CN110757926A - Synthetic paper - Google Patents

Synthetic paper Download PDF

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Publication number
CN110757926A
CN110757926A CN201810828671.5A CN201810828671A CN110757926A CN 110757926 A CN110757926 A CN 110757926A CN 201810828671 A CN201810828671 A CN 201810828671A CN 110757926 A CN110757926 A CN 110757926A
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China
Prior art keywords
synthetic paper
layer
surface layer
polypropylene
weight
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Pending
Application number
CN201810828671.5A
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Chinese (zh)
Inventor
林小松
吕达民
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Quanzhou Lichang New Material Technology Co Ltd
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Quanzhou Lichang New Material Technology Co Ltd
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Priority to CN201810828671.5A priority Critical patent/CN110757926A/en
Publication of CN110757926A publication Critical patent/CN110757926A/en
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/40—Applications of laminates for particular packaging purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B32B2250/242—All polymers belonging to those covered by group B32B27/32
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21—Anti-static

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to synthetic paper which has a multilayer superposed composite structure and comprises a first surface layer, a second surface layer and a core layer, wherein the core layer is arranged between the first surface layer and the second surface layer, the overall thickness of the synthetic paper is 60-300 micrometers, the thickness of the first surface layer is 5-30 micrometers, the surface roughness of the first surface layer of the synthetic paper is less than 0.100 micrometer, and the raw material of the core layer comprises homopolymerized polypropylene and one or more thermoplastic resins used as organic foaming materials. The synthetic paper provided by the embodiment of the invention has the advantages that the first surface has a low static electricity effect, the adsorptivity to a static electricity protective film is good, and the flatness is high.

Description

Synthetic paper
Technical Field
The invention belongs to the technical field of polymer films, and particularly relates to synthetic paper.
Background
With the increasing development of flat panel display technology, a variety of flat panel display devices are appearing in the market. The top layer of the display screen of the flat panel display device is a transparent glass panel or a panel made of other materials, and the display screen panel is in a sheet shape and has certain hardness. A display screen panel of a smart phone is a typical display screen panel, and is generally manufactured by cutting a large-sized panel into a plurality of small-sized panels of a specific size, and then transporting the cut display screen panel to an assembly process of a display production line, and mounting the cut display screen panel on a top layer of the display screen.
In the prior art, cutting a large-size panel is a continuous process, as shown in fig. 1, a cut display screen panel 1001 is generally not directly mounted on a top layer of the display screen, and due to requirements on transportation and cleanliness of the display screen panel, a plurality of cut display screen panels are sequentially received on a base paper 1002 at intervals, and then covered with an electrostatic protection film 1003, so that the display screen panel 1001 is clamped and wrapped between the base paper 1002 and the electrostatic protection film 1003, as shown in fig. 1. When the display screen panel is mounted, the upper electrostatic protection film 1003 is merely required to be peeled off, and the display screen panel 1001 is sucked and mounted.
At present, the base paper for bearing the display screen panel can be selected from glassine paper coated with silicone oil, and because the glassine paper as the base paper is cut, paper scraps can be generated in the cutting process, and part of the paper scraps can be remained on the surface of the glassine paper, so that the cleanliness of the surface of the base paper is influenced, and the sticking effect between the display panel and the glassine paper is reduced. Meanwhile, since the surface of the glassine paper is coated with the silicone oil, when the display screen panel is supported on the glassine paper, the silicone oil can be transferred to the display screen panel, so that the panel is polluted, and the transparency of the display panel is affected.
In order to solve the above-mentioned drawbacks of silicone oil-coated glassine as a base paper, a solution using an existing synthetic paper as a base paper has been proposed, the synthetic paper does not generate paper dust during cutting, but the existing synthetic paper has poor adsorptivity and is difficult to adsorb to glass and an electrostatic protective film of a display screen panel, and the display screen panel is easily displaced and is not firmly fixed when being clamped between the synthetic paper and the electrostatic protective film. In order to increase the adsorbability of the base paper, for example, a transparent polypropylene film OPP can be pasted on the synthetic paper, but the polypropylene film OPP can generate low molecular material precipitates, pollute the display screen panel and influence the service performance of the display screen panel. After the synthetic paper is coated, the synthetic paper coated with the synthetic paper is bent due to the difference in shrinkage rate between the synthetic paper and a coating film of, for example, a polypropylene film, thereby affecting the wrapping effect of the display panel. In addition, the film is pasted on the synthetic paper, so that the packaging cost is increased, and the pasting solvent is remained and is not environment-friendly.
Disclosure of Invention
In order to solve the technical problem, an embodiment of the present invention provides a synthetic paper, which has a multilayer laminated composite structure, and includes a first surface layer, a second surface layer, and a core layer, where the core layer is disposed between the first surface layer and the second surface layer, the synthetic paper has an overall thickness of 60 to 300 micrometers, the first surface layer has a thickness of 5 to 30 micrometers, the surface roughness of the first surface layer of the synthetic paper is less than 0.100 micrometer, and the core layer is made of a raw material including homopolypropylene and one or more thermoplastic resins as an organic foaming material.
Further, the foaming material is one or more of polyethylene terephthalate, polybutylene terephthalate, polyamide resin and polystyrene.
Furthermore, the core layer comprises 5-30 wt% of organic foaming material, 0-15 wt% of titanium dioxide, 0-10 wt% of migration antistatic agent and the balance of homopolymerized polypropylene.
Further, the raw material of the first surface layer comprises homo-polypropylene, co-polypropylene or a mixture of homo-polypropylene and co-polypropylene, and the weight ratio of the homo-polypropylene to the co-polypropylene in the mixture is 1:4 to 4: 1.
Further, the raw material of the first skin layer further includes a non-migrating antistatic agent in an amount of not more than 40% by weight.
