CN110668724A - Waste ceramic polishing sludge slurry and preparation method thereof - Google Patents

Waste ceramic polishing sludge slurry and preparation method thereof Download PDF

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Publication number
CN110668724A
CN110668724A CN201910960261.0A CN201910960261A CN110668724A CN 110668724 A CN110668724 A CN 110668724A CN 201910960261 A CN201910960261 A CN 201910960261A CN 110668724 A CN110668724 A CN 110668724A
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ceramic polishing
waste ceramic
sludge
slurry
suspension
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肖敏
刘福财
张信祯
黎浩
李斯思
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Guangdong Gateway New Materials Technology Co Ltd
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Guangdong Gateway New Materials Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/16Waste materials; Refuse from building or ceramic industry
    • C04B18/165Ceramic waste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention belongs to the technical field of solid waste resource utilization, and particularly relates to a waste ceramic polishing sludge slurry and a preparation method thereof, wherein the preparation method comprises the following steps: collecting waste ceramic polishing sludge, and then diluting the waste ceramic polishing sludge into a first sludge suspension with the concentration of 50-55%; sequentially carrying out precipitation treatment and filtration treatment on the first sludge suspension to obtain a second sludge suspension with the particle size of less than or equal to 0.15 mm; and (3) carrying out surface impurity removal treatment on the second sludge suspension, and then adding a dispersing agent and a diluting agent for mixing to obtain the waste ceramic polishing sludge slurry with the concentration of 40-50%. The preparation method is simple in process and low in cost, and the prepared waste ceramic polishing sludge slurry has good dispersibility and stability, so that the resource utilization rate of the waste ceramic polishing sludge is improved, waste can be changed into valuable, the landfill treatment of the waste ceramic polishing sludge is reduced, and the pollution of the waste ceramic polishing sludge to the environment is reduced.

Description

Waste ceramic polishing sludge slurry and preparation method thereof
Technical Field
The invention belongs to the technical field of resource utilization of solid wastes, and particularly relates to a waste ceramic polishing sludge slurry and a preparation method thereof.
Background
China is a big country for producing and consuming building ceramics. According to literature statistics, the ceramic polishing waste is produced by 1000 ten thousand tons every year in China. The solid waste with large amount has great harm to the environment and people, so the method has important significance for the research of recycling the ceramic waste. At present, ceramic waste is used for producing porous ceramic, and is added into a formula, but the treatment method has the disadvantages of high energy consumption, high cost, small yield and limited treatment capacity, and is not suitable for popularization and reference. The Wandongmei and Penggu utilize ceramic waste to develop solid concrete materials, but the method needs more high-strength adhesives and has more complex forming and is not suitable for wide application. In foreign countries, more than 40% of the ceramic waste can be recycled, and the rest can be prepared into ceramic waste powder to be supplied to other usable factories. The most important method of enterprises in China is landfill, a large amount of accumulated ceramic waste occupies the land, and seriously pollutes water, air and soil environments which human beings rely on for survival, so that the contradiction with ecological environment is more and more sharp, and a more reasonable and effective treatment method is urgently sought.
The study of the Shizheng and the like shows that: the addition of 5-10% of waste ceramic polishing sludge can improve the working performance of concrete, improve the compressive strength of concrete at each age and obviously improve the durability of concrete. However, when the amount of the ceramic polishing sludge exceeds 20%, the mechanical property and durability of the concrete are greatly reduced. In the doctor's paper of ceramic polishing sludge characteristics and comprehensive utilization research of gazang of university of southern China (2008), it is disclosed that the polishing sludge has a certain activity of volcanic ash, the cement mortar strength activity index can reach 84% under normal temperature conditions, and the polishing sludge has the potential to be used as an auxiliary cementing material.
