CN110668566A - Device and method for sludge reduction and total nitrogen removal by sludge fermentation coupled with short-range denitrification in series with two-stage anaerobic ammonia oxidation - Google Patents
Device and method for sludge reduction and total nitrogen removal by sludge fermentation coupled with short-range denitrification in series with two-stage anaerobic ammonia oxidation Download PDFInfo
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Abstract
污泥发酵耦合短程反硝化串联二级厌氧氨氧化实现污泥减量与总氮去除的装置与方法属污水生物处理领域。装置包括原水箱、污泥贮存罐、硝化液水箱、中间水箱、两个SBR反应器、出水箱。剩余污泥进入污泥发酵耦合短程反硝化反应器,通过发酵将污泥中的难降解有机物转化为易降解有机物;然后硝化液进入污泥发酵耦合短程反硝化反应器,以发酵产物为碳源反应,完成亚硝的积累;最后该反应器的出水与生活污水一同进入厌氧氨氧化生物膜反应器,实现总氮去除。该方法将污泥发酵耦合短程反硝化与厌氧氨氧化串联在一起,既降低污泥处置的费用又节约了碳源,同时为厌氧氨氧化菌提供更适宜的生存条件,从而实现污泥减量与总氮去除。
A device and method for sludge fermentation coupled with short-range denitrification in series with two-stage anaerobic ammonium oxidation to realize sludge reduction and total nitrogen removal belong to the field of sewage biological treatment. The device includes a raw water tank, a sludge storage tank, a nitrifying liquid water tank, an intermediate water tank, two SBR reactors, and a water outlet tank. The excess sludge enters the sludge fermentation coupled short-range denitrification reactor, and the refractory organic matter in the sludge is converted into easily degradable organic matter through fermentation; then the nitrification solution enters the sludge fermentation coupled with the short-range denitrification reactor, and the fermentation product is used as the carbon source reaction to complete the accumulation of nitrous; finally, the effluent from the reactor and the domestic sewage enter the anammox biofilm reactor to achieve total nitrogen removal. The method combines sludge fermentation coupled with short-range denitrification and anammox in series, which not only reduces the cost of sludge disposal, but also saves carbon sources, and provides more suitable living conditions for anammox bacteria, thereby realizing sludge disposal. Reduction and total nitrogen removal.
Description
技术领域technical field
本发明涉及的污泥发酵耦合短程反硝化串联二级厌氧氨氧化同步实现污泥减量与总氮去除的装置与方法,属于污水生物处理技术领域,是实现剩余污泥无害化减量同时实现总氮去除的试验装置和方法。The invention relates to a device and method for synchronously realizing sludge reduction and total nitrogen removal by coupling with short-range denitrification and series two-stage anaerobic ammonia oxidation, belonging to the technical field of sewage biological treatment, and is a method for realizing the harmless reduction of excess sludge. A test device and method for simultaneously realizing total nitrogen removal.
背景技术Background technique
随着工业的发展,居民生活水平的提高,水体中氮磷等营养物质随之增多,富营养化问题频繁发生。水体中磷的去除可通过生物吸附、化学沉降等多种方法去除,而氮元素只能通过氮循环将化合态的氮氧化还原为氮气从而排除水体。所以探究新型的脱氮工艺尤为重要。With the development of industry and the improvement of living standards of residents, nutrients such as nitrogen and phosphorus in the water body have increased, and eutrophication problems have occurred frequently. Phosphorus in water can be removed by various methods such as biological adsorption and chemical sedimentation, while nitrogen can only be removed from water by redoxing combined nitrogen to nitrogen through nitrogen cycle. Therefore, it is particularly important to explore new denitrification processes.
其中,厌氧氨氧化工艺由于其高效性、经济型以及具有良好的节能效果,被多数学者青睐。与传统硝化反硝化相比,短程硝化耦合厌氧氨氧化可以节省58.6%的曝气与100%的碳源,而短程反硝化耦合厌氧氨氧化则可以节省44.9%的曝气与73%的碳源。Among them, anammox process is favored by most scholars due to its high efficiency, economy and good energy saving effect. Compared with traditional nitrification and denitrification, short-path nitrification coupled with anammox can save 58.6% of aeration and 100% of carbon sources, while short-path denitrification coupled with anammox can save 44.9% of aeration and 73% of carbon sources. carbon source.
在工程中厌氧氨氧化的实现仍存在一定障碍,如厌氧氨氧化菌富集较为困难、厌氧氨氧化菌对亚硝酸盐的竞争力弱于NOB以及城市污水处理水量大等。相比于短程硝化工艺,短程反硝化避免了NOB竞争亚硝酸盐的情况,具有稳定性强,不易被破坏的优点。但是短程反硝化菌对碳源的选择性强,富集较为困难,且富集的短程反硝化菌可以利用易降解有机物,不能利用难降解有机物。通过研究表明,通过水解酸化技术可以实现难降解有机物向易降解有机物的转化的问题。There are still some obstacles in the realization of anammox in engineering, such as the difficulty of enrichment of anammox bacteria, the weaker competitiveness of anammox bacteria for nitrite than NOB, and the large amount of urban sewage treatment water. Compared with the short-path nitrification process, the short-path denitrification avoids the competition of NOB for nitrite, and has the advantages of strong stability and not easy to be destroyed. However, the short-range denitrifying bacteria have strong selectivity to carbon sources, and the enrichment is difficult, and the enriched short-range denitrifying bacteria can utilize easily degradable organic matter, but cannot utilize refractory organic matter. The research shows that the conversion of refractory organic matter to easily degradable organic matter can be realized by hydrolysis and acidification technology.
