CN110595243A - Heat storage material filling method for improving solid sensible heat storage density and heat storage device - Google Patents

Heat storage material filling method for improving solid sensible heat storage density and heat storage device Download PDF

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Publication number
CN110595243A
CN110595243A CN201910827271.7A CN201910827271A CN110595243A CN 110595243 A CN110595243 A CN 110595243A CN 201910827271 A CN201910827271 A CN 201910827271A CN 110595243 A CN110595243 A CN 110595243A
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China
Prior art keywords
heat storage
storage material
solid heat
particle
particle solid
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CN201910827271.7A
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Chinese (zh)
Inventor
寇翠青
柳一曼
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Hebei Chuangshi New Material Technology Co Ltd
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Hebei Chuangshi New Material Technology Co Ltd
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Priority to CN201910827271.7A priority Critical patent/CN110595243A/en
Publication of CN110595243A publication Critical patent/CN110595243A/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/0056Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using solid heat storage material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Building Environments (AREA)

Abstract

The invention discloses a heat storage material filling method and a heat storage device for improving solid sensible heat storage density, which comprise the following steps: laying small-particle solid heat storage materials at the bottom of the shell, laying medium-particle solid heat storage materials on the small-particle solid heat storage materials, and laying large-particle solid heat storage materials on the medium-particle solid heat storage materials; laying medium-particle solid heat storage materials on the large-particle solid heat storage materials, and laying small-particle solid heat storage materials on the medium-particle solid heat storage materials; and continuously paving small-particle solid heat storage materials, paving medium-particle solid heat storage materials on the small-particle solid heat storage materials, and paving large-particle solid heat storage materials on the medium-particle solid heat storage materials. According to the invention, the solid heat storage material is filled in layers by grain size division without pressing, so that the void ratio of the solid heat storage material can be reduced to the greatest extent, the solid sensible heat storage density is improved, and the heat storage efficiency is further improved.