The waste ceramic polishing sludge contains more silicon dioxide and aluminum trioxide in direct components, so the waste ceramic polishing sludge is a cheap active admixture, but the waste ceramic polishing sludge contains partial impurities such as broken porcelain, wood strips or paper scraps, and the waste ceramic polishing sludge is difficult to directly utilize. Most of the waste ceramic polishing sludge is processed by squeezing, drying, sorting and grinding modes and then recycled, so that the direct cost is high, the energy consumption is high, the efficiency is low, stable suspension is difficult to form after water is directly added, and the ash forms a precipitation state in a short time, so that stable sludge slurry is difficult to form, and the mass application of the sludge slurry in concrete is limited. We need to consider whether the waste ceramic polishing sludge can be prepared into slurry with stable performance, thereby realizing the mass application of the waste ceramic polishing sludge in concrete.
Disclosure of Invention
The invention aims to provide a waste ceramic polishing slurry and a preparation method thereof, and aims to solve the technical problem that the existing waste ceramic polishing slurry is unstable.
In order to achieve the purpose, the invention adopts the following technical scheme:
the invention provides a preparation method of waste ceramic polishing sludge slurry on one hand, which comprises the following steps:
collecting waste ceramic polishing sludge, and then diluting the waste ceramic polishing sludge into a first sludge suspension with the concentration of 50-55%;
sequentially carrying out precipitation treatment and filtration treatment on the first sludge suspension to obtain a second sludge suspension with the particle size of less than or equal to 0.15 mm;
and (3) carrying out surface impurity removal treatment on the second sludge suspension, and then adding a dispersing agent and a diluting agent for mixing to obtain the waste ceramic polishing sludge slurry with the concentration of 40-50%.
The preparation method of the waste ceramic polishing sludge slurry provided by the invention comprises the steps of firstly preliminarily diluting collected waste ceramic polishing sludge into a first sludge suspension with certain dispersibility and concentration of 50-55%, then precipitating and filtering to obtain a second sludge suspension with good activity index and particle size of less than or equal to 0.15mm, and finally adding a dispersing agent and a diluting agent into the second sludge suspension to be uniformly mixed to form the waste ceramic polishing sludge slurry with final concentration of 40-50%; the preparation method is simple in process and low in cost, and the prepared waste ceramic polishing sludge slurry has good dispersibility and stability, so that the resource utilization rate of the waste ceramic polishing sludge is improved, waste can be changed into valuable, the landfill treatment of the waste ceramic polishing sludge is reduced, and the pollution of the waste ceramic polishing sludge to the environment is reduced.
In another aspect, the invention provides a waste ceramic polishing slurry, which is obtained by the preparation method of the waste ceramic polishing slurry.
The waste ceramic polishing slurry provided by the invention is prepared by the special preparation method, and the obtained waste ceramic polishing slurry has good dispersibility and stability, so that the resource utilization rate of the waste ceramic polishing slurry is improved, waste can be changed into valuable, the landfill treatment of the waste ceramic polishing slurry is reduced, and the pollution of the waste ceramic polishing slurry to the environment is reduced.
Drawings
In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings needed to be used in the embodiments or the prior art descriptions will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without inventive exercise.
FIG. 1 is a schematic structural view of an apparatus for preparing a waste ceramic polishing slurry according to an embodiment of the present invention;
wherein, in the figures, the respective reference numerals:
1, a first sedimentation tank; 1-1 a first mixer; 1-2, a second stirrer; 1-3 partition walls; 1-4 of a filter valve;
2, a second sedimentation tank; 2-1, a third stirrer;
3, a mixing pool; 3-1, a fourth stirrer;
4, a storage tank; 4-1 circulating pump;
51 a first filter head; 61 a first pump; 71 a first pump tube;
52 a second filter head; 62 a second pump; 72 a second pump tube;
53 third filter head; 63 a third pump; 73 third pump line.
