CN110672458A - Method for rapidly evaluating vanadium-titanium magnetite concentrate agglomeration economy - Google Patents

Method for rapidly evaluating vanadium-titanium magnetite concentrate agglomeration economy Download PDF

Info

Publication number
CN110672458A
CN110672458A CN201910833323.1A CN201910833323A CN110672458A CN 110672458 A CN110672458 A CN 110672458A CN 201910833323 A CN201910833323 A CN 201910833323A CN 110672458 A CN110672458 A CN 110672458A
Authority
CN
China
Prior art keywords
ore
sintering
unit consumption
equation
vanadium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910833323.1A
Other languages
Chinese (zh)
Other versions
CN110672458B (en
Inventor
饶家庭
王禹键
胡鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
Original Assignee
Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd filed Critical Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
Priority to CN201910833323.1A priority Critical patent/CN110672458B/en
Publication of CN110672458A publication Critical patent/CN110672458A/en
Application granted granted Critical
Publication of CN110672458B publication Critical patent/CN110672458B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N5/00Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid
    • G01N5/04Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid by removing a component, e.g. by evaporation, and weighing the remainder
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • C22B1/14Agglomerating; Briquetting; Binding; Granulating
    • C22B1/16Sintering; Agglomerating
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N31/00Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
    • G01N31/12Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using combustion

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Pathology (AREA)
  • Immunology (AREA)
  • General Physics & Mathematics (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention relates to the technical field of ferrous metallurgy, and discloses a rapid evaluation method for vanadium-titanium magnetite concentrate agglomeration economy. The method comprises the following steps: s1, determining the components and the prices of the sintering raw material and the blast furnace raw material; s2, calculating the charging grade of the pellet according to the mixture ratio of the pellet and the bentonite; s3, calculating theoretical ore unit consumption and a blast furnace burden structure table according to the charging grade; s4, calculating the TFe content of the sinter and the unit consumption of the sinter according to the blast furnace burden structure table; s5, constructing a linear equation set according to the slag alkalinity, the TFe content of the sintering ore, the unit consumption of the sintering ore, the sintering fuel ratio and the flux ratio, and solving the unit consumption of the sintering raw materials; and S6, calculating the proportion and the components of the sintering raw materials and the cost of pig iron to obtain the rule of the influence of the change of the proportion of the pellets on the structure of the sintered ore blending. The method can quickly analyze the influence rule of the change of the pellet proportioning on the sintering proportioning structure when the set load of the blast furnace TiO2, the slag alkalinity and the furnace feeding grade are unchanged.