各城市污水处理厂每天要排放大量的剩余污泥,其处理与处置费用高,同时如果处理不当将会成为另一种形式的污染。且目前城市污水多为低C/N,这使得传统的脱氮工艺中需投加碳源,而剩余污泥本就是一种复杂形式的碳源,可以将剩余污泥的水解产物作为有机碳源帮助实现脱氮过程,此法既实现了剩余污泥的减量同时又节省了碳源。The urban sewage treatment plants discharge a large amount of excess sludge every day, and the treatment and disposal costs are high. At the same time, if the treatment is improper, it will become another form of pollution. And most of the current urban sewage has low C/N, which makes it necessary to add a carbon source in the traditional denitrification process, and the excess sludge is a complex form of carbon source, and the hydrolyzed product of the excess sludge can be used as organic carbon. This method not only realizes the reduction of excess sludge but also saves carbon sources.
剩余污泥中活性微生物的组成不同,对反应系统存在一定的影响,所以可以通过一定的技术手段进行预处理,降低剩余污泥活性,减少对短程反硝化的影响。目前污泥预处理的方法包括物理法和化学法两种,物理法包括超声、热水解、机械粉碎等,化学法主要以投加化学药品为主。相比于化学法,物理法更简单、安全且易控制。The composition of active microorganisms in excess sludge is different, which has a certain impact on the reaction system. Therefore, certain technical means can be used for pretreatment to reduce the activity of excess sludge and reduce the impact on short-range denitrification. At present, the methods of sludge pretreatment include physical method and chemical method. The physical method includes ultrasonic, thermal hydrolysis, mechanical pulverization, etc. The chemical method is mainly based on the addition of chemicals. Compared with chemical methods, physical methods are simpler, safer and easier to control.
若基于以上手段的技术控制,则有望实现污泥发酵耦合短程反硝化从而实现污泥减量的转化和亚硝酸盐的稳定积累。If the technical control is based on the above means, it is expected to realize sludge fermentation coupled with short-range denitrification to realize the conversion of sludge reduction and the stable accumulation of nitrite.
反硝化菌的产率系数为0.3g VSS/g NH4 +-N,而厌氧氨氧化菌产率系数仅为0.066gVSS/g NH4 +-N,因此,反硝化菌生长速率远远高于厌氧氨氧化菌生长速率,同时两种菌均可利用亚硝酸盐为底物产生氮气,所以当系统中存在足量有机物与硝酸盐或亚硝酸盐时,反硝化菌逐渐成为优势菌,而厌氧氨氧化菌数量逐渐减少。两种菌种间的竞争可以通过分开工作的方式得以解决。The yield coefficient of denitrifying bacteria is 0.3g VSS/g NH 4 + -N, while the yield coefficient of anammox bacteria is only 0.066gVSS/g NH 4 + -N, so the growth rate of denitrifying bacteria is much higher Due to the growth rate of anammox bacteria, both bacteria can use nitrite as a substrate to generate nitrogen gas, so when there is sufficient organic matter and nitrate or nitrite in the system, denitrifying bacteria gradually become dominant bacteria. The number of anammox bacteria gradually decreased. The competition between the two species can be resolved by working separately.
污泥发酵耦合短程反硝化串联厌氧氨氧化工艺:一方面可以在一个SBR反应器内实现污泥发酵耦合短程反硝化,在无外加碳源的基础上同时完成短程反硝化和污泥减量。通过向SBR反应器中投加水解酸化耦合短程反硝化的活性污泥,在反应过程中可以实现污泥发酵耦合短程反硝化工艺。在污泥发酵过程中,产生易降解有机物,为短程反硝化提供碳源,从而实现亚硝酸盐的积累。同时将剩余污泥的水解产物作为有机碳源帮助实现脱氮过程,此法既实现了剩余污泥的减量同时又节省了碳源。Sludge fermentation coupled with short-range denitrification and tandem anammox process: On the one hand, sludge fermentation coupled with short-range denitrification can be realized in one SBR reactor, and short-range denitrification and sludge reduction can be accomplished at the same time on the basis of no external carbon source. . By adding the activated sludge of hydrolysis and acidification coupled with short-range denitrification into the SBR reactor, the process of sludge fermentation coupled with short-range denitrification can be realized during the reaction process. In the process of sludge fermentation, easily degradable organic matter is produced to provide carbon source for short-range denitrification, thereby realizing the accumulation of nitrite. At the same time, the hydrolyzate of the excess sludge is used as an organic carbon source to help realize the denitrification process. This method not only realizes the reduction of the excess sludge but also saves the carbon source.
另一方面,在一个SBBR反应器内实现厌氧氨氧化脱氮。通过向SBBR反应器内投加富集厌氧氨氧化菌的生物膜填料,可实现厌氧氨氧化菌的附着生长,保持厌氧氨氧化菌的生物量。由SBR反应器的排水中的亚硝酸盐与生活污水中的氨氮进行厌氧氨氧化反应,剩余的亚硝酸盐可由生活污水携带的少量反硝化菌利用其中的有机物进行反硝化,综上可实现总氮的去除。On the other hand, anammox denitrification is achieved in an SBBR reactor. By adding biofilm packing enriched with anammox bacteria into the SBBR reactor, the attached growth of anammox bacteria can be realized and the biomass of anammox bacteria can be maintained. The nitrite in the drainage of the SBR reactor and the ammonia nitrogen in the domestic sewage undergo an anaerobic ammonium oxidation reaction, and the remaining nitrite can be denitrified by a small amount of denitrifying bacteria carried by the domestic sewage using the organic matter in it. Total nitrogen removal.