Detailed Description
In order to make the technical problems, technical solutions and advantageous effects to be solved by the present invention more clearly apparent, the present invention is further described in detail below with reference to the following embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
On the one hand, the embodiment of the invention provides a preparation method of waste ceramic polishing sludge slurry, which comprises the following steps:
s01: collecting waste ceramic polishing sludge, and then diluting the waste ceramic polishing sludge into a first sludge suspension with the concentration of 50-55%;
s02: sequentially carrying out precipitation treatment and filtration treatment on the first sludge suspension to obtain a second sludge suspension with the particle size of less than or equal to 0.15 mm;
s03: and (3) carrying out surface impurity removal treatment on the second sludge suspension, and then adding a dispersing agent and a diluting agent for mixing to obtain the waste ceramic polishing sludge slurry with the concentration of 40-50%.
The preparation method of the waste ceramic polishing sludge slurry provided by the embodiment of the invention comprises the steps of firstly preliminarily diluting collected waste ceramic polishing sludge into a first sludge suspension with certain dispersibility and concentration of 50-55%, then precipitating and filtering to obtain a second sludge suspension with good activity index and particle size of less than or equal to 0.15mm, and finally adding a dispersing agent and a diluting agent into the second sludge suspension to be uniformly mixed to form the waste ceramic polishing sludge slurry with final concentration of 40-50%; the preparation method is simple in process and low in cost, and the prepared waste ceramic polishing sludge slurry has good dispersibility and stability, so that the resource utilization rate of the waste ceramic polishing sludge is improved, waste can be changed into valuable, the landfill treatment of the waste ceramic polishing sludge is reduced, and the pollution of the waste ceramic polishing sludge to the environment is reduced.
The waste ceramic polishing slurry prepared by the embodiment of the invention is waste ceramic polishing slurry for concrete.
In one embodiment, the step of diluting the waste ceramic polishing sludge into a first sludge suspension having a concentration of 50-55% comprises: adding water, and stirring for 10-15 min. If the solid concentration in the first sludge suspension is more than 55%, the first sludge suspension is very viscous and not easy to disperse uniformly, and large particles are not easy to precipitate at the bottom, and a large number of experimental studies show that the waste ceramic polishing sludge slurry finally added with the dispersing agent can form stable slurry after being diluted to 40% -50%, and is not easy to delaminate; so that the sludge is diluted to an optimum concentration of 50-55% at the initial dilution.
In one embodiment, the filtration treatment comprises suction filtration with a filter screen having a diameter of 0.15mm or less. For example, particles having a size of greater than 0.15mm may be removed by filtration through a filter screen having a diameter of 0.15mm, resulting in a suspension having particles having a size of less than 0.15 mm. If the particle size is too large, the activity index of the sludge is lowered.
In one embodiment, the diluent comprises water. The dispersing agent comprises at least one of sodium pentapolyphosphate, sodium tridecyl, glycerol monostearate, hexenyl distearamide and sodium diacetate; the dispersant increases the repulsive force among particles to overcome the agglomeration caused by the van der Waals attractive force among the particles, thereby playing the roles of preventing sedimentation and reducing the viscosity of the slurry. Further, the dispersant accounts for 0.3-0.5% of the mass fraction of the ceramic polishing slurry. Namely, the ratio of the dispersant to the total mass of the waste ceramic polishing slurry is 3-5: 1000.
in one embodiment, the second sludge suspension is kept still for 5-15min, and is stirred for 3-5min after impurities on the surface of the liquid are removed.
In one embodiment, the amount of water added can be determined by testing the water content of the waste ceramic polishing sludge prior to diluting the waste ceramic polishing sludge into a first sludge suspension having a concentration of 50-55%; the amount of water added can be determined by testing the water content of the second sludge suspension before adding the dispersant and the diluent for mixing.
And finally, pumping the prepared waste ceramic polishing slurry into a storage tank for later use, wherein a circulating pump in the storage tank needs to be started for 5-10 minutes every 12 hours, so that the waste ceramic polishing slurry is prevented from being deposited and layered, and the stability of the performance of the waste ceramic polishing slurry is prevented from being influenced.
