contact separation type nano generator 120 arranged in each cavity of the star-shaped engine, a one-way gas circuit control module 130, a circuit management module 140 and an electrochemical degradation module 150; the star-shaped engine rotates along with the pushing of external mechanical energy to drive the piston of each chamber to move; the contact separation type nano generator generates electricity along with the movement of the piston; the unidirectional gas circuit control module is used for driving gas in an open environment to be introduced into the electrochemical degradation module by utilizing the movement of the piston so as to dissolve water-soluble pollutants in the gas into a degradation pool of the electrochemical degradation module; the circuit management module is used for managing the electric energy generated by the contact separation type nanometer generator and providing the electric energy for the electrochemical degradation module so as to degrade the water-soluble pollutants in the degradation pool.
Among the common gaseous pollutants, there is a class of polluting gases that are water soluble, such as sulfur oxides, nitrogen oxides, and the like. Compared with direct treatment, the pollutants are absorbed and enriched by the aqueous solution, and better degradation and treatment are facilitated.
Therefore, the embodiment of the invention utilizes the star-structure friction nano generator to introduce the gas in the open atmospheric environment into the aqueous solution by utilizing the control of the one-way gas path under the driving of the external mechanical energy (such as wind energy) so as to absorb the soluble pollutants in the aqueous solution. Meanwhile, along with driving, the friction nano generator generates electric energy based on the Maxwell displacement current principle, and pollutants in the water solution are degraded by combining an electrochemical system through circuit management and rectification. Based on the drive of natural energy such as wind, water flow and the like, the invention solves the problems of synchronous aqueous solution absorption and electrochemical degradation of soluble gas pollutants in open atmospheric environment by utilizing a friction nano generator with a star-shaped engine structure and one-way gas circuit control and matching with an electrochemical degradation system.
In one embodiment, the radial engine may be used in conjunction with a power drive, including but not limited to: wind power and water flow; when wind blows or water flow drives the power driving device, the star-shaped engine is driven to rotate. Of course, other mechanical energy may be used to drive the radial engine, for example, other new energy such as water flow may be used to drive the radial engine to rotate.
Further, the contact separation type nano-generator includes: the stacked friction nano-generator is formed by connecting more than one contact separation type nano-generator in series; the stacked friction nano-generator is connected end to end and is folded and placed in the cavity; when the piston in the chamber moves, the stacked friction nano-generator is in contact separation to generate a potential difference.
Specifically, in order to generate as much electric energy as possible with better utilization of space, 1 is a stacked triboelectric nanogenerator used in the present embodiment, which is composed of a contact separation type triboelectric nanogenerator of a plurality of cells. The base material polyester 1 was first cut into a plurality of circular shapes connected in series. On one hand, the substrate can provide support for other materials, and on the other hand, the bending can be guaranteed, so that the contact separation can be conveniently completed along with the movement of the piston to generate electric energy. Thereafter, 0.5mm thick foam 3 was attached to each round polyester unit as a buffer layer for the tribo nanogenerator. The electrode material was copper foil 4(30 μm), and the dielectric material was polytetrafluoroethylene film 5(80 μm). When the polytetrafluoroethylene 5 and the copper 4 are contacted with each other, the polytetrafluoroethylene 5 and the copper 4 are electrified in a friction mode, wherein the polytetrafluoroethylene 5 is negatively electrified, and the copper 4 is positively electrified. The generator units are connected in parallel. The above materials are used only in the present embodiment, and contact separation type friction nano-generator made of other materials can also be used in the present system.
Further, to that end, the circuit management module includes: and the rectification modules correspond to the chambers one by one and are used for converting electric energy generated by the contact separation type nano generator into direct current and connecting the direct current to the electrochemical degradation module.
Still further, the electrochemical degradation module comprises: the electrolytic cell is provided with a working electrode and a counter electrode in the electrolytic cell; when the circuit management module accesses direct current to the working electrode, including but not limited to a nickel electrode, and the counter electrode, including but not limited to a platinum electrode, the water soluble contaminants in the electrolytic cell degrade.
Specifically, referring to fig. 4, inside the dotted line frame 11 is a star-type engine structure friction nano-generator and a one-way air path control module. The main components of the current management module 12 are rectifier bridges, the number of which is the same as the number of chambers. After rectification, an electrocatalysis system is connected. In this embodiment, a mature electrocatalytic system is selected, in which the nickel foam electrode 13 serves as the working electrode and the platinum electrode 14 serves as the counter electrode. With the help of the wind cup 15, the wind energy can be converted into mechanical energy, and then the whole system is driven to work.
