CN110591577A - Anti-counterfeiting transfer paper with small crystal point effect and preparation method thereof - Google Patents

Anti-counterfeiting transfer paper with small crystal point effect and preparation method thereof Download PDF

Info

Publication number
CN110591577A
CN110591577A CN201910713145.9A CN201910713145A CN110591577A CN 110591577 A CN110591577 A CN 110591577A CN 201910713145 A CN201910713145 A CN 201910713145A CN 110591577 A CN110591577 A CN 110591577A
Authority
CN
China
Prior art keywords
coating
transfer
layer
counterfeiting
paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910713145.9A
Other languages
Chinese (zh)
Inventor
刘念
张华�
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI VISION-TECH NEW MATERIALS Co Ltd
Original Assignee
SHANGHAI VISION-TECH NEW MATERIALS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI VISION-TECH NEW MATERIALS Co Ltd filed Critical SHANGHAI VISION-TECH NEW MATERIALS Co Ltd
Priority to CN201910713145.9A priority Critical patent/CN110591577A/en
Publication of CN110591577A publication Critical patent/CN110591577A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/82Paper comprising more than one coating superposed
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04Physical treatment, e.g. heating, irradiating
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04Physical treatment, e.g. heating, irradiating
    • D21H25/06Physical treatment, e.g. heating, irradiating of impregnated or coated paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/28Presence of paper
    • C09J2400/283Presence of paper in the substrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)

Abstract

The invention discloses a preparation method of anti-counterfeiting transfer paper with a small crystal point effect, which comprises the following steps: 1) preparing a transfer coating by using a modified acrylate polymer as a base resin; 2) coating the transfer coating on a PET film to obtain a transfer layer; 3) molding the transfer layer on a molding press to obtain a laser information layer; 4) carrying out vacuum aluminum plating on the transfer layer to obtain an aluminum plating layer; 5) coating water-soluble glue on the aluminum-plated layer, compounding with base paper and drying; 6) coating a back glue material on the back of the composite paper, and drying; 7) and peeling the PET base film on the surface of the composite paper to obtain the anti-counterfeiting transfer paper with the small crystal point effect. The anti-counterfeiting transfer paper with the small crystal point effect, which is prepared by the preparation method, has the advantages that the small crystal point particles visible under ultraviolet light are dispersed in the middle of the laser information layer, other anti-counterfeiting function layers are not required to be added, the risk that a single laser film is easy to copy can be avoided, the anti-counterfeiting effect is enhanced by combining with the laser information layer, the printing adaptability is not influenced, and the anti-counterfeiting effect is easy to inquire.

Description

Anti-counterfeiting transfer paper with small crystal point effect and preparation method thereof
Technical Field
The invention relates to the field of package printing, in particular to anti-counterfeiting transfer paper with a small crystal point effect and a preparation method thereof.
Background
Transfer paper is one of the most widely used tobacco packaging materials. However, with the development of economy, the contradiction between counterfeiting and anti-counterfeiting is more and more sharp, and in order to protect enterprise brands and market and the legitimate rights and interests of consumers, certain anti-counterfeiting measures are imperative. The transfer paper with the anti-counterfeiting function is widely favored by merchants, and not only can have the anti-counterfeiting property, but also has the effect of improving the brand image of the merchants. The traditional anti-counterfeiting means of the transfer paper is to transfer the laser mould printed with the patterns to the packaging paper through the processes of bonding, compounding and the like, so that the transfer paper obtains special patterns and anti-counterfeiting marks. However, due to the wide application of the laser transfer film, the existing laser plate is easy to copy, and the anti-counterfeiting effect is greatly reduced.
In the preparation process of the transfer paper, if special materials are added into the coating, the surface of the transfer paper can obtain a small crystal point effect (under ultraviolet light), and then the transfer paper is combined with the laser information layer, so that the anti-counterfeiting effect can be increased, and the printing adaptability is not influenced. Therefore, how to prepare the anti-counterfeiting transfer paper with the small crystal point effect is a technical problem which needs to be solved by the technical personnel in the field at present.
Disclosure of Invention
In order to solve the problems of the prior art, the invention provides anti-counterfeiting transfer paper with a small crystal point effect and a preparation method thereof.
In order to achieve the purpose, the invention adopts the technical scheme that:
the invention provides a preparation method of anti-counterfeiting transfer paper with a small crystal point effect, which comprises the following steps:
(1) preparing a transfer coating: preparing a transfer coating by taking the modified acrylate polymer as base resin and adding 0.1-0.3% of anti-counterfeiting material;
(2) coating: coating the transfer coating on a PET base film to obtain a transfer layer;
(3) die pressing: pressing a holographic pattern on the PET coated with the transfer coating to obtain a laser layer;
(4) aluminum plating: vacuum aluminizing the laser film on a vacuum aluminizing machine to obtain an aluminized layer;
(5) compounding: coating water-soluble glue on the aluminum-plated layer, then compounding with base paper and drying to obtain composite paper;
(6) back gluing: coating a back sizing material on the back of the composite paper, and drying;
(7) stripping: and peeling the PET film on the surface of the composite paper to obtain the anti-counterfeiting transfer paper with the small crystal point effect.
Further, the step (2) adopts a single-side one-time coating mode, a 110-pass 130-wire gauze roller is used, the coating is carried out at the middle clamping edge, the clamping edge width at one side is 0.2-0.5mm, and the dry coating amount is 1.45-1.75g/m2
Further, in the step (3), the pressure is 160-170 ℃ and 0.3-0.4 MPa.
Further, the vacuum aluminum plating conditions in the step (4) are as follows: the vacuum degree is 0.2-0.3Pa, and the temperature is 140-160 ℃.
Further, the thickness of the aluminum plating layer in the step (4) is
Further, the wet coating amount of the composite glue in the step (5) is 7.5-8.5g/m2
Further, the wet coating amount of the back adhesive in the step (6) is 4.5-5.5g/m2
The invention provides anti-counterfeiting transfer paper with a small crystal point effect, which comprises a transfer layer, a laser layer, an aluminum plating layer, a glue layer, base paper and a back glue layer which are sequentially arranged from top to bottom and have the small crystal point effect.
Further, the small-grained effect is visible under ultraviolet light and invisible to the naked eye.
Compared with the prior art, the invention has the following advantages:
the preparation process is simple, the prepared anti-counterfeiting transfer paper with the small crystal point effect has the advantages that the small crystal point particles visible under ultraviolet light are dispersed in the middle of the laser information layer, other anti-counterfeiting function layers are not needed to be added, the risk that a single laser film is easy to copy can be avoided, the anti-counterfeiting effect is enhanced by combining with the laser information layer, the printing adaptability is not influenced, and the anti-counterfeiting effect is easy to inquire.
Detailed Description
The present invention will now be described in detail and specifically with reference to the following examples so as to provide a better understanding of the present invention, but the following examples are not intended to limit the scope of the present invention.
Example 1
The preparation method of the anti-counterfeiting transfer paper with the small crystal point effect comprises the following steps:
(1) preparing a transfer coating: the transfer coating is prepared by taking the modified acrylate polymer as base resin and adding 0.1% of anti-counterfeiting material, and the solid content is 25%;
(2) coating: coating the transfer coating on a PET film by a single-sided one-step coating mode by using a 110-wire gauze roller, clamping edges in the middle during coating, controlling the width of the clamping edges at one side to be 0.2mm, and controlling the dry coating amount to be 1.45g/m2
(3) Die pressing: the temperature is 165 ℃, the pressure is 0.32Mpa, the speed is 60m/min, and laser patterns are pressed, clear and transparent;
(4) aluminum plating: vacuum aluminizing the transfer layer on a vacuum aluminizing machine under the condition that the vacuum degree is 0.2Pa and the temperature is 140 ℃, wherein the thickness of the aluminized layer isObtaining an aluminum-plated layer;
(5) compounding: mixing 7.5g/m2Coating the transfer glue on the aluminum-plated layer, compounding the transfer glue with base paper, and drying;
(6) back gluing: coating 4.5g/m on the base paper2Carrying out gum material back and drying;
(7) stripping: and peeling the PET film on the surface of the composite paper to obtain the anti-counterfeiting transfer paper with the small crystal point effect.
Example 2
The preparation method of the anti-counterfeiting transfer paper with the small crystal point effect comprises the following steps:
(1) preparing a transfer coating: the transfer coating is prepared by taking the modified acrylate polymer as base resin and adding 0.3% of anti-counterfeiting material, and the solid content is 18%;
(2) coating: coating the transfer coating on a PET film by using a 130-wire gauze roller in a single-sided one-step coating mode, clamping edges in the middle during coating, controlling the width of the clamping edges at one side to be 0.5mm, and controlling the dry coating amount to be 1.65g/m2
(3) Die pressing: the temperature is 165 ℃, the pressure is 0.32Mpa, the speed is 55m/min, and laser patterns are pressed, clear and transparent;
(4) aluminum plating: vacuum aluminizing the transfer layer on a vacuum aluminizing machine under the condition that the vacuum degree is 0.3Pa and the temperature is 160 ℃, wherein the thickness of the aluminizing layer isObtaining an aluminum-plated layer;
(5) compounding: mixing 8.5g/m2Coating the transfer glue on the aluminum-plated layer, compounding the transfer glue with base paper, and drying;
(6) back gluing: coating 5.5g/m on the base paper2Carrying out gum material back and drying;
(7) stripping: and peeling the PET film on the surface of the composite paper to obtain the anti-counterfeiting transfer paper with the small crystal point effect.
Example 3
The preparation method of the anti-counterfeiting transfer paper with the small crystal point effect comprises the following steps:
(1) preparing a transfer coating: preparing a transfer coating by taking the modified acrylate polymer as base resin and adding 0.2% of anti-counterfeiting material;
(2) coating: coating the transfer coating on a PET film by using a 130-wire gauze roller in a single-sided one-step coating mode, clamping edges in the middle during coating, controlling the width of the clamping edges at one side to be 0.4mm, and controlling the dry coating amount to be 1.65g/m2Then pressing the film to obtain a pearl transfer layer;
(3) die pressing: the temperature is 165 ℃, the pressure is 0.32Mpa, the speed is 55m/min, and the laser pattern is pressed. The pattern is clear and bright;
(4)aluminum plating: vacuum aluminizing the transfer layer on a vacuum aluminizing machine under the condition that the vacuum degree is 0.3Pa and the temperature is 150 ℃, wherein the thickness of the aluminizing layer isObtaining an aluminum-plated layer;
(5) compounding: mixing 8.0g/m2Coating the transfer glue on the aluminum-plated layer, compounding the transfer glue with base paper, and drying;
(6) back gluing: coating 5.5g/m on the base paper2Carrying out gum material back and drying;
(7) stripping: and peeling the PET film on the surface of the composite paper to obtain the anti-counterfeiting transfer paper with the small crystal point effect.
TABLE 1 paper Property test results
While the invention has been described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the invention.

Claims (10)

1. A preparation method of anti-counterfeiting transfer paper with a small crystal point effect is characterized by comprising the following steps:
(1) preparing a transfer coating: preparing a transfer coating by taking the modified acrylate polymer as base resin and adding 0.1-0.3% of anti-counterfeiting material;
(2) coating: coating the transfer coating on a PET base film to obtain a transfer layer;
(3) die pressing: pressing a holographic pattern on the PET coated with the transfer coating to obtain a laser layer;
(4) aluminum plating: vacuum aluminizing the laser film on a vacuum aluminizing machine to obtain an aluminized layer;
(5) compounding: coating water-soluble glue on the aluminum-plated layer, then compounding with base paper and drying to obtain composite paper;
(6) back gluing: coating a back sizing material on the back of the composite paper, and drying;
(7) stripping: and peeling the PET film on the surface of the composite paper.
2. The preparation method as claimed in claim 1, wherein the step (2) adopts a single-sided one-step coating manner, a 110-130 wire gauze roller is used, the coating is carried out with a central card edge, the width of the card edge at one side is 0.2-0.5mm, and the dry coating amount is 1.45-1.75g/m2
3. The method as set forth in claim 1, wherein the compression temperature in step (3) is 160 ℃ and 170 ℃ and the pressure is 0.3 to 0.4 MPa.
4. The manufacturing method according to claim 1, wherein the vacuum aluminum plating conditions in the step (4) are: the vacuum degree is 0.2-0.3Pa, and the temperature is 140-160 ℃.
5. The production method according to claim 1, wherein the thickness of the aluminum plating layer in the step (4) is set to be
6. The preparation method according to claim 1, characterized in that the wet coating amount of the composite glue in the step (5) is 7.5-8.5g/m2
7. The method according to claim 1, wherein the amount of the back adhesive wet-applied in the step (6) is 4.5 to 5.5g/m2
8. A transfer paper having a small crystal point effect produced by the method of any one of claims 1 to 7.
9. The anti-counterfeiting transfer paper with the small crystal point effect according to claim 8, which comprises a transfer layer with the small crystal point effect, a laser layer, an aluminum plated layer, a glue layer, a base paper and a back glue layer which are sequentially arranged from top to bottom.
10. The anti-counterfeiting transfer paper with the small crystal point effect according to claim 8, wherein the small crystal point effect is visible under ultraviolet light and invisible to naked eyes.
CN201910713145.9A 2019-08-02 2019-08-02 Anti-counterfeiting transfer paper with small crystal point effect and preparation method thereof Pending CN110591577A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910713145.9A CN110591577A (en) 2019-08-02 2019-08-02 Anti-counterfeiting transfer paper with small crystal point effect and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910713145.9A CN110591577A (en) 2019-08-02 2019-08-02 Anti-counterfeiting transfer paper with small crystal point effect and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110591577A true CN110591577A (en) 2019-12-20

Family

ID=68853409

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910713145.9A Pending CN110591577A (en) 2019-08-02 2019-08-02 Anti-counterfeiting transfer paper with small crystal point effect and preparation method thereof

Country Status (1)