Further, the raw material of the second surface layer comprises homo-polypropylene, co-polypropylene or a mixture of homo-polypropylene and co-polypropylene, and the weight ratio of homo-polypropylene to co-polypropylene in the mixture is 1:4 to 4: 1.
Further, the raw material of the second surface layer also comprises polyethylene and 0-40 wt% of non-migratory antistatic agent, wherein the weight ratio of homo-polypropylene, co-polypropylene or the mixture of homo-polypropylene and co-polypropylene to the polyethylene in the raw material of the second surface layer is 1:3 to 3: 1.
Further, the thickness of the first surface layer of the synthetic paper is 10-20 microns, the surface roughness of the first surface layer is less than 0.050 micron, the thickness of the second surface layer is 5-30 microns, the overall thickness of the synthetic paper is 170-220 microns, and the density of the synthetic paper is 0.55-0.90g/cm3。
Further, the synthetic paper has a three-layer superposed composite structure including a first surface layer, a second surface layer and a core layer.
Further, the synthetic paper has a five-layer superposed composite structure and comprises a first surface layer, a first secondary surface layer, a core layer, a second secondary surface layer and a second surface layer, wherein the first secondary surface layer is arranged between the core layer and the first surface layer, the second secondary surface layer is arranged between the core layer and the second surface layer, the thicknesses of the first secondary surface layer and the second secondary surface layer are 3-15 micrometers, the synthetic paper comprises 0-15% by weight of titanium dioxide, 0-40% by weight of non-migratory antistatic agent, and the balance is homopolymerized polypropylene.
The invention has the beneficial effects that: when the biaxially oriented synthetic paper provided by the embodiment of the invention is used as the base paper of a packaging material and is combined with the electrostatic protection film to be applied to product packaging, the base paper has a low electrostatic effect, the base paper has good adsorbability to the electrostatic protection film, no additional film is required to be coated on the base paper, and the flatness is high. The biaxially oriented synthetic paper and the electrostatic protection film can be used for effectively positioning and packaging products, and can be easily uncovered from the base paper when the products need to be used.
Drawings
FIG. 1 is a top view of a prior art multiple piece display screen panel package;
FIG. 2 is a cross-sectional view of a co-extruded biaxially oriented synthetic paper having a three-ply laminated composite structure according to an embodiment of the present invention;
FIG. 3 is a cross-sectional view of a coextruded biaxially oriented synthetic paper having a five-layer laminated composite structure according to an embodiment of the present invention;
FIG. 4 is a process flow diagram of a method for manufacturing a co-extruded biaxially oriented synthetic paper according to an embodiment of the present invention;
FIG. 5 is a schematic view of an embodiment of the present invention showing the application of the co-extruded biaxially oriented synthetic paper as a packaging base paper;
fig. 6 and 7 are schematic views of packaging using a coextruded biaxially oriented synthetic paper according to an embodiment of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described in further detail below with reference to specific embodiments and the accompanying drawings. Those skilled in the art will appreciate that the present invention is not limited to the drawings and the following examples.
Example 1:
the embodiment of the invention provides synthetic paper, which is shown in fig. 2 and has a three-layer superposed composite structure, and the synthetic paper comprises a first surface layer 1, a second surface layer 2 and a core layer 3, wherein the core layer 3 is arranged between the first surface layer 1 and the second surface layer 2, and the first surface layer 1 is a bearing layer. The thickness of the first skin layer 1 is 5-30 microns, preferably 10-20 microns. The surface roughness (Ra value) of the first surface layer 1 of the synthetic paper is less than 0.100 micrometer (measured with a german markov surface roughness measurement instrument (model: Marsurf M300C) according to ISO12085 "geometry specification"), preferably less than 0.050 micrometer. The density of the synthetic paper is 0.55-0.90g/cm3Preferably 0.60 to 0.70g/cm3。
The core layer 3 comprises homo polypropylene and organic foaming material, and may further comprise additives, such as titanium dioxide and migratory antistatic agent. The raw material ratio is as follows: 5-30% of organic foaming material, 0-15% of titanium dioxide, 0-10% of migration antistatic agent and the balance of homopolymerized polypropylene. Among them, the organic foaming material is one or more thermoplastic resins, and preferably one or more of polyethylene terephthalate, polybutylene terephthalate, polyamide resin and polystyrene are used.
The raw material of the first skin layer 1 (and/or the second skin layer 2) includes homopolypropylene (unless otherwise specified, "polypropylene" which is not defined in the present specification means "homopolypropylene"), copolypropylene or a mixture of homopolypropylene and copolypropylene in a weight ratio of homopolypropylene to copolypropylene of 1:4 to 4:1, and may further include an auxiliary agent such as a non-migrating antistatic agent in an amount of not more than 40% by weight, whereby the first skin layer 1 has a glossy surface. It should be noted that, by adding the polypropylene copolymer to the raw material of the first surface layer 1, the melting point of the raw material can be effectively reduced, the melting point can be reduced during the manufacturing process, and the heat sealing and bonding/adsorption performance of the synthetic paper product can be improved.
The material of the second surface layer 2 comprises polyethylene and one or two of co-polypropylene and homo-polypropylene, the weight ratio of co/homo-polypropylene to polyethylene is 1:3 to 3:1, the material of the second surface layer 2 may further comprise an auxiliary agent, for example, a non-migrating antistatic agent in an amount of not more than 40% by weight. Polyethylene is added as a main raw material to increase the roughness of the second surface layer 2, so that the second surface layer 2 has a matte surface. The thickness of the second skin layer 2 is 5-30 microns.
