CN110664056A - Waterproof and antibacterial zipper and preparation method thereof - Google Patents

Waterproof and antibacterial zipper and preparation method thereof Download PDF

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Publication number
CN110664056A
CN110664056A CN201910906190.6A CN201910906190A CN110664056A CN 110664056 A CN110664056 A CN 110664056A CN 201910906190 A CN201910906190 A CN 201910906190A CN 110664056 A CN110664056 A CN 110664056A
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China
Prior art keywords
zipper
chain
belt
waterproof
antibacterial
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CN201910906190.6A
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Chinese (zh)
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CN110664056B (en
Inventor
陈东圳
陈彤善
丁元清
高沛炫
贺辛亥
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Shaanxi Jingcheng Huibo New Material Technology Co.,Ltd.
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Xian Polytechnic University
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Publication of CN110664056A publication Critical patent/CN110664056A/en
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    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B19/00—Slide fasteners
    • A44B19/24—Details
    • A44B19/32—Means for making slide fasteners gas or watertight
    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B19/00—Slide fasteners
    • A44B19/24—Details
    • A44B19/34—Stringer tapes; Flaps secured to stringers for covering the interlocking members
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/06—Coating with compositions not containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C23C14/20—Metallic material, boron or silicon on organic substrates
    • C23C14/205—Metallic material, boron or silicon on organic substrates by cathodic sputtering
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34—Sputtering
    • C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04—Polysiloxanes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • Materials For Medical Uses (AREA)
  • Slide Fasteners (AREA)

Abstract

The waterproof and antibacterial zipper comprises a zipper belt and zipper teeth arranged on the zipper belt, wherein the zipper teeth are correspondingly provided with pull heads, the zipper teeth are made of fluorosilicone resin materials, the zipper belt comprises a body and a deposition layer outside the body, and the pull heads clamp the zipper teeth on two sides; the preparation method of the zipper comprises the following steps: step 1: manufacturing two chain belts by using a silicon dioxide and polydimethylsiloxane composite material, and manufacturing chain teeth by using fluorosilicone resin; step 2: treating the surface of the silicon dioxide and polydimethylsiloxane composite material to obtain an interface chemical structure beneficial to nano silver deposition, then depositing metal nano silver particles to grow on the surface of the chain belt, and fixing the chain teeth on two sides of the chain belt respectively to form the chain belt with the chain teeth; and step 3: the zipper belt is provided with a pull head and a limiting code, and the waterproof and antibacterial zipper is obtained. The waterproof and antibacterial zipper has high waterproof strength, long service life and good antibacterial performance.

