CN110663936B - Processing method for reducing GI value of rice starch - Google Patents

Processing method for reducing GI value of rice starch Download PDF

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CN110663936B
CN110663936B CN201910961244.9A CN201910961244A CN110663936B CN 110663936 B CN110663936 B CN 110663936B CN 201910961244 A CN201910961244 A CN 201910961244A CN 110663936 B CN110663936 B CN 110663936B
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陈玲
曾茜茜
郑波
何海
李晓玺
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South China University of Technology SCUT
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Abstract

The invention discloses a processing method for reducing GI value of rice starch. The method comprises the following steps: (1) Uniformly mixing 20 parts by mass of rice starch and 0.5-2 parts by mass of guar gum or carrageenan to obtain compound powder; (2) Regulating the water content of the compound powder, then extruding at 80-90 ℃, drying the extruded product at 30-60 ℃ for 8-24 hours, crushing, and sieving to obtain the rice starch-non-starch polysaccharide compound with lower GI value. The invention combines the advantages of extrusion treatment, hot air drying and non-starch polysaccharide additives, and can increase the RS content of the extruded starch from 14.5% to 67.5%, and reduce the PGI value from 82.3 to 61.8.

Description

Processing method for reducing GI value of rice starch
Technical Field
The invention belongs to the technical field of foods, and particularly relates to a processing method for reducing the GI value of rice starch.
Background
With the development of economy and the continuous improvement of living standard, the dietary nutrition composition and common clinical diseases of people are greatly changed. Starch is used as one of three nutritional components of food, and has a large proportion in human diet, so that not only can energy substances necessary for human survival be provided, but also physiological functions such as human body glucose metabolism, lipid metabolism, intestinal microorganism diversity and the like can be regulated and controlled, and further the health of human beings is influenced. After entering the human body, the starch is hydrolyzed into glucose under the participation of various enzymes in the digestive tract, and finally is absorbed in the small intestine to supply energy for the human body. According to the different digestion rates in human bodies, starches can be mainly classified into fast digestion starches, slow digestion starches and anti-digestion starches, and most of the starches are fast digestion starches, are easily digested and absorbed by human bodies and further generate high blood sugar reaction, which is not consistent with the modern nutrition and health concept. Therefore, the multiscale structure of the starch is changed through different processing modes or physical modification, so that the digestion, absorption and metabolism of the starch in the gastrointestinal tract of a human body are regulated and controlled, and the nutrition function of the starch is improved, and the starch has important application value.
Glycemic Index (GI) and anti-digestive starch (RS) content are two important indicators that characterize the rate of starch digestion. Wherein the GI value may reflect the degree to which ingested food causes an increase in blood glucose in the human body. High GI foods have a fast rate of digestion in the gastrointestinal tract and produce large amounts of glucose in a short period of time. While low GI foods are slowly digested and absorbed in the gastrointestinal tract, with long residence times, and slowly produce glucose. Long-term ingestion of low GI foods has been reported to reduce the incidence and prevalence of heart disease, diabetes and certain cancers (Hyun-JungChung, dong-HoonShin, et al In vitro starch digestibility and estimated glycemic index of chemically modified corn starches [ J ] Food Research International,2008,6 (41): 579-585). However, accurate measurement of GI values requires a large number of zoological and anthropometric tests, which are time-consuming and costly. In 1999, englyst et al (K.Englyst, H.Englyst, et al Rapid available glucose in foods: an in vitro measurement that reflects the glycemic response [ J ]. American Journal of Clinical Nutrition,1999, 69:448-454.) found a significant correlation between glycemic response and Rapidly Available Glucose (RAG), meaning that in vivo glycemic response can be reflected by measuring RAG content in food in vitro. At present, the method is widely adopted at home and abroad. Related studies have also used predicted blood glucose concentrations (PGI) as measured by in vitro digestion experiments to characterize the rate of digestion and absorption of starch in humans. RS refers to the part of starch which cannot be digested by the small intestine but can be fermented in the large intestine, and has low digestion rate and can resist the degradation of digestive enzymes in the small intestine.
Currently, methods for modifying starch structures mainly include chemical, physical, biological and complex methods. Among them, the green and environment-friendly physical method is popular among the public. In the physical modification method, the digestion rate of the starch can be changed by the technologies of high pressure, normal pressure cooking, extrusion and the like, so that the GI value of the starch is reduced. The extrusion technology is a physical modification technology integrating a plurality of unit operations such as mixing, homogenizing, curing and forming of materials, starch is subjected to the comprehensive effects of high pressure, high temperature and high shearing while moving forwards along with the rotation of a screw, and compared with other physical processing technologies, the extrusion technology has stronger acting force on the starch and has larger influence on the multi-scale structure of the starch.
After the starch is extruded, molecular chains are exposed, the starch is gelatinized and degraded, and the starch digestion is often promoted by singly using an extrusion technology, so that the starch digestion rate is reduced to a limited extent. Many researchers have improved the digestion rate of starch by adding hydrocolloids, flour, soy oil, and the like. But with single or composite additive+extrusion techniques there is limited modification of the starch structure.
Disclosure of Invention
In order to solve the defects and shortcomings of the prior art, the invention aims to provide a processing method for reducing the GI value of rice starch. The method comprises adding non-starch polysaccharide (guar gum, carrageenan), extrusion treatment and hot air drying.
The invention aims at realizing the following technical scheme:
a processing method for reducing GI value of rice starch comprises the following steps:
(1) Uniformly mixing 20 parts by mass of rice starch and 0.5-2 parts by mass of guar gum or carrageenan to obtain compound powder;
(2) Regulating the water content of the compound powder, then extruding at 80-90 ℃, drying the extruded product at 30-60 ℃ for 8-24 hours, crushing, and sieving to obtain the rice starch-non-starch polysaccharide compound with lower GI value.
The adding amount of the guar gum or the carrageenan in the step (1) is 1-2 parts by mass. The mass parts of guar gum or carrageenan are based on the dry basis of rice starch.
The water content of the compound powder in the step (2) is 40-45%.
The rotating speed of the extrusion treatment in the step (2) is 150-250 r/min. The extrusion treatment is performed using an extruder, preferably an extruder, more preferably a micro-extruder.
The extrusion temperature in the step (2) is 85-90 ℃.
The drying temperature in the step (2) is 30-40 ℃ and the drying time is 24 hours.
The mesh number of the screening in the step (2) is 100-200 meshes.
Compared with the prior art, the invention has the following advantages:
(1) The invention combines the advantages of extrusion treatment, low-temperature hot air drying and non-starch polysaccharide additives, overcomes the limitation of a single technology, has remarkable effect of non-starch polysaccharide plus extrusion treatment plus low-temperature hot air drying, and can increase the RS content of the extruded starch from 14.5% to 67.5%, and reduce the PGI from 82.3 to 61.8.
(2) The invention uses extrusion technology, which is beneficial to the unique mechanical structure, and the sample can be subjected to the comprehensive actions of high pressure, high temperature, high shearing and the like in the cavity, so that the starch gelatinization degree is higher, and the chain segment stretching is more sufficient. The dissociated molecular chain is easy to be embedded and wound by the added guar gum and carrageenan to form a compound.
(3) The invention adopts the hot air drying technology, on one hand, the sample can be dried, and on the other hand, the starch sample is easy to regenerate under the environment of high moisture and medium and low temperature, and ordered crystallization is formed by rearrangement, so that the amylase resistance is enhanced, and the blood sugar reaction is reduced.
(4) The invention uses guar gum and carrageenan with simple branch structure, wherein the carrageenan has more linear chain structure and has stronger regulating and controlling capability on the GI value of the extruded rice starch. The carrageenan can improve RC by 41.1% -53%, reduce PGI by 14.4% -19.2%, the guar gum can improve RC by 27.5% -46.4%, reduce PGI by 18% -20.5, and pectin with complex branch structure can improve RC by 38.1% and reduce PGI by 12.
Drawings
FIG. 1 is an SEM image of an extruded rice starch sample of comparative example 1.
Fig. 2 is an SEM image of the extruded rice starch-guar gum composite of example 1.
Fig. 3 is an SEM image of the extruded rice starch-guar gum composite of example 2.
Fig. 4 is an SEM image of the extruded rice starch-guar gum composite of example 3.
Fig. 5 is an SEM image of the extruded rice starch-guar gum composite of example 4.
Fig. 6 is an SEM image of the extruded rice starch-carrageenan composite of example 5.
Fig. 7 is an SEM image of the extruded rice starch-carrageenan composite of example 6.
Fig. 8 is an SEM image of the extruded rice starch-carrageenan composite of example 7.
Fig. 9 is an SEM image of the extruded rice starch-carrageenan composite of example 8.
FIG. 10 is an SEM image of an extruded rice starch-pectin composite (0.5 parts pectin added) of comparative example 6.
FIG. 11 is an SEM image of an extruded rice starch-pectin composite (1 part pectin added) of comparative example 6.
FIG. 12 is an SEM image of an extruded rice starch-pectin composite (1.5 parts pectin added) of comparative example 6.
FIG. 13 is an SEM image of an extruded rice starch-pectin composite (2 parts pectin added) of comparative example 6.
FIG. 14 is a sample plot of the rice starch-non-starch polysaccharide mixture prior to extrusion in comparative example 7.
FIG. 15 is a graph of a sample of the rice starch-non-starch polysaccharide complex after extrusion in comparative example 7.
Detailed Description
The present invention will be described in further detail with reference to examples and drawings, but embodiments of the present invention are not limited thereto.
The number of the sieves described in the examples and comparative examples herein was 100 mesh; RDS, SDS, RS, RC, PGI is respectively quick-digestion starch, slow-digestion starch, anti-digestion component and predicted glycemic index; the Pe, the Gg and the Cg are pectin, guar gum and carrageenan respectively; the parts are mass parts; the moisture content refers to the mass content; the extrusion treatments were all carried out using a mini-extruder (model Hakke MiniLab II, thermo Fisher, germany).
The digestibility and relative crystallinity tests described in the examples and comparative examples herein were all performed according to conventional methods in the art, with the relative crystallinity being tested using XRD testing methods.
Example 1
Weighing 20 parts of rice starch and 0.5 part of guar gum (2.5% based on the dry basis of the rice starch) according to mass fraction, preparing into compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 1.
Table 1 digestibility of extruded rice starch-guar gum complexes
Figure BDA0002228983570000051
Example 2
Weighing 20 parts of rice starch and 1 part of guar gum (5% based on the dry basis of the rice starch) according to mass fraction, preparing into compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 2.
Table 2 digestibility of extruded rice starch-guar gum complexes
Figure BDA0002228983570000052
Example 3
Weighing 20 parts of rice starch and 1.5 parts of guar gum (7.5% based on the dry basis of the rice starch) according to mass fraction, preparing into compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 3.