The final waste ceramic polishing slurry has a solid concentration of 40-50%, an average particle size of 1-100 μm, and does not settle after standing for 12 hours. And the energy consumption is low, the dispersion is uniform, the viscosity is low, the cement can be used as an auxiliary cementing material of concrete, cheap resources such as ceramic polishing sludge are fully utilized, and the environment-friendly and economic benefits are achieved.
On the other hand, the embodiment of the invention also provides the waste ceramic polishing slurry, which is obtained by the preparation method of the waste ceramic polishing slurry provided by the embodiment of the invention.
The waste ceramic polishing sludge slurry provided by the embodiment of the invention is prepared by the special preparation method of the embodiment of the invention, and the obtained waste ceramic polishing sludge slurry has good dispersibility and stability, so that the resource utilization rate of the waste ceramic polishing sludge is improved, waste can be changed into valuable, the landfill treatment of the waste ceramic polishing sludge is reduced, and the pollution of the waste ceramic polishing sludge to the environment is reduced.
In the embodiment of the invention, the average particle size of particles in the ceramic polishing slurry is 1-100 μm; the ceramic polishing slurry is kept still for 12 hours, and the concentration difference of the upper suspension and the lower suspension is less than 3 percent.
The invention is described in further detail with reference to a part of the test results, which are described in detail below with reference to specific examples.
Example 1
An apparatus for preparing a waste ceramic polishing slurry, as shown in fig. 1, comprising: the device comprises a first sedimentation tank 1, a second sedimentation tank 2, a mixing tank 3 and a storage tank 4, wherein the first sedimentation tank 1, the second sedimentation tank 2, the mixing tank 3 and the storage tank 4 are communicated in sequence;
a partition wall 1-3 is arranged in the first sedimentation tank 1, the partition wall 1-3 divides the first sedimentation tank 1 into a first chamber and a second chamber (not marked in the figure), and the partition wall 1-3 is provided with a filter valve 1-4 to communicate the first chamber with the second chamber; the first stirring machine 1-1 is arranged in the first chamber 1, the second stirring machine 1-2 is arranged in the second chamber 1, the third stirring machine 2-1 is arranged in the second sedimentation tank 2, the fourth stirring machine 3-1 is arranged in the mixing tank 3, and the circulating pump 4-1 is arranged in the storage tank 4.
A first pump 61 is arranged between the first sedimentation tank 1 and the second sedimentation tank 2, and a first filter head 51 is arranged at one end of the first pump 61 close to the first sedimentation tank 1; a second pump 62 is arranged between the second sedimentation tank 2 and the mixing tank 3, and a second filter head 52 is arranged at one end of the second pump 62 close to the second sedimentation tank 2; a third pump 63 is arranged between the mixing tank 3 and the storage tank 4, and a third filter head 53 is arranged at one end, close to the mixing tank 3, of the third pump 63; the first pump 61 is connected with the second sedimentation tank 2 through a first pump pipe 71, the second pump 62 is connected with the mixing tank 3 through a second pump pipe 72, and the third pump 63 is connected with the storage tank 4 through a third pump pipe 73.
The first filtering head 51, the second filtering head 52 and the third filtering head 53 are internally provided with filtering nets with the diameter less than or equal to 0.15 mm.
When the device is used, the waste ceramic polishing sludge is firstly put into the first chamber of the sedimentation tank 1, water is added, and the first stirrer 1-1 is used for stirring for 10-15 minutes to dilute into suspension with the concentration of 50-55%; the upper suspension flows into a second chamber of the sedimentation tank 1 through a control valve 1-4 on the partition wall 1-3, and a second stirrer 1-2 continues to stir for 3-5 minutes; pumping the second sediment 2 (the filter screen of the first filter head 51 arranged at the upstream of the first pump machine 61 is used for filtering, the particle size of the filtered suspension is less than 0.15mm) by using the first pump machine 61, standing for 5-15 minutes, removing light substances and foams floating on the liquid surface by using corresponding tools, and then stirring for 3-5 minutes by using a third stirrer 2-1; the S suspension is pumped into a mixing tank 3 by a second pump 62 (a second filter head 52 arranged at the upstream of the second pump 62 is also provided with a filter screen for filtration), dispersant and water are added into the mixing tank 3, a fourth stirrer 3-1 is used for stirring for 1-2 minutes, the waste ceramic polishing slurry is diluted to stable slurry with the concentration of 40-50%, and finally the stable slurry is pumped into a storage tank 4 for standby.