Description

Waterproof and antibacterial zipper and preparation method thereof
Technical Field
The invention belongs to the technical field of special clothes, and particularly relates to a waterproof and antibacterial zipper and a preparation method of the zipper.
Background
For a novel super-hydrophobic antibacterial waterproof zipper, the waterproof zipper firstly needs to have good waterproof performance, and then special functions of the zipper, such as high durability, can be used on work clothes in severe environments (high temperature and low temperature). In addition, in some special clothes, the super-strong antibacterial performance can be exerted, and special biomedical application is realized.
Most of existing waterproof zippers in the market are coated with coatings, the waterproof zippers are produced along with the appearance of fabric waterproof coatings at the earliest time, a nylon chain needs to be sewn on a zipper belt in the traditional waterproof nylon zipper, liquid-tight damage is easily caused when the zipper belt is stressed, gaps (including a joint of a pull head and a stopper) exist when zipper teeth of a plastic-steel zipper are meshed, the characteristics possibly influence the liquid-tight effect of the zipper, the durability and the strength are not ideal, the waterproof coatings can fall off after a period of time, and the waterproof function is greatly reduced; therefore, in summary, the existing waterproof slide fastener has the problems of low waterproof strength, short service life and low antibacterial property.
Disclosure of Invention
The invention aims to provide a waterproof and antibacterial zipper, which solves the problems of low waterproof strength, short service life and low antibacterial performance of the conventional waterproof zipper.
The invention also provides a preparation method of the zipper.
The technical scheme adopted by the invention is that,
the utility model provides a waterproof antibacterial zip fastener, includes the chain belt and sets up the chain tooth on the chain belt, the chain tooth correspondence is provided with the pull head, and the chain tooth adopts fluorine silicon resin material, and the chain belt includes body and this external sedimentary deposit, pull head centre gripping both sides chain tooth, and the pull head promotes through external force and makes the chain tooth intermeshing of both sides or throw off.
The invention is also characterized in that the chain belt body is made of silicon dioxide and polydimethylsiloxane composite material, and alkyl chain chemical functional groups are deposited on the surface of the silicon dioxide and polydimethylsiloxane composite material.
The surface of the silicon dioxide and polydimethylsiloxane composite material is deposited with nano silver particles by a magnetron sputtering method, and the nano silver particles are passivated by octadecyl mercaptan molecules.
Each chain belt is provided with a limiting code, the limiting codes are positioned at two ends of the chain belt and comprise a front code positioned at one end of the chain belt and a rear code positioned at the other end of the chain belt.
The slider is made of metal material.
A preparation method of a waterproof and antibacterial zipper specifically comprises the following steps:
step 1: two chain belts are made of silicon dioxide and polydimethylsiloxane composite materials, the chain teeth are made of fluorosilicone resin,
step 2: treating the surface of the silicon dioxide and polydimethylsiloxane composite material by using 3-aminopropyltriethoxysilane to obtain an interface chemical structure for nano-silver deposition, depositing nano-silver particles on the surface of a chain belt by a magnetron sputtering method, enabling the nano-silver particles to grow on the surface of the chain belt closely, and fixing chain teeth on two sides of the chain belt respectively; forming a chain belt with chain teeth;
and step 3: and (3) configuring a pull head for the chain belts with the chain teeth in the step (2), respectively arranging a front stop and a rear stop at two ends of each chain belt, and enabling the front stop of one chain belt to correspond to the rear stop of the other chain belt, so as to obtain the waterproof and antibacterial zipper.
The waterproof and antibacterial zipper has the beneficial effects that the strength and toughness of polydimethylsiloxane are improved by using the silicon dioxide and polydimethylsiloxane composite material, the zipper belt of the waterproof zipper is prepared, the strength and toughness of the zipper belt are improved, the surface of the material has super-hydrophobicity, water can be effectively prevented from permeating and soaking, and meanwhile, the nano-silver particles have strong sterilizing capability, so that the application of aseptic and wearable can be realized. And the two materials have high elasticity, and can meet the design requirement of the special waterproof zipper of the clothes.
Drawings
FIG. 1 is a schematic view showing a structure of a waterproof and antibacterial slide fastener and a method for manufacturing the same according to the present invention;
FIG. 2 is a schematic view of PDMS superhydrophobicity in a waterproof and antibacterial zipper and a method for preparing the zipper according to the present invention;
FIG. 3 is a schematic view of a waterproof and antibacterial zipper and a super-hydrophobic SiO2@ PDMS in the preparation method thereof according to the present invention;
FIG. 4 is a schematic diagram of the super-hydrophobic SiO2@ PDMS @ Ag in the waterproof and antibacterial zipper and the preparation method thereof.
In the figure, 1, a chain belt, 2, a chain tooth, 3, a pull head, 4, a front code, 5, a rear code and 6, nano silver particles.
Detailed Description
The present invention will be described in detail with reference to the following embodiments.
