CN1105517C - Microwave processing method for reducing nitrosamine content in smoke of cigarette - Google Patents
Microwave processing method for reducing nitrosamine content in smoke of cigarette Download PDFInfo
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- CN1105517C CN1105517C CN00112252.5A CN00112252A CN1105517C CN 1105517 C CN1105517 C CN 1105517C CN 00112252 A CN00112252 A CN 00112252A CN 1105517 C CN1105517 C CN 1105517C
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- cigarette
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- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 50
- 239000000779 smoke Substances 0.000 title claims abstract description 39
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 238000003672 processing method Methods 0.000 title 1
- 230000005855 radiation Effects 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 10
- 150000004005 nitrosamines Chemical class 0.000 claims description 6
- 235000019505 tobacco product Nutrition 0.000 claims description 6
- 241000208125 Nicotiana Species 0.000 description 10
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 10
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 6
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 6
- 229960002715 nicotine Drugs 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000012856 packing Methods 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000000120 microwave digestion Methods 0.000 description 3
- UMFJAHHVKNCGLG-UHFFFAOYSA-N n-Nitrosodimethylamine Chemical compound CN(C)N=O UMFJAHHVKNCGLG-UHFFFAOYSA-N 0.000 description 3
- XKABJYQDMJTNGQ-VIFPVBQESA-N n-nitrosonornicotine Chemical compound O=NN1CCC[C@H]1C1=CC=CN=C1 XKABJYQDMJTNGQ-VIFPVBQESA-N 0.000 description 3
- BXYPVKMROLGXJI-JTQLQIEISA-N 3-[(2s)-1-nitrosopiperidin-2-yl]pyridine Chemical compound O=NN1CCCC[C@H]1C1=CC=CN=C1 BXYPVKMROLGXJI-JTQLQIEISA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 230000036952 cancer formation Effects 0.000 description 1
- 231100000504 carcinogenesis Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 235000019506 cigar Nutrition 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- CBMPTFJVXNIWHP-UHFFFAOYSA-L disodium;hydrogen phosphate;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Na+].[Na+].OP([O-])([O-])=O.OC(=O)CC(O)(C(O)=O)CC(O)=O CBMPTFJVXNIWHP-UHFFFAOYSA-L 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- -1 nitrosamine compound Chemical class 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- AXFBAIOSECPASO-UHFFFAOYSA-N pentacyclo[6.6.2.02,7.04,16.011,15]hexadeca-1(14),2(7),3,5,8(16),9,11(15),12-octaene Chemical compound C1=C(C=C23)C4=C5C3=CC=CC5=CC=C4C2=C1 AXFBAIOSECPASO-UHFFFAOYSA-N 0.000 description 1
- 239000008055 phosphate buffer solution Substances 0.000 description 1
- 210000002826 placenta Anatomy 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 210000001835 viscera Anatomy 0.000 description 1
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- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
The present invention relates to a method for reducing the nitrosamine content in smoke of a cigarette. The method has the scheme that the radiation treatment for the finished cigarette is carried out by using a microwave. The cigarette has the original smell after the microwave treatment, but the total nitrosamine content in smoke of the main flow is reduced to 52 to 76%. Moreover, the total nitrosamine content in smoke of the side flow is reduced to 21.5 to 53%.
Description
The present invention relates to the method for microwave radiation processing finished cigarettes.
Cigarette burning produces main flow and side-stream smoke.Main flume is meant that the smoker sucks the flue gas in oral cavity, and side-stream smoke is meant that cigarette props up spontaneous firing and is directly released into airborne flue gas.
Contained nitrosamine causes people's great vigilance with its strong carcinogenicity in the cigarette smoke.Nitrosamine is the extensive chemical carcinogenic substance, has about 90% to be proved to be and to have carcinogenesis surplus in the of 300 in kind of the nitrosamine compound: internal organs that animal is all and organize all can be by induced tumor, and main target organ is liver, oesophagus, lung, stomach and kidney; Can also carry out heredity by placenta, cause the offspring to distort.The Chinese adult male sex on average consumes 10 cigarette for each person every day, and the average annual aggregate consumption of cigarette has reached 18,000 hundred million, accounts for 1/3rd of global aggregate consumption.The cigarette sidestream smoke directly intersperses among among the crowd, and contaminated environment also injures health, and the involuntary smoker who is hurt reaches several hundred million crowds in China.