Please refer to the schematic plan view of the friction nano-generator and the one-way air path module of the radial engine structure. The piston motion can be completed by external mechanical force by using the core driving structure 6 of the radial engine. The figure shows an example of a friction nano-generator with a star-shaped engine structure consisting of five chambers 7. Along with external driving, the piston 8 can perform linear reciprocating motion, and further drives the friction nano generator 9 connected with the piston to continuously contact and separate to generate electric energy. In addition, due to the planar structure of the radial engine, a phase difference can be generated in the electric signals of the friction generator in the cavity. After rectification, different resistances are connected into an external circuit for testing, and the result shows that the average power of the combined action of the five chambers is larger than the sum of the independent actions of the five chambers within a certain external resistance range. In this embodiment, the external resistance ranges from 0 to 300 M.OMEGA..
In addition, on the basis of the above embodiment, in this embodiment, a rainwater collector may be further disposed in the degradation tank, and is used for collecting rainwater into the degradation tank, so as to realize the enrichment of water-soluble pollutants. Specifically, the rain water collector may be provided as a rain cover; the rain cover includes: a rain collecting surface and a water outlet; the peripheral part of the rain collecting surface is higher than the middle part of the rain collecting surface; the water outlet is communicated with the middle part of the rain collecting surface and leads rainwater to the degradation pool.
It should be noted that, in an embodiment, the unidirectional air path control module may include: the first air inlet pipeline is communicated with the cavity, and the second air outlet pipeline is communicated with the cavity; the first air inlet pipeline is provided with an air inlet one-way valve, and the other end of the first air inlet pipeline is communicated with an open atmosphere environment; the second gas outlet pipeline is provided with a gas outlet one-way valve, and the other end of the second gas outlet pipeline is communicated with the degradation tank; when the piston in the cavity moves, the gas in the open atmosphere is led to the degradation pool through the first gas inlet pipeline and the second gas outlet pipeline. That is to say simultaneously during the movement of the piston 8, the gas will be guided in its movement. By using the two check valves 10, the air flow can be controlled to flow in a single direction, and finally, the water is introduced to absorb soluble pollutants.
The embodiment of the invention provides a pollution treatment system based on a star-structure friction nano generator, which comprises: the system comprises a star-shaped engine, and a contact separation type nano generator, a one-way gas circuit control module, a circuit management module and an electrochemical degradation module which are arranged in each cavity of the star-shaped engine; the star-shaped engine rotates along with the pushing of external mechanical energy to drive the piston of each chamber to move; the one-way gas circuit control module is used for driving gas in an open environment to be introduced into the electrochemical degradation module by utilizing the movement of the piston so as to dissolve water-soluble pollutants in the gas into a degradation pool of the electrochemical degradation module; the circuit management module is used for managing the electric energy generated by the contact separation type nanometer generator and providing the electric energy for the electrochemical degradation module so as to degrade the water-soluble pollutants in the degradation tank and effectively control and degrade the gas pollutants in the open environment.
Referring to fig. 5 and 6, fig. 5 is a schematic view illustrating absorption of an aqueous solution in a simulated NOx polluted environment of a pollution treatment system based on a star-structured friction nano-generator according to an embodiment of the present invention; fig. 6 is a schematic view of the detection of the degradation simulation absorption solution product of the pollution treatment system based on the star-structured friction nano-generator according to the embodiment of the present invention.
FIG. 5 is a result of simulating the absorption of aqueous solutions in NOx contaminated environments. Nitrogen oxides are one of the common atmospheric pollutants at present and are readily obtained by the reaction of copper with concentrated nitric acid. In this embodiment, the nitrogen oxides are selected to simulate pollutants and are converted to nitrate and nitrite by absorption in aqueous solution. A friction nano generator with a star-shaped engine structure, a one-way air path control module, an absorption electrolytic cell (containing 50mL of water) and a nitrogen oxide detector are placed in a closed acrylic box. In addition, a direct current motor is used for providing power in the simulation, and the rotating frequency is 3 Hz. And (3) introducing the nitrogen oxide into the box, and reducing the concentration of the nitrogen oxide in the box to 0 after 180min under the condition that the initial concentration is 1 mg/L. Therefore, the system can effectively absorb soluble pollutants in the gas.
FIG. 6 shows the results of the degradation of the absorption liquid obtained from two simulated absorption experiments over a period of time. One from the previous 1mg/L initial NOx experiment and one from the 4.6mg/L initial NOx simulation. In the embodiment, a fan is adopted to simulate natural wind energy for self-driven degradation, the wind speed is 6m/s, and 20mL of absorption liquid is absorbed as reaction liquid. After 24 hours of wind power driving, the increase of the concentration of characteristic degradation product ammonia can be detected, and the system can effectively degrade pollutants in the solution.
The patent can synchronously realize the enrichment and self-driven electrochemical degradation of soluble gas pollutants in water by utilizing the star-shaped structure friction nano generator, gas circuit control and circuit management.
Referring to fig. 7, fig. 7 is a flowchart of a pollution treatment method based on a star-structured friction nano-generator according to an embodiment of the present invention.
