CN110544728A - Light flexible photovoltaic module - Google Patents

Light flexible photovoltaic module Download PDF

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Publication number
CN110544728A
CN110544728A CN201910843053.2A CN201910843053A CN110544728A CN 110544728 A CN110544728 A CN 110544728A CN 201910843053 A CN201910843053 A CN 201910843053A CN 110544728 A CN110544728 A CN 110544728A
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CN
China
Prior art keywords
film layer
photovoltaic module
layer
mass
accounts
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910843053.2A
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Chinese (zh)
Inventor
吴韦
刘志锋
林建伟
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Taizhou Zhonglai Optoelectronics Technology Co Ltd
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Taizhou Zhonglai Optoelectronics Technology Co Ltd
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Priority to CN201910843053.2A priority Critical patent/CN110544728A/en
Publication of CN110544728A publication Critical patent/CN110544728A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0481Encapsulation of modules characterised by the composition of the encapsulation material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • H01L31/0543Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means comprising light concentrating means of the refractive type, e.g. lenses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/10Photovoltaic [PV]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/52PV systems with concentrators

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The invention provides a light flexible photovoltaic assembly, which sequentially comprises a TFB film layer, a water-blocking film layer, a composite glass fiber layer, a battery string and an FFC double-sided fluorine-containing back film layer from top to bottom, wherein the TFB film layer and the water-blocking film layer, the water-blocking film layer and the composite glass fiber layer, the composite glass fiber layer and the battery string and the FFC double-sided fluorine-containing back film layer are connected through EVA films; coating liquid is sprayed on one side of the TFB film layer far away from the water blocking film layer, and the water blocking film layer sequentially comprises an EVA adhesive layer, a PET film layer, a high barrier layer, a PE protective layer and an EVA adhesive layer from top to bottom. The invention not only reduces the weight of the photovoltaic module to 3.5 kg/square meter, so that the requirement on roof bearing is far lower than that of the conventional module, but also ensures that the photovoltaic module has flexibility, can be installed on a curved roof, does not need to use an installation support for installation when being installed, can realize the installation of the photovoltaic module only by installing adhesive strips on an installation surface, and the installation position is not limited.

