CN110591353A - Nylon hose formula - Google Patents

Nylon hose formula Download PDF

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Publication number
CN110591353A
CN110591353A CN201910928278.8A CN201910928278A CN110591353A CN 110591353 A CN110591353 A CN 110591353A CN 201910928278 A CN201910928278 A CN 201910928278A CN 110591353 A CN110591353 A CN 110591353A
Authority
CN
China
Prior art keywords
parts
nylon
antioxidant
nylon hose
mercaptobenzimidazole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910928278.8A
Other languages
Chinese (zh)
Inventor
高腾
李新忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XUZHOU TENGFEI ENGINEERING PLASTIC Co Ltd
Original Assignee
XUZHOU TENGFEI ENGINEERING PLASTIC Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XUZHOU TENGFEI ENGINEERING PLASTIC Co Ltd filed Critical XUZHOU TENGFEI ENGINEERING PLASTIC Co Ltd
Priority to CN201910928278.8A priority Critical patent/CN110591353A/en
Publication of CN110591353A publication Critical patent/CN110591353A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a nylon hose formula which comprises the following raw materials in parts by weight: 60-75 parts of nylon, 15-18 parts of main toughening agent, 0.1-1 part of auxiliary toughening agent, 0.2-1.2 parts of anti-aging agent, 0.2-1.2 parts of antioxidant and 6-25 parts of compatilizer. Compared with the prior art, the product of the invention has better toughness and impact strength, and can meet the use requirements in the environment of large flow and high pressure, so the invention can be widely applied to the field of polymer material processing.

Description

Nylon hose formula
Technical Field
The invention relates to a nylon hose formula, and belongs to the field of polymer processing.
Background
Nylon, which is a commonly used engineering material, has excellent corrosion resistance, tensile strength, abrasion resistance, and fluidity, and thus is easy to process and manufacture, and thus is widely used in various aspects of industry, such as automobiles, electronic and electronic appliances, machinery, and living goods.
In practical use engineering, especially in the process of conveying liquid or fluid materials, the shape of the hose may not be fixed, and in addition, in a conveying environment with large flow and high pressure, the hose is greatly impacted, so that a nylon material with excellent toughness and high impact strength is needed. Therefore, various improvements are made on nylon materials by domestic and foreign companies, and super-tough nylon alloys, high-impact nylon alloys and other materials are derived.
The invention discloses a super-tough nylon alloy and a preparation process thereof, which greatly improve the strength and impact resistance of the nylon alloy; the invention discloses a super-tough nylon 6 alloy prepared by an in-situ method and a method thereof, which greatly improve the toughness of the nylon alloy. Although the above patents all obtain comparatively excellent nylon materials, none of them provides a technical scheme which can improve the toughness of nylon materials and also can improve the high impact strength of nylon materials.
Disclosure of Invention
The invention aims to provide a nylon material with good toughness and high impact strength.
The invention discloses a nylon hose formula which comprises the following components:
further, the nylon is nylon 66.
Further, the main toughening agent is a copolymer of ethylene and higher alpha-olefin.
Further, the auxiliary toughening agent is hydrogenated styrene-butadiene-styrene block copolymer.
Further, the anti-aging agent is 2-mercaptobenzimidazole.
Further, the antioxidant is antioxidant 1010.
Further, the compatilizer is polypropylene grafted maleic anhydride.
Further, the nylon 6660 parts, the ethylene-higher alpha-olefin copolymer 15 parts, the hydrogenated styrene-butadiene-styrene block copolymer 0.1 part, the 2-mercaptobenzimidazole 0.2 part, the antioxidant 10100.2 part, and the polypropylene grafted maleic anhydride 6 parts.
The modified polypropylene composite material comprises 6667.5 parts of nylon, 16.5 parts of ethylene and higher alpha-olefin copolymer, 0.55 part of hydrogenated styrene-butadiene-styrene block copolymer, 0.7 part of 2-mercaptobenzimidazole, 10100.7 parts of antioxidant and 15.5 parts of polypropylene grafted maleic anhydride.
Further, the nylon 6675 parts, the ethylene/higher alpha-olefin copolymer 18 parts, the hydrogenated styrene-butadiene-styrene block copolymer 1 part, the 2-mercaptobenzimidazole 1.2 parts, the antioxidant 10101.2 parts, and the polypropylene grafted maleic anhydride 25 parts.
Compared with the prior art, the product of the invention has better toughness and impact strength, and can meet the use requirements under the environment of large flow and high pressure. In addition, the raw materials of the formula are derived from the existing mature technology, so the invention has the characteristics of low cost, easy processing and manufacturing and the like, thereby having better market prospect.
Detailed Description
The present invention will be described in further detail with reference to the following examples, but it should be noted that the numbers, scientific terms, processing methods and the like in the following examples are only used for better describing and explaining the present invention, and are not intended to limit the present invention, and the protection scope of the present invention is not limited thereto.
Example one
The formula of the nylon hose comprises the following components in parts by weight: nylon 6660 parts, ethylene and higher alpha-olefin copolymer 15 parts, hydrogenated styrene-butadiene-styrene block copolymer 0.1 parts, 2-mercaptobenzimidazole 0.2 parts, antioxidant 10100.2 parts, polypropylene grafted maleic anhydride 6 parts.
Example two
The formula of the nylon hose comprises the following components in parts by weight: 6667.5 parts of nylon, 16.5 parts of ethylene and higher alpha-olefin copolymer, 0.55 part of hydrogenated styrene-butadiene-styrene block copolymer, 0.7 part of 2-mercaptobenzimidazole, 10100.7 parts of antioxidant and 15.5 parts of polypropylene grafted maleic anhydride.
EXAMPLE III
The formula of the nylon hose comprises the following components in parts by weight: nylon 6675 parts, ethylene and higher alpha-olefin copolymer 18 parts, hydrogenated styrene-butadiene-styrene block copolymer 1 parts, 2-mercaptobenzimidazole 1.2 parts, antioxidant 10101.2 parts, polypropylene grafted maleic anhydride 25 parts.
Proved by verification and practical production application, the hose manufactured by the nylon hose formula provided by the invention can meet the requirement of high strength and toughness and improve the high impact resistance of the hose.
The above are embodiments of the present invention, and any changes and substitutions without inventive step in the claims of the present invention are within the scope of the present invention.

Claims (10)

1. The formula of the nylon hose is characterized in that: the formula of the nylon hose comprises the following components:
2. the nylon hose formulation of claim 1, wherein: the nylon is nylon 66.
3. The nylon hose formulation of claim 1, wherein: the main toughening agent is a copolymer of ethylene and higher alpha-olefin.
4. The nylon hose formulation of claim 1, wherein: the auxiliary toughening agent is hydrogenated styrene-butadiene-styrene block copolymer.
5. The nylon hose formulation of claim 1, wherein: the anti-aging agent is 2-mercaptobenzimidazole.
6. The nylon hose formulation of claim 1, wherein: the antioxidant is antioxidant 1010.
7. The nylon hose formulation of claim 1, wherein: the compatilizer is polypropylene grafted maleic anhydride.
8. The nylon hose formulation according to any one of claims 1 to 6, wherein: the modified polypropylene composite material comprises, by weight, 6660 parts of nylon, 15 parts of an ethylene-higher alpha-olefin copolymer, 0.1 part of a hydrogenated styrene-butadiene-styrene block copolymer, 0.2 part of 2-mercaptobenzimidazole, 10100.2 parts of an antioxidant and 6 parts of polypropylene grafted maleic anhydride.
9. The nylon hose formulation according to any one of claims 1 to 6, wherein: 6667.5 parts of nylon, 16.5 parts of ethylene and higher alpha-olefin copolymer, 0.55 part of hydrogenated styrene-butadiene-styrene block copolymer, 0.7 part of 2-mercaptobenzimidazole, 10100.7 parts of antioxidant and 15.5 parts of polypropylene grafted maleic anhydride.
10. The nylon hose formulation according to any one of claims 1 to 6, wherein: the modified polypropylene composite material comprises, by weight, 6675 parts of nylon, 18 parts of the ethylene and higher alpha-olefin copolymer, 1 part of the hydrogenated styrene-butadiene-styrene block copolymer, 1.2 parts of 2-mercaptobenzimidazole, 10101.2 parts of an antioxidant and 25 parts of polypropylene grafted maleic anhydride.
CN201910928278.8A 2019-09-28 2019-09-28 Nylon hose formula Pending CN110591353A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910928278.8A CN110591353A (en) 2019-09-28 2019-09-28 Nylon hose formula

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910928278.8A CN110591353A (en) 2019-09-28 2019-09-28 Nylon hose formula

Publications (1)

Publication Number Publication Date
CN110591353A true CN110591353A (en) 2019-12-20

Family

ID=68864584

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910928278.8A Pending CN110591353A (en) 2019-09-28 2019-09-28 Nylon hose formula

Country Status (1)

Country Link
CN (1) CN110591353A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113801468A (en) * 2021-09-17 2021-12-17 东风商用车有限公司 Modified material for trailer spiral pipe and trailer spiral pipe

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1657568A (en) * 2004-12-07 2005-08-24 青岛科技大学 Super-toughness fire resistant nylon alloy

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1657568A (en) * 2004-12-07 2005-08-24 青岛科技大学 Super-toughness fire resistant nylon alloy

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113801468A (en) * 2021-09-17 2021-12-17 东风商用车有限公司 Modified material for trailer spiral pipe and trailer spiral pipe
CN113801468B (en) * 2021-09-17 2023-10-24 东风商用车有限公司 Modified material for spiral pipe of trailer and spiral pipe of trailer

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