CN110527389A - A kind of antibacterial spraying film materials - Google Patents

A kind of antibacterial spraying film materials Download PDF

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Publication number
CN110527389A
CN110527389A CN201910496003.1A CN201910496003A CN110527389A CN 110527389 A CN110527389 A CN 110527389A CN 201910496003 A CN201910496003 A CN 201910496003A CN 110527389 A CN110527389 A CN 110527389A
Authority
CN
China
Prior art keywords
film materials
citric acid
casein
spraying film
trimethoprim
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910496003.1A
Other languages
Chinese (zh)
Inventor
李学军
蒋海燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BEIJING GAOKEMAI TECHNOLOGY DEVELOPMENT Co Ltd
Original Assignee
BEIJING GAOKEMAI TECHNOLOGY DEVELOPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BEIJING GAOKEMAI TECHNOLOGY DEVELOPMENT Co Ltd filed Critical BEIJING GAOKEMAI TECHNOLOGY DEVELOPMENT Co Ltd
Priority to CN201910496003.1A priority Critical patent/CN110527389A/en
Publication of CN110527389A publication Critical patent/CN110527389A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

Abstract

The present invention relates to a kind of antibacterial spraying film materials, it by weight percentage include: Nano silica sol 30-50%, polyacrylate 20-40%, 12 5-15% of alcohol ester, casein 3-8%, trimethoprim 5-15%, dodecyl benzyl dimethyl ammonium chloride 1-3%, citric acid 2-5%, the present invention only need to be on the article for needing to sterilize under spray two, it is gently slightly smeared with napkin paper, the film of layer of transparent is just formed by sterilised object surface, first original germ contamination face is completely covered, play the role of disinfection and isolation, second this tunic has the function of comparable inhibition bacterial growth, it descends slowly and lightly from air or contact stain bring bacterium, existence can not be multiplied on membrane body, play the purpose for keeping electrodeless surface cleaning.Third, this film and body surface binding strength are very high, do not fall off under the friction of general 2 kilograms of pressure up to thousand times.

Description

A kind of antibacterial spraying film materials
Technical field
The present invention relates to biological environmental production technologies, and in particular to a kind of antibacterial spraying film materials.
Background technique
Common sterilization method is to carry out smearing wiping to body surface with disinfectant, kills bacterium thereon, works as wiping It regards as having reached on the article without bacterium after the completion using standard.But when we wipe article, in air Germ be not killed, the article sterilized can be still in contact with manpower, clothing, vessel etc., these all can energy band Carry out the secondary pollution of bacterium.Widespread practice is in high-risk environment, artificially to shorten the period of secondary sterilization at present, to kill The germ that breeding is got up rapidly.Both time-consuming in this way or laborious, and do not allow manageability.
Summary of the invention
The present invention in view of the above-mentioned problems, a kind of antibacterial spraying film materials are made, only need on the article for needing to sterilize under spray two, It is gently slightly smeared with napkin paper, is just formed the film of layer of transparent by sterilised object surface, first by original germ contamination face It is completely covered, plays the role of disinfection and isolation, second this tunic has comparable inhibition bacterial growth, descends slowly and lightly from air Or contact stain bring bacterium, existence can not be multiplied on membrane body, play the purpose for keeping electrodeless surface cleaning.Third, This film and body surface binding strength are very high, do not fall off under the friction of general 2 kilograms of pressure up to thousand times.Normal wet cloth cleaning It can be kept 2 days to one week or more under wiping, as long as membrane body exists, bacterium can not survive on film.To reach Continuous sterilization The purpose for keeping environment clean.
The purpose of the present invention is be achieved through the following technical solutions: by weight percentage including: Nano silica sol 30- 50%, polyacrylate 20-40%, 12 5-15% of alcohol ester, casein 3-8%, trimethoprim 5-15%, dodecyl Dimethyl benzyl ammonium chloride 1-3%, citric acid 2-5%.
It in preferred embodiments, by weight percentage include: Nano silica sol 35-45%, polyacrylate 25- 35%, 12 8-13% of alcohol ester, casein 4-6%, trimethoprim 8-13%, dodecyl benzyl dimethyl ammonium chloride 1- 3%, citric acid 3-4%.
It in preferred embodiments, by weight percentage include: Nano silica sol 40%, polyacrylate 30%, alcohol Rouge ten two 10%, casein 5%, trimethoprim 10%, dodecyl benzyl dimethyl ammonium chloride 2%, citric acid 3%.
Production method is to pour above-mentioned material in stirred tank into, in stirred tank under room temperature, with every 500 revs/min High-speed stirred is to forming homogeneous latex emulsion.
The invention has the benefit that
1, there is extremely strong antibacterial effect, detection is prevented compound mould up to 0 grade, and anti-candida albicans are up to 99.9%;
2, i.e. spray is used, fast filming, is only needed one minute;
3, sustained anti-microbial, antibacterial effect sustainable several weeks;
Specific embodiment
Below with reference to specific embodiment, the present invention is further illustrated.
A kind of antibacterial spraying film materials of the embodiment of the present invention.
Embodiment 1:
Include: by weight percentage Nano silica sol 35%, polyacrylate 40%, alcohol ester ten two 10%, casein 3%, Trimethoprim 8%, dodecyl benzyl dimethyl ammonium chloride 2%, citric acid 2%.
A kind of production method of antibacterial spraying film materials, comprising the following steps:
1, raw material is successively put in proportion into stirred tank,
2, it is stirred 20 minutes with 200 rotary speed per minute.
3, temperature of charge needs 10 degree Celsius or more when stirring.
4, pH value is adjusted with citric acid to be maintained between 4-5.
Embodiment 2:
It by weight percentage include: Nano silica sol 45%, polyacrylate 30%, alcohol ester ten two 8%, casein 6%, first Oxygen benzylamine pyrimidine 5%, dodecyl benzyl dimethyl ammonium chloride 3%, citric acid 3%.
A kind of production method of antibacterial spraying film materials, comprising the following steps:
1, raw material is successively put in proportion into stirred tank,
2, it is stirred 30 minutes with 200 rotary speed per minute.
3, temperature of charge needs 10 degree Celsius or more when stirring.
4, pH value is adjusted with citric acid to be maintained between 4-5.
Embodiment 3:
Include: by weight percentage Nano silica sol 40%, polyacrylate 30%, alcohol ester ten two 10%, casein 5%, Trimethoprim 10%, dodecyl benzyl dimethyl ammonium chloride 2%, citric acid 3%.
A kind of production method of antibacterial spraying film materials, comprising the following steps:
1, raw material is successively put in proportion into stirred tank,
2, it is stirred 25 minutes with 200 rotary speed per minute.
3, temperature of charge needs 10 degree Celsius or more when stirring.
4, pH value is adjusted with citric acid to be maintained between 4-5.
The performance test results are as follows:
Finally, it should be noted that above-described embodiments are merely to illustrate the technical scheme, rather than to it Limitation;Although the present invention is described in detail referring to the foregoing embodiments, those skilled in the art should understand that: It can still modify to technical solution documented by previous embodiment, or to part of or all technical features into Row equivalent replacement;And these modifications or substitutions, it does not separate the essence of the corresponding technical solution various embodiments of the present invention technical side The range of case.

