CN110699719B - Method for preparing compact electrophoretic coating on surface of magnesium alloy - Google Patents
Method for preparing compact electrophoretic coating on surface of magnesium alloy Download PDFInfo
- Publication number
- CN110699719B CN110699719B CN201911084743.0A CN201911084743A CN110699719B CN 110699719 B CN110699719 B CN 110699719B CN 201911084743 A CN201911084743 A CN 201911084743A CN 110699719 B CN110699719 B CN 110699719B
- Authority
- CN
- China
- Prior art keywords
- magnesium alloy
- coating
- electrophoretic
- prepared
- electrophoretic coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/42—Electroplating: Baths therefor from solutions of light metals
- C25D3/44—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/20—Pretreatment
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
- C25D5/42—Pretreatment of metallic surfaces to be electroplated of light metals
Abstract
The invention discloses a method for preparing a compact electrophoretic coating on the surface of a magnesium alloy, and belongs to the field of surface treatment of metal materials. The method specifically comprises the following steps: pretreating the magnesium alloy; electroplating aluminum on the ionic liquid on the surface of the magnesium alloy; preparing an electrophoretic coating; and (5) coating electrophoretic paint. Before the electrophoretic coating is coated, an aluminum coating is deposited on the surface of the magnesium alloy in an ionic liquid electroplating mode, and electrophoretic coating is carried out on the prepared aluminum coating, so that the problems of uneven surface potential of the magnesium alloy and easy corrosion of the magnesium alloy in an electrophoretic solution can be effectively solved by the aluminum coating, and the prepared electrophoretic coating is more compact. The preparation method disclosed by the invention is simple and efficient in manufacturing process, has low requirements on the whole experimental process, and the prepared electrophoretic coating on the surface of the magnesium alloy is uniform, compact and flat, so that the magnesium alloy can be effectively protected from being damaged by corrosion. The result of the neutral salt spray test shows that the surface of the magnesium alloy is not corroded after 500 hours in a neutral salt spray environment, and the electrophoretic coating is complete and is not damaged.
Description
Technical Field
The invention belongs to the field of surface treatment of metal materials, and particularly relates to a method for preparing a compact electrophoretic coating on the surface of a magnesium alloy.
Background
Magnesium alloys have been widely used in the fields of aerospace, weaponry, engineering materials, biomaterials, etc. due to their characteristics of small density, high strength and specific stiffness, and excellent electrical and thermal conductivity. However, magnesium is relatively active in chemical property, and the magnesium alloy is extremely easy to corrode due to the lower standard electrode potential. Therefore, how to improve the corrosion resistance of magnesium alloy products has become a hot spot of research in recent years.
The electrophoretic coating is an effective means for preventing metal corrosion, and deposits charged coating particles on the surface of a metal workpiece under the action of an electric field force to form a uniform protective film, thereby achieving excellent corrosion resistance. Theoretically, the electrophoretic coating is coated on the surface of the magnesium alloy, so that the magnesium alloy can be well protected from being damaged by corrosion. However, the electrophoretic coating directly coated on the surface of the magnesium alloy is very loose and has many holes due to the reasons that the surface potential of the magnesium alloy is not uniform, the electrophoretic liquid is easy to cause magnesium alloy corrosion and the like, and the magnesium alloy is difficult to be effectively protected.
Therefore, how to solve the problem of compactness of the electrophoretic coating coated on the surface of the magnesium alloy is the key for realizing that the electrophoretic coating protects the magnesium alloy from corrosion. The present invention has been made to solve the above problems.
Disclosure of Invention
The invention aims to provide a method for preparing a compact electrophoretic coating on the surface of a magnesium alloy, which has simple and efficient manufacturing process.
The purpose of the invention is realized by the following technical scheme:
the invention provides a method for depositing an aluminum coating on the surface of a magnesium alloy by using an ionic liquid electroplating mode before coating an electrophoretic coating, and performing electrophoretic coating on the prepared aluminum coating, wherein the aluminum coating can effectively solve the problems of uneven surface potential of the magnesium alloy and easy corrosion of the magnesium alloy in an electrophoretic solution, so that the prepared electrophoretic coating is uniform and compact, and the magnesium alloy is protected from being damaged by corrosion.