Description

Method for rapidly evaluating vanadium-titanium magnetite concentrate agglomeration economy
Technical Field
The invention relates to the technical field of ferrous metallurgy, in particular to a rapid evaluation method for vanadium-titanium magnetite concentrate agglomeration economy.
Background
Due to TiO in vanadium-bearing titanium magnetite concentrate2Content and slag TiO2The influence of content control, when the different agglomeration modes of vanadium titanium magnetite concentrate are put into the furnace, the structure influence to the sintering material is big, but the essence is that the vanadium titanium magnetite concentrate in the sintering raw material shifts to the pellet ore, and this has great difference with ordinary ore smelting. In brief, after the vanadium-titanium magnetite concentrate is made into pellets and put into a furnace, along with the increase of the proportion of the pellets of the blast furnace, the proportion of the vanadium-titanium magnetite concentrate in sintering is reduced, and the proportion of other common powder ores and a flux and the components of the sinter are greatly changed. The method has important significance in analyzing the influence of the changes of the sintering material structure and the process parameters on the economic indexes of the sintering technology and the economic influence on the blast furnace burden along with the increase of the blast furnace vanadium-titanium pellet proportion.
The currently used evaluation method is to adopt a trial calculation method in a compiled Excel file, modify related data for many times, and check whether related results meet assumed requirements to obtain a corresponding scheme, which is time-consuming and labor-consuming.
The patent introduces a rapid evaluation method for vanadium-titanium magnetite concentrate agglomeration economy, which is based on the set TiO of a blast furnace2Under the condition of unchanged load, slag alkalinity and charging grade, the influence rule of blast furnace pellet ore proportioning increase on the sintering ore proportioning structure can be rapidly analyzed, and 9 groups of schemes and economic evaluation results can be obtained at one time.
Disclosure of Invention
The invention aims to solve the problems that the existing evaluation method in the prior art is time-consuming and labor-consuming, and provides a rapid evaluation method for the economical efficiency of vanadium-titanium magnetite concentrate agglomeration, which can rapidly analyze the influence rule of the increase of the blast furnace pellet ratio on the sintering ore proportioning structure.
In order to achieve the aim, the invention provides a method for quickly evaluating the agglomeration economy of vanadium-titanium magnetite concentrates, which comprises the following steps:
s1, determining the components and the prices of the sintering raw material and the blast furnace raw material;
s2, calculating the charging grade of the pellet according to the mixture ratio of the pellet and the bentonite;
s3, calculating theoretical ore unit consumption and a blast furnace burden structure table according to the charging grade;
s4, calculating the TFe content of the sinter and the unit consumption of the sinter according to the blast furnace burden structure table;
s5, constructing a linear equation set according to the slag alkalinity, the TFe content of the sintering ore, the unit consumption of the sintering ore, the sintering fuel ratio and the flux ratio, and solving the unit consumption of the sintering raw materials;
and S6, calculating the proportion and the components of the sintering raw materials and the cost of pig iron to obtain the rule of the influence of the change of the proportion of the pellets on the structure of the sintered ore blending.
Preferably, in step S1, the sintering raw material contains vanadium-titanium magnetite concentrate, high-powder ore, medium-powder ore, quicklime, limestone and coke powder,
the vanadium-titanium magnetite concentrate contains 53-60 wt% of TFe and 2-4 wt% of SiO20.1-1 wt% CaO, 2-4 wt% MgO, 2-4 wt% Al2O3And 6-13% by weight of TiO2
The high-powder ore contains TFe 58-61 wt% and SiO 5-9 wt%20.1-1 wt% CaO, 0.5-1.5 wt% MgO and 1-2 wt% Al2O3
The middling ore contains 40-50 wt% of TFe and 15-25 wt% of SiO21-3 wt% CaO, 2-4 wt% MgO and 4-6 wt% Al2O3
Preferably, in step S1, the blast furnace raw material contains sintered ore, pellet, bentonite, lump ore, coke and pulverized coal,
the pellet contains 52-60 wt% of TFe and 5-6 wt% of SiO20.1-1 wt% CaO, 2-4 wt% MgO, 3-4 wt% Al2O3And 5-10 wt% TiO2
The lump ore contains 58-59 wt% of TFe and 8-9 wt%% SiO20.5-1.5 wt% CaO, 0.5-1.2 wt% MgO and 2-3 wt% Al2O3
Preferably, in step S2, the charged grade of the pellets is calculated according to the following formula,
wherein M represents the charging grade of the pellet, N represents the TFe content of the vanadium-titanium magnetite concentrate, P represents the proportion of the vanadium-titanium magnetite concentrate, and Q represents the proportion of bentonite.
Preferably, in step S3, the ore in the theoretical ore unit consumption is pellet ore and lump ore; the calculation formula of the theoretical ore unit consumption is as follows,
R=945/A
wherein R represents theoretical ore unit consumption, and A represents furnace charging grade.
Preferably, in step S4, the TFe content of the sintered ore is calculated by the following equilibrium equation:
A=B1×C1+B2×C2+B3×C3
wherein A represents the charged grade, B represents the charged grade1Represents the proportion of the sintered ore, C1Denotes the TFe content of the sinter, B2Represents the proportion of pellets, C2Represents the TFe content of the pellets, B3Represents the proportion of lump ore, C3Represents the TFe content of the lump ore;
wherein, A, B1、B2、C2、B3、C3Are all known quantities.
Preferably, in step S4, the sintered ore unit consumption is calculated by the following equilibrium equation:
F=(945/A)×B1
wherein F represents the unit consumption of the sinter, A and B1The meaning of (a) is the same as previously described.
Preferably, in step S5, the system of linear equations includes 5 equilibrium equations:
equation 1: sintering raw material firing residue value of sintering process is unit consumption of sintering ore
Figure BDA0002191438230000032
Wherein, X2The unit consumption, X, of the vanadium-titanium magnetite concentrate representing the sinter consumption3Denotes unit consumption, X, of high-fines ore4Denotes the unit consumption of middlings, X5Indicating unit consumption of quicklime, X6Denotes the unit consumption of limestone, X7The unit consumption of coke powder is shown, and Sum represents the yield of sinter;
equation 2: the TFe content of the sintered ore calculated in the blast furnace burden structure table is equal to the TFe content of the corresponding sintered ore in the sintering raw material in the sintering step