The invention provides a waterproof and antibacterial zipper, which comprises a zipper belt 1 and zipper teeth 2 arranged on the zipper belt 1, wherein the zipper teeth 2 are correspondingly provided with pull heads 3, the zipper teeth 2 are made of fluorosilicone resin materials, the zipper belt 1 comprises a body and a deposition layer outside the body, the pull heads 3 clamp the zipper teeth on two sides, the pull heads 3 are pushed by external force to slide, and then the zipper teeth 2 on two sides are mutually meshed or separated.
The zipper teeth 2 are made of fluorosilicone resin materials, and the design has the performances of high temperature resistance (200 ℃) and low temperature (55 ℃), a series of excellent performances such as weather resistance, compression resilience, rebound resilience, electrical performance, demolding performance and the like, and also has the performances such as fuel oil resistance, solvent resistance and the like.
Further, the chain belt 1 body is made of a silicon dioxide and polydimethylsiloxane composite material, and a chemical functional group with a super-hydrophobic alkyl chain is deposited on the surface of the silicon dioxide and polydimethylsiloxane composite material.
As shown in fig. 3, the strength and toughness of the Polydimethylsiloxane (PDMS) shown in fig. 2 are improved by using the composite material of silica and polydimethylsiloxane (SiO2@ PDMS), the fastener tape 1 of the waterproof slide fastener is prepared, the strength and toughness of the fastener tape are improved, and the surface of the material also has superhydrophobicity, which can effectively prevent water from infiltrating and wetting.
Further, as shown in fig. 4, the surface of the silica and polydimethylsiloxane composite material is deposited with metallic nano silver particles 1 by a magnetron sputtering method, and the nano silver particles 1 are passivated with octadecyl mercaptan molecules.
This further increases the chain belt hydrophobicity and creates a double hydrophobic layer. Meanwhile, the nano silver particles 1 have an ultra-strong sterilization function, and can be used in a sterile wearable manner.
Further, still dispose every chain belt configuration limit code in the limit code at chain belt 1 both ends respectively, the limit code is located the chain belt both ends, and limit code is including the preceding sign indicating number 4 that is located chain belt one end and the back sign indicating number 5 that is located the chain belt other end, and preceding sign indicating number 4 and back sign indicating number 5 are located the corresponding end of two chain belts 1, are provided with the setting through the limit code for the zip fastener is free to be switched spacingly, has improved the practicality of zip fastener.
The slider 3 is made of a metal material. The metal slider 3 has good high-temperature and low-temperature resistance, and is suitable for the waterproof and antibacterial zipper.
The preparation method of the zipper specifically comprises the following steps:
step 1: manufacturing two chain belts by using a silicon dioxide and polydimethylsiloxane composite material, and manufacturing chain teeth by using fluorosilicone resin;
step 2: treating the surface of the silicon dioxide and polydimethylsiloxane composite material by using 3-aminopropyltriethoxysilane to obtain an interface chemical structure beneficial to nano-silver deposition, depositing metal nano-silver particles on the surface of the chain belt by a magnetron sputtering method to enable the nano-silver particles to grow on the surface of the chain belt closely, and fixing the chain teeth on two sides of the chain belt respectively to form the chain belt with the chain teeth;
and step 3: and (3) configuring a pull head for the chain belts with the chain teeth in the step (2), respectively arranging a front stop and a rear stop at two ends of each chain belt, and enabling the front stop of one chain belt to correspond to the rear stop of the other chain belt, so as to obtain the waterproof and antibacterial zipper.
Examples
The method for preparing a waterproof and antibacterial slide fastener of the present invention is explained in detail by the following specific examples:
step 1: two chain belts are made of silicon dioxide and polydimethylsiloxane composite materials, the chain teeth are made of fluorosilicone resin, the chain teeth made of fluorosilicone resin materials and the chain belt made of the silicon dioxide and polydimethylsiloxane composite materials corresponding to the chain teeth are formed,
step 2: treatment of silica and polydimethylsiloxane SiO with 3-Aminopropyltriethoxysilane (APTES)2The surface of @ PDMS, the interface chemical structure which is beneficial to the deposition of nano silver is obtained. Then, depositing metal nano silver on the surface of the chain belt to enable silver particles to grow on the surface of the chain belt closely, wherein the SiO2@ PDMS composite material super-hydrophobic surface refers to that the static contact angle to water is smaller than 150 degrees, the rolling angle to water is smaller than 10 degrees, and the chain teeth in the step 1 are respectively fixed on two sides of the chain belt where the silver particles grow closely to form the chain belt with the chain teeth;
and step 3: configuring a pull head for the chain belts with the chain teeth in the step 2, respectively arranging a limiting block at one end of each of the two chain belts, and connecting the other ends of the two chain belts through the limiting blocks to obtain the waterproof and antibacterial zipper
The waterproof and antibacterial zipper is characterized in that a chain belt is made of silicon dioxide (SiO2) @ Polydimethylsiloxane (PDMS) composite material, the surface of the material contains a super-hydrophobic alkyl chain chemical functional group, and biocompatibility is good. For some marine suits, diving suits and life jackets, metal nano-silver particles can be deposited on a chain belt by a magnetron sputtering method, octadecyl mercaptan molecules are modified to passivate the surface of the nano-silver particles, the chain belt hydrophobicity is further increased, and a double hydrophobic layer is constructed. Meanwhile, the nano silver particles have an ultra-strong sterilization function and can be worn and applied in an antibacterial and sterile space.