A method for preparing a compact electrophoretic coating on the surface of a magnesium alloy specifically comprises the following steps:
step 1, pretreating magnesium alloy. The magnesium alloy is respectively polished by sand paper of 150 meshes, 400 meshes, 800 meshes and 1200 meshes, is washed clean by deionized water and is put into acetone for 10 minutes by ultrasound. Then, the magnesium alloy is put into an alkali solution prepared from sodium hydroxide, anhydrous sodium carbonate and sodium dodecyl benzene sulfonate, and alkali washing is carried out in a water bath environment at the temperature of 60 ℃.
And 2, electroplating aluminum on the surface of the magnesium alloy by using the ionic liquid. Preparing AlCl with the molar ratio of 2:13-1-butyl-3-methylimidazole(BMIC) solution, using magnesium alloy as cathode, aluminium sheet with purity of 99.99% as anode, the distance between cathode and anode is 1-2 cm. Adopting constant current electrodeposition with current density of 10-15mA/cm2And electroplating aluminum for 30-35 min.
And 3, preparing the electrophoretic paint. The FY-0216 electrophoresis raw material is continuously stirred at room temperature for 48 hours to finish curing.
And 4, coating the electrophoretic paint. Washing the prepared magnesium alloy covered with the aluminum plating layer by using deionized water, and using the magnesium alloy as a cathode, a graphite electrode as an anode, working voltage of 70-100V, electrophoresis time of 2-3 minutes, a distance between the cathode and the anode of 4-5cm, and electrophoretic coating at a solution temperature of 25-30 ℃. The magnesium alloy after electrophoresis is washed clean by deionized water, dried and cured for 20-25 minutes at the temperature of 170-180 ℃.
In step 1, the concentrations of sodium hydroxide, anhydrous sodium carbonate and sodium dodecylbenzenesulfonate were 50g/L, 15g/L and 2g/L, respectively.
In step 2, AlCl is prepared3AlCl when in solution in-1-butyl-3-methylimidazole (BMIC)3Add slowly to BMIC and stir well, all operations were performed at room temperature in a glove box under an argon atmosphere. And after the electroplating is finished, washing the sample with dichloromethane and deionized water, and naturally drying.
In step 3, the electrophoretic material is stirred by magnetic stirring, and the evaporation of water in the material is noted.
In step 4, the area of the graphite electrode is 1/4 of the magnesium alloy electrode, and the electrophoretic solution attached to the surface of the magnesium alloy after electrophoresis must be washed clean by deionized water.
The invention has the beneficial effects that:
the preparation method is simple and efficient in manufacturing process, has low requirements on the whole experimental process, and the prepared magnesium alloy surface electrophoretic coating is uniform, compact and flat. The experimental data were evaluated as follows:
the electrophoretic coating prepared by the method is compared with the electrophoretic coating prepared by directly carrying out electrophoretic coating on the magnesium alloy for observation. The comparison shows that the electrophoretic coating prepared by directly carrying out electrophoretic coating on the magnesium alloy is very loose and has more holes, and the surface of the magnesium alloy-aluminum plating layer-electrophoretic coating prepared by the method is very compact, uniform and flat.
The neutral salt spray test is carried out on the prepared magnesium alloy-aluminum plating layer-electrophoretic coating, and the result shows that the surface of the magnesium alloy is not corroded after 500 hours in a neutral salt spray environment, and the electrophoretic coating is complete and is not damaged.
Drawings
FIG. 1 shows the surface morphology of a magnesium alloy-aluminum plating-electrophoretic coating (a) (taking example 1 as an example) prepared by the method of the present invention and an electrophoretic coating (b) prepared by direct electrophoretic coating of a magnesium alloy;
FIG. 2 is a surface morphology of a magnesium alloy-aluminum plating-electrophoretic coating after 500 hours in a neutral salt spray environment.
