CN110611078A - Preparation method of lithium titanate-carbon nanotube electrode material - Google Patents
Preparation method of lithium titanate-carbon nanotube electrode material Download PDFInfo
- Publication number
- CN110611078A CN110611078A CN201810615416.2A CN201810615416A CN110611078A CN 110611078 A CN110611078 A CN 110611078A CN 201810615416 A CN201810615416 A CN 201810615416A CN 110611078 A CN110611078 A CN 110611078A
- Authority
- CN
- China
- Prior art keywords
- titanate
- carbon nanotube
- electrode material
- lithium
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses a preparation method of a novel lithium titanate-carbon nanotube electrode material, which comprises the following steps: s1: mixing an NMP mixture containing 4 wt% of carbon nano tubes, dihydric alcohol and titanate, adding the mixture into a homogeneous reactor, stirring the mixture to perform polymerization reaction to form polymer mixed slurry A with the carbon nano tubes, performing suction filtration on the slurry A, and washing the slurry A with a methanol solution to obtain a polymer M with the carbon nano tubes; s2: mixing the polymer M with the carbon nano tube and a lithium compound, dissolving the mixture in water, then placing the mixture in a homogeneous reactor, stirring the mixture to perform hydrolysis reaction to obtain mixture slurry B, performing suction filtration on the slurry B, and washing the slurry B with a methanol solution to obtain a solid N; s3: and sintering the solid N in a high-temperature furnace in an inert atmosphere to obtain the lithium titanate-carbon nanotube electrode material. The lithium titanate-carbon nanotube electrode material prepared by the preparation method can realize charge and discharge under large current, and solves the problems of capacity attenuation and poor rate capability during charge and discharge under large current.
Description
Technical Field
The invention relates to a lithium titanate-carbon nanotube serving as a negative electrode material of a lithium ion battery and having high capacity and deep charge and discharge capacity and a preparation method thereof.
Background
Lithium titanate negative electrode material (Li) in commercial market at present4Ti5O12) It has high safety, high charge-discharge rate, excellent cycle performance and excellent charge-discharge performancePressure stability, etc., however, Li4Ti5O12The electron conductivity (and lithium ion mobility) of the material is low, so that the capacitance attenuation is large during large-current charge and discharge, and the rate capability is poor.
In the prior art, lithium titanate and a conductive agent with excellent conductive performance, such as graphene, activated carbon and the like, are mainly subjected to composite doping to prepare an electrode material so as to make up for the defect of insufficient conductive capability of the lithium titanate material. Generally, the lithium titanate-activated carbon composite electrode material prepared can cause pore channel blockage, reduce the pore volume of activated carbon and the specific surface area of the composite material, and is not favorable for full exertion of adsorption performance. In the preparation process of the lithium titanate-graphene composite electrode, due to the limitation of the preparation method, the graphene is difficult to be uniformly dispersed in the slurry, and the battery capacity, the charge-discharge rate and other performances of the prepared electrode are not ideal.
Disclosure of Invention
The invention aims to provide a novel preparation method of a lithium titanate-carbon nanotube electrode material aiming at the defects in the prior art, which comprises the following steps:
s1: mixing and adding a carbon nano tube, dihydric alcohol, titanate and a dispersing agent into a homogeneous reactor, stirring to perform polymerization reaction to form polymer mixed slurry A with the carbon nano tube, performing suction filtration on the slurry A, and washing with a washing solvent to obtain a polymer M with the carbon nano tube;
the dispersant in S1 is an organic substance that is liquid at room temperature, other than water and organic acids, such as at least one of alcohols, ethers, aldehydes, ketones, esters, amines, amides, and hydrocarbons, but is not limited to these types of solvents.
The washing solvent in S1 is an organic substance that is liquid at room temperature, excluding water and organic acids, such as at least one of alcohols, ethers, aldehydes, ketones, esters, amines, amides, and hydrocarbons, but is not limited to these types of solvents.
