CN110734707A - practical environment-friendly cleaning adhesive tape - Google Patents

practical environment-friendly cleaning adhesive tape Download PDF

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Publication number
CN110734707A
CN110734707A CN201910916099.2A CN201910916099A CN110734707A CN 110734707 A CN110734707 A CN 110734707A CN 201910916099 A CN201910916099 A CN 201910916099A CN 110734707 A CN110734707 A CN 110734707A
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CN
China
Prior art keywords
environment
practical
friendly cleaning
layer
rubber
Prior art date
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Pending
Application number
CN201910916099.2A
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Chinese (zh)
Inventor
龙治香
光忠明
周晓南
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Jiangsu Jinghua New Materials Technology Co Ltd
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Jiangsu Jinghua New Materials Technology Co Ltd
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Priority to CN201910916099.2A priority Critical patent/CN110734707A/en
Publication of CN110734707A publication Critical patent/CN110734707A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J107/00Adhesives based on natural rubber
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J109/00Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09J109/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C09J161/14Modified phenol-aldehyde condensates
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J193/00Adhesives based on natural resins; Adhesives based on derivatives thereof
    • C09J193/04Rosin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/26Presence of textile or fabric
    • C09J2400/263Presence of textile or fabric in the substrate

Abstract

The invention provides practical environment-friendly cleaning adhesive tapes, which comprise a release layer, an adhesive layer and a substrate layer which are sequentially arranged, wherein the preparation raw materials of the adhesive layer comprise, by weight, 30-45% of rubber, 20-35% of resin, 1-3% of an anti-aging agent, 1-3% of a softening agent and 30-45% of a solvent.

