CN110743766A - Natural gas pipeline corrosion prevention method - Google Patents

Natural gas pipeline corrosion prevention method Download PDF

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Publication number
CN110743766A
CN110743766A CN201911084986.4A CN201911084986A CN110743766A CN 110743766 A CN110743766 A CN 110743766A CN 201911084986 A CN201911084986 A CN 201911084986A CN 110743766 A CN110743766 A CN 110743766A
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Prior art keywords
graphene
coating
pipeline
parts
thickness
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CN201911084986.4A
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Chinese (zh)
Inventor
赵海阳
李�灿
刘建
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Jiangsu Kedun Testing Technology Co Ltd
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Jiangsu Kedun Testing Technology Co Ltd
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Priority to CN201911084986.4A priority Critical patent/CN110743766A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/22Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes
    • B05D7/222Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes of pipes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/58No clear coat specified
    • B05D7/582No clear coat specified all layers being cured or baked together
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/106Anti-corrosive paints containing metal dust containing Zn
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2254/00Tubes
    • B05D2254/04Applying the material on the interior of the tube
    • B05D2254/06Applying the material on the interior and exterior of the tube
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2504/00Epoxy polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2507/00Polyolefins
    • B05D2507/01Polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00Inorganic fillers
    • B05D2601/20Inorganic fillers used for non-pigmentation effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00Inorganic fillers
    • B05D2601/20Inorganic fillers used for non-pigmentation effect
    • B05D2601/28Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0893Zinc

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses an underground gas pipeline anticorrosion method, which is characterized in that an anticorrosion layer is arranged inside and outside a pipeline, the anticorrosion effect of the pipeline is improved, the anticorrosion layer uses a graphene primer coating and a graphene finish coating, so that corrosive media (such as water, oxygen, acid, alkali, salt and the like) can be effectively isolated from protected metal, corrosion is prevented, zinc powder is doped in the graphene primer coating, the pipeline is protected by a cathode, and a polyethylene protective layer can reduce the damage of the external coating of the pipeline.