Description

Heat storage material filling method for improving solid sensible heat storage density and heat storage device
Technical Field
The present invention relates to a method for filling a thermal storage material for increasing the thermal storage density of sensible heat of a solid, and also relates to a thermal storage apparatus using the method for filling a thermal storage material.
Background
Sensible heat storage is heat absorbed or released when the temperature of a substance rises or falls, and the property of the substance does not change. The sensible heat storage material is divided into a liquid type and a solid type, and the common high-temperature solid sensible heat storage material is gravel, sand, bricks, ceramics, glass, iron, aluminum, concrete, ore, magnesia bricks and the like.
For high temperature solid sensible heat substances, the heat carrying medium or the medium for absorbing thermal energy or heat from an external source is a fluid substance. The heat transfer fluid may be water, air, any hydrocarbon fluid (e.g., hot oil), molten salts (e.g., sodium nitrate, potassium nitrate, magnesium chloride, etc.), or mixtures of these salts. The heat carrier materials, hydrocarbon fluids, molten salts, must be characterized by a low melting point so that they do not solidify during flow in the circuit. At present, the main heat exchange form of the high-temperature solid heat storage material is convection of heat carrying fluid air.
The Chinese patent application (application number: 201811189662.2) discloses a solid electric heat storage device, which comprises a sealed shell, a heat storage body, a heat storage air channel, a heating plate, an air inlet distribution plate and an air outlet distribution plate; four heat storage air channels are uniformly arranged in the heat storage body along the flowing direction of the heat storage air. The heat storage device has the following defects: the heat storage air channel is arranged in the heat storage body in order to realize heat exchange of the heat storage body, so that the channel needs to be specially designed on the heat storage body, the complexity of the forming process of the heat storage body is increased, and meanwhile, the production cost is also increased. The heat accumulator can adopt a magnesium iron brick, and the heat accumulator comprises the following components in percentage by weight: 60.5 percent of MgO, 20.5 percent of Fe2O3, 9.5 percent of FeO and 5 percent of SiO2, and the balance of water. In the preparation process, the components are firstly crushed into granules, which improves the difficulty of the preparation process of the magnesium-iron brick, and the production cost is higher, and then, the various crushed and granulated components are bonded together, and a channel is also required to be reserved to realize air heat exchange, however, the bonding is to remove the gap, and the air duct is additionally provided with the gap, so that the improvement of the sensible heat storage density of the solid is not facilitated, and the heat storage efficiency cannot be improved.
Disclosure of Invention
The first purpose of the invention is to provide a heat storage material filling method which is low in cost and small in process difficulty and can improve the solid sensible heat storage density.
The first object of the invention is achieved by the following technical measures: a heat storage material filling method for improving solid sensible heat storage density is characterized by comprising the following steps:
s1, laying a layer of small-particle solid heat storage material at the bottom of the shell, laying a layer of medium-particle solid heat storage material on the small-particle solid heat storage material, and laying a layer of large-particle solid heat storage material on the medium-particle solid heat storage material;
s2, laying a layer of medium-particle solid heat storage material on the large-particle solid heat storage material, and laying a layer of small-particle solid heat storage material on the medium-particle solid heat storage material;
s3, continuously laying a layer of small-particle solid heat storage material, laying a layer of medium-particle solid heat storage material on the small-particle solid heat storage material, and laying a layer of large-particle solid heat storage material on the medium-particle solid heat storage material;
s4, repeating the steps S2 and S3 until:
filling a medium-particle solid heat storage material into the gap, and filling a small-particle solid heat storage material into gaps among the solid heat storage materials and the gaps between the solid heat storage materials and the shell when the height of the gap between the solid heat storage materials and the top surface of the shell is smaller than the particle size of the large-particle solid heat storage material and larger than the particle size of the small-particle solid heat storage material;
and secondly, when the height of a gap between the solid heat storage material and the top surface of the shell is smaller than the particle size of the medium-particle solid heat storage material, filling small-particle solid heat storage materials in the gap, and filling gaps among the solid heat storage materials and between the solid heat storage materials and the shell with the small-particle solid heat storage materials.
Because the solid dominant heat storage material has a rigid appearance, the solid dominant heat storage material is not easy to realize gapless sealing with the four walls of the container and the pipelines penetrating through the solid dominant heat storage material (except high temperature and non-deterioration fusion). In the case of a regular solid heat-accumulative material, if the smallest units of the material can be completely and closely spread, the volume of one heat-accumulative body theoretically corresponds to the filling rate of the heat-accumulative material. However, the solid heat-accumulative material cannot be completely filled and filled.