Description

practical environment-friendly cleaning adhesive tape
Technical Field
The invention relates to adhesive tapes, in particular to cleaning adhesive tapes.
Background
The floor and the wall at home have stubborn garbage such as chewing gum, cobweb, hair and the like or difficult-to-clean parts such as corners and bed bottoms, a mop used by people can not be completely cleaned normally, water stains can be left on the floor to moisten the indoor, although the floor sweeping robot on the market can avoid points, the floor sweeping robot can only suck dust on the floor, the cleaning efficiency or the cleaning efficiency of large-size garbage and cobwebs at hidden dead corners such as walls and bed sides is not high, and the cleaning adhesive tape can be used for assisting the cleaning tool to clean the parts which are difficult to clean by the cleaning tool.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides practical environment-friendly cleaning adhesive tapes, which have fixed viscosity, can adhere to stains which are difficult to clean, and have small size and soft material, so that corners which are difficult to clean can be cleaned.
The technical scheme adopted by the invention is as follows:
practical environment-friendly cleaning adhesive tape comprises a release layer, an adhesive layer and a substrate layer which are sequentially arranged, wherein the raw materials for preparing the adhesive layer comprise the following components in percentage by weight:
Figure BDA0002215963320000011
further , the weight ratio of resin to rubber is 0.5-0.75.
the rubber is smoked sheet rubber and/or styrene-butadiene rubber, and the rubber is added to give good cohesion to the adhesive.
the resin is or more of hydrogenated rosin resin, terpene phenolic resin and aliphatic petroleum resin, and the addition of the resin can endow the adhesive with high stripping force and high initial viscosity.
, the anti-aging agent is zinc dibutyl dithiocarbamate and/or 2, 6-di-tert-butyl-p-cresol, and can effectively relieve the phenomenon that the adhesive tape is obviously aged due to the influence of oxygen, ultraviolet and other factors in the air.
, the softener is or more of liquid styrene butadiene rubber, liquid polyisobutylene and liquid nitrile butadiene rubber, and the softener can effectively reduce the bulk viscosity of the rubber and improve the initial viscosity of the rubber.
, the substrate layer is a non-woven fabric layer.
, the non-woven fabric has a tensile strength greater than 50 MPa.
, the adhesive layer has a thickness of 15-40 μm.
, the release layer is glassine release paper which is environment-friendly and degradable.
The invention has the beneficial effects that:
according to the invention, natural rubber and synthetic resin are combined as raw materials in a specific ratio, so that the prepared adhesive can effectively improve the holding viscosity, stripping force and initial viscosity of an adhesive layer, and can effectively adsorb various dirt; the high-strength non-woven fabric is used as the substrate layer, so that the substrate cannot be damaged when the cleaning adhesive tape is peeled off after being attached, and parts which are difficult to clean by cleaning tools such as a broom, a mop and a sweeping robot can be effectively cleaned.
Detailed Description
In order to fully understand the technical contents of the present invention, the technical solution of the present invention will be further described and illustrated by specific examples.
In the following description, "%" and "part" representing amounts are based on weight unless otherwise specified. Unless otherwise indicated, all numbers expressing feature sizes, quantities, and physical characteristics used in the specification and claims are to be understood as being modified in all instances by the term "about". Accordingly, unless indicated to the contrary, the numerical parameters set forth in the foregoing specification and attached claims are approximations that can be suitably varied by those skilled in the art in seeking to obtain the desired properties utilizing the teachings disclosed herein. The use of numerical ranges by endpoints includes all numbers within that range and any range within that range, for example, 1 to 5 includes 1, 1.2, 1.4, 1.55, 2, 2.75, 3, 3.80, 4, and 5, and the like.
It should also be noted that the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises the series of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus, and the term "preferably" refers to a preferred alternative but is not limited to only the selected alternative.
A release layer: can be glassine release paper, PEK release paper, CCK release paper and SCK release paper, and can also be PET release film, PVC release film, PE release film, OPP release film, PC release film, PS release film, PMMA release film, BOPP release film, TPX release film, PTFE release film, monosilicon release film, polyester release film, Teflon release film, polyphenyl ether release film, polytetrafluoroethylene release film and the like; preferably degradable glassine release paper; the thickness of the release layer is not particularly limited.
The adhesive layer is formed by preparing raw materials of an adhesive, wherein the raw materials comprise, by weight, 30-45% of rubber, 20-35% of resin, 1-3% of an anti-aging agent, 1-3% of a softening agent and 30-45% of a solvent, wherein the rubber is preferably smoked sheet rubber and/or styrene butadiene rubber, the natural rubber is selected to endow the adhesive with good cohesive force, so that the adhesive holding property of an adhesive layer is improved, the resin is preferably or more of hydrogenated rosin resin, terpene phenolic resin and aliphatic petroleum resin, the resin is selected to endow the adhesive layer with good stripping property and high initial viscosity, the anti-aging agent is preferably zinc dibutyldithiocarbamate and/or 2, 6-di-tert-butyl-p-cresol, the softening agent is preferably or more of liquid styrene butadiene rubber, liquid polyisobutylene and liquid butadiene-acrylonitrile rubber, the solvent is preferably toluene, and steps are carried out, and the weight ratio of the resin to the rubber is preferably 0.5-0.75.
Substrate layer: may be a film such as a film formed of polyvinyl chloride (PVC), Polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), polytetrafluoroethylene (ptfe) or a composite thereof; or fabrics and flannelette, such as fabrics and flannelette made of cotton, viscose and PET; it may also be a paper-like substrate; the non-woven fabric with the tensile strength of more than 50MPa is preferred to ensure that the base material cannot be damaged when the adhesive tape is peeled off after being attached.
Examples
1. The weight percentages of the raw materials for preparing the adhesive in each example are as follows:
note: comparative examples 1-2 compared with examples 1-8, the weight ratio of resin to rubber in comparative examples 1-2 was not within the optimum ratio range of 0.5-0.75.
2. The specific components of the raw materials in each example are as follows:
Figure BDA0002215963320000042
Figure BDA0002215963320000051
note: when a material contains multiple components, the weight of each component is equal.
3. Preparation of the Adhesives
The formulations of the above examples were prepared according to the following preparation method:
step 1, plasticating the smoked sheet rubber to -nylon viscosity of 55, and cutting the styrene butadiene rubber into blocks for later use;
step 2: adding the solvent into a stirring reaction kettle according to the formula amount, starting stirring, then adding the anti-aging agent and the softening agent, and stirring for 25 minutes;
and step 3: adding the prepared smoked sheet rubber and styrene butadiene rubber, stirring for 40 minutes, adding the resin, and stirring for 8 hours;
and 4, step 4: stopping stirring, cooling the stirring reaction kettle to below 45 ℃, and discharging to obtain the adhesive.
4. Preparation of adhesive tapes
Step 1, selecting a base material (non-woven fabric) and release paper (glassine release paper), and pre-coating a layer of an adhesive film layer with the thickness of 15-50 microns (preferably 25-40 microns) on th release paper;
step 2: setting the temperature value range of the electrothermal blowing drying box to be 60-100 ℃, and setting the electrothermal blowing drying box to be a plurality of sections of drying areas with different temperatures;
and step 3: enabling the release paper with the adhesive layer to pass through an electrothermal blowing drying oven according to the speed of 30m/min, and enabling the adhesive layer to complete a crosslinking reaction;
step 4, after drying, cooling, and transferring and attaching the adhesive film pre-coated on the th release paper to the surface of the base material;
and 5, repeating the steps 1-4, transferring and adhering the adhesive film layer pre-coated on the second piece of release paper to the other surfaces of the non-woven fabric, and recovering the second piece of release paper to obtain the adhesive tape.
5. Test of adhesive tape Properties
The cleaning tapes prepared in examples 1 to 8 were tested for initial adhesion according to the standard PSTC-6(14#) rolling ball method; testing 180-degree peel strength of the adhesive layer according to the standard PSTC-101; the adhesive layer was tested for tack at ambient temperature according to standard PSTC-107. The test results are given in the following table:
Figure BDA0002215963320000061
as can be seen from the above table, when the ratio of the weight of the resin to the weight of the rubber in the raw materials is between 0.5 and 0.75, the obtained adhesive tape has better performance.
In conclusion, the practical environment-friendly cleaning adhesive tape provided by the invention has good initial adhesion, peeling strength and adhesive holding performance
It is true that the above-described embodiments are only preferred embodiments of the present invention, and any other embodiments that do not exceed the scope of the present invention are also included in the present invention.
Although the preferred embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims.