TABLE 3 digestion Properties of extruded Rice starch-guar gum complexes
Figure BDA0002228983570000061
Example 4
Weighing 20 parts of rice starch and 2 parts of guar gum (10% based on the dry basis of the rice starch) according to mass fraction, preparing into compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 4.
Table 4 digestibility of extruded rice starch-guar gum complexes
Figure BDA0002228983570000062
Example 5
Weighing 20 parts of rice starch and 0.5 part of carrageenan (2.5% based on the dry basis of the rice starch) according to mass fraction, preparing into compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 5.
TABLE 5 digestion Properties of extruded Rice starch-carrageenan complexes
Figure BDA0002228983570000063
Example 6
Weighing 20 parts of rice starch and 1 part of carrageenan (5% based on the dry basis of the rice starch) according to mass fraction, preparing into compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 6.
Table 6 digestibility of extruded rice starch-carrageenan complexes
Figure BDA0002228983570000071
Example 7
Weighing 20 parts of rice starch and 1.5 parts of carrageenan (7.5% based on the dry basis of the rice starch) according to mass fraction to prepare compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 7.
TABLE 7 digestion Properties of extruded Rice starch-carrageenan complexes
Figure BDA0002228983570000072
Example 8
Weighing 20 parts of rice starch and 2 parts of carrageenan (10% based on the dry basis of the rice starch) according to mass fraction, preparing into compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 8.
Table 8 digestibility of extruded rice starch-carrageenan complexes
Figure BDA0002228983570000081
Example 9
Weighing 20 parts of rice starch and 0.5 part of carrageenan (2.5% based on the dry basis of the rice starch) according to mass fraction, preparing into compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is.150r/min. The extruded product was then baked in an oven at 30℃for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 9.
Table 9 digestibility of extruded rice starch-carrageenan complexes
Figure BDA0002228983570000082
Example 10
Weighing 20 parts of rice starch and 2 parts of carrageenan (10% based on the dry basis of the rice starch) according to mass fraction, preparing into compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 90 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 8 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 10.
Table 10 digestibility of extruded rice starch-carrageenan complexes
Figure BDA0002228983570000083
Comparative example 1
Weighing 20 parts of rice starch, and blending the water content of the rice starch to 40%. And then baked in an oven at 40 c for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 11.
Table 11 digestibility of rice starch
Figure BDA0002228983570000091
Comparative example 2
Weighing 20 parts of rice starch, blending the water content of the rice starch to 40%, and performing extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 12.
Table 12 digestibility of extruded rice starch
Figure BDA0002228983570000092
Comparative example 3
Weighing 20 parts of rice starch, blending the water content of the rice starch to 40%, and performing extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 100 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 13.
TABLE 13 digestion Properties of extruded rice starch
Figure BDA0002228983570000093
Comparative example 4
Weighing 20 parts of rice starch, blending the water content of the rice starch to 40%, and performing extrusion treatment under the conditions that the extrusion temperature is 95 ℃ and the screw speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 14.
Table 14 digestibility of extruded rice starch
Figure BDA0002228983570000094
Comparative example 5
Weighing 20 parts of rice starch and 0.5 part of guar gum (2.5% based on the dry basis of the rice starch) according to mass fraction, preparing into compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 70 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 15.
Table 15 digestibility of extruded rice starch-carrageenan complexes
Figure BDA0002228983570000101
Comparative example 6
Weighing 4 groups of 20 parts of rice starch according to mass fraction, respectively mixing with 0.5 part, 1 part, 1.5 parts and 2 parts of pectin (2.5%, 5%, 7.5% and 10% based on dry rice starch) to obtain compound powder, and uniformly mixing. And then blending the water content of the compound powder to 40%, and carrying out extrusion treatment under the conditions that the extrusion temperature is 85 ℃ and the screw rotating speed is 150 r/min. The extruded product was then baked in an oven at 40 ℃ for 24 hours. Finally, the dried sample is crushed and sieved by a 100-mesh sieve, and the digestion performance of the sample is measured. The results are shown in Table 16.
Table 16 digestibility of extruded rice starch-pectin composites
Figure BDA0002228983570000102
Comparative example 7
Weighing 2 groups of 20 parts of rice starch according to mass fraction, respectively preparing compound powder with 2.5 parts of guar gum and 2.5 parts of carrageenan (12.5% based on dry basis of rice starch), and uniformly mixing. And then the water content of the compound powder is regulated to 40 percent. As shown in fig. 14 and 15, the compound powder is not uniformly stirred, and the caking phenomenon is obvious, which is probably caused by excessive addition of hydrophilic colloid, stronger water competitiveness and easy combination of water with carrageenan and guar gum, and the large caking phenomenon occurs in the system. After extrusion (extrusion temperature 85 ℃ C., screw speed 150 r/min), the starch clusters are sticky and hard, and are difficult to extrude from the extruder.
Table 17 shows the relative crystallinity of the extruded rice starch and extruded rice starch-non-starch polysaccharide complexes.
TABLE 17 relative crystallinity of extruded rice starch and extruded rice starch-non-starch polysaccharide complexes
Figure BDA0002228983570000111
The above examples are preferred embodiments of the present invention, but the embodiments of the present invention are not limited to the above examples, and any other changes, modifications, substitutions, combinations, and simplifications that do not depart from the spirit and principle of the present invention should be made in the equivalent manner, and the embodiments are included in the protection scope of the present invention.