S2: mixing the polymer M with the carbon nano tube and a lithium compound, mixing the mixture with water, putting the mixture into a homogeneous reactor, stirring the mixture to perform hydrolysis reaction to obtain mixture slurry B, and performing suction filtration on the slurry B to obtain a solid N;
s3: and sintering the solid N in a high-temperature furnace in an inert atmosphere to obtain the lithium titanate-carbon nanotube electrode material.
Preferably, the glycol in step S1 is at least one selected from the group consisting of ethylene glycol, 1, 3-propanediol and 1, 2-propanediol.
Preferably, the titanate in step S1 is at least one selected from butyl titanate, isopropyl titanate, n-propyl titanate, ethyl titanate and methyl titanate.
Preferably, the weight ratio X of the dihydric alcohol to the carbon nanotubes in the step S1 is selected from 100:0.1 to 1:1, preferably from 50:1 to 10: 1.
Preferably, in the step S1, the weight ratio Y of the titanate to the carbon nanotube is 5:1 to 100: 1.
Preferably, the compound of lithium in step S2 is selected from: lithium oxides, hydroxides, carbonates, bicarbonates, nitrates, nitrites, organic carboxylates, organometallic compounds or mixtures of these compounds.
Preferably, the ratio Z of the number of lithium (Li) atoms to the number of titanium (Ti) atoms of the titanate in step S1 and the lithium compound in step S2 is selected from 3:5 to 6: 5.
Preferably, the temperature of the homogeneous reactor in the steps S1 and S2 is set to 50 to 250 ℃, preferably 100 to 200 ℃.
Preferably, the mixture slurry in steps S1 and S2 is reacted in the homogeneous reactor for 0.2-15 h.
Preferably, the sintering temperature in step S3 is selected from 300-800 deg.C, and the preferred temperature is 400 deg.C to 750 deg.C.
Preferably, the inert gas in step S3 is at least one of nitrogen, argon, helium and neon.
Compared with the prior art, the invention has the beneficial effects that:
in the preparation process of the lithium titanate-carbon nanotube electrode material, the carbon nanotubes are uniformly distributed in the lithium titanate particle phase by reasonably setting the preparation steps and the process parameters.
In the lithium titanate-carbon nanotube lithium electrode material prepared by the preparation method, the crystal size of lithium titanate is nanoscale, the diffusion distance of lithium ions in the crystal is reduced, but the performance of lithium titanate is not changed, the addition of the carbon nanotube improves the performance of a conductor of the material, and the increased pore structure (the interface pore of the carbon nanotube and the lithium titanate is beneficial to the entering of an electrolyte solution) is beneficial to Li+Migration of (2), reduction of Li+The transfer impedance of the capacitor enables the capacitor to realize charging and discharging under large current, and solves the problems of capacity attenuation and poor rate capability during charging and discharging under large current.
In the test of a button battery prepared by taking lithium titanate-carbon nanotube material as an anode and metallic lithium as a cathode, the measured specific capacity is 221mAh/g (much higher than that of Li) under the condition of charging and discharging with the current density of 300mA/g4Ti5O12175mAh/g) and no capacity fading after 500 charges and discharges.
Drawings
Fig. 1 is a synthesis principle of the lithium titanate-carbon nanotube electrode material prepared in example 1, where MOF is a polymer formed by polymerization of isopropyl titanate and ethylene glycol, CNT is a carbon nanotube,
fig. 2 is an SEM photograph of the lithium titanate-carbon nanotube electrode material prepared in example 1.
FIG. 3 is an XRD pattern of lithium titanate and lithium titanate-carbon nanotube electrode material prepared in example 1, LTO-CNTs represents lithium titanate-carbon nanotube negative electrode material, LTO represents lithium titanate Li4Ti5O12。
FIG. 4 is an AC impedance diagram of the lithium titanate-carbon nanotube electrode material prepared in example 1, LTO-CNTs represents the lithium titanate-carbon nanotube material, pure LTO represents the lithium titanate Li4Ti5O12。
FIG. 5 is a cycle curve of a charge and discharge test performed on the lithium titanate-carbon nanotube electrode material of example 1 at a current density of 300 mA/g.
