CN110627359B - Frit for glaze and preparation method thereof - Google Patents
Frit for glaze and preparation method thereof Download PDFInfo
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- CN110627359B CN110627359B CN201911066699.0A CN201911066699A CN110627359B CN 110627359 B CN110627359 B CN 110627359B CN 201911066699 A CN201911066699 A CN 201911066699A CN 110627359 B CN110627359 B CN 110627359B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 229910052629 lepidolite Inorganic materials 0.000 claims abstract description 42
- 239000002893 slag Substances 0.000 claims abstract description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 18
- 239000010453 quartz Substances 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 238000002386 leaching Methods 0.000 claims abstract description 12
- 238000005470 impregnation Methods 0.000 claims abstract description 11
- 238000001802 infusion Methods 0.000 claims abstract description 11
- 229910052701 rubidium Inorganic materials 0.000 claims abstract description 10
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000002844 melting Methods 0.000 claims description 25
- 230000008018 melting Effects 0.000 claims description 25
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 18
- 239000011159 matrix material Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 12
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 12
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 12
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims description 11
- 238000000227 grinding Methods 0.000 claims description 9
- 239000011344 liquid material Substances 0.000 claims description 8
- 239000000919 ceramic Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 4
- 238000010791 quenching Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 230000000171 quenching effect Effects 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 238000010304 firing Methods 0.000 claims 1
- 238000005245 sintering Methods 0.000 abstract description 5
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 abstract description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052700 potassium Inorganic materials 0.000 abstract description 3
- 239000011591 potassium Substances 0.000 abstract description 3
- 229910052710 silicon Inorganic materials 0.000 abstract description 3
- 239000010703 silicon Substances 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 13
- 239000008187 granular material Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- KOPBYBDAPCDYFK-UHFFFAOYSA-N Cs2O Inorganic materials [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 238000004814 ceramic processing Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- AKUNKIJLSDQFLS-UHFFFAOYSA-M dicesium;hydroxide Chemical compound [OH-].[Cs+].[Cs+] AKUNKIJLSDQFLS-UHFFFAOYSA-M 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910001953 rubidium(I) oxide Inorganic materials 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a frit for glaze and a preparation method thereof, wherein the frit for glaze comprises the following raw materials in parts by mass: 70-80 parts by mass of lepidolite roasting impregnation slag, 3-8 parts by mass of calcite and 3-5 parts by mass of quartz. According to the frit for glaze, a certain amount of rubidium element is contained in the lepidolite roasting impregnation slag, so that the color of a sintered glaze surface is improved, and the prepared glaze surface is good in glossiness and flatness; through sintering the lepidolite roasting infusion slag, the lepidolite roasting infusion slag can be utilized, and the environment is protected while waste is utilized; the lepidolite roasting leaching residue contains potassium element, calcium element, aluminum element and silicon element which can be utilized to prepare the frit for glaze.
Description
Technical Field
The invention relates to the technical field of ceramic manufacturing, in particular to a frit for glaze and a preparation method thereof.
Background
Glaze is a glassy substance formed by sintering a glaze at a high temperature. The glaze is usually ball-milled to prepare slurry cloth, the slurry cloth is applied to the surface of a ceramic blank, and then high-temperature sintering is carried out. The glaze layer has multiple functions of antifouling, wear resistance, decoration and the like.
Lepidolite is also known as lepidolite, a monoclinic system. Often in the form of a collection of fine scale shapes. Pale purple, and sometimes yellow-green. Glass gloss. Lepidolite is mostly used for refining lithium carbonate, and a large amount of industrial waste residues are generated in the refining process, cannot be effectively utilized, and greatly harm the environment.
Therefore, there is a need to provide a novel frit for glaze, which solves the above-mentioned problems.
Disclosure of Invention
The invention mainly aims to provide a frit for glaze and a preparation method thereof, and aims to solve the technical problem that the conventional lepidolite roasting impregnating slag cannot be effectively utilized.
In order to achieve the purpose, the frit for glaze provided by the invention comprises the following raw materials in parts by weight:
70-80 parts by mass of lepidolite roasting impregnation slag, 3-8 parts by mass of calcite and 3-5 parts by mass of quartz.
Preferably, the raw materials further comprise the following components in parts by weight:
5-8 parts by mass of barium carbonate, 10-14 parts by mass of alumina, 1-3 parts by mass of potassium carbonate and 1-2 parts by mass of strontium carbonate.