Figure BDA0002191438230000041
Wherein, X2-X7And Sum have the same meaning as previously described;
equation 3: according to the smelting characteristics of the blast furnace process, the SiO of the molten iron is deducted from all the raw materials entering the furnace2Equation of equilibrium of alkalinity
Figure BDA0002191438230000042
Wherein, X1Vanadium-titanium magnetite concentrate unit consumption, X, representing pellet consumption2-X7Has the same meaning as described above, X8Denotes the unit consumption of bentonite, X9Denotes unit consumption, X, of lump ore10Denotes the unit consumption of coke, X11Representing the unit consumption of coal dust, R2Representing the binary basicity of the slag;
equation 4: the proportion of the quicklime in the sintering mixture is a fixed value D
Wherein, X2-X7The meanings of (1) are as described aboveAnd D represents the proportion of the quicklime in the sintering mixture;
equation 5: the initial value of the carbon content in the sintering mixture is a fixed value E
Figure BDA0002191438230000044
Wherein, X1-X7The meaning of E is the same as that of the previous description, E represents the initial value of the carbon content in the sintering mixture, and 0.85 is the carbon content of the coke powder;
in the calculation process, X1、X2And X8-X11Is a known quantity, X3-X7For unknown quantity, the unique solution X satisfying the equation can be obtained according to 5 balance equations3-X7
Preferably, in equation 3, R2Is a value actually set according to production.
Preferably, R2Was 1.05.
Preferably, in equation 4, D is a value set according to the basicity, and preferably, D is 0.08.
Preferably, in equation 5, E is a value set according to the sintering process requirements, and preferably, E is 0.035.
The method of the invention sets the TiO of the blast furnace2Under the condition of unchanged load, slag alkalinity and charging grade, the influence rule of the increase of the blast furnace pellet ore proportion on the sintering ore proportioning structure can be rapidly analyzed, and 9 groups of schemes and economic evaluation results can be obtained at one time.
Drawings
FIG. 1 is a graph showing the relationship between the pig iron cost and the pellet ratio in example 2;
FIG. 2 is a solver interface in example 2.
Detailed Description
The following detailed description of embodiments of the invention refers to the accompanying drawings. It should be understood that the detailed description and specific examples, while indicating the present invention, are given by way of illustration and explanation only, not limitation.
The endpoints of the ranges and any values disclosed herein are not limited to the precise range or value, and such ranges or values should be understood to encompass values close to those ranges or values. For ranges of values, between the endpoints of each of the ranges and the individual points, and between the individual points may be combined with each other to give one or more new ranges of values, and these ranges of values should be considered as specifically disclosed herein.
The invention provides a method for quickly evaluating the economy of vanadium-titanium magnetite concentrate agglomeration, which comprises the following steps:
s1, determining the components and the prices of the sintering raw material and the blast furnace raw material;
s2, calculating the charging grade of the pellet according to the mixture ratio of the pellet and the bentonite;
s3, calculating theoretical ore unit consumption and a blast furnace burden structure table according to the charging grade;
s4, calculating the TFe content of the sinter and the unit consumption of the sinter according to the blast furnace burden structure table;
s5, constructing a linear equation set according to the slag alkalinity, the TFe content of the sintering ore, the unit consumption of the sintering ore, the sintering fuel ratio and the flux ratio, and solving the unit consumption of the sintering raw materials;
and S6, calculating the proportion and the components of the sintering raw materials and the cost of pig iron to obtain the rule of the influence of the change of the proportion of the pellets on the structure of the sintered ore blending.
The method of the invention sets the TiO of the blast furnace2Under the condition of unchanged load, slag alkalinity and charging grade, the influence rule of the increase of the blast furnace pellet ore proportion on the sintering ore proportioning structure can be rapidly analyzed, and 9 groups of schemes and economic evaluation results can be obtained at one time. In the present invention, unless otherwise specified, TFe means total iron.
In the method of the present invention, in step S1, the sintering raw material contains vanadium-titanium magnetite concentrate, high-fine ore, medium-fine ore, quicklime, limestone, and coke powder. The mixture of the quicklime and the limestone is a solvent, and the coke powder is sintering fuel.
The vanadium-titanium magnetite concentrate contains 53-60 wt% of TFe and 2-4 wt%SiO of (2)20.1-1 wt% CaO, 2-4 wt% MgO, 2-4 wt% Al2O3And 6-13% by weight of TiO2. The vanadium-titanium magnetite concentrate also contains S and V which influence the desulfurization cost2O5And the like.
The high-powder ore contains TFe 58-61 wt% and SiO 5-9 wt%20.1-1 wt% CaO, 0.5-1.5 wt% MgO and 1-2 wt% Al2O3. The high-powder ore also contains other components such as S, P and the like.
The middling ore contains 40-50 wt% of TFe and 15-25 wt% of SiO21-3 wt% CaO, 2-4 wt% MgO and 4-6 wt% Al2O3. The middlings can also contain other components such as S and P.
In a preferred embodiment, the vanadium-titanium magnetite concentrate contains 54 wt.% of TFe, 3.8 wt.% of SiO20.5 wt% CaO, 2.8 wt% MgO, 3.5 wt% Al2O3And 12.2% by weight of TiO2(ii) a The high-fines ore contained 60 wt.% TFe, 6 wt.% SiO20.5% by weight of CaO, 1.5% by weight of MgO and 2% by weight of Al2O3(ii) a The middlings contained 42.5 wt.% of TFe and 17.5 wt.% of SiO22% by weight of CaO, 3% by weight of MgO and 5% by weight of Al2O3
In the method of the present invention, in step S1, the blast furnace raw material contains sintered ore, pellet, bentonite, lump ore, coke, and pulverized coal.
The pellet contains 52-60 wt% of TFe and 5-6 wt% of SiO20.1-1 wt% CaO, 2-4 wt% MgO, 3-4 wt% Al2O3And 5-10 wt% TiO2. The pellet also contains V2O5And the like.
The lump ore contains 58-59 wt% of TFe and 8-9 wt% of SiO20.5-1.5 wt% CaO, 0.5-1.2 wt% MgO and 2-3 wt% Al2O3. The lump ore also contains C and the likeAnd (c) other components.
In the method of the present invention, in step S2, the charged grade of the pellets is calculated according to the following formula,
Figure BDA0002191438230000071