The organic foaming material is added into the raw material of the core layer, so that the foaming of the core layer is relatively uniform, and the surface of the core layer 3 is relatively flat. The thickness of the first surface layer 1 covering the core layer 3 is thicker than that of the surface layer in the prior art (less than 5 micrometers), so that the thicker first surface layer 1 covers the foamed core layer, the surface roughness (Ra value) of the first surface layer 1 of the synthetic paper is ensured to be less than 0.100 micrometer, and the use requirement of packaging is met.
In addition, the overall thickness of the synthetic paper of the embodiment of the invention can reach 60-300 microns, and the effect is better within the thickness range of 170-220 microns.
In order to make the surface of the first surface layer of the carrier layer have a low electrostatic effect, the carrier layer has good adsorptivity to the electrostatic protection film and high flatness. In addition, it is optional to add a non-migrating antistatic agent to the first skin layer, or to add a migrating antistatic agent to the core layer.
Example 2:
in example 1 of the present invention, a co-extruded biaxially oriented synthetic paper having a three-layer-superimposed composite structure is specifically described. In another embodiment of the present invention, as shown in fig. 3, the coextruded biaxially oriented synthetic paper has a five-layer laminated composite structure comprising, in order, a first skin layer 1 and a first secondary skin layer4. Core layer 3, second surface layer 5 and second surface layer 2, first surface layer 1 is the load-bearing layer. The thickness of the first skin layer 1 is 5 to 30 micrometers, preferably 10 to 20 micrometers, respectively. The surface roughness (Ra value) of the first surface layer 1 of the synthetic paper is less than 0.100 micrometer (measured with a german markov surface roughness measurement instrument (model: Marsurf M300C) according to ISO12085 "geometry specification"), preferably less than 0.050 micrometer. The density of the synthetic paper is 0.50-0.90g/cm3Preferably 0.60 to 0.70g/cm3。
Compared with the synthetic paper of the embodiment 1, the embodiment is provided with the first secondary surface layer 4 and the second secondary surface layer 5 between the core layer and the first surface layer 1 and the second surface layer 2 respectively, the thickness of the first secondary surface layer 4 and the second secondary surface layer 5 is 3-15 microns, and the first secondary surface layer 4 and the second secondary surface layer 5 comprise 0-15% by weight of titanium dioxide, 0-40% by weight of non-migratory antistatic agent, and the balance is polypropylene. In this embodiment, owing to increased subsurface 4, 5, so increased the whole thickness of top layer outside the core layer of synthetic paper, can suitably reduce the thickness on first, second top layer, more do benefit to and guarantee that surface roughness is less, increased the interlaminar adhesive force of synthetic paper simultaneously.
Example 3:
referring to fig. 4, the method for manufacturing the co-extruded biaxially oriented synthetic paper of the present invention includes the following steps:
an extrusion step: drying each layer of raw materials in the multilayer structure of the synthetic paper at 40-100 ℃, uniformly stirring, extruding the stirred raw materials in each layer into a plurality of flow channels which are arranged in a T-shaped die head in a laminated manner according to a laminated structure by respective extruders at the working temperature of 220-300 ℃, co-extruding and forming to form a multilayer composition, and allowing the composition to flow out through the T-shaped die head.
For the production of the synthetic paper of example 1, the T-die block included three flow channels arranged in a stacked manner, the raw material of the first skin layer 1 after stirring entered the upper flow channel of the T-die, the raw material of the second skin layer 2 after stirring entered the lower flow channel of the T-die, the raw material of the core layer 3 after stirring entered the middle flow channel of the T-die, and the three-layer composition was formed by co-extrusion molding and flowed out through the T-die.
For manufacturing the synthetic paper of example 2, the T-shaped module includes five stacked flow channels, and the raw materials of the first surface layer 1, the first secondary surface layer 4, the core layer 3, the second secondary surface layer 5, and the second surface layer 2 after stirring sequentially enter the five flow channels of the T-shaped die head from top to bottom, and are co-extruded to form a five-layer composition, which flows out through the T-shaped die head.
And (3) cooling: the composition from the T-die was applied to the surface of the first chill roll and immersed in a cooling water bath on the underside of the first chill roll as the first chill roll was rotated. The first cooling roller is provided with a cooling medium circulation passage, the cooling water tank is also provided with cooling water circulation, the working temperature of the cooling roller is 15-60 ℃, and the working temperature of the cooling water tank is 18-70 ℃. The composition from the T-die is thereby rapidly cooled to form a stack of compositions at a temperature between 60 and 120 ℃. Such rapid cooling results in compositions that are small, numerous, relatively soft, easy to stretch, and have good clarity.
To further enhance the cooling effect, the composition from the T-die is allowed to closely adhere to the surface of the first cooling roll, and an air knife may be provided at a position opposite to the position where the composition from the T-die is extruded onto the surface of the first cooling roll, and an air current having a certain pressure (5 to 12MPa) is discharged from the air knife, and the air current is applied to the back side of the composition laminate which comes into contact with the surface of the first cooling roll, and the air between the composition laminate and the first cooling roll is expelled, so that the composition laminate closely adheres to the surface of the first cooling roll, and the temperature of the composition can be lowered.
Longitudinally drawing: the cooled thick sheet is preheated by sequentially arranging a plurality of preheating rollers in the advancing direction of the composite laminated sheet, the preheating rollers are circularly heated by hot oil, the preheating temperature is 120-. The preheated composite lamination is stretched by a plurality of stretching rollers in the advancing direction by means of the difference of the rotating speed, and the working temperature of a longitudinal stretching area is 100-140 ℃. And (3) shaping the longitudinally stretched composite lamination at the temperature of 120-160 ℃, and performing secondary crystallization to eliminate the internal stress of the composite lamination.
The composite laminate is longitudinally stretched 3-6 times through the longitudinal drawing step.
