CN110676467B - Air electrode production equipment - Google Patents
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 61
- 239000000463 material Substances 0.000 claims abstract description 105
- 238000005507 spraying Methods 0.000 claims abstract description 91
- 239000002002 slurry Substances 0.000 claims abstract description 76
- 238000003828 vacuum filtration Methods 0.000 claims abstract description 31
- 239000003054 catalyst Substances 0.000 claims abstract description 27
- 238000002156 mixing Methods 0.000 claims abstract description 23
- 238000003756 stirring Methods 0.000 claims description 30
- 230000003197 catalytic effect Effects 0.000 claims description 29
- 230000007246 mechanism Effects 0.000 claims description 25
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- 238000005520 cutting process Methods 0.000 claims description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- 238000000967 suction filtration Methods 0.000 claims description 12
- 239000007921 spray Substances 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 6
- 238000011084 recovery Methods 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 claims description 3
- 238000012544 monitoring process Methods 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims 4
- 238000001125 extrusion Methods 0.000 claims 1
- 238000010924 continuous production Methods 0.000 abstract description 7
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 5
- 238000005096 rolling process Methods 0.000 abstract description 4
- 238000001914 filtration Methods 0.000 description 16
- 239000000446 fuel Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000007731 hot pressing Methods 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8828—Coating with slurry or ink
- H01M4/8832—Ink jet printing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8896—Pressing, rolling, calendering
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Inert Electrodes (AREA)
Abstract
Description
技术领域technical field
本发明涉及金属燃料电池生产领域,特别是涉及一种空气电极生产设备。The invention relates to the field of metal fuel cell production, in particular to an air electrode production equipment.
背景技术Background technique
金属燃料电池是一种半燃料电池,是以金属铝、锂、镁、锌等为燃料,与空气中的氧气发生氧化还原反应产生电能的一种电池,也叫金属空气电池,与一般锂离子电池相比,它具有比能量高、安全环保、价格低廉等优点。Metal fuel cell is a kind of semi-fuel cell, which uses metal aluminum, lithium, magnesium, zinc, etc. as fuel, and generates electricity by redox reaction with oxygen in the air. It is also called metal-air battery. Compared with batteries, it has the advantages of high specific energy, safety and environmental protection, and low price.
在氧化还原反应中,金属铝、锂、镁、锌等为电池负极,空气中的氧气为电池正极。而空气电极提供氧气还原反应的场所,是金属燃料电池的重要组成部分,其主要由催化层,集流层,防水层三部分组成。空气电极必须能够使空气中的氧很容易渗透进入电池参加反应,同时又必须充分疏水,以确保电解液不会渗出,还需具有良好的导电性,以便电流导出。In the redox reaction, metal aluminum, lithium, magnesium, zinc, etc. are the negative electrode of the battery, and oxygen in the air is the positive electrode of the battery. The air electrode provides the place for the oxygen reduction reaction, which is an important part of the metal fuel cell, which is mainly composed of a catalytic layer, a current collector layer, and a waterproof layer. The air electrode must be able to allow the oxygen in the air to easily penetrate into the battery to participate in the reaction, and at the same time must be sufficiently hydrophobic to ensure that the electrolyte does not seep out, and must also have good electrical conductivity so that the current can be exported.
由于金属燃料电池仍未广泛商业化,关于空气电极的生产工艺,目前很多空气电极主要是通过手工辊压或者热压将催化层、集流层、防水层压合在一起。整个制作过程手工操作较多,很难保证材料的均匀性和一致性,导致最终制备的空气电极性能一致性较差,同时制作工序复杂、效率低,难以进行规模化生产。Since metal fuel cells have not yet been widely commercialized, as for the production process of air electrodes, many air electrodes are currently mainly laminated by manual rolling or hot pressing of the catalytic layer, the current collector layer, and the waterproof layer. The entire production process requires a lot of manual operations, which makes it difficult to ensure the uniformity and consistency of materials, resulting in poor performance consistency of the final prepared air electrode. At the same time, the production process is complex and low in efficiency, making it difficult to scale production.
因此,如何提供一种空气电极生产设备,以解决现有空气电极主要通过手工制作无法保证材料的均匀性和一致性,从而导致最终制备的空气电极性能一致性较差,以及制作工序复杂、效率低,难以进行规模化生产的问题实属必要。Therefore, how to provide an air electrode production equipment to solve the problem that the existing air electrodes cannot guarantee the uniformity and consistency of materials mainly through manual production, resulting in poor performance consistency of the final prepared air electrodes, as well as complex and efficient production processes. Low, it is necessary to carry out large-scale production problems.