wherein M represents the charging grade of the pellet, N represents the TFe content of the vanadium-titanium magnetite concentrate, P represents the proportion of the vanadium-titanium magnetite concentrate, and Q represents the proportion of bentonite.
In step S2, the purpose of calculating the feed grade of the pellet is to calculate the TFe grade of the sintered ore under the condition that the feed grade of the blast furnace ore is specified.
In the method of the invention, in step S3, the ore in the theoretical ore unit consumption is pellet ore and lump ore; the calculation formula of the theoretical ore unit consumption is as follows,
R=945/A
wherein R represents theoretical ore unit consumption, and A represents furnace charging grade.
In the method of the present invention, in step S4, the TFe content of the sintered ore is calculated by the following equilibrium equation:
A=B1×C1+B2×C2+B3×C3
wherein A represents the charged grade, B represents the charged grade1Represents the proportion of the sintered ore, C1Denotes the TFe content of the sinter, B2Represents the proportion of pellets, C2Represents the TFe content of the pellets, B3Represents the proportion of lump ore, C3Represents the TFe content of the lump ore;
wherein, in the equilibrium equation, A, B1、B2、C2、B3、C3Are known amounts.
In calculating the TFe content of the sinter, B140-75%, B220-60%, B32 to 5 percent; specifically, B1May be 65%, 55%, 45%, 75%, B2Can be 20%, 22%, 24%, 26%,28% or 55%, B3May be 2%, 3%, 4% or 5%; preferably, B170% of B 225% of B3The content was 3%.
In the method of the present invention, in step S4, the sintered ore specific consumption is calculated by the following equilibrium equation:
F=(945/A)×B1
wherein F represents the unit consumption of the sinter, A and B1The meaning of (a) is the same as previously described.
In the method of the present invention, in step S5, the system of linear equations includes 5 equilibrium equations:
equation 1: sintering raw material firing residue value of sintering process is unit consumption of sintering ore
Figure BDA0002191438230000081
Wherein, X2The unit consumption, X, of the vanadium-titanium magnetite concentrate representing the sinter consumption3Denotes unit consumption, X, of high-fines ore4Denotes the unit consumption of middlings, X5Indicating unit consumption of quicklime, X6Denotes the unit consumption of limestone, X7Indicating the unit consumption of coke powder and Sum indicating the production of sinter.
Equation 2: the TFe content of the sintered ore calculated in the blast furnace burden structure table is equal to the TFe content of the corresponding sintered ore in the sintering raw material in the sintering step
Figure BDA0002191438230000082
Wherein, X2-X7And Sum have the same meaning as previously described.
Equation 3: according to the smelting characteristics of the blast furnace process, the SiO of the molten iron is deducted from all the raw materials entering the furnace2Equation of equilibrium of alkalinity
Figure BDA0002191438230000091
Wherein, X1Indicating pellet consumptionUnit consumption of vanadium-titanium magnetite concentrate, X2-X7Has the same meaning as described above, X8Denotes the unit consumption of bentonite, X9Denotes unit consumption, X, of lump ore10Denotes the unit consumption of coke, X11Representing the unit consumption of coal dust, R2Representing the binary basicity of the slag.
Equation 4: the proportion of the quicklime in the sintering mixture is a fixed value D
Figure BDA0002191438230000092
Wherein, X2-X7The meaning of D is the same as that described above, and D represents the proportion of quicklime in the sinter mix.
Equation 5: the initial value of the carbon content in the sintering mixture is a fixed value E
Figure BDA0002191438230000093
Wherein, X1-X7The meaning of E is the same as that described above, E represents the initial value of the carbon content in the sinter mix, and 0.85 represents the carbon content of the coke powder.
In the calculation process, X1、X2And X8-X11Is a known quantity, X3-X7For unknown quantity, the unique solution X satisfying the equation can be obtained according to 5 balance equations3-X7
In the method of the present invention, in equation 3, R2Is a value set according to actual production, preferably, R2Was 1.05.
In the method of the present invention, in equation 4, D is a value set according to the basicity, and preferably, D is 0.08.
In the method of the present invention, in equation 5, E is a value set according to the sintering process requirement, and preferably, E is 0.035.
The present invention will be described in detail below by way of examples, but the scope of the present invention is not limited thereto.
Example 1
S1, selecting components and prices of a vanadium-titanium magnetite concentrate and corresponding sintering raw materials and blast furnace raw materials, wherein the components of the vanadium-titanium magnetite concentrate and corresponding sintering raw materials and blast furnace raw materials are shown in Table 1;
TABLE 1
Figure BDA0002191438230000101
Cf in Table 1 represents fixed carbon, and Ig is a burnout value, i.e., a weight change width after baking at 1000 ℃ X1-X11Same as described above;
s2, calculating the charging grade of the pellet according to the mixture ratio of the pellet and the bentonite;
s3, specifying the furnace charging grade to be 50.5 percent and furnace charging TiO2When the load is 130kg/t, calculating the theoretical ore unit consumption and a blast furnace burden structure table;
s4, calculating the TFe content of the sinter and the unit consumption of the sinter according to the blast furnace burden structure table;
s5, constructing a linear equation set comprising 5 balance equations, solving the unit consumption of the sintering raw materials,
equation 1: sintering raw material firing residue value of sintering process is unit consumption of sintering ore
Figure BDA0002191438230000102
Wherein, X2The unit consumption, X, of the vanadium-titanium magnetite concentrate representing the sinter consumption3Denotes unit consumption, X, of high-fines ore4Denotes the unit consumption of middlings, X5Indicating unit consumption of quicklime, X6Denotes the unit consumption of limestone, X7The unit consumption of coke powder is shown, and Sum represents the yield of sinter;
equation 2: the TFe content of the sintered ore calculated in the blast furnace burden structure table is equal to the TFe content of the corresponding sintered ore in the sintering raw material in the sintering step
Wherein, X2-X7And Sum have the same meaning as previously described;
equation 3: according to the smelting characteristics of the blast furnace process, the SiO of the molten iron is deducted from all the raw materials entering the furnace2Equation of equilibrium of alkalinity
Figure BDA0002191438230000112