Preferably, the raw materials comprise, by mass, 0.1-0.5 parts of rubidium element, and the rubidium element is introduced through lepidolite roasting and impregnating slag.
The invention also provides a preparation method of the frit for glaze, which comprises the following steps:
step one, roasting lepidolite leaching residues, calcite and quartz to generate a matrix;
step two, grinding the substrate produced in the step one into powder;
step three, melting the powder obtained in the step two to form a liquid substance;
step four, water quenching is carried out on the liquid material obtained by melting in the step three to obtain a block-shaped glassy material, and then the block-shaped glassy material is crushed into frit particles to prepare the frit for glaze.
The invention also provides that the roasting temperature in the first step is 1000-1200 ℃.
The invention also provides the following steps:
according to the mass parts, 70-80 parts of lepidolite roasting infusion slag, 3-8 parts of calcite and 3-5 parts of quartz are roasted to generate a matrix.
Preferably, the third step includes:
and (3) adding 5-8 parts by mass of barium carbonate, 10-14 parts by mass of alumina, 1-3 parts by mass of potassium carbonate and 1-2 parts by mass of strontium carbonate into the powder obtained in the step two, and melting the powder together to form a liquid substance.
The invention also provides a ceramic glaze material prepared by using the frit for glaze as a raw material.
According to the frit for glaze, a certain amount of rubidium element is contained in the lepidolite roasting impregnation slag, so that the color of a sintered glaze surface is improved, and the prepared glaze surface is good in glossiness and flatness; through sintering the lepidolite roasting infusion slag, the lepidolite roasting infusion slag can be utilized, and the environment is protected while waste is utilized; the lepidolite roasting leaching residue contains potassium element, calcium element, aluminum element and silicon element which can be utilized to prepare the frit for glaze.
Drawings
Fig. 1 is a schematic flow chart of a method for preparing a frit for glaze according to an embodiment of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In addition, the technical solutions in the embodiments of the present invention may be combined with each other, but it must be based on the realization of those skilled in the art, and when the technical solutions are contradictory or cannot be realized, such a combination of technical solutions should not be considered to exist, and is not within the protection scope of the present invention.
Unless otherwise specifically stated, various raw materials, reagents, instruments, equipment and the like used in the present invention are commercially available or can be prepared by existing methods.
The invention provides a frit for glaze, which comprises the following raw materials in parts by weight:
70-80 parts by mass of lepidolite roasting impregnation slag, 3-8 parts by mass of calcite and 3-5 parts by mass of quartz.
Lepidolite having a chemical formula of K ((Li)2-xAl1+x(Al2xSi4-2xO10)(F，OH)2) And) is a layered silicate mineral. In the general lithium extraction process, lepidolite and sulfate are mixed and then roasted at high temperature, metal ions in the sulfate are replaced by lithium ions through high-temperature ion replacement to form soluble lithium sulfate, and the soluble lithium sulfate is leached by water or dilute acid and then filtered to leave filtrate. Rubidium and cesium elements in the lepidolite remain in the slag.
The calcite can increase the refractive index of the glaze, improve the glossiness and improve the light transmission; meanwhile, calcium oxide generated by the heated decomposition of calcite can be used as a high-temperature fluxing agent to reduce the melting temperature and the high-temperature viscosity; and controlling 3-8 parts by mass of calcite to avoid devitrification of the glaze surface caused by excessive crystallization.
More easily-melted substances CaO and Na in lepidolite roasting leaching slag and calcite2O、K2O, MgO, and the like, to be fused with quartz and lepidolite to calcine silicate in the impregnation slag to generate transparent glass, so that the glaze is bright and the glossiness of the glaze is improved. Meanwhile, the mechanical strength of the glaze is increased, the hardness of the glaze is improved, and the ceramic crystal is wear-resistant, has good chemical stability and is not influenced by the erosion of acid.
Further, the raw materials also comprise the following components:
5-8 parts by mass of barium carbonate, 10-14 parts by mass of alumina, 1-3 parts by mass of potassium carbonate and 1-2 parts by mass of strontium carbonate. The raw materials contain 0.1-0.5 parts by mass of rubidium element, and the rubidium element is introduced through lepidolite roasting impregnation slag.
The addition of barium carbonate can reduce the melting temperature, so that when the prepared frit for glaze is used for ceramic processing, the temperature of the glaze can be consistent with that of a blank, and the glaze luster is increased.