本串联工艺不仅工艺简单,还具有厌氧氨氧化、污泥发酵、短程反硝化等工艺的各自优势,同时实现污泥减量和总氮的去除。The tandem process is not only simple in process, but also has the respective advantages of anaerobic ammonia oxidation, sludge fermentation, short-range denitrification and other processes, and simultaneously realizes sludge reduction and total nitrogen removal.
发明内容SUMMARY OF THE INVENTION
本发明所要解决的技术问题是提供一种一级污泥发酵耦合短程反硝化串联二级厌氧氨氧化工艺的装置和方法,来通过污泥发酵提供碳源、产生并积累亚硝酸盐氮的积累,实现剩余污泥的减量以及节省碳源,然后串联厌氧氨氧化,实现总氮去除的问题。The technical problem to be solved by the present invention is to provide a device and method for a first-stage sludge fermentation coupled with a short-range denitrification and a series of two-stage anammox processes, so as to provide a carbon source, generate and accumulate nitrite nitrogen through sludge fermentation. Accumulation, reducing excess sludge and saving carbon sources, and then anaerobic ammonia oxidation in series to achieve total nitrogen removal.
本发明的目的是通过以下技术方案来解决的:一级污泥发酵耦合短程反硝化串联二级厌氧氨氧化实现污泥减量以及总氮去除的装置与方法,其特征在于,包括城市污水原水水箱(1)、污泥混合液贮存罐(2)、硝化液水箱(3)、污泥发酵耦合短程反硝化反应器(4)、中间水箱(5)、厌氧氨氧化生物膜反应器(6)、出水水箱(7)。The object of the present invention is to be solved by the following technical solutions: a device and method for realizing sludge reduction and total nitrogen removal by first-stage sludge fermentation coupled with short-range denitrification in series with two-stage anaerobic ammonium oxidation, characterized in that it includes municipal sewage Raw water tank (1), sludge mixed liquid storage tank (2), nitrification liquid tank (3), sludge fermentation coupled short-range denitrification reactor (4), intermediate water tank (5), anammox biofilm reactor (6), the water outlet tank (7).
所述污泥混合液贮存罐(2)设有搅拌装置Ⅲ(2.1);所述污泥发酵耦合短程反硝化反应器(4)内置有进泥泵(4.1)、进水泵Ⅰ(4.2)、排水电动阀Ⅰ(4.3)、搅拌装置Ⅰ(4.4)、DO在线检测仪Ⅰ(4.5)、第一取样口(4.6)、第二取样口(4.7);所述厌氧氨氧化生物膜反应器(6)内置进水泵Ⅱ(6.1)、中间水箱水泵(6.2)、电动排水阀Ⅱ(6.3)、搅拌装置Ⅱ(6.4)、DO在线检测仪Ⅱ(6.5)、填料及填料架(6.6)、取样口(6.7);所述出水水箱(7)设有溢流管(7.1)、排水管(7.2)。The sludge mixed liquor storage tank (2) is provided with a stirring device III (2.1); the sludge fermentation coupled short-range denitrification reactor (4) is provided with a built-in sludge feed pump (4.1), feed pump I (4.2), Drainage electric valve I (4.3), stirring device I (4.4), DO online detector I (4.5), first sampling port (4.6), second sampling port (4.7); the anammox biofilm reactor (6) Built-in inlet water pump II (6.1), intermediate water tank water pump (6.2), electric drain valve II (6.3), stirring device II (6.4), DO online detector II (6.5), packing and packing frame (6.6), A sampling port (6.7); the water outlet tank (7) is provided with an overflow pipe (7.1) and a drain pipe (7.2).
其中所述污泥混合液贮存罐(2)通过进泥泵(4.1)与污泥发酵耦合短程反硝化反应器(4)相连接;硝化液水箱(3)通过进水泵Ⅰ(4.2)与污泥发酵耦合短程反硝化反应器(4)相连接;污泥发酵耦合短程反硝化反应器(4)排水电动阀Ⅰ(4.3)与中间水箱(5)相连接;中间水箱(5)通过中间水箱水泵(6.2)与厌氧氨氧化生物膜反应器(6)相连接;城市污水原水水箱(1)通过进水泵Ⅱ(6.1)与厌氧氨氧化生物膜反应器(6)相连接;厌氧氨氧化生物膜反应器(6)电动排水阀Ⅱ(6.3)与出水水箱(7)相连接。Wherein, the sludge mixed liquid storage tank (2) is connected with the sludge fermentation coupled short-range denitrification reactor (4) through the sludge feed pump (4.1); The sludge fermentation is coupled with the short-range denitrification reactor (4); the sludge fermentation is coupled with the short-range denitrification reactor (4), and the drain electric valve I (4.3) is connected with the intermediate water tank (5); the intermediate water tank (5) passes through the intermediate water tank The water pump (6.2) is connected with the anammox biofilm reactor (6); the urban sewage raw water tank (1) is connected with the anammox biofilm reactor (6) through the feed pump II (6.1); The electric drain valve II (6.3) of the ammonia oxidation biofilm reactor (6) is connected with the water outlet tank (7).