Wherein, X1Vanadium-titanium magnetite concentrate unit consumption, X, representing pellet consumption2-X7Has the same meaning as described above, X8Denotes the unit consumption of bentonite, X9Denotes unit consumption, X, of lump ore10Denotes the unit consumption of coke, X11Representing the unit consumption of coal dust, R2Denotes the binary basicity of the slag, R2Is 1.1;
equation 4: the proportion of the quicklime in the sintering mixture is a fixed value of 0.08
Figure BDA0002191438230000113
Wherein, X2-X7The meaning of (a) is the same as previously described;
equation 5: the initial value of the carbon content in the sintering mixture is a fixed value of 0.035
Figure BDA0002191438230000114
Wherein, X1-X7The meaning of (A) is the same as that described above, 0.85 is the carbon content of the coke powder;
in the calculation process, X1、X2And X8-X11Is a known quantity, X3-X7For unknown quantity, the unique solution X satisfying the equation can be obtained according to 5 balance equations3-X7
S6, calculating the proportion and the components of the sintering raw materials and the cost of pig iron, and the rule of the influence of the change of the proportion of the obtained pellet on the structure of the sintered ore blending is shown in Table 2.
TABLE 2
Figure BDA0002191438230000121
As can be seen from table 2, as the pellet ratio is increased from 20% to 50%, when the vanadium-titanium magnetite concentrate is made of Panzhihua vanadium-titanium magnetite concentrate with 54% of TFe content, the pig iron ore blending cost is in a downward trend; the ratio of vanadium-titanium magnetite concentrate in sintering is reduced from 47.13% to 17.72%, the ratio of high-powder ore is increased from 33.82% to 56.07%, the sintering alkalinity is increased from 1.77 to 2.69, and CaO and SiO in sintered ore2The sum of the contents of (A) is increased from 14.5% to 20.7%. From the experience of sintering practice, the proportion of the vanadium-titanium magnetite concentrate is reduced, the proportion of common ore is increased, and the improvement of the sintering alkalinity and the silicon-calcium level are beneficial to the improvement of the quality of a sintered product.
Example 2
Analyzing the influence rule of the change of the pellet mixture ratio on the sintered ore proportioning structure according to the method described in example 1, except that in step S1, the vanadium-titanium magnetite concentrate is a white martensite-titanium magnetite concentrate with a TFe content of 56%, and the composition thereof is shown in table 3; in step S3, the furnace grade is 51.5%, and the furnace TiO is charged2The load was 125 kg/t; in step S5, the slag binary basicity R21.05, the obtained relationship diagram of the pig iron cost and the pellet ratio is shown in fig. 1, the influence rule of the change of the obtained pellet ratio on the sintering ore blending structure is shown in table 4, and the solver interface is shown in fig. 2.
TABLE 3
Name of article Tfe/% SiO2/% CaO/% MgO/% Al2O3/% TiO2/% Ig/%
White-horse vanadium-titanium magnetite concentrate 56.50 3.60 0.50 3.20 3.50 10.20 -1.50
TABLE 4
Figure BDA0002191438230000131
As can be seen from table 4, as the pellet ratio is increased from 20% to 60%, when all the vanadium-titanium magnetite concentrates are white horse vanadium-titanium magnetite concentrates with a TFe content of 56%, the pig iron ore blending cost is in a downward trend; the ratio of vanadium-titanium-iron concentrate in sintering is reduced from 59% to 19.9%, the ratio of high-powder ore is increased from 18.4% to 39.5%, the sintering alkalinity is increased from 1.73 to 2.95, and CaO and SiO in sintered ore2The sum of the contents of (A) is increased from 14.7% to 24.6%. From the experience of sintering practice, the proportion of the vanadium-titanium magnetite concentrate is reduced, the proportion of common ore is increased, and the improvement of the sintering alkalinity and the silicon-calcium level are beneficial to the improvement of the quality of a sintered product. As can be seen from Table 4, when the pellet ratio is 50%, the pig iron ore blending cost is reduced by 27.6 yuan/t iron as compared with that when the pellet ratio is 20%Left and right.
Example 3
The method of example 1 was used to analyze the influence of the change of the pellet mix ratio on the sintered mix structure, except that in step S1, the vanadium-titanium magnetite concentrate was a white martensite-titanium magnetite concentrate having a TFe content of 59%, and the composition thereof is shown in table 5; in step S3, the charged grade is designated as 53%, and charged TiO is designated2The load was 125 kg/t; in step S5, the slag binary basicity R2The ratio was 1.05, and the rule of the influence of the change in the ratio of the obtained pellets on the structure of the sintered ore blend is shown in Table 6.
TABLE 5
Name of article Tfe/% SiO2/% CaO/% MgO/% Al2O3/% TiO2/% Ig/%
White-horse vanadium-titanium magnetite concentrate 59.00 2.00 0.40 2.50 3.00 10.40 -1.50
TABLE 6
As can be seen from table 6, when the feed grade is 53%, the pig iron ore blending cost is in a downward trend when the vanadium-titanium magnetite concentrate is completely used as the amantadine vanadium-titanium magnetite concentrate with the TFe content of 59% as the pellet ratio is increased from 20% to 60%; the ratio of vanadium-titanium magnetite concentrate in sintering is reduced from 63.6% to 28.1%, the ratio of high-powder ore is increased from 10.8% to 25.5%, the sintering alkalinity is increased from 1.75 to 2.47, and CaO and SiO in sintered ore2The sum of the contents of (A) increases from 13.0% to 24.1%. From the experience of sintering practice, the proportion of the vanadium-titanium magnetite concentrate is reduced, the proportion of common ore is increased, and the improvement of the sintering alkalinity and the silicon-calcium level are beneficial to the improvement of the quality of a sintered product. As can be seen from Table 6, when the pellet ratio is 50%, the pig iron ore blending cost is reduced by about 23 yuan/t iron as compared with that when the pellet ratio is 20%. Compared with the example 2, the proportion of the middlings is greatly increased, and the middlings are mainly influenced by the low silicon content of the white-mare vanadium-titanium magnetite concentrate with the TFe content of 59%.
The preferred embodiments of the present invention have been described above in detail, but the present invention is not limited thereto. Within the scope of the technical idea of the invention, many simple modifications can be made to the technical solution of the invention, including combinations of various technical features in any other suitable way, and these simple modifications and combinations should also be regarded as the disclosure of the invention, and all fall within the scope of the invention.