Detailed Description
The following further describes embodiments of the present invention with reference to the accompanying drawings:
the magnesium alloy is AZ 91D; acetone, sodium hydroxide, anhydrous sodium carbonate and sodium dodecylbenzenesulfonate were produced by shinko technology development ltd, Tianjin; AlCl3Manufactured by the national drug group chemical reagents limited; 1-butyl-3-methylimidazole (BMIC) ionic liquids are manufactured by Linzhoueneng, Inc.; FY-0216 electrophoretic paint is produced by Feiyang paint Co.
A method for preparing a compact electrophoretic coating on the surface of a magnesium alloy specifically comprises the following steps:
step 1: pretreating the magnesium alloy;
step 2: electroplating aluminum on the ionic liquid on the surface of the magnesium alloy;
and step 3: preparing an electrophoretic coating;
and 4, step 4: and (5) coating electrophoretic paint.
The specific steps of the step 1 are as follows:
step (1.1) polishing the magnesium alloy by using 150-mesh, 400-mesh, 800-mesh and 1200-mesh abrasive paper respectively, washing the magnesium alloy by using deionized water, and putting the magnesium alloy into acetone for ultrasonic treatment for 10 minutes;
and (1.2) putting the magnesium alloy into an alkali liquor prepared from sodium hydroxide, anhydrous sodium carbonate and sodium dodecyl benzene sulfonate, and carrying out alkali washing in a water bath environment at 60 ℃.
The specific steps of the step 2 are as follows: preparing AlCl with the molar ratio of 2:13The 1-butyl-3-methylimidazole (BMIC) solution is prepared by electroplating aluminum by using a magnesium alloy as a cathode and an aluminum sheet with the purity of 99.99% as an anode through constant-current electrodeposition.
The specific steps of the step 3 are as follows: the FY-0216 electrophoresis raw material is continuously stirred at room temperature for 48 hours to finish curing.
The specific steps of the step 4 are as follows:
step (4.1) washing the prepared magnesium alloy covered with the aluminum coating with deionized water and taking the magnesium alloy as a cathode and a graphite electrode as an anode for electrophoretic coating;
and (4.2) washing the magnesium alloy subjected to electrophoresis with deionized water, drying, and curing at the temperature of 170-180 ℃ for 20-25 minutes.
In step 1, the concentrations of sodium hydroxide, anhydrous sodium carbonate and sodium dodecylbenzenesulfonate were 50g/L, 15g/L and 2g/L, respectively.
In step 2, AlCl is prepared3AlCl when in solution in-1-butyl-3-methylimidazole (BMIC)3Slowly adding into BMIC and stirring, and performing all operations in a glove box under argon protective atmosphere at room temperature; the distance between the cathode and the anode is 1-2cm, and the current density is 10-15mA/cm2And the deposition time is 30-35 minutes, and after the electroplating is finished, the sample is washed clean by dichloromethane and deionized water and is naturally air-dried.
In step 3, the electrophoretic raw material is stirred by magnetic stirring.
In step 4, the area of the graphite electrode is 1/4 of the magnesium alloy electrode, the working voltage is 70-100V, the electrophoresis time is 2-3 minutes, the distance between the cathode and the anode is 4-5cm, the solution temperature is 25-30 ℃, and the baking temperature and time are adjusted along with the electrophoresis parameters.
Example 1:
(1) the magnesium alloy is respectively polished by sand paper of 150 meshes, 400 meshes, 800 meshes and 1200 meshes, is washed clean by deionized water and is put into acetone for 10 minutes by ultrasound. 25g of sodium hydroxide, 7.5g of anhydrous sodium carbonate and 1g of sodium dodecyl benzene sulfonate are weighed and dissolved in 500mL of water to prepare an alkali liquor, and then the magnesium alloy is put into the prepared alkali liquor to be subjected to alkali washing in a water bath environment at 60 ℃.
(2) Weighing AlCl3 and 1-butyl-3-methylimidazole (BMIC) according to the molar ratio of 2:1, mixing to prepare a solution, taking magnesium alloy as a cathode, taking an aluminum sheet with the purity of 99.99% as an anode, and setting the distance between the cathode and the anode to be 1 cm. The aluminum was electroplated using constant current electrodeposition at a current density of 10mA/cm2 for a deposition time of 30 minutes.