Country Link
CN (1) CN110591577A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111645436A (en) * 2020-06-12 2020-09-11 山东泰宝包装制品有限公司 Laser encrypted anti-counterfeiting transfer paper and preparation method thereof
CN113564969A (en) * 2021-08-03 2021-10-29 新郑市吉龙包装材料有限公司 Production process of golden laser transfer paper
CN115260561A (en) * 2022-09-26 2022-11-01 江苏泽邦包装材料有限公司 Anti-counterfeiting transfer film based on PET laser and production process thereof
CN115284763A (en) * 2022-07-20 2022-11-04 鹤山雅图仕印刷有限公司 Production process of paper flat drill

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101570946A (en) * 2009-05-11 2009-11-04 浙江亚欣纸业有限公司 Paint for packing anti-counterfeit paper and preparation method thereof
CN204039844U (en) * 2014-07-14 2014-12-24 湖北鸿连实业有限公司 One has antiforge function bond paper
CN105926356A (en) * 2016-06-21 2016-09-07 上海睿途新材料科技有限公司 Matte aluminum-plated paper and preparation method thereof
CN206204688U (en) * 2016-06-21 2017-05-31 上海睿途新材料科技有限公司 A kind of not general color dumb light aluminized paper of paint film
CN108999033A (en) * 2018-06-08 2018-12-14 滁州卷烟材料厂 A kind of cigarette package fluorescence falsification preventing aluminium-foil paper

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101570946A (en) * 2009-05-11 2009-11-04 浙江亚欣纸业有限公司 Paint for packing anti-counterfeit paper and preparation method thereof
CN204039844U (en) * 2014-07-14 2014-12-24 湖北鸿连实业有限公司 One has antiforge function bond paper
CN105926356A (en) * 2016-06-21 2016-09-07 上海睿途新材料科技有限公司 Matte aluminum-plated paper and preparation method thereof
CN206204688U (en) * 2016-06-21 2017-05-31 上海睿途新材料科技有限公司 A kind of not general color dumb light aluminized paper of paint film
CN108999033A (en) * 2018-06-08 2018-12-14 滁州卷烟材料厂 A kind of cigarette package fluorescence falsification preventing aluminium-foil paper

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111645436A (en) * 2020-06-12 2020-09-11 山东泰宝包装制品有限公司 Laser encrypted anti-counterfeiting transfer paper and preparation method thereof
CN111645436B (en) * 2020-06-12 2022-05-24 山东泰宝包装制品有限公司 Laser encrypted anti-counterfeiting transfer paper and preparation method thereof
CN113564969A (en) * 2021-08-03 2021-10-29 新郑市吉龙包装材料有限公司 Production process of golden laser transfer paper
CN115284763A (en) * 2022-07-20 2022-11-04 鹤山雅图仕印刷有限公司 Production process of paper flat drill
CN115260561A (en) * 2022-09-26 2022-11-01 江苏泽邦包装材料有限公司 Anti-counterfeiting transfer film based on PET laser and production process thereof
CN115260561B (en) * 2022-09-26 2022-12-09 江苏泽邦包装材料有限公司 Anti-counterfeiting transfer film based on PET laser and production process thereof

Similar Documents

Publication Publication Date Title
CN110591577A (en) Anti-counterfeiting transfer paper with small crystal point effect and preparation method thereof
CN103054284B (en) Metallic coin stamped with holographic anti-counterfeiting pattern and manufacturing method thereof
CN100577913C (en) Packing paper with micro-sign for cigarette and producing method thereof
CN105313516B (en) A kind of anti-fake blocking film and preparation method thereof with 3D effect
CN106087590A (en) The wrapping paper of a kind of band halo of many colours effect and production technology thereof
CN100588773C (en) Transparent color fluorescence anti-forge band and production method thereof
CN202913312U (en) Vacuum direct-plating laser paper
CN106965610A (en) A kind of cold wave film production process
CN209779338U (en) Laser paper
CN1127431C (en) Holographic image located packing film, and its preparing process and usage
CN1131149C (en) Technology for transferring antiforge laser marker onto plastic package
CN2625153Y (en) Printing and coloring holographic blocking foil
CN202434123U (en) Anti-counterfeit material capable of locating transmission optical variable image
CN1079324A (en) A kind of multifunctional anti-falsifying label and manufacture method thereof
CN1104529C (en) Holographic card paper making process
US20060073299A1 (en) Method for forming a metallic appearance on the sides of memo pads
CN211280455U (en) Gilt transfer film of fresnel lens location
CN206649819U (en) A kind of false-proof film of random grain
CN110682707A (en) Laser holographic composite film and preparation method thereof
CN220520970U (en) Transfer base film paper and preparation system thereof, packaging film and preparation system thereof
CN104999824B (en) A kind of bound book and preparation method thereof
CN2414098Y (en) Local holographic card paper
CN204914972U (en) Bound book
CN214476015U (en) Transparent holographic information anti-counterfeiting mark
CN115874490B (en) Multilayer anti-counterfeiting medium frame paper and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20191220

RJ01 Rejection of invention patent application after publication