FIG. 6 is a multiplying power cycle diagram of the lithium titanate-carbon nanotube electrode material and lithium titanate of example 1 under different current densities, wherein the charging and discharging tests are performed at current densities of 100mA/g, 200mA/g, 300mA/g, 400mA/g and 500mA/g, and after 20 cycles at each current density, the cycle is returned to the current density of 100mA/g for 20 cycles, and the test is ended.
Fig. 7 is a multiplying power cycle diagram of the lithium titanate-carbon nanotube electrode material of example 2 under different current densities, wherein the charging and discharging tests are performed at current densities of 100mA/g, 200mA/g, 300mA/g, 400mA/g and 500mA/g, and after 20 cycles at each current density, the test is ended after the current density returns to the current density of 100mA/g and the cycle is performed for 20 cycles.
Fig. 8 is a multiplying power cycle diagram of the lithium titanate-carbon nanotube electrode material of example 3 under different current densities, wherein a charge and discharge test is performed at current densities of 100mA/g, 200mA/g, 300mA/g, 400mA/g, and 500mA/g, and after 20 cycles at each current density, the test is ended after the current density returns to the current density of 100mA/g and the cycle is performed for 20 cycles.
Detailed Description
The lithium titanate-carbon nanotube electrode material and the preparation method thereof according to the technical scheme of the present invention are further described in detail below with reference to specific embodiments and accompanying drawings.
Example one
Weighing 3.1251g of carbon nano tube (dispersed in NMP and having the content of 4wt percent), the NMP mixture and 12.5062g of ethylene glycol, adding the mixture into a 100mL reaction kettle, and then adding 4.457g of isopropyl titanate into a glove box; after ventilation, the mixture is placed in a homogeneous reactor at 200 ℃ and reacts for 12 hours at the rotating speed of 10r/min to obtain slurry A;
cooling the slurry A, then carrying out suction filtration, washing with 10mL of methanol, putting 2.0190g of product into a reaction kettle, adding 5.0746g of lithium hydroxide aqueous solution (1.0mol/L), and then placing the mixture into a 200 ℃ homogeneous reactor to react for 12 hours at the rotating speed of 10 r/min; obtaining slurry B;
(III) filtering the slurry B to separate out solids, taking the solids and placing the solids in a tube furnace at 700 ℃ N2Sintering for 4 hours in the atmosphere to obtain a lithium titanate electrode material;
(IV) placing the lithium titanate electrode material, the PVDF NMP solution (3 wt%) and the conductive carbon black in a ball milling tank according to the mass ratio of less than 8:1:1, ball milling for 30min to obtain electrode slurry,
the above materials, PVDF (3% PVDF in N-methylpyrrolidone solution), and conductive carbon black were mixed at a mass ratio of 8:1:1 to prepare a slurry. Coating the slurry on copper foil, drying for 2h at 120 ℃ in nitrogen, taking the prepared pole piece as a positive electrode, taking a metal Li piece as a negative electrode and taking 1.0M LiPF6And (3) preparing a half cell by using the carbonate solution as an electrolyte.
The accompanying drawings in the specification can analyze that the lithium titanate-carbon nanotube electrode material has several remarkable characteristics:
the synthesis principle of the lithium titanate-carbon nanotube electrode material in fig. 1 can be known as follows:
the preparation method comprises the steps of putting a Carbon Nano Tube (CNT), isopropyl titanate and ethylene glycol into a homogeneous reactor, fully stirring and reacting, carrying out polymerization reaction on the isopropyl titanate and the ethylene glycol to generate a polymer (MOF), and uniformly wrapping the Carbon Nano Tube (CNT) in a polymer (MOF) structure generated by the reaction of the isopropyl titanate and the ethylene glycol. Separating the polymer with CNT, adding lithium hydroxide aqueous solution, continuously stirring and reacting for a certain time, carrying out on-site hydrolysis reaction on the solid polymer around the CNT to form TiOx (OH) y. mLiOH, uniformly wrapping the periphery of the CNT to obtain a solid product (TiOx (OH) y. mLiOH-CNT), and finally sintering the solid product (TiOx (OH) y. mLiOH-CNT) at high temperature in an inert gas atmosphere to obtain an electrode material, thereby realizing uniform distribution of carbon nanotubes in a lithium titanate particle phase and fully conducting Li with good lithium titanate+The ionic characteristics and the CNT electron conductors are combined, so that the capacitance, the charge and discharge rate and the stability of the electrode material are effectively improved.