Claims (10)

1. A method for rapidly evaluating the agglomeration economy of vanadium-titanium magnetite concentrates is characterized by comprising the following steps:
s1, determining the components and the prices of the sintering raw material and the blast furnace raw material;
s2, calculating the charging grade of the pellet according to the mixture ratio of the pellet and the bentonite;
s3, calculating theoretical ore unit consumption and a blast furnace burden structure table according to the charging grade;
s4, calculating the TFe content of the sinter and the unit consumption of the sinter according to the blast furnace burden structure table;
s5, constructing a linear equation set according to the slag alkalinity, the TFe content of the sintering ore, the unit consumption of the sintering ore, the sintering fuel ratio and the flux ratio, and solving the unit consumption of the sintering raw materials;
and S6, calculating the proportion and the components of the sintering raw materials and the cost of pig iron to obtain the rule of the influence of the change of the proportion of the pellets on the structure of the sintered ore blending.
2. The method of claim 1, wherein the sintering raw material contains vanadium-titanium magnetite concentrate, high-fine ore, medium-fine ore, quicklime, limestone and coke powder in step S1,
the vanadium-titanium magnetite concentrate contains 53-60 wt% of TFe and 2-4 wt% of SiO20.1-1 wt% CaO, 2-4 wt% MgO, 2-4 wt% Al2O3And 6-13% by weight of TiO2
The high-powder ore contains TFe 58-61 wt% and SiO 5-9 wt%20.1-1 wt% CaO, 0.5-1.5 wt% MgO and 1-2 wt% Al2O3
The middling ore contains 40-50 wt% of TFe and 15-25 wt% of SiO21-3 wt% CaO, 2-4 wt% MgO and 4-6 wt% Al2O3
3. The method of claim 1, wherein the blast furnace raw material comprises sintered ore, pellet ore, bentonite, lump ore, coke, and fine coal at step S1,
the pellet contains 52-60 wt% of TFe and 5-6 wt% of SiO20.1-1 wt% CaO, 2-4 wt% MgO, 3-4 wt% Al2O3And 5-10 wt% TiO2
The lump ore contains 58-59 wt% of TFe and 8-9 wt% of SiO20.5-1.5 wt% CaO, 0.5-1.2 wt% MgO and 2-3 wt% Al2O3
4. The method as claimed in claim 1, wherein, in step S2, the charged grade of the pellets is calculated according to the following formula,
Figure FDA0002191438220000021
wherein M represents the charging grade of the pellet, N represents the TFe content of the vanadium-titanium magnetite concentrate, P represents the proportion of the vanadium-titanium magnetite concentrate, and Q represents the proportion of bentonite.
5. The method as claimed in claim 1, wherein in step S3, the ore in the theoretical ore unit consumption is pellet ore and lump ore; the calculation formula of the theoretical ore unit consumption is as follows,
R=945/A
wherein R represents theoretical ore unit consumption, and A represents furnace charging grade.
6. The method according to claim 1, wherein in step S4, the TFe content of the sinter is calculated by the following equilibrium equation:
A=B1×C1+B2×C2+B3×C3
wherein A represents the charged grade, B represents the charged grade1Represents the proportion of the sintered ore, C1Denotes the TFe content of the sinter, B2Represents the proportion of pellets, C2Represents the TFe content of the pellets, B3Represents the proportion of lump ore, C3Represents the TFe content of the lump ore;
wherein, A, B1、B2、C2、B3、C3Are all known quantities.
7. The method according to claim 1, wherein in step S4, the sintered ore specific consumption is calculated by the following equilibrium equation:
F=(945/A)×B1
wherein F represents the unit consumption of the sinter, A and B1The meaning of (a) is the same as previously described.
8. The method of claim 1, wherein in step S5, the system of linear equations includes 5 equilibrium equations:
equation 1: sintering raw material firing residue value of sintering process is unit consumption of sintering ore
Figure FDA0002191438220000031
Wherein, X2The unit consumption, X, of the vanadium-titanium magnetite concentrate representing the sinter consumption3Denotes unit consumption, X, of high-fines ore4Denotes the unit consumption of middlings, X5Indicating unit consumption of quicklime, X6Denotes the unit consumption of limestone, X7The unit consumption of coke powder is shown, and Sum represents the yield of sinter;
equation 2: the TFe content of the sintered ore calculated in the blast furnace burden structure table is equal to the TFe content of the corresponding sintered ore in the sintering raw material in the sintering step
Figure FDA0002191438220000032
Wherein, X2-X7And Sum have the same meaning as previously described;
equation 3: according to the smelting characteristics of the blast furnace process, the SiO of the molten iron is deducted from all the raw materials entering the furnace2Equation of equilibrium of alkalinity
Figure FDA0002191438220000034
Wherein, X1Vanadium-titanium magnetite concentrate unit consumption, X, representing pellet consumption2-X7Of (1) containsAs defined above, X is8Denotes the unit consumption of bentonite, X9Denotes unit consumption, X, of lump ore10Denotes the unit consumption of coke, X11Representing the unit consumption of coal dust, R2Representing the binary basicity of the slag;
equation 4: the proportion of the quicklime in the sintering mixture is a fixed value D
Figure FDA0002191438220000033
Wherein, X2-X7The meaning of D is the same as that of the previous description, D represents the proportion of quicklime in the sinter mixture;
equation 5: the initial value of the carbon content in the sintering mixture is a fixed value E
Figure FDA0002191438220000041
Wherein, X1-X7The meaning of E is the same as that of the previous description, E represents the initial value of the carbon content in the sintering mixture, and 0.85 is the carbon content of the coke powder;
in the calculation process, X1、X2And X8-X11Is a known quantity, X3-X7For unknown quantity, the unique solution X satisfying the equation can be obtained according to 5 balance equations3-X7
9. The method of claim 8, wherein in equation 3, R2Is a value set according to actual production, preferably, R2Was 1.05.
10. The method according to claim 8, wherein in equation 4, D is a value set according to basicity, preferably D is 0.08; in equation 5, E is a value set according to the sintering process requirement, and preferably, E is 0.035.
CN201910833323.1A 2019-09-04 2019-09-04 Method for rapidly evaluating vanadium-titanium magnetite concentrate agglomeration economy Active CN110672458B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910833323.1A CN110672458B (en) 2019-09-04 2019-09-04 Method for rapidly evaluating vanadium-titanium magnetite concentrate agglomeration economy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910833323.1A CN110672458B (en) 2019-09-04 2019-09-04 Method for rapidly evaluating vanadium-titanium magnetite concentrate agglomeration economy