Example 2
A method for preparing a waste ceramic polishing slurry for concrete, which is carried out in the apparatus of example 1, comprises the steps of:
s11: testing the water content of the waste ceramic polishing sludge, weighing the waste ceramic polishing sludge, putting the waste ceramic polishing sludge into a first sedimentation tank, adding water, stirring the waste ceramic polishing sludge for 10 to 15 minutes, and diluting the waste ceramic polishing sludge into 50 percent suspension;
s12: pumping the suspension prepared in the step S11 into a second sedimentation tank through a filter screen, standing for 5-15 minutes, scooping out impurities floating on the liquid surface with a spoon, and stirring for 3-5 minutes, wherein the particle size of the suspension is smaller than 0.15 mm;
s13: pumping the suspension prepared in the step S12 into a mixing tank through a slurry pump with a filter screen, testing the water content, adding a dispersing agent and water into the mixing tank, stirring for 1-2 minutes, diluting the waste ceramic polishing slurry into stable slurry with the concentration of 50%, and finally pumping into a storage tank for later use.
Example 3
A method for preparing a waste ceramic polishing slurry for concrete, which is carried out in the apparatus of example 1, comprises the steps of:
s21: testing the water content of the waste ceramic polishing sludge, weighing the waste ceramic polishing sludge, putting the waste ceramic polishing sludge into a first sedimentation tank, adding water, stirring the waste ceramic polishing sludge for 10 to 15 minutes, and diluting the waste ceramic polishing sludge into 50 percent suspension;
s22: pumping the suspension prepared in the step S21 into a second sedimentation tank through a filter screen, standing for 5-15 minutes, scooping out impurities floating on the liquid surface by using a spoon, and then stirring for 3-5 minutes;
s23: pumping the suspension prepared in the step S22 into a mixing tank through a slurry pump with a filter screen, testing the water content, adding a dispersing agent and water into the mixing tank, stirring for 1-2 minutes, diluting the waste ceramic polishing slurry to 40% stable slurry, and finally pumping the slurry into a storage tank for later use.
Comparative example 1
The procedure is as in example 2 except that no dispersant is added.
Comparative example 2
The same conditions as in example 2 were used except that the slurry of the waste ceramic polishing slurry was finally diluted to a 35% concentration.
Comparative example 3
The conditions were the same as in example 2 except that the waste ceramic polishing slurry was finally diluted to a 30% concentration.
Performance testing
The waste ceramic polishing slurry obtained in the examples 2 to 3 and the comparative examples 1 to 3 was subjected to a settling test after being left to stand for different periods of time, and the experimental data are shown in table 1:
TABLE 1
Figure BDA0002228680450000091
From table 1, in comparative example 1, no dispersant is added, and compared with example 1, the suspension is obviously layered after standing for 6 hours and 12 hours, the suspension is unstable, and the concentration difference of the upper suspension and the lower suspension is 65% when the suspension is standing for 12 hours; in comparative example 2, the waste ceramic polishing slurry is diluted to 35% concentration, compared with example 1, standing for 6h and 12h obviously stratifies, and the concentration difference of the upper layer suspension and the lower layer suspension is 50.1% when standing for 12 h; in comparative example 3, the slurry of the waste ceramic polishing slurry was diluted to 30% concentration, and compared with example 1, the slurry was significantly layered after standing for 6 hours, and was severely layered after standing for 12 hours, and the difference in the concentration between the upper and lower layer suspensions was 41.3%. Through a large number of experiments, the concentration ranges of the dispersing agent and the waste ceramic polishing sludge slurry selected in the embodiment of the invention are optimal.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention are intended to be included within the scope of the present invention.