Claims (6)

1. The utility model provides a waterproof antibiotic zip fastener, its characterized in that includes chain belt (1) and sets up chain tooth (2) on chain belt (1), chain tooth (2) correspond and are provided with pull head (3), chain tooth (2) adopt fluorine silicon resin material, chain belt (1) includes body and this external sedimentary deposit, pull head (3) centre gripping both sides chain tooth (2), pull head (3) promote through external force and make chain tooth (2) intermeshing or the disengagement of both sides.
2. The waterproof and antibacterial zipper according to claim 1, characterized in that the body of the zipper tape (1) is made of silica and polydimethylsiloxane composite material, and alkyl chain chemical functional groups are deposited on the surface of the silica and polydimethylsiloxane composite material.
3. A waterproof and antibacterial zipper according to claim 2, wherein the surface of the silica and polydimethylsiloxane composite material is deposited with nano silver particles (6) by magnetron sputtering, and the nano silver particles (6) are passivated by octadecyl mercaptan molecules.
4. The waterproof and antibacterial zipper according to claim 1, characterized in that each zipper belt (1) is provided with a limit code at both ends of the zipper belt, and the limit code comprises a front code (4) at one end of the zipper belt and a rear code (5) at the other end of the zipper belt.
5. A waterproof and antibacterial slide fastener according to claim 1, characterized in that said slider (3) is of metal material.
6. The waterproof and antibacterial zipper according to claims 1-5, wherein the preparation method of the zipper specifically comprises the following steps:
step 1: two chain belts are made of silicon dioxide and polydimethylsiloxane composite materials, the chain teeth are made of fluorosilicone resin,
step 2: treating the surface of the silicon dioxide and polydimethylsiloxane composite material by using 3-aminopropyltriethoxysilane to obtain an interface chemical structure for nano-silver deposition, depositing nano-silver particles on the surface of the chain belt by a magnetron sputtering method to enable the nano-silver particles to grow on the surface of the chain belt closely, and fixing the chain teeth on two sides of the chain belt respectively to form the chain belt with the chain teeth;
and step 3: and (3) configuring a pull head for the chain belts with the chain teeth in the step (2), respectively arranging a front stop and a rear stop at two ends of each chain belt, and enabling the front stop of one chain belt to correspond to the rear stop of the other chain belt, so as to obtain the waterproof and antibacterial zipper.
CN201910906190.6A 2019-09-24 2019-09-24 Waterproof and antibacterial zipper and preparation method thereof Active CN110664056B (en)