发明内容SUMMARY OF THE INVENTION
鉴于以上所述现有技术的缺点,本发明的目的在于提供一种空气电极生产设备,用于解决现有技术中空气电极主要通过手工制作无法保证材料的均匀性和一致性,从而导致最终制备的空气电极性能一致性较差,以及制作工序复杂、效率低,难以进行规模化生产等的问题。In view of the above-mentioned shortcomings of the prior art, the object of the present invention is to provide an air electrode production equipment, which is used to solve the problem that the air electrode in the prior art cannot guarantee the uniformity and consistency of the material mainly by hand-made, thereby leading to the final preparation. The air electrode has poor performance consistency, complex production process, low efficiency, and difficulty in large-scale production.
为实现上述目的及其他相关目的,本发明提供一种空气电极生产设备,所述生产设备包括:In order to achieve the above-mentioned purpose and other related purposes, the present invention provides a kind of air electrode production equipment, and the described production equipment includes:
第一混料单元,用于制备催化层浆料;the first mixing unit, used for preparing the catalyst layer slurry;
第二混料单元,用于制备防水层浆料;The second mixing unit is used to prepare the slurry of the waterproof layer;
第一喷涂单元,包括拉送第一物料的第一拉送机构及第一喷涂口,其中,所述第一物料包括第一集流层;The first spraying unit includes a first pulling mechanism and a first spraying port for pulling a first material, wherein the first material includes a first current collecting layer;
第二喷涂单元,包括拉送第二物料的第二拉送机构及第二喷涂口,其中,所述第二物料包括第二集流层;The second spraying unit includes a second pulling mechanism and a second spraying port for pulling the second material, wherein the second material includes a second current collecting layer;
输送单元,包括网孔输送带,用于承载并带动经喷涂的所述第一物料及经喷涂的所述第二物料移动;a conveying unit, including a mesh conveyor belt for carrying and driving the sprayed first material and the sprayed second material to move;
真空抽滤单元,包括真空抽滤装置,所述真空抽滤装置设置于所述网孔输送带的下方,用于对经喷涂的所述第一物料及经喷涂的所述第二物料进行真空抽滤;The vacuum suction filtration unit includes a vacuum suction filtration device, and the vacuum suction filtration device is arranged below the mesh conveyor belt for vacuuming the sprayed first material and the sprayed second material suction filtration;
辊压成型单元,设置于所述输送单元的右边,用于将所述真空抽滤后的所述第一物料及所述第二物料辊压成型,形成空气电极片;A roll forming unit, arranged on the right side of the conveying unit, is used for roll forming the first material and the second material after the vacuum filtration to form an air electrode sheet;
所述第一喷涂口与所述第二喷涂口设置于所述网孔输送带上方并沿所述网孔输送带输送方向间隔一定距离。The first spraying port and the second spraying port are arranged above the mesh conveyor belt and spaced a certain distance along the conveying direction of the mesh conveyor belt.
优选地,所述第一喷涂单元位于所述第二喷涂单元的左边,所述第一喷涂口用于将所述催化层浆料喷涂至所述第一拉送机构拉送的所述第一物料上,所述第二喷涂口用于将所述防水层浆料喷涂至经所述真空抽滤单元抽滤后的所述催化层浆料上。Preferably, the first spraying unit is located on the left side of the second spraying unit, and the first spraying port is used for spraying the catalyst layer slurry to the first spraying unit pulled by the first pulling mechanism On the material, the second spraying port is used for spraying the waterproof layer slurry onto the catalytic layer slurry filtered by the vacuum filtration unit.
优选地,所述第二喷涂单元位于所述第一喷涂单元的左边,所述第二喷涂口用于将所述防水层浆料喷涂至所述第二拉送机构拉送的所述第二物料上,所述第一喷涂口用于将所述催化层浆料喷涂至经所述真空抽滤单元抽滤后的所述防水层浆料上。Preferably, the second spraying unit is located on the left side of the first spraying unit, and the second spraying port is used for spraying the waterproof layer slurry to the second spraying unit pulled by the second pulling mechanism On the material, the first spraying port is used for spraying the catalytic layer slurry onto the waterproof layer slurry filtered by the vacuum filtration unit.