Description

Light flexible photovoltaic module
Technical Field
The invention relates to the technical field of photovoltaic modules, in particular to a light flexible photovoltaic module.
Background
At present, most solar cell modules in the market are fixed and installed through a bracket, and can only be installed in a plane area. The installation cost for installing and fixing the photovoltaic module through the bracket is high, and the installation position is relatively fixed; in addition, the surface of the conventional photovoltaic module is packaged by using glass, so that the weight of the photovoltaic module per se is 12kg per square meter, which has certain requirement on the bearing capacity of a roof.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a light flexible photovoltaic module, which adopts the technical scheme that:
The photovoltaic module sequentially comprises a TFB film layer, a water-blocking film layer, a composite glass fiber layer, a battery string and an FFC double-sided fluorine-containing back film layer from top to bottom, wherein the TFB film layer and the water-blocking film layer, the water-blocking film layer and the composite glass fiber layer, the composite glass fiber layer and the battery string and the FFC double-sided fluorine-containing back film layer are connected through EVA films; coating liquid is sprayed on one side of the TFB film layer, which is far away from the water blocking film layer, and the water blocking film layer sequentially comprises an EVA adhesive layer, a PET film layer, a high-barrier layer, a PE protective layer and an EVA adhesive layer from top to bottom.
The invention provides a light flexible photovoltaic module, which also comprises the following auxiliary technical scheme:
Wherein, the side of the FFC double-sided fluorine-containing back film layer far away from the battery string is provided with an aluminum foil.
And the aluminum foil is adhered to one side of the fluorine-containing back film layer far away from the battery string through an electrochemical method.
Wherein the coating liquid comprises modified silane, ethanol and an additive.
Wherein the additive is water or octanol, and the mass percent of the additive is 1.5-2.5%.
The EVA film comprises a main material, a light absorber, a light stabilizer, an antioxidant and a curing agent.
The light stabilizer is bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate, the antioxidant is tris (nonylphenyl) phosphite, and the curing agent is 2, 5-dimethyl-2, 5-di-tert-butyl hexane peroxide.
the ethylene-vinyl acetate copolymer comprises, by mass, 97.8% -98%, 2-hydroxy-4-n-octoxybenzophenone 0.28% -0.32%, bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate 0.08% -0.12%, tris (nonylphenyl) phosphite 0.18% -0.22%, and 2, 5-dimethyl-2, 5-di-tert-butyl-hexane peroxide 1.45% -1.55%.
The ethylene-vinyl acetate copolymer is 97.9% by mass, the 2-hydroxy-4-n-octoxybenzophenone is 0.3% by mass, the bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate is 0.1% by mass, the tris (nonylphenyl) phosphite is 0.2% by mass, and the 2, 5-dimethyl-2, 5-di-tert-butylperoxyhexane is 1.5% by mass.
Wherein in the ethylene-vinyl acetate copolymer, the mass percentage of the vinyl acetate is 21%.
The implementation of the invention comprises the following technical effects:
According to the light flexible photovoltaic module, the cover plate of the conventional photovoltaic module is replaced by glass to form the TFB film layer in the application, and the coating liquid is sprayed on one side, far away from the composite glass fiber layer, of the TFB film layer, so that the weight of the photovoltaic module is reduced, the photovoltaic module is flexible and can be installed on a curved roof; the coating liquid can fill pits on the TFB film layer, so that the side, in contact with the outside, of the TFB film layer becomes flat and smooth, the light permeability increasing performance is improved, and the optical permeability of the cover plate is increased to be more than 2%; the PET rete in the water blocking film can reduce surface energy, reduces the adhesion of dust, makes the dust take away easily by wind, and can effectively prevent water vapor permeation.
And, flexible photovoltaic module of light in this application need not to use the installing support to install when the installation, only needs to install the adhesive tape on the installation face, can realize photovoltaic module's installation, and its mounted position is unrestricted, and because photovoltaic module's weight reduces to 3.5 kg/square meter in this application, consequently, its requirement is less than conventional subassembly requirement far away to the roof bearing.
Drawings
Fig. 1 is a schematic structural view of a lightweight flexible photovoltaic module of the present invention.
In the figure, 1-TFB film layer, 2-water-resistant film, 3-composite glass fiber layer, 4-battery string, 5-FFC double-sided fluorine-containing back film layer and 6-EVA film.
Detailed Description
Reference will now be made in detail to the exemplary embodiments, examples of which are illustrated in the accompanying drawings. When the following description refers to the accompanying drawings, like numbers in different drawings represent the same or similar elements unless otherwise indicated. The embodiments described in the following exemplary embodiments do not represent all embodiments consistent with the present invention. Rather, they are merely examples of apparatus and methods consistent with certain aspects of the invention, as detailed in the appended claims.
As shown in fig. 1, the light flexible photovoltaic module provided by the invention comprises a TFB film layer 1, a water-blocking film layer 2, a composite glass fiber layer 3, a battery string 4 and an FFC double-sided fluorine-containing back film layer 5 in sequence from top to bottom, wherein the TFB film layer 1 and the water-blocking film layer 2, the water-blocking film layer 2 and the composite glass fiber layer 3, the composite glass fiber layer 3 and the battery string 4, and the battery string 4 and the FFC double-sided fluorine-containing back film layer 5 are connected through an EVA film 6; coating liquid is sprayed on one side, far away from the water blocking film layer 2, of the TFB film layer 1, and the water blocking film layer 2 sequentially comprises an EVA adhesive layer, a PET film layer, a high barrier layer, a PE protective layer and an EVA adhesive layer from top to bottom.