本发明还提供了一种一级污泥发酵耦合短程反硝化串联二级厌氧氨氧化的方法,其具体启动及调控步骤如下:The present invention also provides a method for the first-level sludge fermentation coupled with short-range denitrification in series with the second-level anaerobic ammonium oxidation, and the specific start-up and control steps are as follows:
1)系统启动:将水解酸化耦合短程反硝化污泥投加至污泥发酵耦合短程反硝化反应器(4)内,使接种后反应器内污泥浓度达到2000~6000mg/L(以反应器有效容积计);将富集厌氧氨氧化菌的生物膜填料投加至厌氧氨氧化生物膜反应器(6)内,使厌氧氨氧化菌的生物膜填料占厌氧氨氧化生物膜反应器(6)有效体积的20%~80%。1) System start-up: Add hydrolysis acidification coupled short-range denitrification sludge to the sludge fermentation coupled short-range denitrification reactor (4), so that the sludge concentration in the reactor after inoculation reaches 2000-6000 mg/L (with the reactor Effective volume meter); add the biofilm packing enriched with anammox bacteria into the anammox biofilm reactor (6), so that the biofilm packing of anammox bacteria accounts for the anammox biofilm 20% to 80% of the effective volume of the reactor (6).
2)剩余污泥、硝化液、原水与中间亚硝酸盐溶液进量的确定:2) Determination of the amount of excess sludge, nitrification solution, raw water and intermediate nitrite solution:
取剩余污泥在30摄氏度下使其进行发酵,通过对SCOD浓度进行测定,当SCOD浓度无增长趋势且20分钟内SCOD值不再增长时,此时为该浓度下污泥发酵的最大潜力。Take the remaining sludge and ferment it at 30 degrees Celsius. By measuring the SCOD concentration, when the SCOD concentration has no increasing trend and the SCOD value does not increase within 20 minutes, it is the maximum potential of sludge fermentation at this concentration.
在污泥发酵耦合短程反硝化反应器(4)内根据计算公式(1)(2)确定有机物与硝酸盐进量:In the sludge fermentation coupled short-range denitrification reactor (4), the organic matter and nitrate feeds are determined according to the calculation formulas (1) and (2):
V1+V2=V·P1 (2)V 1 +V 2 =V·P 1 (2)
注:式中SCOD为该剩余污泥最大发酵潜力下的SCOD浓度;Note: SCOD in the formula is the SCOD concentration under the maximum fermentation potential of the excess sludge;
V1、V2、V分别为有机物进量、硝酸盐溶液进量与反应器有效体积V 1 , V 2 , V are the organic matter feed, the nitrate solution feed and the effective volume of the reactor, respectively
NO3 -为进水硝酸盐浓度;NO 3 - is the influent nitrate concentration;
C/N为设定值,取值在3:1~6:1范围内任取;C/N is the set value, and the value can be arbitrarily selected within the range of 3:1 to 6:1;
P1为排水比,设定值,取60%。P 1 is the drainage ratio, the set value, which is 60%.
在厌氧氨氧化生物膜反应器(6)内根据计算公式(3)(4)确定原水与中间水箱水进量:In the anammox biofilm reactor (6), according to the calculation formula (3) (4), determine the raw water and intermediate water tank water inflow:
V3+V4=V·P2 (4)V 3 +V 4 =V·P 2 (4)
注:式中NO2 -为中间水箱中NO2 -浓度、NH4 +-为原水NH4 +浓度;Note: in the formula NO 2 - is the NO 2 - concentration in the intermediate water tank, NH 4 +- is the raw water NH 4 + concentration;
V3、V4、V分别为NO2 -溶液进量、NH4 +溶液进量与反应器有效体积;V 3 , V 4 , and V are the NO 2 - solution feed, the NH 4 + solution feed and the effective volume of the reactor, respectively;
P2为排水比,设定值,为50%;P 2 is the drainage ratio, the set value, which is 50%;
NO2 -/NH4 +为设定比值,取值在1.4:1~2:1范围内任取。NO 2 - /NH 4 + is the set ratio, and the value can be arbitrarily selected within the range of 1.4:1 to 2:1.
3)运行时调节操作如下:3) The adjustment operation at runtime is as follows:
将剩余污泥投加至污泥混合液贮存罐(1),每周期开始前启动搅拌器(1.1)使剩余污泥混合均匀,然后启动进泥泵(4.1),在每周期开始时将V1体积的剩余污泥混合液抽入污泥发酵耦合短程反硝化反应器(4)内,进行污泥发酵;Add the excess sludge to the sludge mixed liquid storage tank (1), start the agitator (1.1) before the start of each cycle to mix the excess sludge evenly, and then start the sludge feed pump (4.1), at the beginning of each cycle V 1 volume of excess sludge mixed solution is pumped into the sludge fermentation coupled short-range denitrification reactor (4) to carry out sludge fermentation;
污泥发酵耦合短程反硝化反应器(4)运行时,每周期先厌氧搅拌200~800min,SCOD值达最大发酵潜力的95%以上时结束厌氧搅拌;然后启动进水泵Ⅰ(4.2)将硝化液水箱(3)中V2体积的硝化液抽入污泥发酵耦合短程反硝化反应器(4)内,使污泥发酵耦合短程反硝化反应器(4)内硝酸盐氮浓度为设定浓度,设定浓度满足C/N在3:1~6:1;缺氧搅拌至亚硝酸盐转化率达80%以上或硝氮浓度小于3mg/L,然后停止搅拌开始沉淀排水10分钟,闲置后进入下一个周期。When the sludge fermentation is coupled with the short-range denitrification reactor (4), anaerobic stirring is performed for 200-800 minutes in each cycle, and the anaerobic stirring is terminated when the SCOD value reaches more than 95% of the maximum fermentation potential; The nitrifying liquid in the nitrifying liquid tank ( 3 ) is pumped into the sludge fermentation coupled short-path denitrification reactor (4), so that the nitrate nitrogen concentration in the sludge fermentation coupling short-path denitrification reactor (4) is set to Concentration, set the concentration to meet the C/N ratio of 3:1 to 6:1; stir in anoxic until the nitrite conversion rate reaches more than 80% or the nitrate concentration is less than 3mg/L, then stop stirring and start precipitation and drainage for 10 minutes, idle Then enter the next cycle.