The embodiment of the invention provides a pollution treatment method based on a star-structured friction nano-generator, which is applied to a pollution treatment system based on the star-structured friction nano-generator in any one of the above examples, and comprises the following steps:
step S11: when the star-shaped engine rotates along with the pushing of external mechanical energy, the pistons of all the chambers are driven to move;
step S12: the contact separation type nano generator generates electricity along with the movement of the piston;
step S13: the unidirectional gas circuit control module drives gas in an open environment to be introduced into the electrochemical degradation module by utilizing the movement of the piston so that water-soluble pollutants in the gas are dissolved into a degradation pool of the electrochemical degradation module;
step S14: the circuit management module manages the electric energy generated by the contact separation type nanometer generator and provides electric energy for the electrochemical degradation module so as to degrade water-soluble pollutants in the degradation pool.
The method has been explained in the above embodiments of a pollution treatment system based on a star-structured friction nano-generator, and will not be described herein.
Although the invention has been described in detail above with reference to a general description and specific examples, it will be apparent to one skilled in the art that modifications or improvements may be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.

Claims (10)

1. A pollution treatment system based on a star-structured friction nanogenerator is characterized by comprising: the system comprises a star-shaped engine, and a contact separation type nano generator, a one-way gas circuit control module, a circuit management module and an electrochemical degradation module which are arranged in each cavity of the star-shaped engine;
the star-shaped engine rotates along with the pushing of external mechanical energy to drive the piston of each chamber to move;
the contact separation type nano generator generates electricity along with the movement of the piston;
the unidirectional gas circuit control module is used for driving gas in an open environment to be introduced into the electrochemical degradation module by utilizing the movement of the piston so as to dissolve water-soluble pollutants in the gas into a degradation pool of the electrochemical degradation module;
the circuit management module is used for managing the electric energy generated by the contact separation type nanometer generator and providing the electric energy for the electrochemical degradation module so as to degrade the water-soluble pollutants in the degradation pool.
2. The pollutant treating system of claim 1,
the water-soluble contaminants include, but are not limited to: sulfur oxides, nitrogen oxides.
3. The pollutant treating system of claim 1,
the star engine is connected with a power driving device, including but not limited to: wind power and water flow;
when wind blows or water flow drives the power driving device, the star-shaped engine is driven to rotate.
4. The pollutant treating system of claim 1,
the contact separation type nano-generator comprises: the stacked friction nano-generator is formed by connecting more than one contact separation type nano-generator in series;
the stacked friction nano-generator is connected end to end and is folded and placed in the cavity;
when the piston in the chamber moves, the stacked friction nano-generator is in contact separation to generate a potential difference.
5. The pollutant treating system of claim 1,
the circuit management module comprises: and the rectification modules correspond to the chambers one by one and are used for converting electric energy generated by the contact separation type nano generator into direct current and connecting the direct current to the electrochemical degradation module.
6. The pollutant treating system of claim 1,
the electrochemical degradation module comprises: the electrolytic cell is provided with a working electrode and a counter electrode in the electrolytic cell;
when the circuit management module accesses direct current to the working electrode and the counter electrode, water-soluble pollutants in the electrolytic cell are degraded.
7. The pollutant treatment system of claim 6, further comprising: and the rainwater collector is used for collecting rainwater into the degradation tank so as to realize the enrichment of water-soluble pollutants.
8. The pollutant treating system of claim 7,
the rainwater collector is a rain cover;
the rain cover includes: a rain collecting surface and a water outlet; the peripheral part of the rain collecting surface is higher than the middle part of the rain collecting surface; the water outlet is communicated with the middle part of the rain collecting surface and leads rainwater to the degradation pool.
9. The pollutant treating system of any one of claims 1 to 8,
one-way gas circuit control module includes: the first air inlet pipeline is communicated with the cavity, and the second air outlet pipeline is communicated with the cavity;
the first air inlet pipeline is provided with an air inlet one-way valve, and the other end of the first air inlet pipeline is communicated with an open atmosphere environment;
the second gas outlet pipeline is provided with a gas outlet one-way valve, and the other end of the second gas outlet pipeline is communicated with the degradation tank;
when the piston in the cavity moves, the gas in the open atmosphere is led to the degradation pool through the first gas inlet pipeline and the second gas outlet pipeline.
10. A pollution treatment method based on a star-structured friction nano-generator, which is applied to the pollution treatment system based on the star-structured friction nano-generator as claimed in any one of claims 1 to 9, and is characterized by comprising the following steps:
when the star-shaped engine rotates along with the pushing of external mechanical energy, the pistons of all the chambers are driven to move;
the contact separation type nano generator generates electricity along with the movement of the piston;
the unidirectional gas circuit control module drives gas in an open environment to be introduced into the electrochemical degradation module by utilizing the movement of the piston so that water-soluble pollutants in the gas are dissolved into a degradation pool of the electrochemical degradation module;
the circuit management module manages the electric energy generated by the contact separation type nanometer generator and provides electric energy for the electrochemical degradation module so as to degrade water-soluble pollutants in the degradation pool.
CN201911167430.1A 2019-11-25 2019-11-25 Pollution treatment system and method based on star-structure friction nano generator Pending CN110759435A (en)

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