(3) The FY-0216 electrophoresis raw material is continuously stirred at room temperature for 48 hours to finish curing.
(4) And (3) washing the prepared magnesium alloy covered with the aluminum coating by using deionized water, and taking the magnesium alloy as a cathode, a graphite electrode as an anode, working voltage of 70V, electrophoresis time of 2 minutes, a distance between the cathode and the anode of 4cm, and electrophoretic coating at a solution temperature of 25 ℃. And washing the magnesium alloy subjected to electrophoresis with deionized water, drying in the air, and curing at the temperature of 170 ℃ for 20 minutes.
Example 2:
(1) the magnesium alloy is respectively polished by sand paper of 150 meshes, 400 meshes, 800 meshes and 1200 meshes, is washed clean by deionized water and is put into acetone for 10 minutes by ultrasound. 25g of sodium hydroxide, 7.5g of anhydrous sodium carbonate and 1g of sodium dodecyl benzene sulfonate are weighed and dissolved in 500mL of water to prepare an alkali liquor, and then the magnesium alloy is put into the prepared alkali liquor to be subjected to alkali washing in a water bath environment at 60 ℃.
(2) Weighing AlCl3 and 1-butyl-3-methylimidazole (BMIC) according to the molar ratio of 2:1, mixing to prepare a solution, taking magnesium alloy as a cathode, taking an aluminum sheet with the purity of 99.99% as an anode, and enabling the distance between the cathode and the anode to be 2 cm. The aluminum was electroplated using constant current electrodeposition at a current density of 15mA/cm2 for a deposition time of 30 minutes.
(3) The FY-0216 electrophoresis raw material is continuously stirred at room temperature for 48 hours to finish curing.
(4) And (3) washing the prepared magnesium alloy covered with the aluminum coating by using deionized water, and taking the magnesium alloy as a cathode, a graphite electrode as an anode, a working voltage of 85V, an electrophoresis time of 2.5 minutes, a distance between the cathode and the anode of 4cm, and a solution temperature of 30 ℃ for electrophoretic coating. And washing the magnesium alloy subjected to electrophoresis with deionized water, drying in the air, and curing at the temperature of 170 ℃ for 25 minutes.
Example 3:
(1) the magnesium alloy is respectively polished by sand paper of 150 meshes, 400 meshes, 800 meshes and 1200 meshes, is washed clean by deionized water and is put into acetone for 10 minutes by ultrasound. 25g of sodium hydroxide, 7.5g of anhydrous sodium carbonate and 1g of sodium dodecyl benzene sulfonate are weighed and dissolved in 500mL of water to prepare an alkali liquor, and then the magnesium alloy is put into the prepared alkali liquor to be subjected to alkali washing in a water bath environment at 60 ℃.
(2) Weighing AlCl3 and 1-butyl-3-methylimidazole (BMIC) according to the molar ratio of 2:1, mixing to prepare a solution, taking magnesium alloy as a cathode, taking an aluminum sheet with the purity of 99.99% as an anode, and setting the distance between the cathode and the anode to be 1 cm. The aluminum was electroplated using constant current electrodeposition at a current density of 10mA/cm2 for a deposition time of 35 minutes.
(3) The FY-0216 electrophoresis raw material is continuously stirred at room temperature for 48 hours to finish curing.
(4) And (3) washing the prepared magnesium alloy covered with the aluminum coating by using deionized water, taking the magnesium alloy as a cathode, taking a graphite electrode as an anode, carrying out electrophoretic coating at the working voltage of 100V, the electrophoretic time of 3 minutes, the distance between the cathode and the anode of 5cm and the solution temperature of 25 ℃. And washing the magnesium alloy subjected to electrophoresis with deionized water, drying in the air, and curing at the temperature of 180 ℃ for 25 minutes.