The TFB film layer sequentially comprises an outer protection layer PVF, a middle layer PET and a fluorine-containing bonding layer from top to bottom.
(1) Outer protective layer PVF — weatherable layer: in order to make the photovoltaic module have good weather resistance, the outer layer material is generally required to contain fluorine, and PVF and PVDF are two well-known weather-resistant high polymer materials, because the C-F bond energy in the outer layer material is 485KJ/mol, the bond energy in organic compound covalent bonds is the largest, only photons with the wavelength less than 220nm can dissociate the C-F bond, and in sunlight, the photons with the wavelength less than 220nm only account for less than 5%, and the few photons with the wavelength less than 220nm are easily absorbed by an ozone layer and can reach the ground very rarely. Therefore, the weather resistance of the photovoltaic module can be greatly improved by providing the PVF protective layer on the outermost layer of the photovoltaic module.
(2) Middle layer PET: the composite material has the advantages of supporting function, high and low temperature resistance, stable mechanical property, excellent electrical insulation, favorable creep resistance, fatigue resistance, friction resistance and dimensional stability, and low gas and steam permeability.
(3) A fluorine-containing bonding layer: since unmodified fluorine-containing films and PET have poor adhesion to EVA, it is necessary to use modified fluorine-containing materials or EVA, PE, and PA films having strong adhesion.
According to the light flexible photovoltaic module, the cover plate of the conventional photovoltaic module is replaced by glass to form the TFB film layer in the application, and the coating liquid is sprayed on one side, far away from the composite glass fiber layer, of the TFB film layer, so that the weight of the photovoltaic module is reduced, the photovoltaic module is flexible and can be installed on a curved roof; the coating liquid can fill pits on the TFB film layer, so that the side, in contact with the outside, of the TFB film layer becomes flat and smooth, the light permeability increasing performance is improved, and the optical permeability of the cover plate is increased to be more than 2%; the PET rete in the water blocking film can reduce surface energy, reduces the adhesion of dust, makes the dust take away easily by wind, and can effectively prevent water vapor permeation.
And, flexible photovoltaic module of light in this application need not to use the installing support to install when the installation, only needs to install the adhesive tape on the installation face, can realize photovoltaic module's installation, and its mounted position is unrestricted, and because photovoltaic module's weight reduces to 3.5 kg/square meter in this application, consequently, its requirement is less than conventional subassembly requirement far away to the roof bearing.
Preferably, an aluminum foil is arranged on one side, far away from the battery string, of the FFC double-sided fluorine-containing back film layer. In the embodiment, the aluminum foil is arranged on the side, far away from the cell string, of the FFC double-sided fluorine-containing back film layer, so that the back surface of the photovoltaic module can also prevent the permeation of water vapor by 100%.
More preferably, the aluminum foil is electrochemically adhered to the fluorine-containing back film layer on a side thereof remote from the cell string.
Preferably, the coating liquid comprises modified silane, ethanol and an additive. Wherein, the additive is an auxiliary agent which can be water, octanol or a mixture of water and octanol, and the mass percentage of the additive is 1.5-2.5%.
Preferably, the EVA film comprises a main material, a light absorber, a light stabilizer, an antioxidant, and a curing agent.
the light stabilizer is bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate, the antioxidant is tris (nonylphenyl) phosphite, and the curing agent is 2, 5-dimethyl-2, 5-di-tert-butyl hexane peroxide.
Preferably, the ethylene-vinyl acetate copolymer accounts for 97.8-98% by mass, the 2-hydroxy-4-n-octoxybenzophenone accounts for 0.28-0.32% by mass, the bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate accounts for 0.08-0.12% by mass, the tris (nonylphenyl) phosphite accounts for 0.18-0.22% by mass, and the 2, 5-dimethyl-2, 5-di-tert-butylperoxyhexane accounts for 1.45-1.55% by mass.
More preferably, the ethylene-vinyl acetate copolymer is 97.9% by mass, the 2-hydroxy-4-n-octoxybenzophenone is 0.3% by mass, the bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate is 0.1% by mass, the tris (nonylphenyl) phosphite is 0.2% by mass, and the 2, 5-dimethyl-2, 5-di-tert-butylperoxyhexane is 1.5% by mass.
Wherein in the ethylene-vinyl acetate copolymer, the mass percentage of the vinyl acetate is 21%. This example increases the hardness of the PVF film by setting the mass percentage of vinyl acetate in the ethylene-vinyl acetate copolymer to 21%.
Other embodiments of the invention will be apparent to those skilled in the art from consideration of the specification and practice of the disclosure disclosed herein. This application is intended to cover any variations, uses, or adaptations of the invention following, in general, the principles of the invention and including such departures from the present disclosure as come within known or customary practice within the art to which the invention pertains. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the invention being indicated by the following claims.
It will be understood that the invention is not limited to the precise arrangements described above and shown in the drawings and that various modifications and changes may be made without departing from the scope thereof. The scope of the invention is limited only by the appended claims.