As can be seen from the SEM image of the lithium titanate-carbon nanotube electrode material in fig. 2, the lithium titanate particles and the carbon nanotubes are uniformly and densely dispersed between each other, and the particles have a uniform size at the nanometer level, and they are agglomerated with each other to form aggregates having a size of about 1 μm, and have a stable framework structure, and at this time, the lithium titanate-carbon nanotube negative electrode material also exhibits the highest capacity.
As can be seen from the XRD patterns of the lithium titanate and lithium titanate-carbon nanotube electrode materials in FIG. 3, compared with the standard spectrum, there are no other impurity peaks, which indicates that the product prepared by using example 1 is relatively pure lithium titanate crystal Li4Ti5O12And carbon nanotubes.
As can be seen from the ac impedance diagram of the lithium titanate-carbon nanotube electrode material in fig. 4, the comparison between the resistance value of the high-frequency region and the pure lithium titanate shows that the addition of the carbon nanotube significantly increases the conductivity of the lithium titanate material and reduces the charge transfer impedance. The slope of the straight line of the low-frequency region of the composite material is also greater than that of the straight line of the pure lithium titanate material, which shows that Li is reduced+Diffusion resistance of ions in the material.
FIG. 4 shows that the charge-discharge cycle was carried out at 0.01V to 2.00V, and at a current density of 100mA/g, the charge-discharge stable cycle capacity was 260mAh/g, and the first charge-discharge cycle efficiency was 86%, indicating that the material had high lithium ion reversibility.
It can be seen from the above examples that the lithium titanate-carbon nanotube electrode material prepared by the method of the present invention has a particle size of mostly nano-scale, lithium titanate particles are uniformly and densely dispersed in carbon nanotubes, and the lithium titanate-carbon nanotube material prepared by the method of example 1 has high purity, and only has a lithium titanate phase. The circulating capacity measured under the current density of 300mA/g is 221mAh/g (much higher than the theoretical 175mAh/g), no attenuation is generated after 500 times of charge and discharge, and the circulating capacity of 200mAh/g is reached under the current density of 500mA/g when the multiplying power performance is tested, so that the material shows good multiplying power performance.
Example two
The difference between the second embodiment and the first embodiment is that the sintering temperature in the step (three) in the second embodiment is changed to 400 ℃, and the rest is the same as that in the first embodiment, and is not described herein.
EXAMPLE III
The difference between the third embodiment and the first embodiment is that the sintering temperature in the third step in the second embodiment is changed to 500 ℃, and the rest is the same as that in the first embodiment, and is not described herein.
As can be understood from the drawings attached to the specification, FIGS. 7 and 8, in the comparison between the second and third examples, the material sintered at 500 ℃ has a higher capacity than that sintered at 400 ℃ in comparison with the second and third examples at different sintering temperatures, and the capacity is 0.4 A.g-1The former is 250mAh/g and the latter is 200mAh/g at the current density. The capacity of the lithium titanate-carbon nanotube material prepared by sintering at 500 ℃ can also maintain 250mAh/g under high rate current density, the attenuation is reduced, and the lithium titanate-carbon nanotube material is prepared in the existing commercial product Li4Ti5O12Above all, only about 170mAh/g or even less can be achieved at 1C.