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Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101744402A (en) * 2008-12-19 2010-06-23 北京振涛国际钛金技术有限公司 Antibacterial deodorant shoe plated with nanosilver by physical vapor deposition method
CN202009751U (en) * 2011-02-24 2011-10-19 骆炳华 Waterproof and airtight zipper
US20130014355A1 (en) * 2011-07-11 2013-01-17 Unizin Company Waterproof zipper, method and apparatus for manufacturing the same
CN203435799U (en) * 2013-02-16 2014-02-19 陈清雄 Water-resistant and breathable resin zipper with nanometer fixture fabric
CN103892522A (en) * 2012-12-28 2014-07-02 浙江伟星实业发展股份有限公司 Garment and antibacterial zipper
CN104363785A (en) * 2012-06-28 2015-02-18 Ykk株式会社 Waterproof slide fastener
CN104695209A (en) * 2013-12-05 2015-06-10 江南大学 Novel antibacterial textile fabric preparation method
CN104738904A (en) * 2015-04-09 2015-07-01 周士志 Automatic zipper structure controlled by fingerprints
CN106832319A (en) * 2017-01-22 2017-06-13 河南大学 A kind of method that original position prepares nano silicon/hydroxyl-terminated injecting two methyl siloxane hybrid material
CN108771307A (en) * 2018-06-04 2018-11-09 道晟拉链科技（太仓）有限公司 A kind of slide fastener with sterilizing function
US20180332908A1 (en) * 2017-05-21 2018-11-22 Brian Quaglia Three-dimensional wetsuit
CN109162091A (en) * 2018-08-29 2019-01-08 华南理工大学 A method of super-hydrophobic antibiotic fabric is prepared based on quaternized silica
CN109181530A (en) * 2018-08-31 2019-01-11 吉林大学 Bis- compound super-hydrophobic coats of scale silica of dimethyl silicone polymer-and forming method thereof
CN109267023A (en) * 2018-08-29 2019-01-25 江苏理工学院 A kind of antibacterial active carbon fiber material and preparation method thereof

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101744402A (en) * 2008-12-19 2010-06-23 北京振涛国际钛金技术有限公司 Antibacterial deodorant shoe plated with nanosilver by physical vapor deposition method
CN202009751U (en) * 2011-02-24 2011-10-19 骆炳华 Waterproof and airtight zipper
US20130014355A1 (en) * 2011-07-11 2013-01-17 Unizin Company Waterproof zipper, method and apparatus for manufacturing the same
CN104363785A (en) * 2012-06-28 2015-02-18 Ykk株式会社 Waterproof slide fastener
CN103892522A (en) * 2012-12-28 2014-07-02 浙江伟星实业发展股份有限公司 Garment and antibacterial zipper
CN203435799U (en) * 2013-02-16 2014-02-19 陈清雄 Water-resistant and breathable resin zipper with nanometer fixture fabric
CN104695209A (en) * 2013-12-05 2015-06-10 江南大学 Novel antibacterial textile fabric preparation method
CN104738904A (en) * 2015-04-09 2015-07-01 周士志 Automatic zipper structure controlled by fingerprints
CN106832319A (en) * 2017-01-22 2017-06-13 河南大学 A kind of method that original position prepares nano silicon/hydroxyl-terminated injecting two methyl siloxane hybrid material
US20180332908A1 (en) * 2017-05-21 2018-11-22 Brian Quaglia Three-dimensional wetsuit
CN108771307A (en) * 2018-06-04 2018-11-09 道晟拉链科技（太仓）有限公司 A kind of slide fastener with sterilizing function
CN109162091A (en) * 2018-08-29 2019-01-08 华南理工大学 A method of super-hydrophobic antibiotic fabric is prepared based on quaternized silica
CN109267023A (en) * 2018-08-29 2019-01-25 江苏理工学院 A kind of antibacterial active carbon fiber material and preparation method thereof
CN109181530A (en) * 2018-08-31 2019-01-11 吉林大学 Bis- compound super-hydrophobic coats of scale silica of dimethyl silicone polymer-and forming method thereof

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Effective date of registration: 20221214

Address after: 712000 415, Building 3, Science and Technology Enterprise Incubation Park, Gaoke 3rd Road, Xianyang Hi tech Industrial Development Zone, Shaanxi Province

Patentee after: Shaanxi Jingcheng Huibo New Material Technology Co.,Ltd.

Address before: 710048 Shaanxi province Xi'an Beilin District Jinhua Road No. 19

Patentee before: XI'AN POLYTECHNIC University