Transversely pulling: preheating the longitudinally drawn composite laminate at the operating temperature of 150 ℃ and 180 ℃ of the heat exchanger, wherein the temperature of the heat exchanger is gradually reduced in the advancing direction of the composite laminate, and the composite laminate releases heat. For example, the composite laminate is transversely drawn by clamping the composite laminate on both sides by clamping devices, and the working temperature of the transverse drawing zone is 130-170 ℃. And (3) shaping the transversely stretched composite lamination at the temperature of 150-180 ℃, and performing secondary crystallization to eliminate the internal stress of the composite lamination. And (3) carrying out air cooling on the laminated plate of the shaped composition to 30-60 ℃.
The composite laminate is stretched 4 to 12 times in the transverse direction through the transverse drawing step to form a film.
A traction rolling step: and cooling the biaxially oriented film to below 40 ℃ by a second cooling roller, and winding by a traction device.
And the thickness of the film is detected between the film and the winding station from the second cooling roller, the detection data is fed back to the control system, and the opening height of each runner of the T-shaped die head can be adjusted, so that the thickness of each extruded raw material layer is adjusted.
Similarly, between the film and the take-up station from the second cooling roll, the film except for the position sandwiched by the sandwiching means on both sides of the film is cut off, and the cut film is crushed and recovered, and is added to the raw material for reuse.
In order to ensure the availability of the cut-off film material, in the extrusion step, the width of one flow channel of the T-die may be set wider than the other flow channels, preferably the flow channel corresponding to the core layer (the thickest core layer), depending on the holding position of the holding means, so that the laminated portion of the composition held in the drawing step is mostly the core layer material, and may be directly used for the core layer material after being cut off in the take-up step.
Because the organic foaming material is used, compared with the inorganic foaming material, the integral preheating and working temperature in the longitudinal drawing step and the transverse drawing step are reduced in the manufacturing process of the synthetic paper.
Example 4:
as shown in fig. 5 to 7, the application of the above-mentioned co-extruded biaxially oriented synthetic paper of the present invention as a packaging base paper will be explained.
When the film is used as a packaging base paper and is combined with an electrostatic protection film to be applied to product packaging, as shown in fig. 5, a display screen panel 22 is taken as an example for description. The co-extrusion two-way stretching synthetic paper is used as the packaging base paper 21, the display screen panel 22 is placed on the packaging base paper 21, the electrostatic protection film 23 covers the packaging base paper 21 and the display screen panel 22, and the electrostatic protection film 23 is adsorbed on the packaging base paper 21 and can be electrostatically adsorbed on the surface of the display screen panel 22. Since the coextruded biaxially oriented synthetic paper of the present invention is foamed by the organic foaming material to form the receiving surface (the first surface of the synthetic paper) with low roughness, the receiving surface has good adsorption capacity with the electrostatic protection film 23 and the display panel 22, and the display panel 22 fixed between the electrostatic protection film 23 and the wrapping base paper 21 will not be displaced.
The process of fig. 6 or fig. 7 may be selected for packaging. As shown in fig. 6, the co-extruded biaxially oriented synthetic paper of the present invention is laid as a packaging base paper 21, then a plurality of display screen panels 22 are laid flat on a receiving surface (first surface of the synthetic paper) of the packaging base paper 21, and finally an electrostatic protection film 23 is attached on the packaging base paper 21 and the display screen panels 22. As shown in fig. 7, the co-extrusion biaxially-oriented synthetic paper of the present invention is laid as the packaging base paper 21, the plurality of display screen panels 22 are placed on the receiving surface of the packaging base paper 21, and the electrostatic protective films 23 are adsorbed on the packaging base paper 21 and the display screen panels 22, which are performed simultaneously, thereby ensuring the continuity of the process and being suitable for industrial continuous production.
When the display screen panel 22 is needed, the upper layer electrostatic protection film 23 is manually or mechanically removed, and the display screen panel 22 is sucked by a suction cup.
In the present embodiment, the display screen panel is used for exemplary illustration, but it can be understood by those skilled in the art that the above packaging method can also be used for packaging other products, such as electronic devices to be transferred, and preventing the products from being contaminated during the transferring process.
Example 1 of Co-extruded biaxially oriented synthetic paper according to an embodiment of the invention
The utility model provides a crowded biaxial tension synthetic paper altogether with three-layer stack composite construction, includes first top layer 1, second top layer 2 and sandwich layer 3, and second top layer 2 and first top layer 1 have the same raw materials ratio, all can regard as the bearer layer.
The core layer 3 comprises the following raw materials in percentage by weight: 26% of polyethylene terephthalate, 6% of titanium dioxide, 2% of a migration antistatic agent and 66% of polypropylene.
The first surface layer 1 comprises the following raw materials in percentage by weight: 100% by weight of polypropylene.
An extrusion step: drying each layer of raw materials in the multilayer structure of the synthetic paper at 60 ℃, uniformly stirring, extruding into a plurality of flow channels which are arranged in a T-shaped die head in a laminated manner according to the laminated structure by an extruder at the working temperature of 240 ℃, co-extruding and molding to form a multilayer composition, and extruding through the T-shaped die head.
And (3) cooling: the composition from the T-die was extruded onto the surface of a first chill roll operating at 25 ℃, a circulating water bath temperature of 28 ℃ and an air knife pressure of 8 MPa. The composition from the T-die was thus rapidly cooled to form a 1.1 meter wide stack of the composition at a temperature of 105 ℃.
Longitudinally drawing: the composition laminate entering the preheating process is preheated by a plurality of preheating rollers, and the temperature of the preheating rollers is gradually increased in the advancing direction of the composition laminate, and the preheating temperature is 135 ℃. The preheated composite laminate was drawn by means of differential rotational speeds from a plurality of draw rolls in the direction of travel, with the longitudinal draw zone operating at a temperature of 125 ℃. The longitudinally stretched composite laminate was then set at 136 ℃.