Claims (13)
1. A preparation method of a lithium titanate-carbon nanotube electrode material is characterized by comprising the following steps:
s1: mixing and adding a carbon nano tube, dihydric alcohol, titanate and a dispersing agent into a reactor, stirring to perform polymerization reaction to form polymer mixed slurry A with the carbon nano tube, separating the slurry A, and washing with a washing solvent to obtain a polymer M with the carbon nano tube;
s2: mixing the polymer M with the carbon nano tube, the lithium compound and water, then placing the mixture in a reactor, stirring and reacting to obtain mixture slurry B, and performing suction filtration on the slurry B to obtain solid N;
s3: and sintering the solid N in a high-temperature furnace in an inert atmosphere to obtain the lithium titanate-carbon nanotube electrode material.
2. The method of claim 1, wherein in step S1, the diol is at least one selected from the group consisting of ethylene glycol, 1, 3-propanediol, and 1, 2-propanediol.
3. The method of claim 1, wherein the titanate in step S1 is at least one selected from butyl titanate, isopropyl titanate, n-propyl titanate, ethyl titanate, and methyl titanate.
4. The method of claim 1, wherein the dispersant in step S1 is an organic substance that is liquid at room temperature except water and organic acids, such as at least one of alcohols, ethers, aldehydes, ketones, esters, amines, amides, and hydrocarbons, but is not limited to these types of solvents.
5. The method of claim 1, wherein the washing solvent in step S1 is an organic substance that is liquid at room temperature except water and organic acids, such as at least one of alcohols, ethers, aldehydes, ketones, esters, amines, amides, and hydrocarbons, but is not limited to these types of solvents.
6. The method for preparing the lithium titanate-carbon nanotube electrode material as claimed in claim 1, wherein in step S1, the weight ratio X of the glycol to the carbon nanotube is selected from 100: 0.1-1: 1, preferably from 50: 1-10: 1.
7. The method for preparing a lithium titanate-carbon nanotube electrode material as claimed in claim 1, wherein the weight ratio Y of the titanate to the carbon nanotube in step S1 is selected from 5:1 to 100: 1.
8. The method of claim 1, wherein the lithium compound in step S2 is selected from the group consisting of: at least one of an oxide, hydroxide, carbonate, bicarbonate, nitrate, nitrite, organic carboxylate, and organic metal compound of lithium.
9. The method for preparing a lithium titanate-carbon nanotube electrode material as claimed in claim 1, wherein the atomic ratio Z of lithium (Li) to titanium (Ti) of the titanate in step S1 and the lithium compound in step S2 is selected from 3:5 to 6: 5.
10. The method for preparing a lithium titanate-carbon nanotube electrode material as claimed in claim 1, wherein the reaction temperature in steps S1 and S2 is 50-250 ℃, preferably 100-200 ℃.
11. The method of claim 1, wherein the reaction time of the mixture slurry in steps S1 and S2 is 0.2-15 h.
12. The method as claimed in claim 1, wherein the sintering temperature in step S3 is selected from 300-800 ℃, preferably 400-750 ℃.
13. The method of claim 1, wherein the inert gas in step S3 is at least one of nitrogen, argon, helium, and neon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810615416.2A CN110611078B (en) | 2018-06-14 | 2018-06-14 | Lithium titanate-carbon nanotube composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810615416.2A CN110611078B (en) | 2018-06-14 | 2018-06-14 | Lithium titanate-carbon nanotube composite material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110611078A true CN110611078A (en) | 2019-12-24 |
| CN110611078B CN110611078B (en) | 2021-04-02 |
Family
ID=68887954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810615416.2A Active CN110611078B (en) | 2018-06-14 | 2018-06-14 | Lithium titanate-carbon nanotube composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110611078B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112408489A (en) * | 2020-11-26 | 2021-02-26 | 中北大学 | Method for refining lithium ion battery anode material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130059174A1 (en) * | 2011-09-07 | 2013-03-07 | Aruna Zhamu | Partially surface-mediated lithium ion-exchanging cells and method for operating same |
| CN106848251A (en) * | 2017-03-15 | 2017-06-13 | 北京朗盛特耐科技有限公司 | A kind of preparation method of CNT lithium titanate composite anode material |