Description

Natural gas pipeline corrosion prevention method
Technical Field
The invention relates to the field of pipeline corrosion prevention, in particular to a natural gas pipeline corrosion prevention method.
Background
The gas pipeline is mainly made of carbon steel materials, and the conveyed gas contains a small amount of corrosive impurities such as water, carbon dioxide, hydrogen sulfide gas and the like, so that the inner wall of the pipeline is corroded after long-time action; the outside of the buried pipeline is corroded due to the action of water, acid, alkali, salt, mineral substances, microorganisms and stray current in soil; corrosion of pipelines causes damage to equipment and accidents, such as fire, explosion, gas leakage, etc., and besides economic loss and environmental damage, life is sometimes injured, so that high attention must be paid to corrosion.
At present, the common method for pipeline corrosion prevention is to add an anticorrosive coating and add cathodic protection, the common external anticorrosive coating is mainly a three-layer polyethylene anticorrosive coating (3PE), but the adhesion between the anticorrosive coating and the outer wall of the pipeline is not enough, so that the anticorrosive coating falls off, and the corrosion of the steel pipe is accelerated; therefore, the pipeline can be additionally provided with a cathode protection device, so that the corrosion of the protected pipeline is slowed down as a cathode in the electrochemical cell, but the cathode protection effect is difficult to achieve due to the problems of improper installation, improper maintenance of the test pile and the like, and the installation and maintenance cost is high.
Disclosure of Invention
The invention aims to provide an underground gas pipeline anticorrosion method which has the advantages of good anticorrosion effect, low use cost, cathode protection effect and internal and external anticorrosion aiming at the defects of the prior art.
The technical scheme adopted by the invention is as follows: a natural gas pipeline corrosion prevention method mainly comprises the following steps:
(1) and polishing, cleaning and drying the inner surface of the pipeline, uniformly coating a second graphene primer coating on the inner surface of the pipeline with the thickness of 0.05mm, coating a second graphene finish coating on the second graphene primer coating with the thickness of 0.1mm after a period of time, and finally curing at room temperature to form the inner anticorrosive coating of the pipeline. (2) Polishing, cleaning and drying the outer surface of the pipeline, uniformly coating the first graphene primer coating on the outer surface of the pipeline with the thickness of 0.05mm, coating the first graphene finish coating on the first graphene primer coating with the thickness of 0.1mm after a period of time, then adding a polyethylene protective layer on the second graphene finish coating with the thickness of 1.5mm, and finally curing at room temperature to form the outer-pipeline anticorrosion coating.
The preparation method of the graphene primer coating comprises the following steps: uniformly stirring fillers such as epoxy resin, zinc powder and graphene powder in a dispersing device according to a certain proportion, then adding other auxiliaries and solvents, grinding to a certain fineness by using a grinder, and filtering to obtain the graphene primer coating;
the preparation method of the graphene finish paint comprises the following steps: uniformly stirring epoxy resin, mica iron oxide and graphene powder filler in a dispersing device according to a certain proportion, then adding other auxiliaries and solvents, grinding to a certain fineness by using a grinding machine, and filtering to obtain a finish paint;
the graphene primer coating comprises the following components: 25-35 parts of epoxy resin, 30-50 parts of zinc powder, 1-2 parts of graphene powder and 15-20 parts of other auxiliaries and solvents;
the graphene finish paint comprises the following components: 35-45 parts of epoxy resin, 20-40 parts of mica iron oxide, 1-3 parts of graphene powder and 20-30 parts of other auxiliaries and solvents;
the thickness of the graphene primer coating is 0.05-0.06mm, the thickness of the graphene finish coating is 0.1-0.2mm, and the thickness of the polyethylene protective layer is 1-2 mm;
the invention has the beneficial effects that:
(1) the graphene primer coating is doped with zinc powder with the self-corrosion potential more negative than that of the metal pipeline, and the zinc powder contained in the coating is preferentially corroded as an anode in the corrosion process, so that the generation and development of the corrosion reaction of the metal pipeline are delayed, and the metal pipeline is effectively protected;
(2) the graphene primer coating and the graphene finish coating have better comprehensive protection performance, and can effectively improve the physical shielding effect and isolate corrosive media (such as water, oxygen, salt mist and the like) from protected metal, thereby preventing the formation of a corrosion battery or inhibiting the diffusion of the corrosion battery;
(3) the polyethylene protective layer can protect the external coating of the pipeline, and the damage of the graphene coating caused by artificial factors in the pipeline installation process is effectively reduced;
(4) the method has the advantages that the anticorrosive layer is arranged inside and outside the pipeline, the pipeline protection effect is improved, the corrosion is reduced, the anticorrosive effect is enhanced, the use cost is reduced, and the practicability is high.
Drawings
FIG. 1: the cross section of the pipeline anticorrosive coating is schematic.
In the figure, 1-pipeline, 2-graphene primer coating I, 3-graphene finishing coating I, 4-polyethylene protective layer, 5-graphene primer coating II and 6-graphene finishing coating II.
Detailed Description
The invention is described in detail below with reference to the following figures and specific examples:
a method of corrosion protection of a natural gas pipeline, comprising:
(1) and (2) polishing, cleaning and drying the inner surface of the pipeline 1, uniformly coating a second graphene primer coating 5 on the inner surface of the pipeline 1 to a thickness of 0.05mm, coating a second graphene finish coating 6 on the second graphene primer coating 5 to a thickness of 0.1mm after a period of time, and finally curing at room temperature to form an inner anticorrosive layer of the pipeline.
(2) The outer surface of the pipeline 1 is polished, cleaned and dried, the first graphene primer coating 2 is uniformly coated on the outer surface of the pipeline 1, the thickness of the first graphene primer coating 2 is 0.05mm, after a period of time, the first graphene finish coating 3 is coated on the first graphene primer coating 2, the thickness of the first graphene primer coating is 0.1mm, then the second graphene finish coating 3 is added with a polyethylene protective layer 4, the thickness of the second graphene finish coating is 1.5mm, and finally the second graphene primer coating is cured at room temperature to form the pipeline outer anticorrosion.
Preparing a graphene primer coating: uniformly stirring 30 parts of epoxy resin, 45 parts of zinc powder and 1 part of graphene powder in a dispersing device, then adding 24 parts of other auxiliary agents and solvents, grinding to a certain fineness by using a grinder, and filtering to obtain the graphene primer coating;
preparing a graphene finish coating: uniformly stirring 40 parts of epoxy resin, 30 parts of mica iron oxide and 2 parts of graphene powder in a dispersing device, then adding 28 parts of other auxiliary agents and solvents, grinding to a certain fineness by using a grinder, and filtering to obtain a finish paint;
although the preferred embodiments of the present patent have been described in detail, the present patent is not limited to the above embodiments, and various changes can be made without departing from the spirit of the present patent within the knowledge of those skilled in the art.