Use filter tip, be included in admixture zeolite in the filter tip (referring to patent CH-A-653200, UA-A-3703901, FR-A-2165174, WO 9607335 and WO 9704865) and all be difficult to selectively remove nitrosamine, more can not solve the pollution problem of passive smoking.Japan Patent (JP6214772) adopts menthol, ascorbic acid, lecithin and 4-hydroxyl-3-methoxylbenxaldehyde etc. to make the adsorbent of tar, can reduce the content of flue gas nicotine, CO, benzo [α] pyrene and nitrosamine when being used for the fire end of cigarette.This method is the cost height not only, and because it only has suction-operated, so effect is not remarkable.
European patent (EP0740907) is Y, X, ZSM-5, micro-pore zeolite such as M and β (aperture is 0.5-0.7nm) mixes among the LC-674 with gel (C-Gel), be sprayed on cigarette on the pipe tobacco after forming suspension, the harmful components in combustion process in the catalytic elimination cigarette smoke comprise nitrosamine.Several main components in the nitrosamine such as nitrosonornicotine (NNN), nitroso anabasine (NAB) equal size descend, and the content of dimethylnitrosamine (NDMA) but has rising.Whether the nitrosamine total amount that does not offer some clarification in this patent in cigarette master, the side-stream smoke is significantly reduced.
The applicant in patent application (CN98111479.2), disclose a kind of in pipe tobacco incorporating modified zeolite reduce content of nitrosamines cigarette in the side-stream smoke; The cigarette that reduces the additive of content of nitrosamines in the cigarette smoke and contain this additive is disclosed in patent application (CN99114106.7), all can significantly reduce the nitrosamine total amount in cigarette main flume and the side-stream smoke, and not change original style of cigarette and mouthfeel.
The feature N-NO key of nitrosamine than common C-H, C-C, C-N key a little less than, about 300 ℃, can be disconnected.
American Qiong Ni R William Si handles, reduces the technology of its tobacco-specific nitrosamine (TSNA) content disclosing drying after the microwave radiation is used for tobacco and hemp results among its patent application WO 9805,226 and WO 9858,555 and the CN97198261.The tobacco product of gained is dry and flavous leaf, and it is compared with the tobacco of conventional drying and contains the almost NNN and the NNK of insignificant amount.But this patent need be used the long-time radiation more than 150 seconds, and the drying etc. that is adapted at tobacco leaf is used in handling in earlier stage.
The microwave handling method that the purpose of this invention is to provide content of nitrosamines in a kind of simpler and easy, reduction cigarette smoke that cost is cheaper.
Technical scheme of the present invention is as follows:
Tobacco product after the cigarette (cigarette props up or cigarettes) is evenly paved, and carries out the microwave radiation, and the operating frequency of microwave device is 2450MHz, and radiant power is 500-2000W, and radiated time is 10-100 second.Tobacco product can reduce the content of nitrosamine in this cigarette smoke after radiation.
The microwave handling method of content of nitrosamines in the reduction cigarette smoke that the present invention uses, it can be with packaged cigarettes directly through microwave treatment, and required small investment, technology are simple especially and cost is cheap.Adopt its mouthfeel of cigarette after the present invention handles constant, and the total amount of nitrosamine is lowered 52-76% in the mainstream smoke, then reduces 21.5-53% in the sidestream smoke, thereby can protects smoker and involuntary smoker's health.
Further specify the present invention by the following examples.
Embodiment:, tobacco product is compared through carrying out same test before and after the microwave treatment for detecting the reduction effect of the present invention for nitrosamine total content in the cigarette shreds.The inventor adopts apparatus and method (the Caldwell W. of Caldwell report, J.Assoc.Off.Anal.Chan., 73 (5), 783,1990) collect side-stream smoke, to use pH value instead be 150mL citric acid-disodium hydrogen phosphate buffer solution of 4.5 but it is collected liquid.To the mensuration that cigarette smoke is collected nitrosamine total content in the liquid, the inventor adopts improved AAS (referring to CN97107228.0A).
[example 1] directly places finished cigarettes (fire-cured tobacco type is renovated packing, and tar content is 18mg, and nicotine content in smoke is 1.2mg) on the rotating disk of MLS-1200Mega micro-wave digestion device and carries out the microwave radiation.Refire test in radiation under the 1000W power after 45 seconds, collect main flow and side-stream smoke and analyze the nitrosamine total content.The nitrosamine total content props up from 6.46nmol/ and is reduced to 3.03nmol/ and props up in the side-stream smoke, has been reduced 53.1%.The nitrosamine total content props up from 1.88nmol/ and is reduced to 0.63nmol/ and props up in the main flume, has been reduced 66.5%.The professional of cigarette factory aspirates evaluation to the cigarette before and after the microwave radiation, confirms that its original style is not changed.