Claims (10)

1. A light flexible photovoltaic module characterized in that: the photovoltaic module sequentially comprises a TFB film layer, a water-blocking film layer, a composite glass fiber layer, a battery string and an FFC double-sided fluorine-containing back film layer from top to bottom, wherein the TFB film layer and the water-blocking film layer, the water-blocking film layer and the composite glass fiber layer, the composite glass fiber layer and the battery string and the FFC double-sided fluorine-containing back film layer are connected through EVA films; coating liquid is sprayed on one side of the TFB film layer, which is far away from the water blocking film layer, and the water blocking film layer sequentially comprises an EVA adhesive layer, a PET film layer, a high-barrier layer, a PE protective layer and an EVA adhesive layer from top to bottom.
2. A lightweight flexible photovoltaic module in accordance with claim 1, wherein: and an aluminum foil is arranged on one side of the FFC double-sided fluorine-containing back film layer, which is far away from the battery string.
3. A lightweight flexible photovoltaic module in accordance with claim 2, wherein: the aluminum foil is adhered to one side, far away from the battery string, of the fluorine-containing back film layer through an electrochemical method.
4. A lightweight flexible photovoltaic module according to any one of claims 1 to 3, wherein: the coating liquid comprises modified silane, ethanol and an additive.
5. The lightweight flexible photovoltaic module of claim 4, wherein: the additive is water or octanol, and the mass percent of the additive is 1.5-2.5%.
6. A lightweight flexible photovoltaic module according to any one of claims 1 to 3, wherein: the EVA film comprises a main material, a light absorber, a light stabilizer, an antioxidant and a curing agent.
7. The lightweight flexible photovoltaic module of claim 6, wherein: the main material is ethylene-vinyl acetate copolymer, the light absorber is 2-hydroxy-4-n-octoxy benzophenone, the light stabilizer is bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate, the antioxidant is tris (nonylphenyl) phosphite, and the curing agent is 2, 5-dimethyl-2, 5-ditert-butyl-hexane peroxide.
8. The lightweight flexible photovoltaic module of claim 7, wherein: the ethylene-vinyl acetate copolymer accounts for 97.8-98% by mass, the 2-hydroxy-4-n-octyloxybenzophenone accounts for 0.28-0.32% by mass, the bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate accounts for 0.08-0.12% by mass, the tris (nonylphenyl) phosphite accounts for 0.18-0.22% by mass, and the 2, 5-dimethyl-2, 5-ditert-butyl-hexane peroxide accounts for 1.45-1.55% by mass.
9. The lightweight flexible photovoltaic module of claim 8, wherein: the ethylene-vinyl acetate copolymer accounts for 97.9% by mass, the 2-hydroxy-4-n-octoxybenzophenone accounts for 0.3% by mass, the bis (2,2,6, 6-tetramethyl-4-piperidyl) sebacate accounts for 0.1% by mass, the tris (nonylphenyl) phosphite accounts for 0.2% by mass, and the 2, 5-dimethyl-2, 5-di-tert-butylperoxyhexane accounts for 1.5% by mass.
10. A lightweight flexible photovoltaic module according to claim 8, further comprising: in the ethylene-vinyl acetate copolymer, the mass percentage of vinyl acetate is 21%.
CN201910843053.2A 2019-09-06 2019-09-06 Light flexible photovoltaic module Pending CN110544728A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114583000A (en) * 2022-03-18 2022-06-03 苏州零碳绿建新能源科技有限公司 Light photovoltaic module and preparation method thereof

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CN203071105U (en) * 2012-12-10 2013-07-17 厦门冠宇科技有限公司 Flexible crystalline silicon solar panel
JP2013145807A (en) * 2012-01-13 2013-07-25 Keiwa Inc Front sheet for solar cell module, and solar cell module including the same
CN104992995A (en) * 2015-05-26 2015-10-21 张家港康得新光电材料有限公司 Composite membrane, preparation method thereof and solar cell assembly
CN106159015A (en) * 2016-07-25 2016-11-23 无锡中洁能源技术有限公司 A kind of solar cell backboard with high flame retardant
CN206179880U (en) * 2016-08-30 2017-05-17 中国乐凯集团有限公司 Multilayer composite films is used in flexible solar cell encapsulation
CN208127220U (en) * 2018-03-30 2018-11-20 君泰创新(北京)科技有限公司 A kind of battery component
US20190252563A1 (en) * 2016-10-31 2019-08-15 Sunman (Hong Kong) Limited Photovoltaic assembly
CN210167364U (en) * 2019-09-06 2020-03-20 泰州中来光电科技有限公司 Light flexible photovoltaic module

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Publication number Priority date Publication date Assignee Title
US20090272436A1 (en) * 2008-05-05 2009-11-05 Osbert Hay Cheung Non-glass photovoltaic module and methods for manufacture
JP2013145807A (en) * 2012-01-13 2013-07-25 Keiwa Inc Front sheet for solar cell module, and solar cell module including the same
CN203071105U (en) * 2012-12-10 2013-07-17 厦门冠宇科技有限公司 Flexible crystalline silicon solar panel
CN104992995A (en) * 2015-05-26 2015-10-21 张家港康得新光电材料有限公司 Composite membrane, preparation method thereof and solar cell assembly
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CN206179880U (en) * 2016-08-30 2017-05-17 中国乐凯集团有限公司 Multilayer composite films is used in flexible solar cell encapsulation
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Publication number Priority date Publication date Assignee Title
CN114583000A (en) * 2022-03-18 2022-06-03 苏州零碳绿建新能源科技有限公司 Light photovoltaic module and preparation method thereof

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