Claims (4)

1. The natural gas pipeline corrosion prevention method is characterized by comprising the following steps of:
(1) polishing, cleaning and drying the inner surface of the pipeline, uniformly coating a second graphene primer coating on the inner surface of the pipeline with the thickness of 0.05mm, coating a second graphene finish coating on the second graphene primer coating with the thickness of 0.1mm after a period of time, and finally curing at room temperature to form an inner anti-corrosion layer of the pipeline;
(2) polishing, cleaning and drying the outer surface of the pipeline, uniformly coating the first graphene primer coating on the outer surface of the pipeline with the thickness of 0.05mm, coating the first graphene finish coating on the first graphene primer coating with the thickness of 0.1mm after a period of time, then adding a polyethylene protective layer on the second graphene finish coating with the thickness of 1.5mm, and finally curing at room temperature to form the outer-pipeline anticorrosion coating.
2. The natural gas pipeline corrosion prevention method according to claim 1, characterized in that the graphene primer coating is prepared by the following components in proportion: 25-35 parts of epoxy resin, 30-50 parts of zinc powder, 1-2 parts of graphene powder and 15-20 parts of other auxiliaries and solvents.
3. The natural gas pipeline corrosion prevention method according to claim 1, characterized in that the graphene topcoat coating is prepared by the following components in proportion: 35-45 parts of epoxy resin, 20-40 parts of mica iron oxide, 1-3 parts of graphene powder and 20-30 parts of other auxiliaries and solvents.
4. The natural gas pipeline corrosion prevention method according to claim 1, wherein the thickness of the graphene primer coating is 0.05-0.06mm, the thickness of the graphene finish coating is 0.1-0.2mm, and the thickness of the polyethylene protective layer is 1-2 mm.
CN201911084986.4A 2019-11-08 2019-11-08 Natural gas pipeline corrosion prevention method Pending CN110743766A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112538816A (en) * 2020-12-22 2021-03-23 沈阳建筑大学 Be applied to marine building's novel anticorrosive steel pipe concrete pier that excels in
CN116475045A (en) * 2022-12-31 2023-07-25 中国铁塔股份有限公司荆门市分公司 Graphene heavy anti-corrosion coating rust removal method based on surface of iron tower steel structure

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6057002A (en) * 1995-11-14 2000-05-02 E. Wood Limited Pipe-coating method and product
CN1597140A (en) * 2004-09-27 2005-03-23 大庆油田建设集团 External anticorrusion layer opening mending method for polyethylene anti corrusion pipeline
KR101561968B1 (en) * 2014-05-12 2015-10-20 이성식 Method for manufacturing steel pipe coating material comprising graphene and sacrificial metal, method for manufacturing coating steel pipe using the same and coating steel pipe by the same
CN105419437A (en) * 2015-12-24 2016-03-23 中国科学院海洋研究所 Supporting anti-corrosive coating modified by graphene, preparation and application thereof
CN105778134A (en) * 2014-12-24 2016-07-20 中国科学院宁波材料技术与工程研究所 Graphene composite polymeric film material and preparation method thereof
CN106337977A (en) * 2016-11-11 2017-01-18 大庆市盛日石油技术开发有限公司 Lubricant, wear-resistant and anti-corrosion graphene pipe and preparation process thereof
CN108561679A (en) * 2018-03-30 2018-09-21 长江大学 A kind of anti-corrosion tubing and casing and preparation method thereof
CN109554064A (en) * 2017-09-25 2019-04-02 上海梅山钢铁股份有限公司 A kind of weather-proof anti-corrosion corrosion-inhibiting coating and preparation method thereof for steel structure surface

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6057002A (en) * 1995-11-14 2000-05-02 E. Wood Limited Pipe-coating method and product
CN1597140A (en) * 2004-09-27 2005-03-23 大庆油田建设集团 External anticorrusion layer opening mending method for polyethylene anti corrusion pipeline
KR101561968B1 (en) * 2014-05-12 2015-10-20 이성식 Method for manufacturing steel pipe coating material comprising graphene and sacrificial metal, method for manufacturing coating steel pipe using the same and coating steel pipe by the same
CN105778134A (en) * 2014-12-24 2016-07-20 中国科学院宁波材料技术与工程研究所 Graphene composite polymeric film material and preparation method thereof
CN105419437A (en) * 2015-12-24 2016-03-23 中国科学院海洋研究所 Supporting anti-corrosive coating modified by graphene, preparation and application thereof
CN106337977A (en) * 2016-11-11 2017-01-18 大庆市盛日石油技术开发有限公司 Lubricant, wear-resistant and anti-corrosion graphene pipe and preparation process thereof
CN109554064A (en) * 2017-09-25 2019-04-02 上海梅山钢铁股份有限公司 A kind of weather-proof anti-corrosion corrosion-inhibiting coating and preparation method thereof for steel structure surface
CN108561679A (en) * 2018-03-30 2018-09-21 长江大学 A kind of anti-corrosion tubing and casing and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112538816A (en) * 2020-12-22 2021-03-23 沈阳建筑大学 Be applied to marine building's novel anticorrosive steel pipe concrete pier that excels in
CN116475045A (en) * 2022-12-31 2023-07-25 中国铁塔股份有限公司荆门市分公司 Graphene heavy anti-corrosion coating rust removal method based on surface of iron tower steel structure

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Application publication date: 20200204