在污泥发酵耦合短程反硝化反应器(4)排水结束后,启动中间水箱水泵(6.2)将中间水箱V3体积的硝化液抽入厌氧氨氧化生物膜反应器(6)内,同时启动水泵Ⅱ(6.1)将V4体积的城市污水原水抽入厌氧氨氧化生物膜反应器(6)内,使其中亚硝酸盐与氨氮的比值满足设定值,设定值在1.4:1~2:1范围内任取;缺氧搅拌至总无机氮浓度低于5mg/L,停止搅拌,沉淀排水10分钟,闲置后进入下一个周期。After the sludge fermentation coupled with the short-range denitrification reactor (4) drains the water, the intermediate water tank water pump (6.2) is started to pump the nitrification solution of the intermediate water tank V 3 volume into the anammox biofilm reactor (6), and at the same time the Pump II (6.1) pumps V4 volume of raw urban sewage into the anaerobic ammonia oxidation biofilm reactor (6), so that the ratio of nitrite to ammonia nitrogen meets the set value, and the set value is 1.4:1~ Anything within the range of 2:1; anoxic stirring until the total inorganic nitrogen concentration is lower than 5mg/L, stop stirring, precipitate and drain for 10 minutes, and enter the next cycle after being idle.
本发明的污泥发酵耦合短程反硝化串联二级厌氧氨氧化实现污泥减量与总氮去除的装置与方法,具有以下优点:The device and method for sludge fermentation coupled with short-range denitrification in series with two-stage anaerobic ammonia oxidation to realize sludge reduction and total nitrogen removal of the present invention have the following advantages:
1)通过污泥发酵技术,实现了剩余活性污泥的减量,并将剩余污泥资源化,减少外碳源的投加,节约了污泥处置的费用。1) Through the sludge fermentation technology, the weight reduction of the excess activated sludge is realized, the excess sludge is recycled, the addition of external carbon sources is reduced, and the cost of sludge disposal is saved.
2)通过条件控制,实现稳定的亚硝酸盐的积累,可为二级厌氧氨氧化工艺提供底物来源,为短程反硝化工艺的实现以及过程控制提供良好的借鉴思路。2) Through condition control, the stable accumulation of nitrite can be achieved, which can provide a substrate source for the secondary anammox process, and provide a good reference for the realization and process control of the short-range denitrification process.
3)在同一反应器内实现污泥发酵耦合短程反硝化,在实现剩余污泥的易降解,将其转化为易降解有机物,为短程反硝化菌提供易降解碳源,在无外加碳源的条件下实现短程反硝化中的亚硝酸盐的积累,节约能源。3) Realize sludge fermentation coupled with short-range denitrification in the same reactor, in order to realize the easy degradation of excess sludge, convert it into easily degradable organic matter, and provide easily degradable carbon source for short-range denitrification bacteria, and in the process without external carbon source Accumulation of nitrite in short-range denitrification can be realized under the condition of energy saving.
4)本工艺装置为二级串联装置,一级反应器进行污泥发酵与短程反硝化,二级反应器进行厌氧氨氧化,此设计避免了反硝化菌与厌氧氨氧化菌竞争底物的情况,同时可以为厌氧氨氧化菌提供更优质的反应条件,更有利于厌氧氨氧化反应的发生。4) This process device is a two-stage series device. The first-stage reactor is used for sludge fermentation and short-range denitrification, and the second-stage reactor is used for anammox. This design avoids competition between denitrifying bacteria and anammox bacteria for substrates. At the same time, it can provide better reaction conditions for anammox bacteria, which is more conducive to the occurrence of anammox reaction.
附图说明Description of drawings
图1为本污泥发酵耦合短程反硝化串联二级厌氧氨氧化实现污泥减量与总氮去除装置的结构示意图。Figure 1 is a schematic diagram of the structure of the sludge fermentation coupled with short-range denitrification in series with two-stage anaerobic ammonium oxidation to achieve sludge reduction and total nitrogen removal.
