CN110556249A - Preparation method of alpha-MnO 2 nanorod array - Google Patents
Preparation method of alpha-MnO 2 nanorod array Download PDFInfo
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- CN110556249A CN110556249A CN201810556726.1A CN201810556726A CN110556249A CN 110556249 A CN110556249 A CN 110556249A CN 201810556726 A CN201810556726 A CN 201810556726A CN 110556249 A CN110556249 A CN 110556249A
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- 239000002073 nanorod Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 13
- 239000000758 substrate Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 239000002041 carbon nanotube Substances 0.000 claims description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- 239000002105 nanoparticle Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 238000001878 scanning electron micrograph Methods 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 239000003990 capacitor Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/46—Metal oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
The invention discloses a preparation method of an alpha-MnO 2 nanorod array, which is characterized in that KMnO 4 is dissolved in water, the PH is adjusted to 1-3 by dilute H 2 SO 4, a substrate material is added, hydrothermal reaction is carried out at 100-140 ℃, after the reaction is finished, washing and drying are carried out to obtain the alpha-MnO 2 nanorod array.
Description
Technical Field
The invention belongs to the technical field of nano material preparation, relates to a preparation method of MnO 2, and particularly relates to a preparation method of an alpha-MnO 2 nanorod array.
Background
2Super Capacitors (Supercapacitors), also called Electrochemical Capacitors (Electrochemical Capacitors), generally have power density 1-2 orders of magnitude higher than that of lithium ion batteries, cycle life 2-3 orders of magnitude higher, energy density 3-4 orders of magnitude higher than that of conventional Capacitors, and the like, and have received extensive attention as a novel, practical, and efficient energy storage device.
MnO 2 forms a plurality of crystal forms including alpha, beta, gamma, delta and the like through different connection modes of MnO 6 octahedron, wherein the three have a pore structure (alpha-MnO 2 is a 2 x 2 large pore structure; beta-MnO 2 is a 1 x 1 pore structure; gamma-MnO 2 is a part of a 2 x 2 small pore structure and a 1 x 1 pore structure), and delta-MnO 2 is an open layered structure. alpha-MnO capacitance performance is the best, while beta-and gamma-MnO 2 are relatively poor. the regulation of morphology can effectively regulate the specific surface area of MnO 2. therefore, MnO 2 with different morphologies in recent years, such as nanorods (Wang, GS; porous absorption properties of Nano-MnO 2 nanoparticles and the applicable Nano electric composites; RSC Advances), Nano-tubes (Jan, S.v.ut; Sealf-sapphire and Nano additive films) can effectively regulate the specific surface area of MnO 2, while the conductivity of Nano particles can be regulated to obtain Nano particles with excellent conductivity and Nano particles (Nano particles) and Nano particles of Nano particles, thus the Nano particles can be synthesized by Nano particles of Nano particles.
Disclosure of Invention
In order to solve the problem of poor conductivity of alpha-MnO 2 prepared by the existing method, the invention provides a preparation method of an alpha-MnO 2 nanorod array.
The technical scheme of the invention is as follows:
The preparation method of the alpha-MnO 2 nanorod array comprises the following steps:
Dissolving KMnO 4 in water, adjusting the pH value to 1-3 by using dilute H 2 SO 4, adding a substrate material, carrying out hydrothermal reaction at 100-140 ℃, washing after the reaction is finished, and drying to obtain the alpha-MnO 2 nanorod array.
Preferably, the concentration of the KMnO 4 solution is 0.01-0.2M.
Preferably, the concentration of the dilute H 2 SO 4 is 1M.
Preferably, the pH value is adjusted to 1-2.
Preferably, the substrate material can be stainless steel sheet, titanium sheet, nickel mesh, gold foil, platinum foil, and carbon material such as carbon fiber and carbon nanotube.
Preferably, the hydrothermal reaction is carried out in a high-pressure reaction kettle, and the volume of the mixed solution is 75-85% of the volume of the reaction kettle.
Preferably, the hydrothermal reaction temperature is 110-130 ℃, and the reaction time is 0.5-2 h.
Compared with the prior art, the invention has the following advantages:
The invention synthesizes the alpha-MnO 2 material with the nanorod array morphology by a simple one-step hydrothermal method, has short synthesis time, low reaction energy consumption, simple process and controllable process, and the prepared alpha-MnO 2 grows on a substrate uniformly and has uniform morphology without agglomeration.
Drawings
FIG. 1 is an XRD pattern of an α -MnO 2 nanorod array prepared in example 2.
FIG. 2 is a high power SEM image of the α -MnO 2 nanorod array prepared in example 2.
FIG. 3 is a low magnification SEM image of an α -MnO 2 nanorod array prepared in example 2.
Fig. 4 is an SEM image of MnO 2 prepared in comparative example 1.
Fig. 5 is an SEM image of MnO 2 prepared in comparative example 2.
Fig. 6 is an SEM image of MnO 2 prepared in comparative example 3.
Detailed Description
The present invention will be described in further detail with reference to the following examples and the accompanying drawings.
Example 1
dissolving 1mmol of KMnO 4 in 40ml of deionized water, adjusting the pH to 1 with 1M H 2 SO 4, adding 3cm by 3cm of carbon cloth as a substrate material, carrying out hydrothermal reaction at 100 ℃ for 0.5h, after the reaction is finished, washing the product with the deionized water, and drying in a 60 ℃ oven to obtain the alpha-MnO 2 nanorod array.
Example 2
Dissolving 2mmol of KMnO 4 in 40ml of deionized water, adjusting the pH to 1 by using 1M H 2 SO 4, adding 3cm by 3cm of carbon cloth as a substrate material, carrying out hydrothermal reaction at 120 ℃ for 0.5h, after the reaction is finished, washing the product with the deionized water, and drying in a 60 ℃ oven to obtain the alpha-MnO 2 nanorod array.
example 3
Dissolving 4mmol of KMnO 4 in 40ml of deionized water, adjusting the pH value to 1 by using 1M H 2 SO 4, adding 3cm by 3cm of carbon cloth as a substrate material, carrying out hydrothermal reaction at 140 ℃ for 0.5h, after the reaction is finished, washing the product with the deionized water, and drying in a 60 ℃ oven to obtain the alpha-MnO 2 nanorod array.
Example 4
dissolving 2mmol of KMnO 4 in 40ml of deionized water, adjusting the pH to 2 with 1M H 2 SO 4, adding 3cm by 3cm of carbon cloth as a substrate material, carrying out hydrothermal reaction at 120 ℃ for 1h, after the reaction is finished, washing the product with the deionized water, and drying in a 60 ℃ oven to obtain the alpha-MnO 2 nanorod array.
Example 5
Dissolving 2mmol of KMnO 4 in 40ml of deionized water, adjusting the pH to 3 by using 1M H 2 SO 4, adding 3cm by 3cm of carbon cloth as a substrate material, carrying out hydrothermal reaction at 120 ℃ for 2h, after the reaction is finished, washing the product with the deionized water, and drying in a 60 ℃ oven to obtain the alpha-MnO 2 nanorod array.
As shown in figure 1, the XRD pattern of the prepared alpha-MnO 2 with the nanorod array morphology is completely consistent with the standard card bar No.72-1982 in a database, which indicates that the crystal phase composition of the product is alpha-MnO 2, and in addition, the peak type of a visible ray diffraction peak is sharp, the peak intensity is high, and the crystal form development is good.
As shown in FIGS. 2 and 3, SEM images of the prepared alpha-MnO 2 with nanorod array morphology show that alpha-MnO 2 is in an array shape, and the array structure is formed by assembling nanorods.
comparative example 1
This comparative example is essentially the same as example 2, except that H 2 SO 4 was replaced with hcl-as can be seen from a comparison of fig. 2 and 4, the product with H 2 SO 4 was rod-shaped, while the product with HCI was ribbon-shaped, indicating that the presence of H 2 SO 4 is an important factor in the formation of a rod-shaped structure.
Comparative example 2
This comparative example is essentially the same as example 2, except that no H 2 SO 4 was added, it can be seen from a comparison of FIGS. 3 and 5 that the product with the addition of H 2 SO 4 was in the form of a higher loading rod, whereas the product without the addition of H 2 SO 4 had only a few needles on the substrate, indicating that the presence of H 2 SO 4 is an important factor in accelerating the progress of the reaction.
Comparative example 3
This comparative example is essentially the same as example 2, except that no H 2 SO 4 was added and the reaction time was extended to 10H-as can be seen from a comparison of fig. 2, fig. 3 and fig. 6, the product with H 2 SO 4 added was rod-like at higher loading, whereas the product without H 2 SO 4 had only a few needles on the substrate, and after greatly extending the reaction time, the product without H 2 SO 4 was less flaky, further illustrating that the presence of H 2 SO 4 is an important factor in accelerating the progress of the reaction and in forming the rod-like structure.
Claims (7)
1. The preparation method of the alpha-MnO 2 nanorod array is characterized by comprising the following steps of:
Dissolving KMnO 4 in water, adjusting the pH value to 1-3 by using dilute H 2 SO 4, adding a substrate material, carrying out hydrothermal reaction at 100-140 ℃, washing after the reaction is finished, and drying to obtain the alpha-MnO 2 nanorod array.
2. The preparation method according to claim 1, wherein the concentration of the KMnO 4 solution is 0.01-0.2M.
3. The method as claimed in claim 1, wherein the dilute H 2 SO 4 is at a concentration of 1M.
4. The method according to claim 1, wherein the pH is adjusted to 1 to 2.
5. The method according to claim 1, wherein the substrate material is selected from the group consisting of stainless steel sheet, titanium sheet, nickel mesh, gold foil, platinum foil, carbon fiber, and carbon nanotube.
6. The preparation method according to claim 1, wherein the hydrothermal reaction is carried out in an autoclave, and the volume of the mixed solution is 75 to 85% of the volume of the autoclave.
7. The preparation method according to claim 1, wherein the hydrothermal reaction temperature is 110 ℃ to 130 ℃ and the reaction time is 0.5h to 2 h.
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Cited By (1)
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CN112981453A (en) * | 2021-02-05 | 2021-06-18 | 常熟理工学院 | Method for preparing water oxidation electrode by using waste stainless steel as base material |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101531402A (en) * | 2009-04-16 | 2009-09-16 | 上海交通大学 | Method for preparing manganese dioxide one-dimensional nanometer material |
CN102660770A (en) * | 2011-02-25 | 2012-09-12 | 大连理工大学 | Preparation method for ZnMn2O4 nanorod by using alpha-MnO2 nanorod template method |
CN103896208A (en) * | 2014-02-19 | 2014-07-02 | 华中师范大学 | Manganese dioxide nanowire array electrode on titanium substrate and preparation method thereof |
CN104078672A (en) * | 2014-06-25 | 2014-10-01 | 复旦大学 | Homologous manganese oxide and spinel-type lithium manganate lithium ion battery and preparation method thereof |
CN105355462A (en) * | 2015-10-13 | 2016-02-24 | 华南理工大学 | Preparation method and application for delta-MnO2 thick film pseudocapacitor electrode |
CN106531449A (en) * | 2016-10-24 | 2017-03-22 | 上海应用技术大学 | Method for preparing nanosheet nuclear shell structure |
US20180069246A1 (en) * | 2012-07-18 | 2018-03-08 | Printed Energy Pty Ltd | Diatomaceous energy storage devices |
-
2018
- 2018-06-01 CN CN201810556726.1A patent/CN110556249A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101531402A (en) * | 2009-04-16 | 2009-09-16 | 上海交通大学 | Method for preparing manganese dioxide one-dimensional nanometer material |
CN102660770A (en) * | 2011-02-25 | 2012-09-12 | 大连理工大学 | Preparation method for ZnMn2O4 nanorod by using alpha-MnO2 nanorod template method |
US20180069246A1 (en) * | 2012-07-18 | 2018-03-08 | Printed Energy Pty Ltd | Diatomaceous energy storage devices |
CN103896208A (en) * | 2014-02-19 | 2014-07-02 | 华中师范大学 | Manganese dioxide nanowire array electrode on titanium substrate and preparation method thereof |
CN104078672A (en) * | 2014-06-25 | 2014-10-01 | 复旦大学 | Homologous manganese oxide and spinel-type lithium manganate lithium ion battery and preparation method thereof |
CN105355462A (en) * | 2015-10-13 | 2016-02-24 | 华南理工大学 | Preparation method and application for delta-MnO2 thick film pseudocapacitor electrode |
CN106531449A (en) * | 2016-10-24 | 2017-03-22 | 上海应用技术大学 | Method for preparing nanosheet nuclear shell structure |
Non-Patent Citations (3)
Title |
---|
WEI XIAO ETC: "Growth of single-crystal α-MnO2 nanotubes prepared by a hydrothermal route and their electrochemical properties", 《JOURNAL OF POWER SOURCES》 * |
沈丁等: "KMnO4 浓度对MnO2 结构和电容性能的影响", 《硅酸盐学报》 * |
陈永等: "不同酸溶液中制备纳米结构MnO2单晶", 《金属学报》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112981453A (en) * | 2021-02-05 | 2021-06-18 | 常熟理工学院 | Method for preparing water oxidation electrode by using waste stainless steel as base material |
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