优选地,所述空气电极生产设备还包括切断单元,设置于所述辊压成型单元的右边,用于切断所述空气电极片。Preferably, the air electrode production equipment further includes a cutting unit, disposed on the right side of the roll forming unit, for cutting the air electrode sheet.
进一步地,所述切断单元采用气动方式切断所述空气电极片。Further, the cutting unit cuts the air electrode sheet in a pneumatic manner.
优选地,所述第一混料单元包括第一搅拌罐、设置于所述第一搅拌罐内的第一叶轮及设置于所述第一搅拌罐底部的第一出料口,所述第一叶轮通过电机驱动旋转以搅拌所述第一搅拌罐内的所述催化层浆料,并通过所述第一出料口将所述催化层浆料排出;所述第二混料单元包括第二搅拌罐、设置于所述第二搅拌罐内的第二叶轮及设置于所述第二搅拌罐底部的第二出料口,所述第二叶轮通过电机驱动旋转以搅拌所述第二搅拌罐内的所述防水层浆料,并通过所述第二出料口将所述防水层浆料排出。Preferably, the first mixing unit includes a first stirring tank, a first impeller disposed in the first stirring tank, and a first discharge port disposed at the bottom of the first stirring tank. The impeller is driven to rotate by a motor to stir the catalyst layer slurry in the first stirring tank, and discharge the catalyst layer slurry through the first discharge port; the second mixing unit includes a second mixing unit. A stirring tank, a second impeller disposed in the second stirring tank, and a second discharge port disposed at the bottom of the second stirring tank, the second impeller is driven to rotate by a motor to stir the second stirring tank The waterproof layer slurry inside, and the waterproof layer slurry is discharged through the second outlet.
优选地,所述防水层浆料包括粉状防水层材料及分散剂,所述催化层浆料包括粉状催化层材料及分散剂。Preferably, the waterproof layer slurry includes a powdery waterproof layer material and a dispersant, and the catalyst layer slurry includes a powdery catalyst layer material and a dispersant.
进一步地,所述防水层材料包括碳粉、粘结剂及造孔剂,所述催化层材料包括碳粉、粘结剂、造孔剂及催化剂,所述第一集流层包括泡沫镍、镍网、泡沫铜、铜网及不锈钢网构成的群组中的一种,所述第二集流层包括泡沫镍、镍网、泡沫铜、铜网及不锈钢网构成的群组中的一种。Further, the waterproof layer material includes carbon powder, a binder and a pore-forming agent, the catalyst layer material includes carbon powder, a binder, a pore-forming agent and a catalyst, and the first current collecting layer includes foamed nickel, One of the group consisting of nickel mesh, foamed copper, copper mesh and stainless steel mesh, the second current collecting layer includes one of the group consisting of foamed nickel, nickel mesh, foamed copper, copper mesh and stainless steel mesh .
优选地,所述第一拉送机构包括第一内辊及第一外辊,所述第一内辊用于拉送所述集流层,所述第一外辊用于拉送滤纸;所述第二拉送机构包括第二内辊及第二外辊,所述第二内辊用于拉送所述集流层,所述第二外辊用于拉送所述滤纸。Preferably, the first pulling mechanism includes a first inner roller and a first outer roller, the first inner roller is used for pulling the current collecting layer, and the first outer roller is used for pulling the filter paper; The second pulling mechanism includes a second inner roller and a second outer roller, the second inner roller is used for pulling the current collecting layer, and the second outer roller is used for pulling the filter paper.
优选地,所述第一喷涂口的宽度与所述第一物料的宽度一致,所述第二喷涂口的宽度与所述第二物料的宽度一致。Preferably, the width of the first spray opening is the same as the width of the first material, and the width of the second spray opening is the same as the width of the second material.
优选地,所述真空抽滤装置包括第一真空抽滤装置及第二真空抽滤装置,所述第一真空抽滤装置设置于所述第一喷涂口与所述第二喷涂口之间的所述网孔输送带的下方,所述第二真空抽滤装置设置于所述第一物料与所述第二物料重合处的所述网孔输送带的下方。Preferably, the vacuum filtering device includes a first vacuum filtering device and a second vacuum filtering device, and the first vacuum filtering device is arranged between the first spraying port and the second spraying port Below the mesh conveyor belt, the second vacuum filtering device is arranged below the mesh conveyor belt where the first material and the second material overlap.