Publications (2)

Publication Number Publication Date
CN110672458A true CN110672458A (en) 2020-01-10
CN110672458B CN110672458B (en) 2022-05-24

Family

ID=69075992

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910833323.1A Active CN110672458B (en) 2019-09-04 2019-09-04 Method for rapidly evaluating vanadium-titanium magnetite concentrate agglomeration economy

Country Status (1)

Country Link
CN (1) CN110672458B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111910072A (en) * 2020-09-09 2020-11-10 鞍钢股份有限公司 Preparation and use methods of pre-reduced fluxed pellets with steel slag as partial raw material
CN113626993A (en) * 2021-07-21 2021-11-09 包头钢铁(集团)有限责任公司 Method for evaluating smelting value of iron ore

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1107182A (en) * 1994-06-01 1995-08-23 重庆大学 Method for controlling low-temperature reduction degradation of blast furnace mineral aggregate and collecting and spraying device
US20020112567A1 (en) * 1997-12-26 2002-08-22 Nkk Corporation Smelting reduction method
CN101880765A (en) * 2010-06-29 2010-11-10 攀钢集团钢铁钒钛股份有限公司 Preparation method of high-titanium type vanadium-titanium magnetite agglomerate added with limonite
CN102206718A (en) * 2010-03-29 2011-10-05 攀钢集团钢铁钒钛股份有限公司 Furnace charge for vanadium-titanium magnetite blast furnace smelting, and blast furnace smelting method
CN102722652A (en) * 2012-06-01 2012-10-10 攀钢集团攀枝花钢钒有限公司 Blast furnace smelting cost calculating and optimizing method
CN103092087A (en) * 2011-11-02 2013-05-08 上海宝信软件股份有限公司 Blast furnace batching optimization method based on linear programming
CN103725872A (en) * 2013-12-20 2014-04-16 攀钢集团成都钢钒有限公司 Method for improving drum index of vanadium-titanium magnetite sinter
US20160045841A1 (en) * 2013-03-15 2016-02-18 Transtar Group, Ltd. New and improved system for processing various chemicals and materials
CN107151717A (en) * 2017-06-07 2017-09-12 攀钢集团攀枝花钢铁研究院有限公司 A kind of high chromium high-titanium type vanadium-titanium magnetite blast furnace ironmaking furnace charge and its blast furnace smelting method
CN108070713A (en) * 2016-11-10 2018-05-25 宝山钢铁股份有限公司 A kind of iron ore sintering method using calcined magnesite ball
CN108796212A (en) * 2017-04-28 2018-11-13 上海梅山钢铁股份有限公司 A kind of method of the compound fine iron breeze production sinter of self-fluxing nature
CN109583118A (en) * 2018-12-10 2019-04-05 武钢集团昆明钢铁股份有限公司 A kind of sintering proportion calculates and sinter Cost Optimization Approach
CN109814506A (en) * 2019-01-28 2019-05-28 辽宁工业大学 The intelligent optimal control device and its control method of metallurgy sintered blending process