Example 4:
(1) the magnesium alloy is respectively polished by sand paper of 150 meshes, 400 meshes, 800 meshes and 1200 meshes, is washed clean by deionized water and is put into acetone for 10 minutes by ultrasound. 25g of sodium hydroxide, 7.5g of anhydrous sodium carbonate and 1g of sodium dodecyl benzene sulfonate are weighed and dissolved in 500mL of water to prepare an alkali liquor, and then the magnesium alloy is put into the prepared alkali liquor to be subjected to alkali washing in a water bath environment at 60 ℃.
(2) Weighing AlCl3 and 1-butyl-3-methylimidazole (BMIC) according to the molar ratio of 2:1, mixing to prepare a solution, taking magnesium alloy as a cathode, taking an aluminum sheet with the purity of 99.99% as an anode, and enabling the distance between the cathode and the anode to be 2 cm. The aluminum was electroplated using constant current electrodeposition at a current density of 15mA/cm2 for a deposition time of 35 minutes.
(3) The FY-0216 electrophoresis raw material is continuously stirred at room temperature for 48 hours to finish curing.
And carrying out electrophoretic coating at the working voltage of 70V, the electrophoretic time of 3 minutes, the distance between a cathode and an anode of 5cm and the solution temperature of 30 ℃. And washing the magnesium alloy subjected to electrophoresis with deionized water, drying in the air, and curing at the temperature of 180 ℃ for 20 minutes.
Example 5:
(1) the magnesium alloy is respectively polished by sand paper of 150 meshes, 400 meshes, 800 meshes and 1200 meshes, is washed clean by deionized water and is put into acetone for 10 minutes by ultrasound. 25g of sodium hydroxide, 7.5g of anhydrous sodium carbonate and 1g of sodium dodecyl benzene sulfonate are weighed and dissolved in 500mL of water to prepare an alkali liquor, and then the magnesium alloy is put into the prepared alkali liquor to be subjected to alkali washing in a water bath environment at 60 ℃.
(2) Weighing AlCl3 and 1-butyl-3-methylimidazole (BMIC) according to the molar ratio of 2:1, mixing to prepare a solution, taking magnesium alloy as a cathode, taking an aluminum sheet with the purity of 99.99% as an anode, and setting the distance between the cathode and the anode to be 1 cm. The aluminum was electroplated using constant current electrodeposition at a current density of 10mA/cm2 for a deposition time of 30 minutes.
(3) The FY-0216 electrophoresis raw material is continuously stirred at room temperature for 48 hours to finish curing.
(4) And (3) washing the prepared magnesium alloy covered with the aluminum coating by using deionized water, and taking the magnesium alloy as a cathode, a graphite electrode as an anode, a working voltage of 85V, an electrophoresis time of 2.5 minutes, a distance between the cathode and the anode of 4cm, and a solution temperature of 25 ℃ for electrophoretic coating. And washing the magnesium alloy subjected to electrophoresis with deionized water, drying in the air, and curing at the temperature of 180 ℃ for 20 minutes.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (1)
1. A method for preparing a compact electrophoretic coating on the surface of a magnesium alloy is characterized by comprising the following steps:
step 1: pretreating the magnesium alloy;
step 2: electroplating aluminum on the ionic liquid on the surface of the magnesium alloy;
and step 3: preparing an electrophoretic coating;
and 4, step 4: coating electrophoretic paint;
the specific steps of the step 1 are as follows:
step (1.1) polishing the magnesium alloy by using 150-mesh, 400-mesh, 800-mesh and 1200-mesh abrasive paper respectively, washing the magnesium alloy by using deionized water, and putting the magnesium alloy into acetone for ultrasonic treatment for 10 minutes;
step (1.2) putting the magnesium alloy into an alkali liquor prepared from sodium hydroxide, anhydrous sodium carbonate and sodium dodecyl benzene sulfonate, and carrying out alkali washing in a water bath environment at 60 ℃;