图中1为城市污水原水水箱,2为污泥混合液贮存罐,3为硝化液水箱,4为污泥发酵耦合短程反硝化反应器,5为中间水箱,6为厌氧氨氧化生物膜反应器,7为出水水箱;2.1为搅拌装置Ⅲ;4.1为进泥泵,4.2为进水泵Ⅰ,4.3为排水电动阀Ⅰ,4.4为搅拌装置Ⅰ,4.5为DO在线检测仪Ⅰ,4.6为第一取样口,4.7为第二取样口;6.1为进水泵Ⅱ,6.2为中间水箱水泵,6.3为电动排水阀Ⅱ,6.4为搅拌装置Ⅱ,6.5为DO在线检测仪Ⅱ,6.6为填料及填料架,6.7为取样口;7.1为出水箱溢流管、7.2为出水箱排水管。In the figure, 1 is the urban sewage raw water tank, 2 is the sludge mixed liquid storage tank, 3 is the nitrification liquid tank, 4 is the sludge fermentation coupled short-range denitrification reactor, 5 is the intermediate water tank, and 6 is the anammox biofilm reaction. 7 is the water outlet tank; 2.1 is the stirring device III; 4.1 is the mud pump, 4.2 is the intake pump I, 4.3 is the drain electric valve I, 4.4 is the stirring device I, 4.5 is the DO online detector I, and 4.6 is the first Sampling port, 4.7 is the second sampling port; 6.1 is the inlet water pump II, 6.2 is the intermediate water tank water pump, 6.3 is the electric drain valve II, 6.4 is the stirring device II, 6.5 is the DO online detector II, 6.6 is the packing and packing frame, 6.7 is the sampling port; 7.1 is the overflow pipe of the water outlet, and 7.2 is the drain pipe of the water outlet.
具体实施方式Detailed ways
下面结合附图和实施例对本发明做进一步的说明:如图1所示,单污泥发酵耦合短程反硝化实现颗粒难降解有机物的转化和亚硝酸盐的积累的装置与方法,其特征在于,包括城市污水原水水箱(1)、污泥混合液贮存罐(2)、硝化液水箱(3)、污泥发酵耦合短程反硝化反应器(4)、中间水箱(5)、厌氧氨氧化生物膜反应器(6)、出水水箱(7)。The present invention will be further described below in conjunction with the accompanying drawings and Examples: as shown in Figure 1, the single sludge fermentation coupled with short-range denitrification realizes the conversion of particulate refractory organic matter and the device and method for the accumulation of nitrite, characterized in that, Including urban sewage raw water tank (1), sludge mixed liquid storage tank (2), nitrification liquid tank (3), sludge fermentation coupled short-range denitrification reactor (4), intermediate water tank (5), anammox biological Membrane reactor (6), outlet water tank (7).
所述污泥混合液贮存罐(2)设有搅拌装置Ⅲ(2.1);所述污泥发酵耦合短程反硝化反应器(4)内置有进泥泵(4.1)、进水泵Ⅰ(4.2)、排水电动阀Ⅰ(4.3)、搅拌装置Ⅰ(4.4)、DO在线检测仪Ⅰ(4.5)、第一取样口(4.6)、第二取样口(4.7);所述厌氧氨氧化生物膜反应器(6)内置进水泵Ⅱ(6.1)、中间水箱水泵(6.2)、电动排水阀Ⅱ(6.3)、搅拌装置Ⅱ(6.4)、DO在线检测仪Ⅱ(6.5)、填料及填料架(6.6)、取样口(6.7);所述出水水箱(7)设有溢流管(7.1)、排水管(7.2)。The sludge mixed liquor storage tank (2) is provided with a stirring device III (2.1); the sludge fermentation coupled short-range denitrification reactor (4) is provided with a built-in sludge feed pump (4.1), feed pump I (4.2), Drainage electric valve I (4.3), stirring device I (4.4), DO online detector I (4.5), first sampling port (4.6), second sampling port (4.7); the anammox biofilm reactor (6) Built-in inlet water pump II (6.1), intermediate water tank water pump (6.2), electric drain valve II (6.3), stirring device II (6.4), DO online detector II (6.5), packing and packing frame (6.6), A sampling port (6.7); the water outlet tank (7) is provided with an overflow pipe (7.1) and a drain pipe (7.2).
其中所述污泥混合液贮存罐(2)通过进泥泵(4.1)与污泥发酵耦合短程反硝化反应器(4)相连接;硝化液水箱(3)通过进水泵Ⅰ(4.2)与污泥发酵耦合短程反硝化反应器(4)相连接;污泥发酵耦合短程反硝化反应器(4)排水电动阀Ⅰ(4.3)与中间水箱(5)相连接;中间水箱(5)通过中间水箱水泵(6.2)与厌氧氨氧化生物膜反应器(6)相连接;城市污水原水水箱(1)通过进水泵Ⅱ(6.1)与厌氧氨氧化生物膜反应器(6)相连接;厌氧氨氧化生物膜反应器(6)电动排水阀Ⅱ(6.3)与出水水箱(7)相连接。Wherein, the sludge mixed liquid storage tank (2) is connected with the sludge fermentation coupled short-range denitrification reactor (4) through the sludge feed pump (4.1); The sludge fermentation is coupled with the short-range denitrification reactor (4); the sludge fermentation is coupled with the short-range denitrification reactor (4), and the drain electric valve I (4.3) is connected with the intermediate water tank (5); the intermediate water tank (5) passes through the intermediate water tank The water pump (6.2) is connected with the anammox biofilm reactor (6); the urban sewage raw water tank (1) is connected with the anammox biofilm reactor (6) through the feed pump II (6.1); The electric drain valve II (6.3) of the ammonia oxidation biofilm reactor (6) is connected with the water outlet tank (7).
试验过程中,具体实验用水以取自北京工业大学家属区生活污水与,具体水质如下:COD浓度为178~298mg/L,NH4 +-N浓度为45~71mg/L,NO2 --N浓度<1mg/L,NO3 --N浓度0.1~1.4mg/L,PO4 3--P浓度4.3~7.6mg/L,pH值为7.3~7.6。污泥发酵所述剩余污泥取自北京工业大学中试二沉池污泥,经物理方法灭活处理后投加至污泥贮存罐(1)。硝化液为实验室硝化反应器出水或硝酸盐废水,混匀后NO3 --N浓度为10~50mg/L。试验系统如图1所示,反应器采用有机玻璃制作,污泥发酵耦合短程反硝化反应器(4)与厌氧氨氧化生物膜反应器(6)有效容积均为10L。During the test, the specific experimental water was taken from the domestic sewage and the family area of Beijing University of Technology. The specific water quality is as follows: COD concentration is 178-298 mg/L, NH 4 + -N concentration is 45-71 mg/L, NO 2 - -N Concentration<1mg/L, NO 3 - -N concentration 0.1~1.4mg/L, PO 4 3- -P concentration 4.3~7.6mg/L, pH value 7.3~7.6. Sludge Fermentation The excess sludge is taken from the sludge of the pilot-scale secondary sedimentation tank of Beijing University of Technology, which is inactivated by a physical method and then added to the sludge storage tank (1). The nitrification solution is the effluent of the laboratory nitrification reactor or the nitrate wastewater, and the NO 3 - -N concentration after mixing is 10-50 mg/L. The test system is shown in Figure 1. The reactor is made of plexiglass, and the effective volume of the sludge fermentation coupled with the short-range denitrification reactor (4) and the anammox biofilm reactor (6) is 10L.
具体运行操作如下:The specific operation is as follows:
1)系统启动:将水解酸化耦合短程反硝化污泥投加至污泥发酵耦合短程反硝化反应器(4)内,使接种后反应器内污泥浓度达到2000~6000mg/L(以反应器有效容积计);将富集厌氧氨氧化菌的生物膜填料投加至厌氧氨氧化生物膜反应器(6)内,使厌氧氨氧化菌的生物膜填料占厌氧氨氧化生物膜反应器(6)有效体积的20%~80%。1) System start-up: Add hydrolysis acidification coupled short-range denitrification sludge to the sludge fermentation coupled short-range denitrification reactor (4), so that the sludge concentration in the reactor after inoculation reaches 2000-6000 mg/L (with the reactor Effective volume meter); add the biofilm packing enriched with anammox bacteria into the anammox biofilm reactor (6), so that the biofilm packing of anammox bacteria accounts for the anammox biofilm 20% to 80% of the effective volume of the reactor (6).
2)剩余污泥、硝化液、原水与中间亚硝酸盐溶液进量的确定:2) Determination of the amount of excess sludge, nitrification solution, raw water and intermediate nitrite solution:
取剩余污泥在30摄氏度下使其进行发酵,通过对SCOD浓度进行测定,当SCOD浓度无增长趋势且20分钟内SCOD值不再增长时,此时为该浓度下污泥发酵的最大潜力。Take the remaining sludge and ferment it at 30 degrees Celsius. By measuring the SCOD concentration, when the SCOD concentration has no increasing trend and the SCOD value does not increase within 20 minutes, it is the maximum potential of sludge fermentation at this concentration.
在污泥发酵耦合短程反硝化反应器(4)内根据计算公式(1)(2)确定有机物与硝酸盐进量:In the sludge fermentation coupled short-range denitrification reactor (4), the organic matter and nitrate feeds are determined according to the calculation formulas (1) and (2):
V1+V2=V·P1 (2)V 1 +V 2 =V·P 1 (2)
注:式中SCOD为该剩余污泥最大发酵潜力下的SCOD浓度;Note: SCOD in the formula is the SCOD concentration under the maximum fermentation potential of the excess sludge;
V1、V2、V分别为有机物进量、硝酸盐溶液进量与反应器有效体积V 1 , V 2 , V are the organic matter feed, the nitrate solution feed and the effective volume of the reactor, respectively
NO3 -为进水硝酸盐浓度;NO 3 - is the influent nitrate concentration;
C/N为设定值,取值在3:1~6:1范围内任取;C/N is the set value, and the value can be arbitrarily selected within the range of 3:1 to 6:1;
P1为排水比,设定值,取60%。P 1 is the drainage ratio, the set value, which is 60%.
在厌氧氨氧化生物膜反应器(6)内根据计算公式(3)(4)确定原水与中间水箱水进量:In the anammox biofilm reactor (6), according to the calculation formula (3) (4), determine the raw water and intermediate water tank water inflow:
V3+V4=V·P2 (4)V 3 +V 4 =V·P 2 (4)
注:式中NO2 -为中间水箱中NO2 -浓度、NH4 +-为原水NH4 +浓度;Note: in the formula NO 2 - is the NO 2 - concentration in the intermediate water tank, NH 4 +- is the raw water NH 4 + concentration;
V3、V4、V分别为NO2 -溶液进量、NH4 +溶液进量与反应器有效体积;V 3 , V 4 , and V are the NO 2 - solution feed, the NH 4 + solution feed and the effective volume of the reactor, respectively;
P2为排水比,设定值,为50%;P 2 is the drainage ratio, the set value, which is 50%;
NO2 -/NH4 +为设定比值,取值在1.4:1~2:1范围内任取。NO 2 - /NH 4 + is the set ratio, and the value can be arbitrarily selected within the range of 1.4:1 to 2:1.