According to the invention, the solid heat storage material is filled in layers by dividing the particle size of the solid heat storage material, and pressing is not needed, so that the void ratio of the solid heat storage material can be reduced to the greatest extent, the solid sensible heat storage density is improved, and the heat storage efficiency is further improved; the invention has simple process and low cost, and is beneficial to wide popularization and use.
Preferably, when the solid heat storage materials with large particles and medium particles are laid, horizontal gaps and vertical gaps consistent with the air inlet and outlet directions are maintained.
Preferably, when the medium-sized solid heat storage material is laid on the large-sized solid heat storage material, the vertical seams which are not aligned with the direction of the incoming and outgoing air are filled with the medium-sized solid heat storage material, but the overall height of the solid heat storage material is not increased.
Preferably, when the small-particle solid heat storage material is laid on the medium-particle solid heat storage material, the perks that are not aligned with the direction of the incoming and outgoing wind are filled with the small-particle solid heat storage material, but the overall height of the solid heat storage material is not increased.
Preferably, the particle size of the large-particle solid heat storage material of the present invention is 10cm or more and 25cm or less, the particle size of the medium-particle solid heat storage material is 5cm or more and 10cm or less, and the particle size of the small-particle solid heat storage material is 2cm or more and 5cm or less.
Preferably, the thickness of each layer of the small-particle solid heat storage material is at least 5 cm; the thickness of the solid heat storage material of the particles in each layer is at least 10 cm.
The solid heat storage material is any one or any combination of two or more than two of gravel, sand, brick, ceramic glass, iron, aluminum, concrete, ore and magnesia brick.
A second object of the present invention is to provide a thermal storage device using the above thermal storage material charging method.
The second object of the invention is achieved by the following technical measures: a thermal storage device using the method for charging a thermal storage material, characterized in that: the solid heat storage material is filled in the shell by using the heat storage material filling method, the heater is arranged at the periphery of the air channel and is positioned in the solid heat storage material and contacted with the solid heat storage material, and the wall surface of the shell where the air inlet and the air outlet are positioned is a grid surface.
In a preferred embodiment of the present invention, the mesh opening size of the mesh surface is 2cm or more and 25cm or less.
In a preferred embodiment of the present invention, the heater is fixed to an inner wall surface of the casing, that is, the inner wall surface is a remaining wall surface of the casing excluding the bottom surface and the mesh surface. The heat conduction of the heater can be improved by adding the metal fins in the heater.
Compared with the prior art, the invention has the following remarkable effects:
the solid heat storage material is filled in layers by dividing the particle size of the solid heat storage material, and the void ratio of the solid heat storage material can be reduced to the greatest extent without pressing, so that the solid sensible heat storage density is improved, and the heat storage efficiency is further improved.
The solid heat storage material is internally provided with the air duct, the wall surface where the air inlet and the air outlet of the shell are located is a grid surface, the grid surface plays a role in ventilation, corners of the solid heat storage material in an irregular shape can extend out through meshes, the solid heat storage material is fixed, and the solid heat storage material can be guaranteed to be stacked and piled up in the shell.
The method is simple in process, low in cost and beneficial to wide popularization and application.
Drawings
The invention is described in further detail below with reference to the figures and the specific embodiments.
FIG. 1 is a schematic view of the construction of a thermal storage device of the present invention;
FIG. 2 is a schematic view of the thermal storage device of the present invention in use.
Detailed Description
As shown in fig. 1, the heat storage device 8 of the present invention includes a casing 1, a solid heat storage material filled in the casing 1, and a heater (not shown in the figure), wherein the casing 1 is a cube, an air duct 2 is arranged in the solid heat storage material, the air duct 2 is a straight air duct, the air duct 2 penetrates through the casing 1 and forms an air inlet and an air outlet on opposite side wall surfaces of the casing 1, the wall surface of the casing 1 where the air inlet and the air outlet are located is a grid surface 3, and the aperture of the grid surface 3 is 2 cm. In the present embodiment, the heater is fixed to the inner wall surface of the housing 1, that is, the inner wall surface may be the top surface, the left and right side surfaces of the housing 1, and the heater is located in the periphery of the air duct 2 and in contact with the solid heat storage material.
The solid heat storage material is filled in the shell according to the following heat storage material filling method, and the solid heat storage material can be any one or any combination of two or more than two of gravel, sand, bricks, ceramic glass, iron, aluminum, concrete, ore and magnesia bricks.
A method for filling a heat storage material for improving the sensible heat storage density of a solid comprises the steps of dividing the solid heat storage material into a large-particle solid heat storage material, a medium-particle solid heat storage material and a small-particle solid heat storage material according to the particle size of the solid heat storage material, wherein the particle size of the large-particle solid heat storage material is larger than or equal to 10cm and smaller than or equal to 25cm, the particle size of the medium-particle solid heat storage material is larger than 5cm and smaller than 10cm, and the particle size of the small-particle solid heat storage material is larger than or equal to 2cm and smaller than or equal to 5 cm. The heat storage material filling method specifically comprises the following steps:
s1, paving a layer of small-particle solid heat storage material at the bottom of the shell, wherein the thickness of the small-particle solid heat storage material is at least 5 cm; laying medium-grained solid heat storage material on the small-grained solid heat storage material, wherein the thickness of the medium-grained solid heat storage material is at least 10 cm; laying large-particle solid heat storage materials on the medium-particle solid heat storage materials;
s2, laying a layer of medium-particle solid heat storage material on the large-particle solid heat storage material, and filling vertical seams which are inconsistent with the air inlet and outlet directions with the medium-particle solid heat storage material when the medium-particle solid heat storage material is laid, but not piling up, namely, the height of the solid heat storage material is the height after the large-particle solid heat storage material is laid;
laying a layer of small-particle solid heat storage material on the medium-particle solid heat storage material, and filling the vertical seams of the small-particle solid heat storage material, which are not consistent with the air inlet and outlet directions, with the small-particle solid heat storage material until the vertical seams are not piled up, namely the height of the solid heat storage material is the height of the medium-particle solid heat storage material after the laying;
s3, continuously laying a layer of small-particle solid heat storage material with the thickness of at least 5cm, and laying medium-particle solid heat storage material with the thickness of at least 10cm on the small-particle solid heat storage material; then, paving a layer of large-particle solid heat storage material on the medium-particle solid heat storage material;
when each layer of solid heat storage material is paved, particularly when large-particle and medium-particle solid heat storage materials are paved, vertical gaps and horizontal gaps consistent with air inlet and outlet are maintained as far as possible, so that the flowing direction of air in the solid heat storage materials is consistent with the air inlet and outlet direction of an air duct, and air circulation is facilitated.
S4, repeating the steps S2 and S3 until:
filling a medium-particle solid heat storage material into the gap, and filling a small-particle solid heat storage material into gaps among the solid heat storage materials and the gaps between the solid heat storage materials and the shell when the height of the gap between the solid heat storage materials and the top surface of the shell is smaller than the particle size of the large-particle solid heat storage material and larger than the particle size of the small-particle solid heat storage material;
and secondly, when the height of a gap between the solid heat storage material and the top surface of the shell is smaller than the particle size of the medium-particle solid heat storage material, filling small-particle solid heat storage materials in the gap, and filling gaps among the solid heat storage materials and between the solid heat storage materials and the shell with the small-particle solid heat storage materials.
As shown in figure 2, when in use, the heat storage device 8 of the invention is arranged in the casing 4 of the industrial air heater, the casing 4 is provided with an air outlet 5 and an air inlet 6, a fan 7 is arranged behind the heat storage device 8 according to the air flow direction, and the fan 7 is close to the air inlet 6. Air A enters the machine shell 4 from the air inlet 6, then enters the air channel through the air inlet on the heat storage device 8, exchanges heat with the solid heat storage material 9 in the heat storage device 8, blows out the air after absorbing heat from the air outlet on the heat storage device 8, and then goes out hot air through the air outlet 5 on the machine shell.
In other embodiments, the mesh openings of the mesh face are greater than or equal to 2cm and less than or equal to 25 cm. The heater is fixed to an inner wall surface of the casing, i.e., the inner wall surface is the remaining wall surface of the casing excluding the bottom surface and the mesh surface. Other heat storage materials can also be used as the solid heat storage material.
The embodiments of the present invention are not limited thereto, and according to the above-mentioned contents of the present invention, the present invention can be modified, substituted or changed in other various forms without departing from the basic technical idea of the present invention.

Claims (10)

1. A heat storage material filling method for improving solid sensible heat storage density is characterized by comprising the following steps:
s1, laying a layer of small-particle solid heat storage material at the bottom of the shell, laying a layer of medium-particle solid heat storage material on the small-particle solid heat storage material, and laying a layer of large-particle solid heat storage material on the medium-particle solid heat storage material;
s2, laying a layer of medium-particle solid heat storage material on the large-particle solid heat storage material, and laying a layer of small-particle solid heat storage material on the medium-particle solid heat storage material;
s3, continuously laying a layer of small-particle solid heat storage material, laying a layer of medium-particle solid heat storage material on the small-particle solid heat storage material, and laying a layer of large-particle solid heat storage material on the medium-particle solid heat storage material;
s4, repeating the steps S2 and S3 until:
filling a medium-particle solid heat storage material into the gap, and filling a small-particle solid heat storage material into gaps among the solid heat storage materials and the gaps between the solid heat storage materials and the shell when the height of the gap between the solid heat storage materials and the top surface of the shell is smaller than the particle size of the large-particle solid heat storage material and larger than the particle size of the small-particle solid heat storage material;
and secondly, when the height of a gap between the solid heat storage material and the top surface of the shell is smaller than the particle size of the medium-particle solid heat storage material, filling small-particle solid heat storage materials in the gap, and filling gaps among the solid heat storage materials and between the solid heat storage materials and the shell with the small-particle solid heat storage materials.
2. The thermal storage material filling method according to claim 1, characterized in that: when the solid heat storage materials with large particles and medium particles are paved, horizontal gaps and vertical gaps which are consistent with the air inlet and outlet directions are maintained.
3. The thermal storage material filling method according to claim 2, characterized in that: when the medium-particle solid heat storage material is paved on the large-particle solid heat storage material, the vertical seams which are inconsistent with the air inlet and outlet directions are filled with the medium-particle solid heat storage material, but the overall height of the solid heat storage material is not increased.
4. The thermal storage material filling method according to claim 3, characterized in that: when the small-particle solid heat storage material is paved on the medium-particle solid heat storage material, the vertical seams which are inconsistent with the air inlet and outlet directions are filled with the small-particle solid heat storage material, but the overall height of the solid heat storage material is not increased.
5. The thermal storage material filling method according to claim 4, characterized in that: the particle size of the large-particle solid heat storage material is greater than or equal to 10cm and less than or equal to 25cm, the particle size of the medium-particle solid heat storage material is greater than 5cm and less than 10cm, and the particle size of the small-particle solid heat storage material is greater than or equal to 2cm and less than or equal to 5 cm.
6. The thermal storage material filling method according to claim 5, characterized in that: the thickness of each layer of the small-particle solid heat storage material is at least 5 cm; the thickness of the solid heat storage material of the particles in each layer is at least 10 cm.
7. The thermal storage material filling method according to claim 6, characterized in that: the solid heat storage material is any one or any combination of two or more than two of gravel, sand, bricks, ceramic glass, iron, aluminum, concrete, ore and magnesia bricks.
8. A thermal storage device using the method for charging a thermal storage material according to any one of claims 1 to 7, characterized in that: the solid heat storage material is filled in the shell by using the heat storage material filling method, the heater is arranged at the periphery of the air channel and is positioned in the solid heat storage material and contacted with the solid heat storage material, and the wall surface of the shell where the air inlet and the air outlet are positioned is a grid surface.
9. The thermal storage device according to claim 8, characterized in that: the aperture of the meshes of the grid surface is more than or equal to 2cm and less than or equal to 25 cm.
10. The thermal storage device according to claim 9, characterized in that: the heater is fixed to an inner wall surface of the casing, that is, the inner wall surface is the remaining wall surface of the casing excluding the bottom surface and the mesh surface.
CN201910827271.7A 2019-09-03 2019-09-03 Heat storage material filling method for improving solid sensible heat storage density and heat storage device Pending CN110595243A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08254396A (en) * 1995-03-16 1996-10-01 Matsushita Electric Works Ltd Heat exchanger
JPH0933184A (en) * 1995-07-17 1997-02-07 Matsushita Electric Works Ltd Heat exchanger
JP2004156793A (en) * 2002-11-01 2004-06-03 Ip:Kk Heat storage device
CN101968240A (en) * 2010-11-16 2011-02-09 上海海事大学 Device and method for movably supplying heat by using phase-change heat-storage balls
WO2013167539A1 (en) * 2012-05-09 2013-11-14 Commissariat à l'énergie atomique et aux énergies alternatives Method for filling a heat storage tank with solid elements
KR20150124510A (en) * 2014-04-28 2015-11-06 현대제철 주식회사 Heat storage member and heat storage apparatus having the same
CN208983905U (en) * 2018-09-03 2019-06-14 中国科学院工程热物理研究所 A kind of packed bed regenerative apparatus

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08254396A (en) * 1995-03-16 1996-10-01 Matsushita Electric Works Ltd Heat exchanger
JPH0933184A (en) * 1995-07-17 1997-02-07 Matsushita Electric Works Ltd Heat exchanger
JP2004156793A (en) * 2002-11-01 2004-06-03 Ip:Kk Heat storage device
CN101968240A (en) * 2010-11-16 2011-02-09 上海海事大学 Device and method for movably supplying heat by using phase-change heat-storage balls
WO2013167539A1 (en) * 2012-05-09 2013-11-14 Commissariat à l'énergie atomique et aux énergies alternatives Method for filling a heat storage tank with solid elements
KR20150124510A (en) * 2014-04-28 2015-11-06 현대제철 주식회사 Heat storage member and heat storage apparatus having the same
CN208983905U (en) * 2018-09-03 2019-06-14 中国科学院工程热物理研究所 A kind of packed bed regenerative apparatus

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