| CN107946554A (en) * | 2017-10-26 | 2018-04-20 | 天津普兰能源科技有限公司 | A kind of preparation method of lithium battery lithium titanate anode material |
-
2018
- 2018-06-14 CN CN201810615416.2A patent/CN110611078B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130059174A1 (en) * | 2011-09-07 | 2013-03-07 | Aruna Zhamu | Partially surface-mediated lithium ion-exchanging cells and method for operating same |
| CN106848251A (en) * | 2017-03-15 | 2017-06-13 | 北京朗盛特耐科技有限公司 | A kind of preparation method of CNT lithium titanate composite anode material |
| CN107946554A (en) * | 2017-10-26 | 2018-04-20 | 天津普兰能源科技有限公司 | A kind of preparation method of lithium battery lithium titanate anode material |
Non-Patent Citations (2)
| Title |
|---|
| JIE SHU等: "In situ fabrication of Li4Ti5O12@CNT composites and their superior lithium storage properties", 《RSC ADVANCES》 * |
| 杨茂萍 等: "碳纳米管修饰钛酸锂的制备及性能", 《电池》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112408489A (en) * | 2020-11-26 | 2021-02-26 | 中北大学 | Method for refining lithium ion battery anode material |
| CN112408489B (en) * | 2020-11-26 | 2023-01-31 | 中北大学 | Method for refining lithium ion battery anode material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110611078B (en) | 2021-04-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110299516B (en) | Preparation method of carbon nanotube array loaded lithium titanate flexible electrode material | |
| US10096822B2 (en) | Lithium ion battery graphite negative electrode material and preparation method thereof | |
| KR102319176B1 (en) | Anode slurry for lithium ion batteries | |
| CN105609730B (en) | A kind of preparation method of silicon/carbon graphite composite negative pole material | |
| CN107732172B (en) | Lithium ion battery cathode material and preparation method thereof | |
| CN103500815A (en) | Soft-carbon composite cathode material of lithium ion battery and preparation method thereof | |
| CN106410153B (en) | A kind of titanium nitride cladding nickel titanate composite material and preparation method and application | |
| CN112768688B (en) | Lithium iron phosphate material, preparation method thereof and lithium ion battery | |
| CN103247802A (en) | Graphite composite negative electrode material for lithium ion battery, preparation method of material, and lithium ion battery | |
| CN115566170B (en) | Preparation method of high-energy-density quick-charging lithium ion battery anode material | |
| CN110635116A (en) | Lithium ion battery cathode material, preparation method thereof, cathode and lithium ion battery | |
| CN114023957B (en) | Selenium-containing compound/carbon fiber energy storage material and preparation method and application thereof | |
| EP4016673A1 (en) | Negative electrode, electrochemical device containing same and electronic device | |
| CN112320792B (en) | Preparation method of negative electrode material for lithium ion battery and product thereof | |
| CN110611078B (en) | Lithium titanate-carbon nanotube composite material and preparation method thereof | |
| CN111162269B (en) | Negative electrode active material for battery and preparation method thereof | |
| KR20190080710A (en) | Method of preparing positve active material, postive active material prepared by same, positive electrode for non-aqueous rechargeable battery, and non-aqueous rechargeable battery | |
| CN117059761A (en) | Sodium ion positive electrode material and preparation method thereof | |
| CN116845191A (en) | Self-supplementing lithium ternary material, preparation method and application | |
| CN116565168A (en) | Phosphorus-silver-silicon co-doped hard carbon composite material and preparation method thereof | |
| CN115893509A (en) | Preparation method of cobaltosic oxide/nitrogen-doped carbon composite material for lithium ion battery cathode material | |
| US20220158175A1 (en) | Anode material, electrochemical device and electronic device including the same | |
| EP4060767A1 (en) | Negative electrode material, electrochemical device including same, and electronic device | |
| JP2022518419A (en) | Negative electrode material, as well as electrochemical and electronic equipment containing it | |
| CN111916685B (en) | Method for preparing titanium-silicon polymeric oxide composite lithium ion battery cathode material by thermal decomposition of organic titanium-silicon polymer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |