CN110639689A - 一种从稀土尾矿中综合回收稀土、锶和钼的选矿方法 - Google Patents
一种从稀土尾矿中综合回收稀土、锶和钼的选矿方法 Download PDFInfo
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- CN110639689A CN110639689A CN201910974205.2A CN201910974205A CN110639689A CN 110639689 A CN110639689 A CN 110639689A CN 201910974205 A CN201910974205 A CN 201910974205A CN 110639689 A CN110639689 A CN 110639689A
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- Prior art keywords
- concentration
- tailings
- rare earth
- concentrate
- molybdenum
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Links
- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 67
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 66
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910052750 molybdenum Inorganic materials 0.000 title claims abstract description 61
- 239000011733 molybdenum Substances 0.000 title claims abstract description 61
- 238000000034 method Methods 0.000 title claims abstract description 42
- 229910052712 strontium Inorganic materials 0.000 title claims abstract description 41
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000012141 concentrate Substances 0.000 claims abstract description 60
- 230000002000 scavenging effect Effects 0.000 claims abstract description 38
- 238000007885 magnetic separation Methods 0.000 claims abstract description 31
- 238000000926 separation method Methods 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 48
- 238000005188 flotation Methods 0.000 claims description 40
- 239000003112 inhibitor Substances 0.000 claims description 35
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 26
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 13
- 230000003213 activating effect Effects 0.000 claims description 12
- SRIJLARXVRHZKD-UHFFFAOYSA-N OP(O)=O.C=CC1=CC=CC=C1 Chemical compound OP(O)=O.C=CC1=CC=CC=C1 SRIJLARXVRHZKD-UHFFFAOYSA-N 0.000 claims description 9
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 9
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 9
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 229910052700 potassium Inorganic materials 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 6
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 6
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- XTKQPOMVAQHMBO-UHFFFAOYSA-N sodium;2-hydroxy-n-oxidobenzamide Chemical compound [Na+].OC1=CC=CC=C1C(=O)N[O-] XTKQPOMVAQHMBO-UHFFFAOYSA-N 0.000 claims description 6
- 239000003607 modifier Substances 0.000 claims description 3
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 2
- 238000011084 recovery Methods 0.000 abstract description 34
- XIJLBSWGPVLQBE-UHFFFAOYSA-N [Sr].[Mo] Chemical compound [Sr].[Mo] XIJLBSWGPVLQBE-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 16
- 239000011707 mineral Substances 0.000 description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229910052758 niobium Inorganic materials 0.000 description 4
- 239000010955 niobium Substances 0.000 description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 4
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000010436 fluorite Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000005065 mining Methods 0.000 description 3
- HBROZNQEVUILML-UHFFFAOYSA-N salicylhydroxamic acid Chemical group ONC(=O)C1=CC=CC=C1O HBROZNQEVUILML-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000012190 activator Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 238000009412 basement excavation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B7/00—Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage
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- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (10)
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CN201910974205.2A CN110639689B (zh) | 2019-10-14 | 2019-10-14 | 一种从稀土尾矿中综合回收稀土、锶和钼的选矿方法 |
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CN201910974205.2A CN110639689B (zh) | 2019-10-14 | 2019-10-14 | 一种从稀土尾矿中综合回收稀土、锶和钼的选矿方法 |
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CN110639689A true CN110639689A (zh) | 2020-01-03 |
CN110639689B CN110639689B (zh) | 2021-05-25 |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103394408A (zh) * | 2013-07-26 | 2013-11-20 | 北京科技大学 | 稀土尾矿中综合回收有价矿物的方法 |
WO2014066668A1 (en) * | 2012-10-24 | 2014-05-01 | Rare Earth Salts Separation And Refining, Llc | Method for rare earth and actinide element recovery, extraction and separations from natural and recycled resources |
US20170028410A1 (en) * | 2015-07-31 | 2017-02-02 | Colorado School Of Mines | Beneficiation of rare earth elements bearing ancylite |
CN106733146A (zh) * | 2017-01-06 | 2017-05-31 | 四川省地质矿产勘查开发局成都综合岩矿测试中心 | 从细粒铁泥含量重的稀土尾矿回收稀土矿物的方法 |
CN107282288A (zh) * | 2017-05-26 | 2017-10-24 | 内蒙古科技大学 | 一种综合回收弱磁性铁、稀土和萤石的选矿方法 |
CN109806966A (zh) * | 2019-02-21 | 2019-05-28 | 中国地质科学院矿产综合利用研究所 | 一种从稀土尾矿中综合回收锶矿物的选矿方法 |
-
2019
- 2019-10-14 CN CN201910974205.2A patent/CN110639689B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014066668A1 (en) * | 2012-10-24 | 2014-05-01 | Rare Earth Salts Separation And Refining, Llc | Method for rare earth and actinide element recovery, extraction and separations from natural and recycled resources |
CN103394408A (zh) * | 2013-07-26 | 2013-11-20 | 北京科技大学 | 稀土尾矿中综合回收有价矿物的方法 |
US20170028410A1 (en) * | 2015-07-31 | 2017-02-02 | Colorado School Of Mines | Beneficiation of rare earth elements bearing ancylite |
CN106733146A (zh) * | 2017-01-06 | 2017-05-31 | 四川省地质矿产勘查开发局成都综合岩矿测试中心 | 从细粒铁泥含量重的稀土尾矿回收稀土矿物的方法 |
CN107282288A (zh) * | 2017-05-26 | 2017-10-24 | 内蒙古科技大学 | 一种综合回收弱磁性铁、稀土和萤石的选矿方法 |
CN109806966A (zh) * | 2019-02-21 | 2019-05-28 | 中国地质科学院矿产综合利用研究所 | 一种从稀土尾矿中综合回收锶矿物的选矿方法 |
Non-Patent Citations (1)
Title |
---|
王成行 等: ""磁选-重选-浮选组合新工艺分选氟碳铈矿型稀土矿的试验研究"", 《稀有金属》 * |
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Address after: 510651 No. 363, Changxin Road, Guangzhou, Guangdong, Tianhe District Patentee after: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Address before: 510651 No. 363, Changxin Road, Guangzhou, Guangdong, Tianhe District Patentee before: Institute of resources comprehensive utilization, Guangdong Academy of Sciences |
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Address after: 510651 No. 363, Changxin Road, Guangzhou, Guangdong, Tianhe District Patentee after: Institute of resources comprehensive utilization, Guangdong Academy of Sciences Address before: No. 363, Changxing Road, Tianhe District, Guangzhou, Guangdong 510650 Patentee before: GUANGDONG INSTITUTE OF RESOURCES COMPREHENSIVE UTILIZATION |
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Application publication date: 20200103 Assignee: Dongguan Linxi Intelligent Technology Co.,Ltd. Assignor: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Contract record no.: X2023980042097 Denomination of invention: A beneficiation method for comprehensive recovery of rare earth, strontium, and molybdenum from rare earth tailings Granted publication date: 20210525 License type: Common License Record date: 20230919 Application publication date: 20200103 Assignee: Huizhou qingleyuan Intelligent Technology Co.,Ltd. Assignor: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Contract record no.: X2023980042094 Denomination of invention: A beneficiation method for comprehensive recovery of rare earth, strontium, and molybdenum from rare earth tailings Granted publication date: 20210525 License type: Common License Record date: 20230919 Application publication date: 20200103 Assignee: Foshan chopsticks Technology Co.,Ltd. Assignor: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Contract record no.: X2023980042086 Denomination of invention: A beneficiation method for comprehensive recovery of rare earth, strontium, and molybdenum from rare earth tailings Granted publication date: 20210525 License type: Common License Record date: 20230919 Application publication date: 20200103 Assignee: Foshan WanChen Technology Co.,Ltd. Assignor: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Contract record no.: X2023980042075 Denomination of invention: A beneficiation method for comprehensive recovery of rare earth, strontium, and molybdenum from rare earth tailings Granted publication date: 20210525 License type: Common License Record date: 20230919 |
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Application publication date: 20200103 Assignee: Bainuo Zhongcheng (Chongqing) Electronic Technology Co.,Ltd. Assignor: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Contract record no.: X2023980042504 Denomination of invention: A beneficiation method for comprehensive recovery of rare earth, strontium, and molybdenum from rare earth tailings Granted publication date: 20210525 License type: Common License Record date: 20230925 |
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Application publication date: 20200103 Assignee: Meizhou Dongnan Jinli Technology Co.,Ltd. Assignor: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Contract record no.: X2023980049304 Denomination of invention: A beneficiation method for comprehensive recovery of rare earth, strontium, and molybdenum from rare earth tailings Granted publication date: 20210525 License type: Common License Record date: 20231204 |