Transversely pulling: the composite laminate after longitudinal drawing is preheated at an operating temperature of 170 ℃ of the heat exchanger, and the temperature of the heat exchanger is gradually decreased in the advancing direction of the composite laminate. The preheated composite laminate was drawn in the transverse direction at an operating temperature of 158 ℃ in the transverse drawing zone. Shaping the transversely stretched composite laminate at 172 deg.C, and air cooling the shaped composite laminate to 40 deg.C. The composite laminate can thus be stretched transversely to 9 meters to form a film.
A traction rolling step: and cooling the biaxially oriented film to 26 ℃ by a second cooling roller, and winding by a traction device.
Through the manufacturing process, the overall thickness of the manufactured synthetic paper is 200 micrometers, wherein the thickness of the first surface layer and the thickness of the second surface layer are respectively 15 micrometers, and the density of the synthetic paper is 0.62g/cm3The surface roughness (Ra value) of the first surface layer 1 of the synthetic paper is less than 0.100 μm.
Example 2 of Co-extruded biaxially oriented synthetic paper according to an embodiment of the present invention
The utility model provides a crowded biaxial tension synthetic paper altogether with three-layer stack composite construction, includes first top layer 1, second top layer 2 and sandwich layer 3, and second top layer 2 and first top layer 1 have the same raw materials ratio, all can regard as the bearer layer.
The core layer 3 comprises the following raw materials in percentage by weight: 20% of polyethylene terephthalate, 8% of titanium dioxide and 72% of polypropylene.
The first surface layer 1 comprises the following raw materials in percentage by weight: 90% by weight of homopolypropylene and 10% by weight of a non-migrating antistatic agent.
Hereinafter, the parameters in the manufacturing method of the synthetic paper of this example are substantially the same as those of example 1.
An extrusion step: drying each layer of raw materials in the multilayer structure of the synthetic paper at 60 ℃, uniformly stirring, extruding into a plurality of flow channels which are arranged in a T-shaped die head in a laminated manner according to the laminated structure by an extruder at the working temperature of 240 ℃, co-extruding and molding to form a multilayer composition, and extruding through the T-shaped die head.
And (3) cooling: the composition from the T-die was extruded onto the surface of a first chill roll operating at 25 ℃, circulating water at 28 ℃ and air knife pressure of 8 MPa. The composition from the T-die was thus rapidly cooled to form a 1.1 meter wide stack of the composition at a temperature of 105 ℃.
Longitudinally drawing: the composition laminate entering the preheating process is preheated by a plurality of preheating rollers, and the temperature of the preheating rollers is gradually increased in the advancing direction of the composition laminate, and the preheating temperature is 135 ℃. The preheated composite laminate was drawn by means of differential rotational speeds from a plurality of draw rolls in the direction of travel, with the longitudinal draw zone operating at a temperature of 125 ℃. The longitudinally stretched composite laminate was then set at 136 ℃.
Transversely pulling: the composite laminate after longitudinal drawing is preheated at an operating temperature of 170 ℃ of the heat exchanger, and the temperature of the heat exchanger is gradually decreased in the advancing direction of the composite laminate. The preheated composite laminate was drawn in the transverse direction at an operating temperature of 158 ℃ in the transverse drawing zone. Shaping the transversely stretched composite laminate at 172 deg.C, and air cooling the shaped composite laminate to 40 deg.C. The composite laminate was thus stretched transversely to 9 meters to form a film.
A traction rolling step: and cooling the biaxially oriented film to 36 ℃ by a second cooling roller, and winding by a traction device.
Through the manufacturing process, the overall thickness of the manufactured synthetic paper is 180 micrometers, wherein the thickness of the first surface layer and the thickness of the second surface layer are respectively 12 micrometers, and the density of the synthetic paper is 0.65g/cm3The surface roughness (Ra value) of the first surface layer 1 of the synthetic paper is less than 0.100 μm.
Example 3 of Co-extruded biaxially oriented synthetic paper according to an embodiment of the invention
The utility model provides a crowded biaxial stretching synthetic paper altogether with three-layer stack composite construction, includes first top layer 1, second top layer 2 and sandwich layer 3, and second top layer 2 and first top layer 1 have different raw materials proportions.
The core layer 3 comprises the following raw materials in percentage by weight: 28 percent of polybutylene terephthalate, 4 percent of titanium dioxide, 68 percent of polypropylene,
the first surface layer 1 comprises the following raw materials in percentage by weight: 90% by weight of homopolypropylene and 10% by weight of a non-migrating antistatic agent.
The second surface layer 2 comprises the following raw materials in proportion: 40% by weight of a copolymer polypropylene and 45% by weight of a polyethylene, and 15% by weight of a non-migrating antistatic agent.
An extrusion step: drying raw materials of each layer in the multilayer structure of the synthetic paper at 75 ℃, uniformly stirring, extruding the raw materials into a plurality of flow channels which are arranged in a T-shaped die head in a laminated mode according to the laminated structure at the working temperature of 240 ℃ by an extruder, co-extruding the raw materials to form a multilayer composition, and extruding the multilayer composition through the T-shaped die head.
And (3) cooling: the composition from the T-die was extruded onto the surface of a first chill roll operating at 25 ℃, a circulating water bath temperature of 28 ℃ and an air knife pressure of 8 MPa. The composition from the T-die was thus rapidly cooled to form a 1.1 meter wide stack of the composition at a temperature of 109 ℃.
Longitudinally drawing: the composition laminate entering the preheating process is preheated by a plurality of preheating rollers, and the temperature of the preheating rollers is gradually increased in the advancing direction of the composition laminate, and the preheating temperature is 125 ℃. The preheated composite laminate is stretched by a plurality of stretching rollers in the advancing direction by means of the difference of rotating speed, and the working temperature of a longitudinal stretching area is 120 ℃. The longitudinally stretched composite laminate was then set at 132 ℃.