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1107182A (en) * 1994-06-01 1995-08-23 重庆大学 Method for controlling low-temperature reduction degradation of blast furnace mineral aggregate and collecting and spraying device
US20020112567A1 (en) * 1997-12-26 2002-08-22 Nkk Corporation Smelting reduction method
CN102206718A (en) * 2010-03-29 2011-10-05 攀钢集团钢铁钒钛股份有限公司 Furnace charge for vanadium-titanium magnetite blast furnace smelting, and blast furnace smelting method
CN101880765A (en) * 2010-06-29 2010-11-10 攀钢集团钢铁钒钛股份有限公司 Preparation method of high-titanium type vanadium-titanium magnetite agglomerate added with limonite
CN103092087A (en) * 2011-11-02 2013-05-08 上海宝信软件股份有限公司 Blast furnace batching optimization method based on linear programming
CN102722652A (en) * 2012-06-01 2012-10-10 攀钢集团攀枝花钢钒有限公司 Blast furnace smelting cost calculating and optimizing method
US20160045841A1 (en) * 2013-03-15 2016-02-18 Transtar Group, Ltd. New and improved system for processing various chemicals and materials
CN103725872A (en) * 2013-12-20 2014-04-16 攀钢集团成都钢钒有限公司 Method for improving drum index of vanadium-titanium magnetite sinter
CN108070713A (en) * 2016-11-10 2018-05-25 宝山钢铁股份有限公司 A kind of iron ore sintering method using calcined magnesite ball
CN108796212A (en) * 2017-04-28 2018-11-13 上海梅山钢铁股份有限公司 A kind of method of the compound fine iron breeze production sinter of self-fluxing nature
CN107151717A (en) * 2017-06-07 2017-09-12 攀钢集团攀枝花钢铁研究院有限公司 A kind of high chromium high-titanium type vanadium-titanium magnetite blast furnace ironmaking furnace charge and its blast furnace smelting method
CN109583118A (en) * 2018-12-10 2019-04-05 武钢集团昆明钢铁股份有限公司 A kind of sintering proportion calculates and sinter Cost Optimization Approach
CN109814506A (en) * 2019-01-28 2019-05-28 辽宁工业大学 The intelligent optimal control device and its control method of metallurgy sintered blending process

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
CHENGUANG YANG等: "《A High-Performance Sintered Iron Electrode for Rechargeable Alkaline Batteries to Enable Large-Scale Energy Storage》", 《JOURNAL OF THE ELECTROCHEWICAL SOCIETY》 *
戴树平: "《烧结矿TFe、碱度稳定性影响因素的探讨》", 《烧结球团》 *
李青松等: "《恒定碱度条件下生石灰配比对烧结矿强度的影响研究》", 《贵州师范大学学报(自然科学版)》 *
石红燕等: "《烧结用料矿耗量理论计算及影响因素辨析》", 《山东冶金》 *
胡鹏等: "《白马钒钛精矿厚料层烧结技术研究》", 《烧结球团》 *
郝绍兰: "《选矿原矿经济性评价方法》", 《甘肃冶金》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111910072A (en) * 2020-09-09 2020-11-10 鞍钢股份有限公司 Preparation and use methods of pre-reduced fluxed pellets with steel slag as partial raw material
CN113626993A (en) * 2021-07-21 2021-11-09 包头钢铁(集团)有限责任公司 Method for evaluating smelting value of iron ore

Also Published As

Publication number Publication date
CN110672458B (en) 2022-05-24

Similar Documents

Publication Publication Date Title
CN101532084B (en) Method for charging iron ore sintering fuel
CN104862436B (en) A kind of large blast furnace banking distribution
CN110672458B (en) Method for rapidly evaluating vanadium-titanium magnetite concentrate agglomeration economy
CN113481382B (en) System and method for smelting tin-containing material
CN110136781B (en) Method for calculating enrichment amount of alkali metal elements in blast furnace
CN111910072A (en) Preparation and use methods of pre-reduced fluxed pellets with steel slag as partial raw material
CN103981310A (en) Method for melting vanadium titano-magnetite by blast furnace
CN108411056A (en) A kind of method that the big proportioning of blast furnace uses lump ore
CN106282453A (en) A kind of method of sefstromite blast furnace process
CN104152614B (en) The distributing process of blast furnace burden
CN105648233A (en) Smelting reduction method for secondary lead
CN102936526B (en) Combustion improver for blast furnace coal powder injection and use method thereof
CN104120207B (en) One joins the raw ferriferous method in ore deposit with tin tail iron ore concentrate and the poor assorted ore deposit of high harmful element
CN108950111A (en) High-grade blast-furnace smelting method for vanadium titano-magnetite
CN110727917B (en) Vanadium-titanium magnetite concentrate blast furnace smelting added imported ore and critical unit price analysis method thereof
CN102839281A (en) Method of producing titanium-bearing metallic pellets used for protecting blast furnace with rotary hearth furnace through direct reduction
CN102787188A (en) Process for smelting vanadium-containing pig iron by high-silicon vanadium titanomagnetite concentrate powder
CN109868336A (en) A kind of method of manganese content in control molten steel
CN107190114B (en) A method of improving high titania type slag fluidity
CN102046817A (en) Method for manufacturing pig iron
DE3307175C2 (en)
CN104911338B (en) A kind of raw materials for sintering composition and acid vanadium titanium sintering deposit and its preparation method and application
CN107967625A (en) A kind of Iron Ore Powder cost performance evaluation method
CN107043836A (en) A kind of method of blast furnace ironmaking
CN102337444A (en) Technology for producing vanadium chromium manganese alloyed pig iron by melting vanadium extraction tailings

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant