CN110527374A - A kind of preparation process of the adaptable high-molecular water paint of base's deformation - Google Patents

A kind of preparation process of the adaptable high-molecular water paint of base's deformation Download PDF

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Publication number
CN110527374A
CN110527374A CN201910677560.3A CN201910677560A CN110527374A CN 110527374 A CN110527374 A CN 110527374A CN 201910677560 A CN201910677560 A CN 201910677560A CN 110527374 A CN110527374 A CN 110527374A
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Prior art keywords
water
pitch
water paint
base
emulsifier
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CN201910677560.3A
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Chinese (zh)
Inventor
金继典
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Anhui Woerde New Materials Co Ltd
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Anhui Woerde New Materials Co Ltd
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Priority to CN201910677560.3A priority Critical patent/CN110527374A/en
Publication of CN110527374A publication Critical patent/CN110527374A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of base deformation adaptable high-molecular water paint preparation process, the formula of the high-molecular water paint includes following component: white water-borne coating 45%-50%, titanium dioxide 3%-7%, calcium carbonate 6%-11%, kaolin 2%-5%, two SiClx powder 1%-5%, pitch 2%-6%, pH buffer 1%-4%, stabilizer 1%-4%, emulsifier 3%-7%, remaining be deionized water；The invention also discloses a kind of preparation process of the adaptable high-molecular water paint of base deformation, the preparation method is the following steps are included: quantitatively weigh, preparation water phase, pitch heating, mixing and emulsification, polymerization reaction；Formula of the present invention is national regulations raw material, and the high-molecular water paint that the present invention prepares is highly improved, its tensile strength, adhesive force and elasticity is set to get a promotion, make that it is suitable for more occasions, effectively improve the adaptability of base's deformation, and the present invention prepares the cost of high-molecular water paint and decreases, and increases enterprise income, is suitble to promote.

Description

A kind of preparation process of the adaptable high-molecular water paint of base's deformation
Technical field
The present invention relates to high-molecular water paint preparation technical field, specially a kind of base deforms adaptable The preparation process of high-molecular water paint.
Background technique
Water paint is with water as solvent or to make the coating of decentralized medium, is a kind of relatively new type painting on Coating Market Material, including water soluble paint, water-reducible coating, three kinds of water-dispersible paint (latex paint), water paint is with water solubility tree Rouge is film forming matter, and using polyvinyl alcohol and its various modifiers as representative, in addition to this there are also water-soluble alkyd resins, water-soluble asphalt mixtures modified by epoxy resin Rouge and inorganic polymer water-base resin etc., water paint have excellent non-stick and durability, but should be noted transport, storage and Anti-corrosion gas defence；
Waterproof material used in building trade is generally divided into three categories: coiled material class, solvent, pitch ointment class, still, all The problems such as there are high temperature to trickle, low-temperature embrittleness, and tensile strength is low, elongation percentage is small, poor adhesive force, meanwhile, the adaptation of base's deformation Ability is weaker, so that high-molecular water paint can not adapt to a variety of use occasions, for this purpose, the present invention proposes what a kind of base deformed The preparation process of adaptable high-molecular water paint.
Summary of the invention
The purpose of the present invention is to provide a kind of preparation works of the adaptable high-molecular water paint of base deformation Skill, to solve the problems mentioned in the above background technology.
To achieve the above object, the invention provides the following technical scheme: a kind of adaptable high score of base deformation Sub- water paint, the formula of the high-molecular water paint include following component: white water-borne coating 45%-50%, titanium dioxide 3%-7%, calcium carbonate 6%-11%, kaolin 2%-5%, two SiClx powder 1%-5%, pitch 2%-6%, pH buffer 1%- 4%, stabilizer 1%-4%, emulsifier 3%-7%, remaining be deionized water.
Preferably, including white water-borne coating 45%, titanium dioxide 7%, calcium carbonate 6%, kaolin 5%, two SiClx powder 1%, pitch 6%, pH buffer 1%, stabilizer 4%, emulsifier 3%, remaining be deionized water.
Preferably, including white water-borne coating 46%, titanium dioxide 6%, calcium carbonate 7%, kaolin 4%, two SiClx powder 2%, pitch 5%, pH buffer 2%, stabilizer 3%, emulsifier 4%, remaining be deionized water.
Preferably, including white water-borne coating 47%, titanium dioxide 5%, calcium carbonate 8%, kaolin 3%, two SiClx powder 3%, pitch 4%, pH buffer 3%, stabilizer 2%, emulsifier 5%, remaining be deionized water.
Preferably, including white water-borne coating 48%, titanium dioxide 4%, calcium carbonate 9%, kaolin 2%, two SiClx powder 4%, pitch 3%, pH buffer 2%, stabilizer 2%, emulsifier 6%, remaining be deionized water.
Preferably, the white water-borne coating is selected from acrylate white coating, aqueous polyurethane white coating or alkyd At least one of resin white coating, emulsifier are dodecyl sodium sulfate.
Preferably, the pitch is at least one of 70 or No. 90 heavy-duty road asphalts, and stabilizer is calcium chloride, ammonium chloride At least one of with polystyrene, pH buffer is sodium bicarbonate.
A kind of preparation process of high-molecular water paint as described above, the preparation method the following steps are included:
S1: quantitatively weighing, and all raw materials are weighed according to above-mentioned component；
S2: water phase is prepared, emulsifier, pH buffer, stabilizer and deionized water are configured to lotion, are warming up to 55- 65℃；
S3: pitch heating, by pitch be heated to 128-135 DEG C it is spare；
S4: mixing and emulsification emulsify heated bitumen and prepared lotion with mulser, after emulsification completely, stirring Any obvious particle is not adhered in handful, to filler is gradually added after room temperature in the case of stirring after cooling, stands defoaming；
S5: the liquid after mixing and emulsifying is added in white water-borne coating and carries out heating reaction, reaction temperature by polymerization reaction It is 60~65 DEG C.
Compared with prior art, the beneficial effects of the present invention are: formula of the present invention is national regulations raw material, And the high-molecular water paint that the present invention prepares is highly improved, and proposes its tensile strength, adhesive force and elasticity It rises, makes the adaptability for effectively improving base's deformation it is suitable for more occasions, and the present invention prepares high-molecular water paint Cost decrease, increase enterprise income, be suitble to promote.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment one
The present invention provides a kind of technical solution: a kind of adaptable high-molecular water paint of base's deformation, the height The formula of molecule water paint includes following component: including white water-borne coating 45%, titanium dioxide 7%, calcium carbonate 6%, kaolinite Native 5%, two SiClx powder 1%, pitch 6%, pH buffer 1%, stabilizer 4%, emulsifier 3%, remaining be deionized water.
Wherein, white water-borne coating is selected from acrylate white coating, and emulsifier is dodecyl sodium sulfate, pitch 70 Number heavy-duty road asphalt, stabilizer is calcium chloride, and pH buffer is sodium bicarbonate.
A kind of preparation process of high-molecular water paint as described above, the preparation method the following steps are included:
S1: quantitatively weighing, and all raw materials are weighed according to above-mentioned component；
S2: water phase is prepared, emulsifier, pH buffer, stabilizer and deionized water are configured to lotion, are warming up to 55 ℃；
S3: pitch heating, by pitch be heated to 128 DEG C it is spare；
S4: mixing and emulsification emulsify heated bitumen and prepared lotion with mulser, after emulsification completely, stirring Any obvious particle is not adhered in handful, to filler is gradually added after room temperature in the case of stirring after cooling, stands defoaming；
S5: the liquid after mixing and emulsifying is added in white water-borne coating and carries out heating reaction, reaction temperature by polymerization reaction It is 60 DEG C.
Embodiment two
The present invention provides a kind of technical solution: a kind of adaptable high-molecular water paint of base's deformation, the height The formula of molecule water paint includes following component: including white water-borne coating 46%, titanium dioxide 6%, calcium carbonate 7%, kaolinite Native 4%, two SiClx powder 2%, pitch 5%, pH buffer 2%, stabilizer 3%, emulsifier 4%, remaining be deionized water.
Wherein, white water-borne coating is selected from aqueous polyurethane white coating, and emulsifier is dodecyl sodium sulfate, and pitch is No. 90 heavy-duty road asphalts, stabilizer are ammonium chloride, and pH buffer is sodium bicarbonate.
A kind of preparation process of high-molecular water paint as described above, the preparation method the following steps are included:
S1: quantitatively weighing, and all raw materials are weighed according to above-mentioned component；
S2: water phase is prepared, emulsifier, pH buffer, stabilizer and deionized water are configured to lotion, are warming up to 57 ℃；
S3: pitch heating, by pitch be heated to 130 DEG C it is spare；
S4: mixing and emulsification emulsify heated bitumen and prepared lotion with mulser, after emulsification completely, stirring Any obvious particle is not adhered in handful, to filler is gradually added after room temperature in the case of stirring after cooling, stands defoaming；
S5: the liquid after mixing and emulsifying is added in white water-borne coating and carries out heating reaction, reaction temperature by polymerization reaction It is 61 DEG C.
Embodiment three
The present invention provides a kind of technical solution: a kind of adaptable high-molecular water paint of base's deformation, the height The formula of molecule water paint includes following component: including white water-borne coating 47%, titanium dioxide 5%, calcium carbonate 8%, kaolinite Native 3%, two SiClx powder 3%, pitch 4%, pH buffer 3%, stabilizer 2%, emulsifier 5%, remaining be deionized water.
Wherein, white water-borne coating is selected from alkyd resin white coating, and emulsifier is dodecyl sodium sulfate, pitch 70 Heavy-duty road asphalt, stabilizer are polystyrene, and pH buffer is sodium bicarbonate.
A kind of preparation process of high-molecular water paint as described above, the preparation method the following steps are included:
S1: quantitatively weighing, and all raw materials are weighed according to above-mentioned component；
S2: water phase is prepared, emulsifier, pH buffer, stabilizer and deionized water are configured to lotion, are warming up to 59 ℃；
S3: pitch heating, by pitch be heated to 131 DEG C it is spare；
S4: mixing and emulsification emulsify heated bitumen and prepared lotion with mulser, after emulsification completely, stirring Any obvious particle is not adhered in handful, to filler is gradually added after room temperature in the case of stirring after cooling, stands defoaming；
S5: the liquid after mixing and emulsifying is added in white water-borne coating and carries out heating reaction, reaction temperature by polymerization reaction It is 62 DEG C.
Example IV
The present invention provides a kind of technical solution: a kind of adaptable high-molecular water paint of base's deformation, the height The formula of molecule water paint includes following component: including white water-borne coating 48%, titanium dioxide 4%, calcium carbonate 9%, kaolinite Native 2%, two SiClx powder 4%, pitch 3%, pH buffer 2%, stabilizer 2%, emulsifier 6%, remaining be deionized water.
Wherein, white water-borne coating is selected from acrylate white coating, and emulsifier is dodecyl sodium sulfate, and No. 90 are handed over again Road asphalt, stabilizer are ammonium chloride, and pH buffer is sodium bicarbonate.
A kind of preparation process of high-molecular water paint as described above, the preparation method the following steps are included:
S1: quantitatively weighing, and all raw materials are weighed according to above-mentioned component；
S2: water phase is prepared, emulsifier, pH buffer, stabilizer and deionized water are configured to lotion, are warming up to 64 ℃；
S3: pitch heating, by pitch be heated to 134 DEG C it is spare；
S4: mixing and emulsification emulsify heated bitumen and prepared lotion with mulser, after emulsification completely, stirring Any obvious particle is not adhered in handful, to filler is gradually added after room temperature in the case of stirring after cooling, stands defoaming；
S5: the liquid after mixing and emulsifying is added in white water-borne coating and carries out heating reaction, reaction temperature by polymerization reaction It is 64 DEG C.
By carrying out composition detection to four groups of embodiments, and one group of high-molecular water paint is picked from the market and is carried out Comparison, testing result are as follows:
From the experimental data of upper table it is found that the 4th group of high-molecular water paint of this programme tension slightly and elasticity most It is good, therefore there is preferable promotional value.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (8)

1. a kind of adaptable high-molecular water paint of base's deformation, it is characterised in that；The high-molecular water paint Formula includes following component: white water-borne coating 45%-50%, titanium dioxide 3%-7%, calcium carbonate 6%-11%, kaolin 2%-5%, two SiClx powder 1%-5%, pitch 2%-6%, pH buffer 1%-4%, stabilizer 1%-4%, emulsifier 3%- 7%, remaining is deionized water.
2. a kind of adaptable high-molecular water paint of base's deformation according to claim 1, it is characterised in that: Including white water-borne coating 45%, titanium dioxide 7%, calcium carbonate 6%, kaolin 5%, two SiClx powder 1%, pitch 6%, pH buffering Agent 1%, stabilizer 4%, emulsifier 3%, remaining be deionized water.
3. a kind of adaptable high-molecular water paint of base's deformation according to claim 1, it is characterised in that: Including white water-borne coating 46%, titanium dioxide 6%, calcium carbonate 7%, kaolin 4%, two SiClx powder 2%, pitch 5%, pH buffering Agent 2%, stabilizer 3%, emulsifier 4%, remaining be deionized water.
4. a kind of adaptable high-molecular water paint of base's deformation according to claim 1, it is characterised in that: Including white water-borne coating 47%, titanium dioxide 5%, calcium carbonate 8%, kaolin 3%, two SiClx powder 3%, pitch 4%, pH buffering Agent 3%, stabilizer 2%, emulsifier 5%, remaining be deionized water.
5. a kind of adaptable high-molecular water paint of base's deformation according to claim 1, it is characterised in that: Including white water-borne coating 48%, titanium dioxide 4%, calcium carbonate 9%, kaolin 2%, two SiClx powder 4%, pitch 3%, pH buffering Agent 2%, stabilizer 2%, emulsifier 6%, remaining be deionized water.
6. a kind of preparation process of the adaptable high-molecular water paint of base's deformation according to claim 1, It is characterized by: the white water-borne coating is selected from acrylate white coating, aqueous polyurethane white coating or alkyd resin At least one of white coating, emulsifier are dodecyl sodium sulfate.
7. a kind of preparation process of the adaptable high-molecular water paint of base's deformation according to claim 1, It is characterized by: the pitch is at least one of 70 or No. 90 heavy-duty road asphalts, stabilizer is calcium chloride, ammonium chloride and gathers At least one of styrene, pH buffer are sodium bicarbonate.
8. a kind of preparation process of the high-molecular water paint as described in claim 1-7 any one, it is characterised in that: the system Preparation Method the following steps are included:
S1: quantitatively weighing, and all raw materials are weighed according to above-mentioned component；
S2: water phase is prepared, emulsifier, pH buffer, stabilizer and deionized water are configured to lotion, are warming up to 55-65 ℃；
S3: pitch heating, by pitch be heated to 128-135 DEG C it is spare；
S4: mixing and emulsification emulsify heated bitumen and prepared lotion with mulser, after emulsification completely, stir on holding in both hands Any obvious particle is not adhered to, to filler is gradually added after room temperature in the case of stirring after cooling, stands defoaming；
S5: the liquid after mixing and emulsifying is added in white water-borne coating and carries out heating reaction, reaction temperature 60 by polymerization reaction ~65 DEG C.
CN201910677560.3A 2019-07-25 2019-07-25 A kind of preparation process of the adaptable high-molecular water paint of base's deformation Pending CN110527374A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113097489A (en) * 2021-04-01 2021-07-09 辽宁奥亿达新材料有限公司 Lithium ion battery carbon negative electrode liquid phase coating material, preparation and coating method
CN114716689A (en) * 2022-04-20 2022-07-08 安徽沃尔德新材料有限公司 Processing technology and device for anti-static biomass water-based acrylate raw material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1104229A (en) * 1994-07-01 1995-06-28 周希民 Polyurethane asphalt waterproof coating and its preparation method
CN101928518A (en) * 2009-06-19 2010-12-29 深圳市卓宝科技股份有限公司 Formula, preparation method and using method of bi-component fast-setting high polymer waterborne coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1104229A (en) * 1994-07-01 1995-06-28 周希民 Polyurethane asphalt waterproof coating and its preparation method
CN101928518A (en) * 2009-06-19 2010-12-29 深圳市卓宝科技股份有限公司 Formula, preparation method and using method of bi-component fast-setting high polymer waterborne coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113097489A (en) * 2021-04-01 2021-07-09 辽宁奥亿达新材料有限公司 Lithium ion battery carbon negative electrode liquid phase coating material, preparation and coating method
CN114716689A (en) * 2022-04-20 2022-07-08 安徽沃尔德新材料有限公司 Processing technology and device for anti-static biomass water-based acrylate raw material

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Application publication date: 20191203