Claims (10)

1. A preparation method of waste ceramic polishing sludge slurry is characterized by comprising the following steps:
collecting waste ceramic polishing sludge, and then diluting the waste ceramic polishing sludge into a first sludge suspension with the concentration of 50-55%;
sequentially carrying out precipitation treatment and filtration treatment on the first sludge suspension to obtain a second sludge suspension with the particle size of less than or equal to 0.15 mm;
and (3) carrying out surface impurity removal treatment on the second sludge suspension, and then adding a dispersing agent and a diluting agent for mixing to obtain the waste ceramic polishing sludge slurry with the concentration of 40-50%.
2. The method of preparing a waste ceramic polishing slurry as claimed in claim 1, wherein the step of diluting the waste ceramic polishing slurry into a first slurry suspension having a concentration of 50-55% comprises: adding water, and stirring for 10-15 min.
3. The method of preparing the waste ceramic polishing slurry according to claim 1, wherein the filtering treatment comprises suction filtration using a filter net having a diameter of 0.15mm or less.
4. The method of preparing the waste ceramic polishing slurry according to claim 1, wherein the dispersant comprises at least one of sodium pentapolyphosphate, sodium tridecyl, glycerol monostearate, hexenyl distearamide, and sodium diacetate; and/or the presence of a gas in the gas,
the diluent comprises water.
5. The method of preparing the waste ceramic polishing slurry according to claim 1, wherein the dispersant accounts for 0.3 to 0.5% by mass of the ceramic polishing slurry.
6. The method of preparing the waste ceramic polishing slurry according to claim 1, wherein the subjecting the second slurry suspension to surface desmearing treatment comprises: and standing the second sludge suspension for 5-15min, removing impurities on the surface of the liquid, and stirring for 3-5 min.
7. The method of preparing a waste ceramic polishing slurry as claimed in any one of claims 1 to 6, wherein the water content of the waste ceramic polishing slurry is measured before the waste ceramic polishing slurry is diluted into the first slurry suspension having a concentration of 50 to 55%; and/or the presence of a gas in the gas,
the water content of the second sludge suspension is tested before the dispersant and diluent are added and mixed.
8. The method of preparing the waste ceramic polishing slurry according to any one of claims 1 to 6, wherein the waste ceramic polishing slurry is a waste ceramic polishing slurry for concrete.
9. A waste ceramic polishing slurry, characterized in that the waste ceramic polishing slurry is obtained by the method for preparing the waste ceramic polishing slurry according to any one of claims 1 to 8.
10. The waste ceramic polishing slurry according to claim 9, wherein the average particle diameter of the particles in the ceramic polishing slurry is 1 to 100 μm; and/or the presence of a gas in the gas,
the ceramic polishing slurry is kept still for 12 hours, and the concentration difference of the upper suspension and the lower suspension is less than 3 percent.
CN201910960261.0A 2019-10-10 2019-10-10 Waste ceramic polishing sludge slurry and preparation method thereof Pending CN110668724A (en)

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Citations (3)

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Publication number Priority date Publication date Assignee Title
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Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1164223A (en) * 1994-09-01 1997-11-05 卡伯特公司 Ceramic slip composition and method for making the same
CN101870546A (en) * 2010-06-01 2010-10-27 广州市保明莱环保科技有限公司 River surge silt harmless and recycling treatment method
CN106220217A (en) * 2016-07-25 2016-12-14 黄贺明 A kind of air-entrained concrete building block and preparation method thereof

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Title
张云龙等: "《碳化硅及其复合材料的制造与应用》", 31 July 2015, 国防工业出版社 *
支斌: "建陶工业固体废弃物再利用技术研究", 《中国优秀硕士学位论文全文数据库(电子期刊)工程科技Ⅰ辑》 *
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