Transversely pulling: the composite laminate after longitudinal drawing is preheated at an operating temperature of 170 ℃ of the heat exchanger, and the temperature of the heat exchanger is gradually decreased in the advancing direction of the composite laminate. The preheated composite laminate was drawn in the transverse direction, and the working temperature in the transverse drawing zone was 130 ℃. Shaping the transversely stretched composite laminate at 150 ℃, and air-cooling the shaped composite laminate to 30 ℃. The composite laminate was thus stretched transversely to 9 meters to form a film.
A traction rolling step: and cooling the biaxially oriented film to 20 ℃ by a second cooling roller, and winding by a traction device.
Through the manufacturing process, the overall thickness of the manufactured synthetic paper is 220 micrometers, wherein the thicknesses of the first surface layer and the second surface layer are respectively 15 micrometers and 10 micrometers, and the density of the synthetic paper is 0.60g/cm3The surface roughness (Ra value) of the first surface layer 1 of the synthetic paper is less than 0.100 μm.
Example of Co-extruded biaxially oriented synthetic paper 4 of an embodiment of the invention
The utility model provides a crowded biaxial stretching synthetic paper altogether with three-layer stack composite construction, includes first top layer 1, sandwich layer 3 and second top layer 2, and second top layer 2 and first top layer 1 have inequality raw materials ratio.
The core layer 3 comprises the following raw materials in percentage by weight: 10 percent of polybutylene terephthalate, 5 percent of polyamide resin, 10 percent of titanium dioxide, 75 percent of polypropylene,
the first surface layer 1 comprises the following raw materials in percentage by weight: 100% by weight of homopolypropylene.
The second surface layer 2 comprises the following raw materials in proportion: 40% by weight of homopolypropylene and 40% by weight of polyethylene, 20% by weight of a non-migrating antistatic agent.
An extrusion step: drying raw materials of each layer in the multilayer structure of the synthetic paper at 75 ℃, uniformly stirring, extruding the raw materials into a plurality of flow channels which are arranged in a T-shaped die head in a laminated mode according to the laminated structure at the working temperature of 240 ℃ by an extruder, co-extruding the raw materials to form a multilayer composition, and extruding the multilayer composition through the T-shaped die head.
And (3) cooling: the composition from the T-die was extruded onto the surface of a first chill roll operating at 25 ℃, a circulating water bath temperature of 28 ℃ and an air knife pressure of 8 MPa. The composition from the T-die was thus rapidly cooled to form a 1.1 meter wide stack of the composition at a temperature of 108 ℃.
Longitudinally drawing: the composition laminate entering the preheating process is preheated by a plurality of preheating rollers, and the temperature of the preheating rollers is gradually increased in the advancing direction of the composition laminate, and the preheating temperature is 125 ℃. The preheated composite laminate is stretched by a plurality of stretching rollers in the advancing direction by means of the difference of rotating speed, and the working temperature of a longitudinal stretching area is 120 ℃. The longitudinally stretched composite laminate was then set at 132 ℃.
Transversely pulling: the composite laminate after longitudinal drawing is preheated at an operating temperature of 170 ℃ of the heat exchanger, and the temperature of the heat exchanger is gradually decreased in the advancing direction of the composite laminate. The preheated composite laminate was drawn in the transverse direction, and the working temperature in the transverse drawing zone was 135 ℃. The transversely stretched composite laminate was shaped at 159 ℃ and air-cooled to 30 ℃. The composite laminate was thus stretched transversely to 9 meters to form a film.
A traction rolling step: and cooling the biaxially oriented film to 22 ℃ by a second cooling roller, and winding by a traction device.
Through the manufacturing process, the overall thickness of the manufactured synthetic paper is 100 micrometers, wherein the thicknesses of the first surface layer and the second surface layer are respectively 8 micrometers and 5 micrometers, and the density of the synthetic paper is 0.72g/cm3The surface roughness (Ra value) of the first surface layer 1 of the synthetic paper is less than 0.100 μm.
Example of Co-extruded biaxially oriented synthetic paper 5 of an embodiment of the invention
The utility model provides a have five layers of stack composite construction crowded biaxial stretching synthetic paper altogether, includes first top layer 1, second top layer 2, first top layer 4, second top layer 5 and sandwich layer 3, and second top layer 2 and first top layer 1 have the same raw materials ratio, all can regard as the bearer layer, and first top layer 4 and second top layer 5 have not the same structure.
The core layer 3 comprises the following raw materials in percentage by weight: 9 percent of polyamide resin, 8 percent of polystyrene, 9 percent of titanium dioxide, 74 percent of polypropylene,
the raw material ratio of the first surface layer 1 and the second surface layer is as follows: 100% by weight of polypropylene.
The first surface layer 4 comprises the following raw materials in percentage by weight: 95 percent of polypropylene and 5 percent of titanium dioxide.
The second surface layer 5 comprises the following raw materials in proportion: polypropylene 98% by weight, migrating antistatic agent 2% by weight.
An extrusion step: drying each layer of raw materials in the multilayer structure of the synthetic paper at 60 ℃, uniformly stirring, extruding into a plurality of flow channels which are arranged in a T-shaped die head in a laminated manner according to the laminated structure by an extruder at the working temperature of 240 ℃, co-extruding and molding to form a multilayer composition, and extruding through the T-shaped die head.
And (3) cooling: the composition from the T-die was extruded onto the surface of a first chill roll operating at 25 ℃, a circulating water bath temperature of 28 ℃ and an air knife pressure of 8 MPa. The composition from the T-die was thus rapidly cooled to form a 1.1 meter wide stack of the composition at a temperature of 106 ℃.
Longitudinally drawing: the composition laminate entering the preheating process is preheated by a plurality of preheating rollers, and the temperature of the preheating rollers is gradually increased in the advancing direction of the composition laminate, and the preheating temperature is 135 ℃. The preheated composite laminate was drawn by means of differential rotational speeds from a plurality of draw rolls in the direction of travel, with the longitudinal draw zone operating at a temperature of 125 ℃. The longitudinally stretched composite laminate was then set at 136 ℃.
Transversely pulling: the composite laminate after longitudinal drawing is preheated at an operating temperature of 170 ℃ of the heat exchanger, and the temperature of the heat exchanger is gradually decreased in the advancing direction of the composite laminate. The preheated composite laminate was drawn in the transverse direction at an operating temperature of 158 ℃ in the transverse drawing zone. Shaping the transversely stretched composite laminate at 172 deg.C, and air cooling the shaped composite laminate to 40 deg.C. The composite laminate was thus stretched transversely to 9 meters to form a film.
A traction rolling step: and cooling the biaxially oriented film to 40 ℃ by a second cooling roller, and winding by a traction device.
Through the manufacturing process, the overall thickness of the manufactured synthetic paper is 150 micrometers, wherein the thickness of the first surface layer and the second surface layer is respectively 3 micrometers, the thickness of the first surface layer and the thickness of the second surface layer are respectively 6 micrometers, and the density of the synthetic paper is 0.68g/cm3The surface roughness (Ra value) of the first surface layer 1 of the synthetic paper is less than 0.100 μm.
Example of Co-extruded biaxially oriented synthetic paper 6 of an embodiment of the invention
The utility model provides a have five layers of stack composite construction crowded biaxial stretching synthetic paper altogether, includes first top layer 1, second top layer 2, first top layer 4, second top layer 5 and sandwich layer 3, and second top layer 2 and first top layer 1 have inequality raw materials ratio, all can regard as the bearer layer, and first top layer 4 and second top layer 5 have the same structure.
The core layer 3 comprises the following raw materials in percentage by weight: 5 percent of polyethylene glycol terephthalate, 5 percent of polybutylene terephthalate, 5 percent of polyamide resin, 4 percent of titanium dioxide, 81 percent of homopolymerized polypropylene,
the first surface layer 1 comprises the following raw materials in percentage by weight: 60% by weight of a copolymer polypropylene and 40% by weight of a homopolymer polypropylene.
The second surface layer 2 comprises the following raw materials in proportion: 42% by weight of polypropylene copolymer, 40% by weight of polyethylene, 18% by weight of a non-migrating antistatic agent.
The raw material ratio of the first secondary surface layer 4 and the second secondary surface layer 5 is as follows: 92% of copolymerized polypropylene and 8% of titanium dioxide.
An extrusion step: drying each layer of raw materials in the multilayer structure of the synthetic paper at 60 ℃, uniformly stirring, extruding into a plurality of flow channels which are arranged in a T-shaped die head in a laminated manner according to the laminated structure by an extruder at the working temperature of 240 ℃, co-extruding and molding to form a multilayer composition, and extruding through the T-shaped die head.
And (3) cooling: the composition from the T-die was extruded onto the surface of a first chill roll operating at 25 ℃, a circulating water bath temperature of 28 ℃ and an air knife pressure of 8 MPa. The composition from the T-die was thus rapidly cooled to form a 1.1 meter wide stack of the composition at a temperature of 105 ℃.
Longitudinally drawing: the composition laminate entering the preheating process is preheated by a plurality of preheating rollers, and the temperature of the preheating rollers is gradually increased in the advancing direction of the composition laminate, and the preheating temperature is 125 ℃. The preheated composite laminate is stretched by a plurality of stretching rollers in the advancing direction by means of the difference of rotating speed, and the working temperature of a longitudinal stretching area is 120 ℃. The longitudinally stretched composite laminate was then set at 132 ℃.
Transversely pulling: the composite laminate after longitudinal drawing is preheated at an operating temperature of 170 ℃ of the heat exchanger, and the temperature of the heat exchanger is gradually decreased in the advancing direction of the composite laminate. The preheated composite laminate was drawn in the transverse direction, and the working temperature in the transverse drawing zone was 149 ℃. Shaping the transversely stretched composite laminate at 172 deg.C, and air-cooling the shaped composite laminate to 30 deg.C. The composite laminate was thus stretched transversely to 9 meters to form a film.
A traction rolling step: and cooling the biaxially oriented film to 20 ℃ by a second cooling roller, and winding by a traction device.
Through the manufacturing process, the overall thickness of the manufactured synthetic paper is 170 micrometers, wherein the thickness of the first surface layer and the second surface layer is 8 micrometers respectively, the thickness of the first surface layer and the thickness of the second surface layer are 13 micrometers respectively, and the density of the synthetic paper is 0.70g/cm3The surface roughness (Ra value) of the first surface layer 1 of the synthetic paper is less than 0.100 μm.
Example 7 of Co-extruded biaxially oriented synthetic paper according to an embodiment of the invention
The utility model provides a have five layers of stack composite construction crowded biaxial stretching synthetic paper altogether, includes first top layer 1, second top layer 2, first top layer 4, second top layer 5 and sandwich layer 3, and second top layer 2 and first top layer 1 have inequality raw materials ratio, and first top layer 1 is as the bearer layer, and first top layer 4 and second top layer 5 have the same structure.
The core layer 3 comprises the following raw materials in percentage by weight: 10 percent of polyamide resin, 11 percent of titanium dioxide, 79 percent of polypropylene,
the first surface layer 1 comprises the following raw materials in percentage by weight: the weight percent of the polypropylene copolymer is 92 percent, and the weight percent of the non-migrating antistatic agent is 8 percent.
The second surface layer 2 comprises the following raw materials in proportion: 42% by weight of a polypropylene copolymer, 45% by weight of a polyethylene, and 13% by weight of a non-migrating antistatic agent.