优选地,所述真空抽滤装置还包括回收罐,用于回收所述催化层浆料及所述防水层浆料中的滤液。Preferably, the vacuum filtration device further comprises a recovery tank for recovering the filtrate in the slurry of the catalytic layer and the slurry of the waterproof layer.
优选地,所述网孔输送带的网孔尺寸介于0.5mm~5mm之间。Preferably, the mesh size of the mesh conveyor belt is between 0.5 mm and 5 mm.
优选地,所述辊压成型单元包括一对辊筒,所述第一物料及所述第二物料经过所述辊筒之间的间隙挤压成型。Preferably, the roll forming unit includes a pair of rollers, and the first material and the second material are extruded and formed through a gap between the rollers.
优选地,所述空气电极生产设备还包括PLC控制单元,用于实时监测和控制所述空气电极生产设备。Preferably, the air electrode production equipment further includes a PLC control unit for real-time monitoring and control of the air electrode production equipment.
如上所述,本发明的空气电极生产设备,具有以下有益效果:通过从制备空气电极所需的粉料开始至形成所述空气电极片,整个过程都是机械化及连续化生产,制作工序简单且效率高,可实现机械化、规模化、连续化生产,降低制造成本;另外,自动化控制单元进一步提高本发明生产设备的自动化水平;最后,机械化、连续化的生产提高了空气电极片性能的一致性。As mentioned above, the air electrode production equipment of the present invention has the following beneficial effects: from the preparation of the powder required for the air electrode to the formation of the air electrode sheet, the entire process is mechanized and continuous production, the production process is simple and High efficiency, mechanized, large-scale and continuous production can be realized, and manufacturing costs can be reduced; in addition, the automatic control unit further improves the automation level of the production equipment of the present invention; finally, the mechanized and continuous production improves the consistency of the performance of the air electrode sheet .
附图说明Description of drawings
图1显示为本发明的空气电极生产装置的立体示意图。FIG. 1 is a schematic perspective view of the air electrode production apparatus of the present invention.
图2显示为本发明的空气电极生产装置的主视图。FIG. 2 is a front view showing the air electrode production apparatus of the present invention.
图3显示为本发明的空气电极生产装置的左视图。FIG. 3 shows a left side view of the air electrode production apparatus of the present invention.
图4显示为本发明的空气电极生产装置的俯视图。FIG. 4 shows a top view of the air electrode production apparatus of the present invention.
元件标号说明Component label description
1 第一混料单元1 The first mixing unit
2 第二混料单元2 Second mixing unit
31 第一拉送机构31 The first pulling mechanism
311 第一内辊311 First inner roller
312 第一外辊312 First outer roller
32 第一喷涂口32 First spray port
33 第一物料33 The first material
331 第一集流层331 First collector layer
332 滤纸332 filter paper
41 第二拉送机构41 The second pulling mechanism
411 第二内辊411 Second inner roller
412 第二外辊412 Second outer roller
42 第二喷涂口42 Second spray port
43 第二物料43 Second material
431 第二集流层431 Second collector layer
432 滤纸432 filter paper
5 输送单元5 Conveyor unit
51 网孔输送带51 mesh conveyor belt
6 真空抽滤单元6 Vacuum filtration unit
7 辊压成型单元7 Roll forming unit
8 切断单元8 Cut off unit
具体实施方式Detailed ways
以下通过特定的具体实例说明本发明的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本发明的其他优点与功效。本发明还可以通过另外不同的具体实施方式加以实施或应用,本说明书中的各项细节也可以基于不同观点与应用,在没有背离本发明的精神下进行各种修饰或改变。The embodiments of the present invention are described below through specific specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the contents disclosed in this specification. The present invention can also be implemented or applied through other different specific embodiments, and various details in this specification can also be modified or changed based on different viewpoints and applications without departing from the spirit of the present invention.
请参阅图1至图4。需要说明的是,本实施例中所提供的图示仅以示意方式说明本发明的基本构想,遂图式中仅显示与本发明中有关的组件而非按照实际实施时的组件数目、形状及尺寸绘制,其实际实施时各组件的型态、数量及比例可为一种随意的改变,且其组件布局型态也可能更为复杂。See Figures 1 through 4. It should be noted that the drawings provided in this embodiment are only to illustrate the basic concept of the present invention in a schematic way, so the drawings only show the components related to the present invention rather than the number, shape and the number of components in actual implementation. For dimension drawing, the type, quantity and proportion of each component can be changed at will in actual implementation, and the component layout may also be more complicated.
如图1至图4所示,本发明提供一种空气电极生产设备,包括:As shown in Figure 1 to Figure 4, the present invention provides an air electrode production equipment, including:
第一混料单元1,用于制备催化层浆料;The first mixing unit 1 is used to prepare the catalyst layer slurry;
第二混料单元2,用于制备防水层浆料;The
第一喷涂单元,包括拉送第一物料33的第一拉送机构31及第一喷涂口32,其中,所述第一物料33包括第一集流层331;The first spraying unit includes a first pulling
第二喷涂单元,包括拉送第二物料43的第二拉送机构41及第二喷涂口42,其中,所述第二物料43包括第二集流层431;The second spraying unit includes a second pulling
输送单元5,包括网孔输送带51,用于承载并带动经喷涂的所述第一物料33及经喷涂的所述第二物料43移动;The conveying
真空抽滤单元6,包括真空抽滤装置,所述真空抽滤装置设置于所述网孔输送带的下方,用于对经喷涂的所述第一物料33及经喷涂的所述第二物料43进行真空抽滤;The
辊压成型单元7,设置于所述输送单元的右边,用于将所述真空抽滤后的所述第一物料 33及所述第二物料43辊压成型,形成空气电极片;The roll forming unit 7 is arranged on the right side of the conveying unit, and is used to roll the
所述第一喷涂口32与所述第二喷涂口42设置于所述网孔输送带51上方并沿所述网孔输送带51输送方向间隔一定距离。The
如图1所示,于所述第一混料单元1制备所述催化层浆料,然后将所述催化层浆料输送至所述第一喷涂单元,优选地,可以使用泵泵送所述催化层浆料至所述第一喷涂单元的所述第一喷涂口32,并通过所述第一喷涂口32将所述催化层浆料喷涂至所述第一拉送机构31拉送的所述第一物料33上,接着通过设置于所述网孔输送带51下方的真空抽滤装置对经喷涂的所述第一物料33进行抽真空,使所述催化层浆料在所述第一物料33上不能自由流动,以形成所述空气电极的催化层。于所述第二混料单元2制备所述防水层浆料,然后将所述防水层浆料输送至所述第二喷涂单元,优选地,可以使用泵泵送所述防水层浆料至所述第二喷涂单元的所述第二喷涂口42,随着所述网孔输送带51的向右传送,当经所述真空抽滤装置抽滤至不能自由流动的所述催化层浆料传送至所述第二喷涂口42时,所述第二喷涂口42将所述防水层浆料喷涂至不能自由流动的所述催化层浆料上,并在此处所述第一物料33与所述第二物料43重合在一起沿随着所述网孔输送带51向右传送接着通过设置于所述网孔输送带51 下方的真空抽滤装置对经喷涂的所述第二物料43进行抽真空,使所述防水层浆料在所述第二物料43上不能自由流动,以形成所述空气电极的防水层。由于所述第一喷涂口32与所述第二喷涂口42设置于所述网孔输送带51上方并沿所述网孔输送带51输送方向间隔一定距离,所以当经喷涂的所述第一物料33输送至所述第二喷涂口42时,所述催化层浆料可被所述真空抽滤装置抽滤至不能自由流动,而当所述第一物料33与所述第二物料43重合后,所述真空抽滤装置主要真空抽滤所述防水层浆料使其不能自由流动。经真空抽滤后的所述第一物料 33、所述第二物料43、所述催化层浆料及所述防水层浆料从所述网孔输送带51进入所述辊压成型单元7,并经辊压形成空气电极片。As shown in FIG. 1, the catalyst layer slurry is prepared in the first mixing unit 1, and then the catalyst layer slurry is sent to the first spraying unit, preferably, a pump can be used to pump the catalyst layer slurry The catalyst layer slurry is sprayed to the first spraying
本实施例中,如图1所示,先形成所述空气电极的所述催化层,即所述第一喷涂单元设置于所述空气电极生产设备的左边,然后形成所述空气电极的所述防水层,即所述第二喷涂单元设置于所述空气电极生产设备的右边。本发明中,所述催化层和所述防水层的制备顺序不受限制,即所述第一喷涂单元也可设置于所述空气电极生产设备的右边,所述第二喷涂单元设置于所述空气电极生产设备的左边,此时,所述第二喷涂口42用于将所述防水层浆料喷涂至所述第二拉送机构41拉送的所述第二物料43上,所述第一喷涂口32用于将所述催化层浆料喷涂至经所述真空抽滤单元抽滤后的所述防水层浆料上,在所述第一喷涂口32与所述第二喷涂口42间隔的距离之间,所述真空抽滤单元6抽滤所述防水层浆料使其不能自由流动,当所述第一物料33与所述第二物料43重合后,所述真空抽滤装置主要真空抽滤所述催化层浆料使其不能自由流动。In this embodiment, as shown in FIG. 1 , the catalytic layer of the air electrode is formed first, that is, the first spraying unit is arranged on the left side of the air electrode production equipment, and then the catalytic layer of the air electrode is formed. The waterproof layer, that is, the second spraying unit is arranged on the right side of the air electrode production equipment. In the present invention, the preparation sequence of the catalytic layer and the waterproof layer is not limited, that is, the first spraying unit can also be arranged on the right side of the air electrode production equipment, and the second spraying unit is arranged on the On the left side of the air electrode production equipment, at this time, the second spraying
如图2及图4所示,所述空气电极生产设备还包括切断单元8,设置于所述辊压成型单元7的右边,用于切断所述空气电极片。经所述辊压成型单元7辊压成型的所述空气电极进入所述切断单元8,将所述空气电极片切断。优选地,所述切断单元8可以调节切断长度,以满足制备不同规格电极的需求。所述切断单元可以采用气动、电动、液压等各种切断方式,较佳地,本实施例中所述切断单元8采用气动方式切断所述空气电极片。As shown in FIG. 2 and FIG. 4 , the air electrode production equipment further includes a cutting unit 8 , which is arranged on the right side of the roll forming unit 7 and is used for cutting the air electrode sheet. The air electrode rolled by the roll forming unit 7 enters the cutting unit 8 to cut the air electrode sheet. Preferably, the cutting unit 8 can adjust the cutting length to meet the requirements of preparing electrodes of different specifications. The cutting unit can adopt various cutting methods such as pneumatic, electric, hydraulic, etc. Preferably, the cutting unit 8 in this embodiment uses a pneumatic method to cut the air electrode sheet.
作为示例,所述第一混料单元1包括第一搅拌罐、设置于所述第一搅拌罐内的第一叶轮及设置于所述第一搅拌罐底部的第一出料口,所述第一叶轮通过电机驱动旋转以搅拌所述第一搅拌罐内的所述催化层浆料,并通过所述第一出料口将所述催化层浆料排出;所述第二混料单元2包括第二搅拌罐、设置于所述第二搅拌罐内的第二叶轮及设置于所述第二搅拌罐底部的第二出料口,所述第二叶轮通过电机驱动旋转以搅拌所述第二搅拌罐内的所述防水层浆料,并通过所述第二出料口将所述防水层浆料排出。通过所述第一叶轮及所述第二叶轮的旋转搅拌可使所述催化层浆料及所述防水层浆料混合均匀且不会发生沉降。As an example, the first mixing unit 1 includes a first stirring tank, a first impeller disposed in the first stirring tank, and a first discharge port disposed at the bottom of the first stirring tank. An impeller is driven to rotate by a motor to stir the catalytic layer slurry in the first stirring tank, and discharge the catalytic layer slurry through the first discharge port; the
作为示例,所述催化层浆料通过将粉状催化层材料分散于分散剂中制成,所述防水层浆料通过将粉状防水层材料分散于分散剂中制成。较佳地,所述分散剂包括异丙酮。As an example, the catalyst layer slurry is prepared by dispersing powdery catalytic layer material in a dispersant, and the waterproof layer slurry is prepared by dispersing powdery waterproof layer material in a dispersant. Preferably, the dispersant includes isoacetone.