The added alumina takes corundum as a main crystal phase, so that the mechanical strength and the hardness of the glaze frit are increased, the high-frequency dielectric loss is small, the high-temperature insulation resistance is high, and the chemical corrosion resistance and the thermal conductivity are good.
The addition of potassium carbonate reduces the melting temperature and increases the coefficient of expansion of the glaze frit.
When preparing the frit for glaze, the generation of air bubbles and pinholes on the ceramic glaze surface can be reduced by adding strontium carbonate.
The lepidolite roasting impregnation slag contains a certain amount of rubidium element, so that the color of the fired glaze is improved, and the prepared glaze has good glossiness and flatness; through sintering the lepidolite roasting infusion slag, the lepidolite roasting infusion slag can be utilized, and the environment is protected while waste is utilized; the lepidolite roasting leaching residue contains potassium element, calcium element, aluminum element and silicon element which can be utilized to prepare the frit for glaze.
The invention also provides a preparation method of the frit for glaze, which comprises the following steps:
s1, roasting the lepidolite leaching residue, calcite and quartz to generate a matrix;
specifically, according to the mass parts, 70-80 parts of lepidolite roasting impregnation slag, 3-8 parts of calcite and 3-5 parts of quartz are roasted at the temperature of 1000-1200 ℃ to generate a matrix.
The sulfate in the lepidolite roasting leaching residue can further generate silicate by being roasted as a matrix in advance, wherein sulfur element is evaporated.
Step S2, grinding the substrate produced in the step S1 into powder;
grinding into powder to facilitate melting in step S3, and mixing.
Step S3, melting the powder obtained in the step S2 to form a liquid substance;
specifically, 5-8 parts by mass of barium carbonate, 10-14 parts by mass of alumina, 1-3 parts by mass of potassium carbonate and 1-2 parts by mass of strontium carbonate are added to the powder obtained in the second step and are melted together to form a liquid substance.
Barium carbonate, aluminum oxide, strontium carbonate and potassium carbonate are added to increase various properties of the glaze frit. The water-soluble raw materials and the silicon dioxide can be melted together by melting and then water quenching.
Step S4, water-quenching the liquid material obtained by melting in step S3 to obtain a block-shaped glassy material, and then crushing the glassy material into frit particles to obtain the above-mentioned frit for glaze.
The invention also provides a ceramic glaze material prepared by using the frit for glaze as a raw material.
The frit for glaze provided by the invention is specifically described by the following specific examples, wherein the lepidolite roasting infusion slag is collected from the country of the western union vone, and the lepidolite roasting infusion slag comprises the following components:
| ％ | ％ | ||
| Li2O | 0.2 | Cs2O | 0.005 |
| SiO2 | 68 | Na2O | 5 |
| Al2O3 | 8 | Rb2O | 2 |
| K2O | 2 | SO3 | 3 |
| Fe2O3 | 0.3 |
example 1
Roasting 80g of lepidolite roasting leaching residue, 6g of calcite and 4g of quartz at 1100 ℃ to generate a matrix, and grinding the matrix into powder; melting at 1100-1500 ℃ to form a liquid substance;
the liquid material obtained by melting is water-quenched to obtain a block-shaped glassy material, and then the glassy material is crushed into frit granules to prepare the frit for glaze.
Example 2
Taking 70g of lepidolite roasting infusion slag, 3g of calcite and 3g of quartz, roasting at the temperature of 1000 ℃ to generate a matrix, and grinding into powder;
to the powder were added 5g of barium carbonate, 10g of alumina, 1g of potassium carbonate, and 1g of strontium carbonate. Melting at 1100-1500 ℃ to form a liquid substance;
the liquid material obtained by melting is water-quenched to obtain a block-shaped glassy material, and then the glassy material is crushed into frit granules to prepare the frit for glaze.
Example 3
Roasting 80g of lepidolite roasting leaching residue, 6g of calcite and 4g of quartz at 1100 ℃ to generate a matrix, and grinding the matrix into powder;
to the powder were added 5g of barium carbonate, 10g of alumina, 1g of potassium carbonate, and 1g of strontium carbonate. Melting at 1100-1500 ℃ to form a liquid substance;
the liquid material obtained by melting is water-quenched to obtain a block-shaped glassy material, and then the glassy material is crushed into frit granules to prepare the frit for glaze.