The raw material ratio of the first secondary surface layer 4 and the second secondary surface layer 5 is as follows: 100% by weight of a copolymer polypropylene.
An extrusion step: drying each layer of raw materials in the multilayer structure of the synthetic paper at 80 ℃, uniformly stirring, extruding into a plurality of flow channels which are arranged in a T-shaped die head in a laminated manner according to the laminated structure by an extruder at the working temperature of 240 ℃, co-extruding and molding to form a multilayer composition, and extruding through the T-shaped die head.
And (3) cooling: the composition from the T-die was extruded onto the surface of a first chill roll operating at 25 ℃, a circulating water bath temperature of 28 ℃ and an air knife pressure of 8 MPa. The composition from the T-die was thus rapidly cooled to form a 1.1 meter wide stack of the composition at a temperature of 105 ℃.
Longitudinally drawing: the composition laminate entering the preheating process is preheated by a plurality of preheating rollers, and the temperature of the preheating rollers is gradually increased in the advancing direction of the composition laminate, and the preheating temperature is 125 ℃. The preheated composite laminate is stretched by a plurality of stretching rollers in the advancing direction by means of the difference of rotating speed, and the working temperature of a longitudinal stretching area is 120 ℃. The longitudinally stretched composite laminate was then set at 132 ℃.
Transversely pulling: the composite laminate after longitudinal drawing is preheated at an operating temperature of 170 ℃ of the heat exchanger, and the temperature of the heat exchanger is gradually decreased in the advancing direction of the composite laminate. The preheated composite laminate was drawn in the transverse direction, and the working temperature in the transverse drawing zone was 156 ℃. Shaping the transversely stretched composite laminate at 172 deg.C, and air-cooling the shaped composite laminate to 30 deg.C. The composite laminate was thus stretched transversely to 9 meters to form a film.
A traction rolling step: and cooling the biaxially oriented film to 20 ℃ by a second cooling roller, and winding by a traction device.
Through the manufacturing process, the whole thickness of the manufactured synthetic paper is 80 micrometers, wherein the thicknesses of the first surface layer and the second surface layer are respectively 4 micrometers and 2 micrometers, the thicknesses of the first surface layer and the second surface layer are both 6 micrometers, and the density of the synthetic paper is 0.80g/cm3The surface roughness (Ra value) of the first surface layer 1 of the synthetic paper is less than 0.100 μm.
Technical parameter comparison table
Figure BDA0001743054380000131
The embodiments of the present invention have been described above. However, the present invention is not limited to the above embodiment. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. A synthetic paper, has multilayer stack composite construction, includes first top layer, second top layer and sandwich layer, the sandwich layer sets up between first top layer and second top layer its characterized in that: the integral thickness of the synthetic paper is 60-300 microns, the thickness of the first surface layer is 5-30 microns, the surface roughness of the first surface layer of the synthetic paper is less than 0.100 micron, and the raw material of the core layer comprises homopolymerized polypropylene and one or more thermoplastic resins used as organic foaming materials.
2. The synthetic paper as recited in claim 1, wherein: the foaming material is one or more of polyethylene terephthalate, polybutylene terephthalate, polyamide resin and polystyrene.
3. The synthetic paper as claimed in claim 1 or 2, characterized in that: the core layer comprises 5-30 wt% of organic foaming material, 0-15 wt% of titanium dioxide, 0-10 wt% of migration antistatic agent and the balance of homopolymerized polypropylene.
4. The synthetic paper as recited in claim 3, wherein: the raw material of the first surface layer comprises homopolymerized polypropylene, copolymerized polypropylene or a mixture of the homopolymerized polypropylene and the copolymerized polypropylene, and the weight ratio of the homopolymerized polypropylene to the copolymerized polypropylene in the mixture is 1:4 to 4: 1.
5. The synthetic paper as recited in claim 4, wherein: the raw material of the first skin layer further includes a non-migrating antistatic agent in an amount of not more than 40% by weight.
6. The synthetic paper as recited in claim 4, wherein: the raw material of the second surface layer comprises homopolymerized polypropylene, copolymerized polypropylene or a mixture of the homopolymerized polypropylene and the copolymerized polypropylene, and the weight ratio of the homopolymerized polypropylene to the copolymerized polypropylene in the mixture is 1:4 to 4: 1.
7. The synthetic paper as recited in claim 6, wherein: the raw material of the second surface layer also comprises polyethylene and 0-40 wt% of non-migratory antistatic agent, wherein the weight ratio of homo-polypropylene, co-polypropylene or the mixture of homo-polypropylene and co-polypropylene to the polyethylene in the raw material of the second surface layer is 1:3 to 3: 1.
8. The synthetic paper as recited in claim 7, wherein: the thickness of the first surface layer of the synthetic paper is 10-20 microns, the surface roughness of the first surface layer is less than 0.050 micron, the thickness of the second surface layer is 5-30 microns, the overall thickness of the synthetic paper is 170-220 microns, and the density of the synthetic paper is 0.55-0.90g/cm3。
9. The synthetic paper as recited in claim 8, wherein: the synthetic paper has a three-layer superposed composite structure and comprises a first surface layer, a second surface layer and a core layer.
10. The synthetic paper as recited in claim 8, wherein: the synthetic paper has a five-layer superposed composite structure and comprises a first surface layer, a core layer, a second surface layer and a second surface layer, wherein the first surface layer is arranged between the core layer and the first surface layer, the second surface layer is arranged between the core layer and the second surface layer, the thicknesses of the first surface layer and the second surface layer are 3-15 micrometers, the synthetic paper comprises 0-15% by weight of titanium dioxide, 0-40% by weight of non-migratory antistatic agent, and the balance is homopolymerized polypropylene.
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