作为示例,所述防水层材料包括碳粉、粘结剂及造孔剂,所述催化层材料包括碳粉、粘结剂、造孔剂及催化剂,所述第一集流层331包括泡沫镍、镍网、泡沫铜、铜网及不锈钢网构成的群组中的一种,所述第二集流层431包括泡沫镍、镍网、泡沫铜、铜网及不锈钢网构成的群组中的一种。As an example, the waterproof layer material includes carbon powder, a binder and a pore-forming agent, the catalyst layer material includes carbon powder, a binder, a pore-forming agent and a catalyst, and the first
较佳地,如图1及图2所示,所述第一拉送机构31包括第一内辊311及第一外辊312,所述第一内辊311用于拉送所述第一集流层331,所述第一外辊312用于拉送滤纸332;所述第二拉送机构41包括第二内辊411及第二外辊412,所述第二内辊411用于拉送所述第二集流层431,所述第二外辊412用于拉送所述滤纸432;所述催化层浆料通过所述第一喷涂口32喷涂至所述第一内辊311拉送的所述第一集流层331上;所述防水层浆料通过所述第二喷涂口42喷涂至所述第二内辊411拉送的所述第二集流层431上,其中所述滤纸332及432需具有一定强度,以防止在真空抽滤过程中发生漏穿现象,同时还需具有较好的过滤所述分散剂的功能。Preferably, as shown in FIG. 1 and FIG. 2 , the first pulling
作为示例,所述第一喷涂口32的宽度与所述第一物料33的宽度一致,所述第二喷涂口 42的宽度与所述第二物料43的宽度一致,可保证浆料均匀喷涂至物料上。较佳地,所述第一喷涂口32及所述第二喷涂口42设置为间隙可调,用于调整浆料的出浆速度。As an example, the width of the first spraying
作为示例,所述真空抽滤装置包括第一真空抽滤装置及第二真空抽滤装置,所述第一真空抽滤装置设置于所述第一喷涂口32与所述第二喷涂口42之间的所述网孔输送带51的下方,所述第二真空抽滤装置设置于所述第一物料33与所述第二物料43重合处的所述网孔输送带51的下方。由于上述两段输送带51上方真空抽滤的物料不同,分别设置不同的真空抽滤装置,即所述第一真空抽滤装置及所述第二真空抽滤装置,可以方便根据具体情况调整真空抽滤参数,以保证真空抽滤效果的一致性。较佳地,所述真空抽滤装置还包括回收罐,用于回收所述催化层浆料及所述防水层浆料中的滤液,以备回收循环使用。As an example, the vacuum filtering device includes a first vacuum filtering device and a second vacuum filtering device, and the first vacuum filtering device is disposed between the first spraying
作为示例,所述网孔输送带51的网孔尺寸介于0.5mm~5mm之间。As an example, the mesh size of the
作为示例,所述辊压成型单元7包括一对辊筒,所述第一物料33及所述第二物料43经过所述辊筒之间的间隙挤压成型。较佳地,所述辊筒之间的间隙可调,以保证辊压形成的所述空气电极片满足不同厚度要求。As an example, the roll forming unit 7 includes a pair of rollers, and the
作为示例,所述空气电极生产设备还包括PLC(Programmable Logic Controller,可编程逻辑控制器)控制单元,用于实时监测和控制所述空气电极生产设备。所述PLC控制单元可以采用触摸屏的方式,在线监测所述第一混料单元1及所述第二混料单元2的液位以及控制浆料流出速度、网孔输送带51运动速度、真空抽滤单元6的真空度及切断单元8的切断速度等,以便使空气电极生产设备的不同单元同步运行。As an example, the air electrode production equipment further includes a PLC (Programmable Logic Controller, programmable logic controller) control unit for real-time monitoring and control of the air electrode production equipment. The PLC control unit can use a touch screen to monitor the liquid level of the first mixing unit 1 and the
经过本发明的空气电极生产设备制备形成的空气电极片依次包括滤纸层、集流层、防水层、催化层、集流层及滤纸层,可通过去除最外层的两层滤纸层,然后经过热压等方式形成所述空气电极。由于所述集流层一般为孔状层,在热压过程中,所述防水层及所述催化层会通过所述集流层的孔压出,从而形成依次层叠的防水层、集流层及催化层的所述空气电极。The air electrode sheet prepared by the air electrode production equipment of the present invention sequentially includes a filter paper layer, a current collector layer, a waterproof layer, a catalytic layer, a current collector layer and a filter paper layer. The air electrode is formed by hot pressing or the like. Since the current collecting layer is generally a porous layer, during the hot pressing process, the waterproof layer and the catalytic layer will be pressed out through the holes of the current collecting layer, thereby forming the waterproof layer and the current collecting layer stacked in sequence. and the air electrode of the catalytic layer.