Example 4
Roasting 75g of lepidolite roasting leaching slag, 8g of calcite and 5g of quartz at 1200 ℃ to generate a matrix, and grinding the matrix into powder; melting at 1100-1500 ℃ to form a liquid substance;
to the powder were added 8g of barium carbonate, 14g of alumina, 3g of potassium carbonate, and 2g of strontium carbonate. Melting at 1100-1500 ℃ to form a liquid substance;
the liquid material obtained by melting is water-quenched to obtain a block-shaped glassy material, and then the glassy material is crushed into frit granules to prepare the frit for glaze.
Example 5
Roasting 75g of lepidolite roasting leaching slag, 8g of calcite and 5g of quartz at 1200 ℃ to generate a matrix, and grinding the matrix into powder; melting at 1100-1500 ℃ to form a liquid substance;
to the powder were added 6g of barium carbonate, 12g of alumina, 2g of potassium carbonate, and 1.5g of strontium carbonate. Melting at 1100-1500 ℃ to form a liquid substance;
the liquid material obtained by melting is water-quenched to obtain a block-shaped glassy material, and then the glassy material is crushed into frit granules to prepare the frit for glaze.
The glaze frits prepared in examples 1 to 5 were added to a feldspar glaze in an amount of 30% by mass, ball-milled, applied to the surface of a green brick, and fired. Adopting GB/T4100-006 mirror image test, the test data is as follows:
| colour(s) | Flatness of | Wear resistance | |
| Example 1 | Uniformity | Smooth and has no obvious pores | 3 |
| Example 2 | Uniformity | Smooth and has no obvious pores | 3 |
| Example 3 | Uniformity | Smooth and has no obvious pores | 3 |
| Example 4 | Uniformity | Smooth and has no obvious pores | 3 |
| Example 5 | Uniformity | Smooth and has no obvious pores | 3 |
The above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, and all modifications and equivalents of the present invention, which are made by the present specification and directly/indirectly applied to other related technical fields within the spirit of the present invention are included in the scope of the present invention.
Claims (6)
1. The frit for glaze is characterized by comprising the following raw materials in parts by mass:
70-80 parts by mass of lepidolite roasting impregnation slag, 3-8 parts by mass of calcite and 3-5 parts by mass of quartz; 5-8 parts by mass of barium carbonate, 10-14 parts by mass of alumina, 1-3 parts by mass of potassium carbonate and 1-2 parts by mass of strontium carbonate;
the raw materials comprise, by mass, 0.1-0.5 parts of rubidium element, and the rubidium element is introduced through lepidolite roasting impregnation slag.
2. The preparation method of the frit for glaze is characterized by comprising the following steps:
step one, roasting lepidolite leaching residues, calcite and quartz to generate a matrix;
step two, grinding the substrate produced in the step one into powder;
step three, melting the powder obtained in the step two to form a liquid substance;
step four, water quenching the liquid material obtained by melting in the step three to obtain a block-shaped glassy material, and then crushing the block-shaped glassy material into frit particles to prepare the glaze frit of claim 1.
3. A method for producing a frit for glaze according to claim 2, wherein the firing temperature in the first step is 1000 to 1200 ℃.
4. A method of producing a frit for glaze as claimed in claim 2, wherein the first step comprises:
according to the mass parts, 70-80 parts of lepidolite roasting infusion slag, 3-8 parts of calcite and 3-5 parts of quartz are roasted to generate a matrix.
5. A method of manufacturing a frit for glaze according to claim 2, wherein the third step comprises:
and (3) adding 5-8 parts by mass of barium carbonate, 10-14 parts by mass of alumina, 1-3 parts by mass of potassium carbonate and 1-2 parts by mass of strontium carbonate into the powder obtained in the step two, and melting the powder together to form a liquid substance.
6. A ceramic glaze produced using the glaze frit of claim 1 as a raw material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911066699.0A CN110627359B (en) | 2019-11-04 | 2019-11-04 | Frit for glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911066699.0A CN110627359B (en) | 2019-11-04 | 2019-11-04 | Frit for glaze and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110627359A CN110627359A (en) | 2019-12-31 |
| CN110627359B true CN110627359B (en) | 2022-03-18 |
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| CN115572067A (en) * | 2022-09-16 | 2023-01-06 | 江西新明珠建材有限公司 | Dry grain glaze, matte ceramic tile and preparation method thereof |
| CN115893844B (en) * | 2022-11-22 | 2024-01-30 | 景德镇陶瓷大学 | Preparation method of ultra-smooth ceramic glaze |
| CN115818963A (en) * | 2022-12-28 | 2023-03-21 | 福建省德化中兴制釉有限公司 | Ceramic frit and preparation method thereof |
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