3)运行时调节操作如下:3) The adjustment operation at runtime is as follows:
将剩余污泥投加至污泥混合液贮存罐(1),每周期开始前启动搅拌器(1.1)使剩余污泥混合均匀,然后启动进泥泵(4.1),在每周期开始时将V1体积的剩余污泥混合液抽入污泥发酵耦合短程反硝化反应器(4)内,进行污泥发酵;Add the excess sludge to the sludge mixed liquid storage tank (1), start the agitator (1.1) before the start of each cycle to mix the excess sludge evenly, and then start the sludge feed pump (4.1), at the beginning of each cycle, the V 1 volume of excess sludge mixed solution is pumped into the sludge fermentation coupled short-range denitrification reactor (4) to carry out sludge fermentation;
污泥发酵耦合短程反硝化反应器(4)运行时,每周期先厌氧搅拌200~800min,SCOD值达最大发酵潜力的95%以上时结束厌氧搅拌;然后启动进水泵Ⅰ(4.2)将硝化液水箱(3)中V2体积的硝化液抽入污泥发酵耦合短程反硝化反应器(4)内,使污泥发酵耦合短程反硝化反应器(4)内硝酸盐氮浓度为设定浓度,设定浓度满足C/N在3:1~6:1;缺氧搅拌至亚硝酸盐转化率达80%以上或硝氮浓度小于3mg/L,然后停止搅拌开始沉淀排水10分钟,闲置后进入下一个周期。When the sludge fermentation is coupled with the short-range denitrification reactor (4), anaerobic stirring is performed for 200-800 minutes in each cycle, and the anaerobic stirring is terminated when the SCOD value reaches more than 95% of the maximum fermentation potential; The nitrifying liquid in the nitrifying liquid tank ( 3 ) is pumped into the sludge fermentation coupled short-path denitrification reactor (4), so that the nitrate nitrogen concentration in the sludge fermentation coupling short-path denitrification reactor (4) is set to Concentration, set the concentration to meet the C/N ratio of 3:1 to 6:1; stir in anoxic until the nitrite conversion rate reaches more than 80% or the nitrate concentration is less than 3mg/L, then stop stirring and start precipitation and drainage for 10 minutes, idle Then enter the next cycle.
在污泥发酵耦合短程反硝化反应器(4)排水结束后,启动中间水箱水泵(6.2)将中间水箱V3体积的硝化液抽入厌氧氨氧化生物膜反应器(6)内,同时启动水泵Ⅱ(6.1)将V4体积的城市污水原水抽入厌氧氨氧化生物膜反应器(6)内,使其中亚硝酸盐与氨氮的比值满足设定值,设定值在1.4:1~2:1范围内任取;缺氧搅拌至总无机氮浓度低于5mg/L,停止搅拌,沉淀排水10分钟,闲置后进入下一个周期。After the sludge fermentation coupled with the short-range denitrification reactor (4) drains the water, the intermediate water tank water pump (6.2) is started to pump the nitrification solution of the intermediate water tank V 3 volume into the anammox biofilm reactor (6), and at the same time the Pump II (6.1) pumps V4 volume of raw urban sewage into the anaerobic ammonia oxidation biofilm reactor (6), so that the ratio of nitrite to ammonia nitrogen meets the set value, and the set value is 1.4:1~ Anything within the range of 2:1; anoxic stirring until the total inorganic nitrogen concentration is lower than 5mg/L, stop stirring, precipitate and drain for 10 minutes, and enter the next cycle after being idle.
实验结果表明,预处理后剩余污泥在污泥发酵阶段可转化为易降解有机物,作为短程反硝化的碳源,其污泥减量效果可达50%~70%;反硝化阶段可以实现亚硝酸盐的积累,积累率达60%~80%,且出水硝氮浓度可忽略不计;厌氧氨氧化阶段厌氧氨氧化菌可将氨氮全部转化为氮气,剩余的亚硝可被反硝化细菌利用生活污水中的有机物还原为氮气,出水总氮均小于5mg/L。The experimental results show that the residual sludge after pretreatment can be converted into easily degradable organic matter in the sludge fermentation stage. As a carbon source for short-range denitrification, the sludge reduction effect can reach 50% to 70%; Nitrate accumulation, the accumulation rate is 60% to 80%, and the concentration of nitrate nitrogen in the effluent is negligible; in the anammox stage, the anammox bacteria can convert all ammonia nitrogen into nitrogen, and the remaining nitrous can be denitrifying bacteria. The organic matter in the domestic sewage is reduced to nitrogen, and the total nitrogen in the effluent is less than 5mg/L.
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| CN112479362A (en) * | 2020-11-10 | 2021-03-12 | 青岛大学 | Device and method for treating municipal sewage by combining sludge fermentation with short-cut denitrification anaerobic ammonia oxidation |
| CN112479361A (en) * | 2020-11-10 | 2021-03-12 | 青岛大学 | Device and method for deeply treating salt-containing wastewater |
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| CN113023869A (en) * | 2021-03-11 | 2021-06-25 | 北京工业大学 | Process for treating high-concentration nitrate wastewater and domestic sewage by using sludge fermentation liquor as carbon source and by using short-range denitrification tandem anaerobic ammonia oxidation |
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| CN112479362A (en) * | 2020-11-10 | 2021-03-12 | 青岛大学 | Device and method for treating municipal sewage by combining sludge fermentation with short-cut denitrification anaerobic ammonia oxidation |
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