综上所述,本发明提供一种空气电极生产设备,包括:第一混料单元,用于制备催化层浆料;第二混料单元,用于制备防水层浆料;第一喷涂单元,包括拉送第一物料的第一拉送机构及第一喷涂口,用于将所述催化层浆料通过所述第一喷涂口喷涂至所述第一拉送机构拉送的所述第一物料上;第二喷涂单元,包括拉送第二物料的第二拉送机构及第二喷涂口,用于将所述防水层浆料通过所述第二喷涂口喷涂至所述第二拉送机构拉送的所述第二物料上;输送单元,包括网孔输送带,用于承载并带动经喷涂的所述第一物料及经喷涂的所述第二物料移动;真空抽滤单元,包括真空抽滤装置,所述真空抽滤装置设置于所述网孔输送带的下方,用于对经喷涂的所述第一物料及经喷涂的所述第二物料进行真空抽滤;辊压成型单元,设置于所述输送单元的右边,用于将所述真空抽滤后的所述第一物料及所述第二物料辊压成型,形成空气电极片;所述第一喷涂口与所述第二喷涂口设置于所述网孔输送带上方并沿所述网孔输送带输送方向间隔一定距离。通过从制备空气电极所需的粉料开始至形成所述空气电极片,整个过程都是机械化及连续化生产,制作工序简单且效率高,可实现机械化、规模化、连续化生产,降低制造成本;另外,自动化控制单元进一步提高本发明生产设备的自动化水平;最后,机械化、连续化的生产提高了空气电极片性能的一致性。所以,本发明有效克服了现有技术中的种种缺点而具高度产业利用价值。To sum up, the present invention provides an air electrode production equipment, comprising: a first mixing unit for preparing a catalyst layer slurry; a second mixing unit for preparing a waterproof layer slurry; a first spraying unit, It includes a first pulling mechanism for pulling the first material and a first spraying port for spraying the catalytic layer slurry through the first spraying port to the first pulling mechanism pulled by the first pulling mechanism. On the material; the second spraying unit, including a second pulling mechanism for pulling the second material and a second spraying port, for spraying the waterproof layer slurry to the second pulling through the second spraying port on the second material pulled by the mechanism; a conveying unit, including a mesh conveyor belt, used to carry and drive the sprayed first material and the sprayed second material to move; a vacuum suction filter unit, including Vacuum filtration device, the vacuum filtration device is arranged below the mesh conveyor belt, and is used for vacuum filtration of the sprayed first material and the sprayed second material; roll forming The unit is arranged on the right side of the conveying unit, and is used to roll the first material and the second material after the vacuum filtration to form an air electrode sheet; the first spraying port and the The second spraying port is arranged above the mesh conveyor belt and is spaced at a certain distance along the conveying direction of the mesh conveyor belt. From the preparation of the powder required for the air electrode to the formation of the air electrode sheet, the whole process is mechanized and continuous production, the production process is simple and efficient, and the mechanized, large-scale and continuous production can be realized, and the manufacturing cost can be reduced. In addition, the automation control unit further improves the automation level of the production equipment of the present invention; finally, the mechanized and continuous production improves the consistency of the performance of the air electrode sheet. Therefore, the present invention effectively overcomes various shortcomings in the prior art and has high industrial utilization value.
上述实施例仅例示性说明本发明的原理及其功效,而非用于限制本发明。任何熟悉此技术的人士皆可在不违背本发明的精神及范畴下,对上述实施例进行修饰或改变。因此,举凡所属技术领域中具有通常知识者在未脱离本发明所揭示的精神与技术思想下所完成的一切等效修饰或改变,仍应由本发明的权利要求所涵盖。The above-mentioned embodiments merely illustrate the principles and effects of the present invention, but are not intended to limit the present invention. Anyone skilled in the art can modify or change the above embodiments without departing from the spirit and scope of the present invention. Therefore, all equivalent modifications or changes made by those with ordinary knowledge in the technical field without departing from the spirit and technical idea disclosed in the present invention should still be covered by the claims of the present invention.
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CN205944249U (en) * | 2016-08-12 | 2017-02-08 | 新材料与产业技术北京研究院 | Air electrode production facility |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2014107211A (en) * | 2012-11-29 | 2014-06-09 | Kyocera Corp | Fuel cell device |
CN105932300A (en) * | 2016-05-30 | 2016-09-07 | 昆明纳太科技有限公司 | Gas diffusion electrode and preparation method thereof |
CN205944249U (en) * | 2016-08-12 | 2017-02-08 | 新材料与产业技术北京研究院 | Air electrode production facility |
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