Claims (10)

  1. The practical environment-friendly cleaning adhesive tape is characterized by comprising a release layer, an adhesive layer and a base material layer which are sequentially arranged, wherein the adhesive layer is prepared from the following raw materials in percentage by weight:
    Figure FDA0002215963310000011
  2. 2. the practical and environment-friendly cleaning tape as claimed in claim 1, wherein the weight ratio of the resin to the rubber is 0.5-0.75.
  3. 3. The practical environment-friendly cleaning adhesive tape according to claim 1 or 2, wherein the rubber is smoked sheet rubber and/or styrene butadiene rubber.
  4. 4. The practical and environment-friendly type cleaning tape according to claim 1 or 2, wherein the resin is or more of hydrogenated rosin resin, terpene phenolic resin and aliphatic petroleum resin.
  5. 5. The practical and environment-friendly cleaning tape as claimed in claim 1, wherein the anti-aging agent is zinc dibutyldithiocarbamate and/or 2, 6-di-tert-butyl-p-cresol.
  6. 6. The practical environment-friendly cleaning tape as claimed in claim 1, wherein the softener is or more of liquid styrene butadiene rubber, liquid polyisobutylene and liquid nitrile butadiene rubber.
  7. 7. The practical environment-friendly cleaning tape as claimed in claim 1, wherein the substrate layer is a non-woven fabric layer.
  8. 8. The practical and environment-friendly cleaning tape as claimed in claim 6, wherein the tensile strength of the non-woven fabric is greater than 50 MPa.
  9. 9. The practical and environment-friendly cleaning tape according to claim 1, wherein the thickness of the adhesive layer is 15-40 μm.
  10. 10. The practical and environment-friendly cleaning tape as claimed in claim 1, wherein the release layer is glassine release paper.
CN201910916099.2A 2019-09-26 2019-09-26 practical environment-friendly cleaning adhesive tape Pending CN110734707A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115216253A (en) * 2022-05-13 2022-10-21 嘉好(太仓)新材料股份有限公司 Special structural adhesive for surgical gown and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109306252A (en) * 2017-07-28 2019-02-05 安徽屹珹新材料科技有限公司 A kind of adhesive layer and its preparation method and application for adhesive tape

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109306252A (en) * 2017-07-28 2019-02-05 安徽屹珹新材料科技有限公司 A kind of adhesive layer and its preparation method and application for adhesive tape

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115216253A (en) * 2022-05-13 2022-10-21 嘉好(太仓)新材料股份有限公司 Special structural adhesive for surgical gown and preparation method thereof
CN115216253B (en) * 2022-05-13 2024-01-16 嘉好(太仓)新材料股份有限公司 Structural adhesive special for surgical gown and preparation method thereof

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