the specific steps of the step 2 are as follows: preparing AlCl with the molar ratio of 2:13The 1-butyl-3-methylimidazole chloride solution is prepared by electroplating aluminum by using a magnesium alloy as a cathode and an aluminum sheet with the purity of 99.99 percent as an anode through constant-current electrodeposition;
the specific steps of the step 3 are as follows: continuously stirring the FY-0216 electrophoresis raw material at room temperature for 48 hours to finish curing;
the specific steps of the step 4 are as follows:
step (4.1) washing the prepared magnesium alloy covered with the aluminum coating with deionized water and taking the magnesium alloy as a cathode and a graphite electrode as an anode for electrophoretic coating;
washing the magnesium alloy subjected to electrophoresis in the step (4.2) with deionized water, drying, and curing at the temperature of 170-180 ℃ for 20-25 minutes;
in the step 1, the concentrations of sodium hydroxide, anhydrous sodium carbonate and sodium dodecyl benzene sulfonate are respectively 50g/L, 15g/L and 2 g/L;
in step 2, AlCl is prepared3Chlorination of 1-butyl-3-methylimidazole with AlCl3Slowly adding into BMIC and stirring, and performing all operations in a glove box under argon protective atmosphere at room temperature; the distance between the cathode and the anode is 1-2cm, and the current density is 10-15mA/cm2Depositing for 30-35 min, washing the sample with dichloromethane and deionized water after electroplating, and naturally drying;
in the step 3, the electrophoretic raw material is stirred in a magnetic stirring mode;
in step 4, the area of the graphite electrode is 1/4 of the magnesium alloy electrode, the working voltage is 70-100V, the electrophoresis time is 2-3 minutes, the distance between the cathode and the anode is 4-5cm, the solution temperature is 25-30 ℃, and the baking temperature and time are adjusted along with the electrophoresis parameters.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911084743.0A CN110699719B (en) | 2019-11-08 | 2019-11-08 | Method for preparing compact electrophoretic coating on surface of magnesium alloy |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201911084743.0A CN110699719B (en) | 2019-11-08 | 2019-11-08 | Method for preparing compact electrophoretic coating on surface of magnesium alloy |
Publications (2)
Publication Number | Publication Date |
---|---|
CN110699719A CN110699719A (en) | 2020-01-17 |
CN110699719B true CN110699719B (en) | 2021-10-26 |
Family
ID=69204627
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201911084743.0A Active CN110699719B (en) | 2019-11-08 | 2019-11-08 | Method for preparing compact electrophoretic coating on surface of magnesium alloy |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN110699719B (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112941497B (en) * | 2021-01-27 | 2023-12-12 | 哈尔滨工程大学 | Preparation method of rapid self-repairing system based on magnesium alloy protective layer |
CN117587487B (en) * | 2024-01-18 | 2024-04-02 | 南京海创表面处理技术有限公司 | High-precision magnesium alloy workpiece surface electroplating equipment and control method |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1737205A (en) * | 2005-07-19 | 2006-02-22 | 郑州大学 | Surface treatment method for magnesium alloy |
CN101147696A (en) * | 2006-09-21 | 2008-03-26 | 张天平 | Method for manufacturing concealed holding groove and concealed tooth arch string |
CN102888630A (en) * | 2011-07-20 | 2013-01-23 | 中国科学院过程工程研究所 | Method for preparing nanometer aluminum or nanometer aluminum coating in low-temperature electro-deposition form by using ion liquid/additive system |
EP2573214A1 (en) * | 2011-09-22 | 2013-03-27 | Sikorsky Aircraft Corporation | Protection of magnesium alloys by aluminum plating from ionic liquids |
CN108517544A (en) * | 2018-06-14 | 2018-09-11 | 中国兵器工业第五九研究所 | The method of Mg alloy surface processing il electrolyte and magnesium alloy before electroplating of aluminium |
CN108716011A (en) * | 2018-06-19 | 2018-10-30 | 哈尔滨工程大学 | A method of improving aluminium coat and Mg alloy surface binding force |
CN109628980A (en) * | 2018-11-07 | 2019-04-16 | 研精舍(上海)精密机械加工有限公司 | A kind of electrophoresis coating technique of magnesium alloy appearance part |