Claims (3)

1. a kind of antibacterial spraying film materials, it is characterised in that: by weight percentage include: Nano silica sol 30-50%, polyacrylic acid Ester 20-40%, 12 5-15% of alcohol ester, casein 3-8%, trimethoprim 5-15%, dodecyl dimethyl Benzylmagnesium chloride Ammonium 1-3%, citric acid 2-5%.
2. antibacterial spraying film materials according to claim 1, it is characterised in that: by weight percentage include: Nano silica sol 35-45%, polyacrylate 25-35%, 12 8-13% of alcohol ester, casein 4-6%, trimethoprim 8-13%, dodecane Base dimethyl benzyl ammonium chloride 1-3%, citric acid 3-4%.
3. antibacterial spraying film materials according to claim 1, it is characterised in that: by weight percentage include: Nano silica sol 40%, polyacrylate 30%, alcohol ester ten two 10%, casein 5%, trimethoprim 10%, dodecyl dimethyl benzyl Ammonium chloride 2%, citric acid 3%.
CN201910496003.1A 2019-06-10 2019-06-10 A kind of antibacterial spraying film materials Pending CN110527389A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910496003.1A CN110527389A (en) 2019-06-10 2019-06-10 A kind of antibacterial spraying film materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910496003.1A CN110527389A (en) 2019-06-10 2019-06-10 A kind of antibacterial spraying film materials

Publications (1)

Publication Number Publication Date
CN110527389A true CN110527389A (en) 2019-12-03

Family

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Family Applications (1)

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CN201910496003.1A Pending CN110527389A (en) 2019-06-10 2019-06-10 A kind of antibacterial spraying film materials

Country Status (1)

Country Link
CN (1) CN110527389A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1544558A (en) * 2003-11-27 2004-11-10 上海大学 Environment protectional photocatalyzed paint for inner wall
CN106337318A (en) * 2016-08-24 2017-01-18 安徽天艺纸业科技有限公司 Production method of waterproof alcohol-proof n-heptane-proof high-brightness fold-resistant scratch-resistant leatherette paper
JP2017137481A (en) * 2016-01-11 2017-08-10 東京インキ株式会社 Antimicrobial coating agent, antimicrobial laminate, manufacturing method of antimicrobial laminate, film or sheet using antimicrobial laminate, packaging container, packaging bad and lid material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1544558A (en) * 2003-11-27 2004-11-10 上海大学 Environment protectional photocatalyzed paint for inner wall
JP2017137481A (en) * 2016-01-11 2017-08-10 東京インキ株式会社 Antimicrobial coating agent, antimicrobial laminate, manufacturing method of antimicrobial laminate, film or sheet using antimicrobial laminate, packaging container, packaging bad and lid material
CN106337318A (en) * 2016-08-24 2017-01-18 安徽天艺纸业科技有限公司 Production method of waterproof alcohol-proof n-heptane-proof high-brightness fold-resistant scratch-resistant leatherette paper

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
刘程等: "《表面活性剂手册》", 31 August 1995, 化学工业出版社 *
朱洪法等: "《工业助剂手册》", 30 June 2007, 金盾出版社 *
蔡建泉: "改性聚丙烯酸酯乳液的合成与粘结性能", 《改性聚丙烯酸酯乳液的合成与粘结性能 *
黎建宏: "《新编药物手册》", 31 March 2004, 江西科学技术出版社 *

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Application publication date: 20191203

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