[example 2] directly places finished cigarettes (fire-cured tobacco type is renovated packing, and tar content is 18mg, and nicotine content in smoke is 1.2mg) on the rotating disk of MLS-1200Mega micro-wave digestion device and carries out the microwave radiation.Refire test in radiation under the 1000W power after 30 seconds, collect main flow and side-stream smoke and analyze the nitrosamine total content.The nitrosamine total content props up from 6.46nmol/ and is reduced to 3.72nmol/ and props up in the side-stream smoke, has been reduced 42.4%.The nitrosamine total content props up from 1.88nmol/ and is reduced to 0.83nmol/ and props up in the main flume, has been reduced 55.9%.The professional of cigarette factory aspirates evaluation to the cigarette before and after the microwave radiation, confirms that its original style is not changed.
[example 3] directly places finished cigarettes (fire-cured tobacco type is renovated packing, and tar content is 18mg, and nicotine content in smoke is 1.2mg) on the rotating disk of MLS-1200Mega micro-wave digestion device and carries out the microwave radiation.Refire test in radiation under the 1000W power after 15 seconds, collect main flow and side-stream smoke and analyze the nitrosamine total content.The nitrosamine total content props up from 6.46nmol/ and is reduced to 5.07nmol/ and props up in the side-stream smoke, has been reduced 21.5%.The nitrosamine total content props up from 1.88nmol/ and is reduced to 1.39nmol/ and props up in the main flume, has been reduced 26.1%.
[example 4] directly places finished cigarettes (fire-cured tobacco type is renovated packing, and tar content is 18mg, and nicotine content in smoke is 1.2mg) on the rotating disk of three happy board household microwave ovens and carries out the microwave radiation.Refire test in radiation under the 850W power after 35 seconds, collect main flow and side-stream smoke and analyze the nitrosamine total content.The nitrosamine total content props up from 6.46nmol/ and is reduced to 3.34nmol/ and props up in the side-stream smoke, has been reduced 48.3%.The nitrosamine total content props up from 1.88nmol/ and is reduced to 0.90nmol/ and props up in the main flume, has been reduced 52.1%.
[example 5] directly places finished cigarettes (mixed type is renovated box packing, and tar content is 11mg, and nicotine content in smoke is 1.0mg) on the rotating disk of three happy board household microwave ovens and carries out the microwave radiation.Refire test in radiation under the 850W power after 35 seconds, collect main flow and side-stream smoke and analyze the nitrosamine total content.The nitrosamine total content props up from 2.71nmol/ and is reduced to 1.53 nmol/ and props up in the side-stream smoke, has been reduced 43.5%; The nitrosamine total content props up from 1.32nmol/ and is reduced to 0.31nmol/ and props up in the main flume, has been reduced 76%.
As from the foregoing, with finished cigarettes directly with after the microwave radiation processing, can be under the situation that does not change the original mouthfeel of cigarette with flue gas in the nitrosamine total content reduce 21.5%-76%.Therefore, the environmental pollution that cigarette smoke caused and just be greatly diminished for the harm of smoker and involuntary smoker's health.Technical application of the present invention is strong, is adapted at large, medium and small type cigar mill and directly applies.
Claims (2)
1. microwave handling method that reduces content of nitrosamines in the cigarette smoke, it is characterized in that tobacco product after the cigarette or box-packed cigarette are evenly paved, carry out the microwave radiation, the frequency of microwave is 2450MHz, radiant power is 500-2000W, radiated time is 10-100 second, can reduce the content of nitrosamine in this cigarette smoke.
2. microwave handling method according to claim 1 is characterized in that said tobacco product is that cigarette after the cigarette props up or cigarettes.
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| Application Number | Priority Date | Filing Date | Title |
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| CN00112252.5A CN1105517C (en) | 2000-05-08 | 2000-05-08 | Microwave processing method for reducing nitrosamine content in smoke of cigarette |
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| CN00112252.5A CN1105517C (en) | 2000-05-08 | 2000-05-08 | Microwave processing method for reducing nitrosamine content in smoke of cigarette |
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| CN1269992A CN1269992A (en) | 2000-10-18 |
| CN1105517C true CN1105517C (en) | 2003-04-16 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102578697A (en) * | 2011-12-20 | 2012-07-18 | 江苏省农业科学院 | Irradiation degradation method for tobacco-specific nitrosamines in cigarette |
| CN102894469B (en) * | 2012-10-31 | 2014-12-24 | 河南中烟工业有限责任公司 | CO2 flow extraction process for reducing tar and harmful components of tobacco |
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