Claims (7)

1. A processing method for reducing the GI value of rice starch is characterized by comprising the following steps:
(1) Uniformly mixing 20 parts by mass of rice starch and 0.5-1 part by mass of guar gum or 0.5-2 parts by mass of carrageenan to obtain compound powder;
(2) Adjusting the water content of the compound powder, then extruding at 80-90 ℃, drying the extruded product at 30-60 ℃ for 8-24 hours, crushing, and sieving to obtain a rice starch-non-starch polysaccharide compound with a lower GI value;
the rotating speed of the extrusion treatment in the step (2) is 150-250 r/min;
and (3) the water content of the compound powder in the step (2) is 40-45%.
2. The processing method for reducing the GI value of rice starch according to claim 1, wherein the guar gum or carrageenan in step (1) is added in an amount of 1 part by mass.
3. The processing method for reducing the GI of rice starch according to claim 1, wherein the extrusion temperature in step (2) is 85-90 ℃.
4. The processing method for reducing the GI value of rice starch according to claim 1, wherein the drying temperature in the step (2) is 30-40 ℃ and the time is 24 hours.
5. The process of claim 1, wherein the extrusion in step (2) is performed using an extruder.
6. The process for reducing the GI of rice starch according to claim 1, wherein said extrusion in step (2) is carried out using an extruder.
7. The method for reducing GI of rice starch according to claim 1, wherein the mesh number of the screen in step (2) is 100 to 200 mesh.
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瓜尔豆胶对马铃薯淀粉消化性和糊化特性的影响;李远等;《食品工业科技》;20181126(第08期);第61-65页 *

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