-
2019
- 2019-11-08 CN CN201911084743.0A patent/CN110699719B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1737205A (en) * | 2005-07-19 | 2006-02-22 | 郑州大学 | Surface treatment method for magnesium alloy |
CN101147696A (en) * | 2006-09-21 | 2008-03-26 | 张天平 | Method for manufacturing concealed holding groove and concealed tooth arch string |
CN102888630A (en) * | 2011-07-20 | 2013-01-23 | 中国科学院过程工程研究所 | Method for preparing nanometer aluminum or nanometer aluminum coating in low-temperature electro-deposition form by using ion liquid/additive system |
EP2573214A1 (en) * | 2011-09-22 | 2013-03-27 | Sikorsky Aircraft Corporation | Protection of magnesium alloys by aluminum plating from ionic liquids |
CN108517544A (en) * | 2018-06-14 | 2018-09-11 | 中国兵器工业第五九研究所 | The method of Mg alloy surface processing il electrolyte and magnesium alloy before electroplating of aluminium |
CN108716011A (en) * | 2018-06-19 | 2018-10-30 | 哈尔滨工程大学 | A method of improving aluminium coat and Mg alloy surface binding force |
CN109628980A (en) * | 2018-11-07 | 2019-04-16 | 研精舍(上海)精密机械加工有限公司 | A kind of electrophoresis coating technique of magnesium alloy appearance part |
Non-Patent Citations (1)
Title |
---|
汽配电泳漆FY0216阴极电泳漆系列;佛山市顺德区勒流镇飞扬涂料有限公司;《http://www.sinmv.com/b2b/show-1975.html》;20170206;第1-2页 * |
Also Published As
Publication number | Publication date |
---|---|
CN110699719A (en) | 2020-01-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101967663B (en) | Method for preparing super-hydrophobic alloy film on surface of metal matrix | |
CN110699719B (en) | Method for preparing compact electrophoretic coating on surface of magnesium alloy | |
JP4530111B2 (en) | Electro-aluminum plating solution and method for forming aluminum plating film | |
CN103255450B (en) | A kind of method that ionic liquid brush is aluminized | |
CN105256343A (en) | Electrogalvanizing method based on choline chloride-xylitol deep eutectic solvent | |
CN101985766B (en) | Method for electroplating Zn-Ti alloy by ionic liquid | |
CN104313652B (en) | Preparation method of aluminum-based multiphase inert composite anode material | |
CN105862093A (en) | Method for electroplating Ni-Cr-PTFE composite coating in ionic liquid | |
CN103382564A (en) | Super-hydrophobic cobalt plating of metal surface and preparation method for super-hydrophobic cobalt plating | |
CN104480499A (en) | Nickel electroplating method adopting ionic liquid | |
CN108425137A (en) | A kind of method that electro-deposition prepares silver-nickel electrical contact | |
CN108642520A (en) | A method of zinc is generated based on choline chloride-malonic acid eutectic system | |
CN108754557A (en) | The method that high current density electrochemistry prepares spelter coating in ionic liquid | |
WO2024056109A1 (en) | "brick-mortar" layered structure corrosion-resistant phosphate composite coating, and preparation method and use therefor | |
CN110714219A (en) | Method for electroplating nickel on magnesium alloy micro-arc oxidation surface | |
CN103898563B (en) | Magnesium lithium alloy method for electroplating nickel on surface | |
CN106435672A (en) | Tin, zinc and nickel electroplating method based on choline chloride-malic acid deep-eutectic solvents | |
CN1737205A (en) | Surface treatment method for magnesium alloy | |
Wang et al. | Electrodeposition of Cu coating with high corrosion resistance on Mg–3.0 Nd–0.2 Zn–0.4 Zr magnesium alloy | |
CN108707934A (en) | A kind of method of fast-growth thickness spelter coating on Copper substrate | |
CN103911649B (en) | A kind of preparation method of zinc bace composite coating layer | |
CN105543926A (en) | Preparation method of corrosion-resistant wear-resistant synergistic coating for surfaces of light alloy and composite material | |
CN104532337A (en) | Electro erosion method for rapidly preparing iron base super-hydrophobic surface in large area | |
CN108707936A (en) | The method that choline chloride-glycerine system electrochemistry prepares metal spelter coating | |
Md et al. | Electrodeposition of copper from a choline chloride based ionic liquid |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |