CN110527372A - A kind of preparation and its application of elastic outer wall finishing material - Google Patents
A kind of preparation and its application of elastic outer wall finishing material Download PDFInfo
- Publication number
- CN110527372A CN110527372A CN201810499467.3A CN201810499467A CN110527372A CN 110527372 A CN110527372 A CN 110527372A CN 201810499467 A CN201810499467 A CN 201810499467A CN 110527372 A CN110527372 A CN 110527372A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- agent
- combinations
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
A kind of elastic outer wall finishing material, specifically, the material includes component A and component B, and the component A includes: the anti-pollution light filler of 100-800 parts by weight of purified water, the first thickener of 1-20 parts by weight, the wetting agent of 0.1-8 parts by weight, the dispersing agent of 1-200 parts by weight, the first defoaming agent of 0.2-20 parts by weight, the pH adjusting agent of 0.1-10 parts by weight, the antifreezing agent of 5-50 parts by weight, the pigment powder of 100-500 parts by weight, filler part of 20-300 parts by weight and 10-200 parts by weight.The component B includes: the lotion of 100-800 parts by weight, the coalescing agent of 1-30 parts by weight, the second defoaming agent of 0.2-20 parts by weight, the dry film mildew-resistant algae-resistant agent of 0.5-20 parts by weight, the in-can preservative of 0.1-5 parts by weight, the second thickener of 0.5-20 parts by weight, 5-300 parts by weight pure water.Elastic outer wall finishing material of the invention has the characteristics that stain resistance is by force and at low cost.
Description
Technical field
The present invention relates to paint fields, and in particular to a kind of elastic outer wall finishing material.
Background technique
With the deterioration of environment, acid rain and ultraviolet light and environmental pollution are also increasingly heavier, various dust in atmosphere and
Smog pollution with oiliness, all can the external wall elastic coating to building have an impact.Wherein, quite a few exterior wall latex paint
Be not as paint film degradation, dusting and lose use value, but because surface is heavily polluted, it appears that very dirty and lose beauty
It sees decorative.This is also exterior wall paint, especially one of the major obstacle of elastic coating popularization and application.Coating stain resistant ability is not only
It is the generally existing common problem of external wall elastic coating and exterior coating and some other exterior wall finish coating such as ceramic tile,
Important weakness when stone material etc. competes.Due to as many as the influence factor of stain resistant, solution is complicated, does not have for a long time
There is an effective universal method, therefore becomes a big technical problem of puzzlement industry circle.
Due to the cost issues that additionally generate such as cleaning of the decline of global air quality and wall face, developed country is also gradually
Pay attention to the stain resistant problem of exterior wall paint, they are using the stain resistance of exterior coating as the key index of assessment exterior wall paint.
The finishing coat that exploitation is not easy to adhere to pollutant has been used as each major company and research institution's research and development focus.Therefore, this project, which is applied, contains
Silicon coating makes pollutant be difficult to infiltrate through in paint film, while the ductility of paint film can be made unaffected again, largely prolongs
The service life for having grown paint film avoids waste caused by the multiple recoating because of product, this is also the development of whole building decoration industry
Eager demand.How to reduce pollutant is the key that solve exterior coating antifouling property to the pollution of building surface.
To sum up, there is an urgent need in the art to develop one kind, to have both stain resistance strong, from a wealth of sources, cheap, at low cost etc.
The elastic outer wall finishing material of function.
Summary of the invention
It is an object of the invention to develop one kind to have both that stain resistance is strong, the functions such as from a wealth of sources, cheap, at low cost
Elastic outer wall finishing material.
A kind of elastic outer wall finishing material of first aspect present invention, which is characterized in that the material includes component A and group
Divide B,
The component A includes:
The component B includes:
Wherein, the weight ratio of the component A and component B is 1-3:1.
In another preferred example, the component A includes:
The component B includes:
In another preferred example, wherein the weight ratio of the component A and component B is 1:1.
In another preferred example, anti-pollution light filler is selected from the group: siliceous light filler, organic composite silicon-containing filler or combinations thereof.
In another preferred example, the component A has the feature that
(i) the first thickener described in is cellulose thickener, and first thickener is selected from the group: methyl is fine
Tie up element, hydroxypropyl methyl cellulose, sodium carboxymethylcellulose, hydroxyethyl cellulose or combinations thereof；And/or
(ii) wetting agent described in is non-ionic wetting agent, and the wetting agent is selected from the group: ethylene oxide epoxy
Propane block copolymerization, phosphoric acid copolymer or combinations thereof；And/or
(iii) dispersing agent described in is selected from the group: ammonium salt dispersing agent, sodium salt dispersing agent, macromolecule dispersing agent or combinations thereof；
And/or
(iv) the first defoaming agent described in is selected from the group: mineral oil defoaming agent, organic silicon defoaming agent, polyethers defoaming
The combination of agent internal heat；And/or
(v) pH adjusting agent described in is multifunction amine auxiliary agent, and the pH adjusting agent is selected from the group: AMP-95,
VANTEX-T, BS-16 or combinations thereof；And/or
(vi) antifreezing agent described in is selected from the group: propylene glycol, ethylene glycol or combinations thereof；And/or
(vii) the pigment powder described in is selected from the group: titanium dioxide, kaolin or combinations thereof；And/or
(viii) the filler powder described in is selected from the group: Paris white, mica powder or combinations thereof.
In another preferred example, the ammonium salt dispersing agent is selected from: co-poly carboxylic acid ammonium salt dispersing agent, the dispersion of ammonium acrylate salt
Agent or combinations thereof.
In another preferred example, the sodium salt dispersing agent is selected from: co-poly carboxylic acid sodium salt dispersing agent, Sodium Polyacrylate salinity
Powder or combinations thereof.
In another preferred example, the high-molecular type dispersing agent is selected from: maleic anhydride of styrene, maleic anhydride and
Copolymer of diisobutylene or combinations thereof.
In another preferred example, the mica powder is white mica powder.
In another preferred example, the mica powder is 500-1500 mesh mica powder.
In another preferred example, the Paris white is 200-1500 mesh Paris white, preferably 500-1200 mesh carbon
Sour calcium powder, most preferably 700-1000 mesh Paris white.
In another preferred example, the filler powder includes:
Paris white 30-200 parts by weight；With
Mica powder 10-150 parts by weight.
In another preferred example, the filler powder includes:
Paris white 100-150 parts by weight；With
Mica powder 20-70 parts by weight.
In another preferred example, the component B has the feature that
(I) lotion described in is selected from the group: acrylate and vinyl acetate emulsion, pure-acrylic emulsion, the third silicon emulsion, styrene-acrylic emulsion or combinations thereof；With/
Or
(II) coalescing agent described in is selected from the group: Lauryl Alcohol ester, Coaso1290, DPnB or combinations thereof；And/or
(III) the second defoaming agent described in is selected from the group: mineral oil defoaming agent, organic silicon defoaming agent, polyethers disappear
Infusion or combinations thereof；And/or
(IV) the dry film mildew-resistant algae-resistant agent described in is selected from the group: benzimidazole methyl carbamate class dry film mildew-resistant algae-resistant
Agent, 2- n-octyl -4- isothiazole -3- ketone dry film mildew-resistant algae-resistant agent or combinations thereof；And/or
(V) in-can preservative described in is fungicide in tank；And/or
(VI) the second thickener described in is selected from the group: polyurethanes thickener, alkali soluble are swollen class thickener or combinations thereof.
Second aspect of the present invention provide it is a kind of prepare elastic outer wall finishing material method, the method comprising steps of
(1) the first mixture and the second mixture are provided, wherein
The preparation that first mixture is under the first stirring condition comprising steps of mix the component A；
The preparation of second mixture under the second stirring condition comprising steps of mix the component B；And
(2) second mixture is added in first mixture under third stirring condition, wherein described
The first mixture and the second mixture weight ratio be 1-3:1.
In another preferred example, the weight ratio of first mixture and the second mixture is 1:1.
In another preferred example, the revolving speed 400-8000r/min of first stirring condition, second stirring condition
Revolving speed 1200-1800r/min, the revolving speed 500-1000r/min of the third stirring condition.
Third aspect present invention provides a kind of anti-pollution new technology of elastic outer wall finishing material, and the technology includes step
It is rapid:
(A) elastic outer wall finishing material is diluted with water, to obtain dilution property stain resistant material, and the elasticity
The weight ratio of exterior wall finish material and water are as follows: 1:1-5；And
(B) the dilution stain resistant material for obtaining step A coats metope.
Fourth aspect present invention provides a kind of anti-pollution film, and the anti-pollution film is by elastic outer wall finishing material in substrate
Upper coating obtains.
Fifth aspect present invention provides a kind of product, and the product includes: substrate；And anti-pollution film.
It should be understood that above-mentioned each technical characteristic of the invention and having in below (eg embodiment) within the scope of the present invention
It can be combined with each other between each technical characteristic of body description, to form a new or preferred technical solution.As space is limited, In
This no longer tires out one by one states.
Specific embodiment
The present inventor's in-depth study by long-term, it has unexpectedly been found that using the formula of specific composition, while using one
A kind of elastic outer wall finishing material for the functions such as stain resistance is strong can be made in fixed anti-pollution light filler.Specifically, the present inventor
Using anti-pollution light filler, have the characteristics that stain resistance, tensile strength are big and elongation at break is high.On this basis, it invents
People completes the present invention.
Term:
In the present invention, term " containing " or " comprising " indicate that various composition can be applied to mixture or group of the invention together
It closes in object.Therefore, term " mainly by ... form " and " consist of " are included in term " containing " or " comprising ".
Term " JG/T 172-2014 ": elastic building paint.Suitable for using synthetic resin emulsion as base-material, with pigment, fill out
Elastic building paint that material and auxiliary agent etc. are formulated is, it is specified that the term and definition of elastic building paint, classification, requirement, examination
Proved recipe method, inspection rule, mark, packaging, transport, storage.
A kind of elastic outer wall finishing material
A kind of elastic outer wall finishing material includes component A and component B,
The component A includes:
The component B includes:
Wherein, the weight ratio of the component A and component B is 1-3:1.
Typically, the component A includes:
The component B includes:
Wherein the weight ratio of the component A and component B is 1:1.
The component A has the feature that
(i) the first thickener described in is cellulose thickener, and first thickener is selected from the group: methyl is fine
Tie up element, hydroxypropyl methyl cellulose, sodium carboxymethylcellulose, hydroxyethyl cellulose or combinations thereof；And/or
(ii) wetting agent described in is non-ionic wetting agent, and the wetting agent is selected from the group: ethylene oxide epoxy
Propane block copolymerization, phosphoric acid copolymer or combinations thereof；And/or
(iii) dispersing agent described in is selected from the group: ammonium salt dispersing agent, sodium salt dispersing agent, macromolecule dispersing agent or combinations thereof；
And/or
(iv) the first defoaming agent described in is selected from the group: mineral oil defoaming agent, organic silicon defoaming agent, polyethers defoaming
The combination of agent internal heat；And/or
(v) pH adjusting agent described in is multifunction amine auxiliary agent, and the pH adjusting agent is selected from the group: AMP-95,
VANTEX-T, BS-16 or combinations thereof；And/or
(vi) antifreezing agent described in is selected from the group: propylene glycol, ethylene glycol or combinations thereof；And/or
(vii) the pigment powder described in is selected from the group: titanium dioxide, kaolin or combinations thereof；And/or
(viii) the filler powder described in is selected from the group: Paris white, mica powder or combinations thereof；And/or
(ix) the anti-pollution light filler described in is selected from the group: siliceous light filler, organic composite silicon-containing filler or combinations thereof.
The ammonium salt dispersing agent is selected from: co-poly carboxylic acid ammonium salt dispersing agent, ammonium acrylate dipersant or combinations thereof.
The sodium salt dispersing agent is selected from: co-poly carboxylic acid sodium salt dispersing agent, Sodium Polyacrylate dipersant or combinations thereof.
The high-molecular type dispersing agent is selected from: the copolymerization of maleic anhydride of styrene, maleic anhydride and diisobutylene
Object or combinations thereof.
The mica powder is white mica powder, preferably, the mica powder is 500-1500 mesh mica powder.
The Paris white is 200-1500 mesh Paris white, preferably 500-1200 mesh Paris white, most preferably
700-1000 mesh Paris white.
The filler powder includes:
Paris white 30-200 parts by weight；With
Mica powder 10-100 parts by weight.
Specifically, the filler powder includes:
Paris white 50-200 parts by weight；With
Mica powder 20-70 parts by weight.
The component B has the feature that
(I) lotion described in is selected from the group: acrylate and vinyl acetate emulsion, pure-acrylic emulsion, the third silicon emulsion, styrene-acrylic emulsion or combinations thereof；With/
Or
(II) coalescing agent described in is selected from the group: Lauryl Alcohol ester, Coaso1290, DPnB or combinations thereof；And/or
(III) the second defoaming agent described in is selected from the group: mineral oil defoaming agent, organic silicon defoaming agent, polyethers disappear
Infusion or combinations thereof；And/or
(IV) the dry film mildew-resistant algae-resistant agent described in is selected from the group: benzimidazole methyl carbamate class dry film mildew-resistant algae-resistant
Agent, 2- n-octyl -4- isothiazole -3- ketone dry film mildew-resistant algae-resistant agent or combinations thereof；And/or
(V) in-can preservative described in is fungicide in tank；And/or
(VI) the second thickener described in is selected from the group: polyurethanes thickener, alkali soluble are swollen class thickener or combinations thereof.
Preparation method
Elastic outer wall finishing material of the invention, preparation method comprising steps of
(1) the first mixture and the second mixture are provided, wherein
The preparation that first mixture is comprising steps of mix the component A under agitation；
The preparation of second mixture comprising steps of mix the component B under agitation；And
(2) under agitation, second mixture is added in first mixture, wherein described
The weight ratio of first mixture and the second mixture is 1-3:1.
Wherein, the weight ratio of first mixture and the second mixture is 1:1.
Anti-pollution new technology
A kind of anti-pollution new technology of elastic outer wall finishing material comprising steps of
(A) elastic outer wall finishing material is diluted with water, to obtain dilution property stain resistant material, and the elasticity
The weight ratio of exterior wall finish material and water are as follows: 1:1-5；And
(B) the dilution stain resistant material for obtaining step A coats metope
A kind of anti-pollution film
A kind of anti-pollution film, typically, the anti-pollution film is by elastic outer wall finishing material of the invention on substrate
Coating obtains, and, anti-pollution film of the invention has the feature that
(a) stain resistance≤16；
(b) elongation at break >=150%；
(c) tensile strength >=2MPa.
A kind of product,
A kind of product, typically, the product include: substrate；And anti-pollution film.
Invention advantage
(1) exterior wall finish material stain resistance is effectively improved.
(2) elasticity of effective guarantee exterior wall finish material.
(3) water imbibition of exterior wall finish material is effectively reduced.
(4) the hard feature of exterior wall finish texture material is effectively played.
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.In the following examples, the experimental methods for specific conditions are not specified, usually according to conventional strip
Part, or according to the normal condition proposed by manufacturer.Unless otherwise stated, otherwise percentage and number are calculated by weight.
Embodiment 1
By the pure water of 17 parts by weight, the hydroxyethyl cellulose 250HBR of 0.35 parts by weight, 0.2 parts by weight (non-ionic)
Dispersing agent (0.2 parts by weight sodium salt SN-DISPERSANT 5040 and the 0.5 parts by weight ammonium salt of LCN070 wetting agent, 0.7 parts by weight
It is special good scatteredTMCA 2500), 154 defoaming agent of SN-DEFOAMER (mineral oils) of 0.2 parts by weight, 0.1 parts by weight AMP-
95PH regulator (multifunction amine), the titanium dioxide (rutile-type 500 of the antifreezing agents (propylene glycol) of 0.9 parts by weight, 18 parts by weight
Mesh), the mica powder (1250 mesh of white mica powder) of 5 parts by weight, the Paris white (ultra-fine calcite in powder, 700 mesh) of 12 parts by weight, 2
Pre- slurry is made in 15 minutes in high speed dispersion (1500r/min) after mixing for the anti-pollution light filler of parts by weight.
Pre- slurry after the completion of the dispersion then film forming with the pure-acrylic emulsion of 32 parts by weight (BLJ-9468), 0.5 parts by weight
Auxiliary agent (Lauryl Alcohol ester), 246 defoaming agent of DISPELAIR CF (mineral oils) of 0.2 parts by weight, 0.5 parts by weight dry film
Mildew and algae agent (Kathon CG mould inhibitor), 0.1 parts by weight 623A tank in fungicide, 0.3 parts by weight RM-8W polyurethane thickening
Agent, 9.95 parts by weight pure water continue to stir at low speed, mix (800r/min), until uniformly.
It tests according to JG/T 172-2014, the results are shown in Table 1, all meets the requirements.
Table 1
Embodiment 2
By the pure water of 15 parts by weight, the hydroxyethyl cellulose 250HBR of 0.38 parts by weight, 0.1 parts by weight AMP-95PH tune
It saves agent (multifunction amine), (0.3 parts by weight sodium salt spy dissipates well the dispersing agent of 0.7 parts by weightTM731A and 0.4 parts by weight ammonium salt
FLOSPERSE XA450), the wetting agent COLORSPERSE 188-A (non-ionic) of 0.1 parts by weight, 0.2 parts by weight
DISPELAIR CF 1551 (organic silicon), the propylene glycol antifreezing agent of 0.8 parts by weight, 20 parts by weight titanium dioxide (rutile-type
500 mesh), the mica powder (1250 mesh of white mica powder) of 7 parts by weight, 13 parts by weight Paris white (ultra-fine calcite in powder, 1000
Mesh), pre- slurry is made in 15 minutes in high speed dispersion (1500r/min) after mixing for the lightweight anti-pollution fillers of 1 parts by weight.
Pre- slurry after the completion of dispersion then with the pure-acrylic emulsion of 30 parts by weight (Yi Ren reaches TM2468M), 1.0 parts by weight
Coalescing agent (Lauryl Alcohol ester), 334 defoaming agent of DEFOAMER (mineral oils) of 0.2 parts by weight, 0.2 parts by weight AA
2316 dry film mildew-resistant algae-resistant agent, 0.1 parts by weight BIOX CM tank in fungicide, 1 parts by weight the poly- ammonia of ACRYSOL RM-2020
Ester thickener, 6.22 parts by weight pure water continue to stir at low speed, mix (800r/min), until uniformly.
It tests according to JG/T 172-2014, the results are shown in Table 2, all meets the requirements.
Table 2
Data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%.
Embodiment 3
By the pure water of 15 parts by weight, hydroxyethyl cellulose NATROSOL 250MBR of 0.20 parts by weight, 0.25 parts by weight
Dispersing agent (0.2 parts by weight TAMOL 731DP sodium salt and 0.3 parts by weight of BS-16PH regulator (multifunction amine), 0.5 parts by weight
885 ammonia salt of LOPON), the wetting agent LTRITON CF-10 (non-ionic) of 0.3 parts by weight, 0.15 parts by weight defoaming agent
FOAMASTER 2380 (organic silicon), the ethylene glycol antifreeze of 0.9 parts by weight, 18 parts by weight titanium dioxide (rutile-type 500
Mesh), the mica powder (1250 mesh of white mica powder) of 2 parts by weight, 8 parts by weight Paris white (ultra-fine calcite in powder, 700 mesh), 3 weights
Pre- slurry is made in 15 minutes in high speed dispersion (1500r/min) after mixing for the anti-pollution light filler of amount part.
Pre- slurry after the completion of dispersion is then newborn with " RS-9689AS " phenylpropyl alcohol of 38 parts by weight Ahmedabad richness Industrial Co., Ltd.s
Liquid, the coalescing agent (COASOL) of 0.8 parts by weight, the defoaming agent (mineral oils) of 0.2 parts by weight FOAMASTER 2380,0.5
Fungicide, 0.8 in the mould algaecides of 248 dry film of AA of parts by weight, the 623A of 0.08 parts by weight and the BT NV2 tank of 0.2 parts by weight
ACRYSOL RL-275 of parts by weight, 11.62 parts by weight pure water continue to stir at low speed, mix (800r/min), until uniformly.
It tests according to JG/T 172-2014, the results are shown in Table 3, all meets the requirements.
Table 3
Data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%.
Comparative example 1
By the pure water of 15 parts by weight, the hydroxyethyl cellulose 250HBR of 0.38 parts by weight, 0.1 parts by weight AMP-95PH tune
It saves agent (multifunction amine), (0.3 parts by weight sodium salt spy dissipates well the dispersing agent of 0.7 parts by weightTM731A and 0.4 parts by weight ammonium salt
FLOSPERSE XA450), the wetting agent COLORSPERSE 188-A (non-ionic) of 0.1 parts by weight, 0.2 parts by weight
DISPELAIR CF 1551 (organic silicon), the propylene glycol antifreezing agent of 0.8 parts by weight, 20 parts by weight titanium dioxide (rutile-type
500 mesh), the mica powder (1250 mesh of white mica powder) of 7 parts by weight, 13 parts by weight Paris white (ultra-fine calcite in powder, 1000
Mesh) after mixing high speed dispersion (1500r/min) pre- slurry is made within 15 minutes.
Pre- slurry after the completion of the dispersion then cream with the pure-acrylic emulsion of 30 parts by weight (Yi Ren reaches TM2468M), 3 parts by weight
DEFOAMER334 defoaming agent (the mineral oil of liquid polymer, the coalescing agent (Lauryl Alcohol ester) of 1.0 parts by weight, 0.2 parts by weight
Class), the 2316 dry film mildew-resistant algae-resistant agent of AA of 0.2 parts by weight, 0.1 parts by weight BIOX CM tank in fungicide, 1 parts by weight
ACRYSOL RM-2020 polyurethane thickener, 6.22 parts by weight pure water continue to stir at low speed, mix (800r/min), until
Uniformly.
It tests according to JG/T 172-2014, the results are shown in Table 4, all meets the requirements.
Table 4
Data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%.
Anti-pollution light filler is not added in comparative example 1, stain resistance is deteriorated, unqualified.
Comparative example 2
By the pure water of 15 parts by weight, hydroxyethyl cellulose NATROSOL 250MBR of 0.20 parts by weight, 0.25 parts by weight
Dispersing agent (0.2 parts by weight TAMOL 731DP sodium salt and 0.3 parts by weight of BS-16PH regulator (multifunction amine), 0.5 parts by weight
885 ammonia salt of LOPON), the wetting agent LTRITON CF-10 (non-ionic) of 0.3 parts by weight, 0.15 parts by weight defoaming agent
FOAMASTER 2380 (organic silicon), the ethylene glycol antifreeze of 0.9 parts by weight, 18 parts by weight titanium dioxide (rutile-type 500
Mesh), the mica powder (1250 mesh of white mica powder) of 2 parts by weight, 8 parts by weight Paris white (ultra-fine calcite in powder, 700 mesh) mixing
Pre- slurry is made in 15 minutes in high speed dispersion (1500r/min) after uniformly.
Pre- slurry after the completion of dispersion is then newborn with " RS-9689AS " phenylpropyl alcohol of 38 parts by weight Ahmedabad richness Industrial Co., Ltd.s
Liquid, the coalescing agent (COASOL) of 0.8 parts by weight, the defoaming agent (mineral oils) of 0.2 parts by weight FOAMASTER 2380,0.5
Fungicide, 0.8 in the mould algaecides of 248 dry film of AA of parts by weight, the 623A of 0.08 parts by weight and the BT NV2 tank of 0.2 parts by weight
ACRYSOL RL-275 of parts by weight, 11.62 parts by weight pure water continue to stir at low speed, mix (800r/min), until uniformly.
It tests according to JG/T 172-2014, as a result as shown in table 5 below, all meets the requirements.
Table 5
Data are 23 DEG C ± 2 DEG C of temperature, the measured value under the conditions of humidity 50% ± 5%.
Anti-pollution light filler is not added in comparative example 2, stain resistance is deteriorated, unqualified.
All references mentioned in the present invention is incorporated herein by reference, independent just as each document
It is incorporated as with reference to such.In addition, it should also be understood that, after reading the above teachings of the present invention, those skilled in the art can
To make various changes or modifications to the present invention, such equivalent forms equally fall within model defined by the application the appended claims
It encloses.
Claims (10)
1. a kind of elastic outer wall finishing material, which is characterized in that the material includes component A and component B,
The component A includes:
The component B includes:
Wherein, the weight ratio of the component A and component B is 1-3:1.
2. elastic outer wall finishing material as described in claim 1, which is characterized in that the component A has the feature that
(i) the first thickener described in is cellulose thickener, and first thickener is selected from the group: Methyl cellulose
Element, hydroxypropyl methyl cellulose, sodium carboxymethylcellulose, hydroxyethyl cellulose or combinations thereof；And/or
(ii) wetting agent described in is non-ionic wetting agent, and the wetting agent is selected from the group: ethylene oxide propylene oxide
Block copolymerization, phosphoric acid copolymer or combinations thereof；And/or
(iii) dispersing agent described in is selected from the group: ammonium salt dispersing agent, sodium salt dispersing agent, macromolecule dispersing agent or combinations thereof；With/
Or
(iv) the first defoaming agent described in is selected from the group: mineral oil defoaming agent, organic silicon defoaming agent, polyethers defoaming agent fire
Gas combination；And/or
(v) pH adjusting agent described in is multifunction amine auxiliary agent, and the pH adjusting agent is selected from the group: AMP-95, VANTEX-T,
BS-16 or combinations thereof；And/or
(vi) antifreezing agent described in is selected from the group: propylene glycol, ethylene glycol or combinations thereof；And/or
(vii) the pigment powder described in is selected from the group: titanium dioxide, kaolin or combinations thereof；And/or
(viii) the filler powder described in is selected from the group: Paris white, mica powder or combinations thereof.
3. elastic outer wall finishing material as described in claim 1, which is characterized in that the anti-pollution light filler is selected from down
Group: siliceous light filler, organic composite silicon-containing filler or combinations thereof.
4. elastic outer wall finishing material as described in claim 1, which is characterized in that the filler powder includes:
Paris white 30-200 parts by weight；With
Mica powder 10-150 parts by weight.
5. elastic outer wall finishing material as described in claim 1, which is characterized in that the component B has the feature that
(I) lotion described in is selected from the group: acrylate and vinyl acetate emulsion, pure-acrylic emulsion, the third silicon emulsion, styrene-acrylic emulsion or combinations thereof；And/or
(II) coalescing agent described in is selected from the group: Lauryl Alcohol ester, Coaso1290, DPnB or combinations thereof；And/or
(III) the second defoaming agent described in is selected from the group: mineral oil defoaming agent, organic silicon defoaming agent, polyethers defoaming agent
Or combinations thereof；And/or
(IV) the dry film mildew-resistant algae-resistant agent described in is selected from the group: the agent of benzimidazole methyl carbamate class dry film mildew-resistant algae-resistant, 2-
N-octyl -4- isothiazole -3- ketone dry film mildew-resistant algae-resistant agent or combinations thereof；And/or
(V) in-can preservative described in is fungicide in tank；And/or
(VI) the second thickener described in is selected from the group: polyurethanes thickener, alkali soluble are swollen class thickener or combinations thereof.
6. a kind of preparation method of the elastic outer wall finishing material as described in claim 1-5 any one, which is characterized in that described
Method comprising steps of
(1) the first mixture and the second mixture are provided, wherein
The preparation that first mixture is under the first stirring condition comprising steps of mix the component A；
The preparation of second mixture under the second stirring condition comprising steps of mix the component B；And
(2) second mixture is added in first mixture under third stirring condition, wherein described the
The weight ratio of one mixture and the second mixture is 1-3:1.
7. the preparation method of elastic outer wall finishing material as claimed in claim 6, which is characterized in that first stirring condition
Revolving speed 400-8000r/min, the revolving speed 1200-1800r/min of second stirring condition, the revolving speed of the third stirring condition
500-1000r/min。
8. a kind of anti-pollution new technology of elastic outer wall finishing material, which is characterized in that the technology comprising steps of
(A) the elastic outer wall finishing material as described in claim 1-5 any one is diluted with water, to be diluted
Property stain resistant material, and the weight ratio of the elastic outer wall finishing material and water are as follows: 1:1-5；And
(B) the dilution stain resistant material for obtaining step A coats metope.
9. a kind of anti-pollution film, and be characterized in that, anti-pollution film elasticity as described in claim 1-5 any one is outer
Wall facing material is coated on substrate and is obtained.
10. a kind of product, which is characterized in that the product includes:
Substrate；And
Anti-pollution film as claimed in claim 9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810499467.3A CN110527372A (en) | 2018-05-23 | 2018-05-23 | A kind of preparation and its application of elastic outer wall finishing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810499467.3A CN110527372A (en) | 2018-05-23 | 2018-05-23 | A kind of preparation and its application of elastic outer wall finishing material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110527372A true CN110527372A (en) | 2019-12-03 |
Family
ID=68657522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810499467.3A Pending CN110527372A (en) | 2018-05-23 | 2018-05-23 | A kind of preparation and its application of elastic outer wall finishing material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110527372A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20090113513A (en) * | 2008-04-28 | 2009-11-02 | 주식회사 이파엘지종합특수방수 | A paint composition for repairing the outer wall and repair method by using of it |
| CN105086742A (en) * | 2015-07-31 | 2015-11-25 | 安徽和润特种玻璃有限公司 | High-tenacity wear-resisting coating film for mouse touch tablet glass |
| CN105462458A (en) * | 2015-12-02 | 2016-04-06 | 铜陵市肆得科技有限责任公司 | Special powder coating added with silica powder and applied to pump valve |
| CN107400397A (en) * | 2016-05-20 | 2017-11-28 | 立邦涂料（中国）有限公司 | A kind of new stain resistant water-based paint compositions and its preparation method and application |
| CN107760065A (en) * | 2017-09-22 | 2018-03-06 | 国网山东省电力公司电力科学研究院 | A kind of method of modifying of super-hydrophobic filler grain for antifouling flush paint and application |
-
2018
- 2018-05-23 CN CN201810499467.3A patent/CN110527372A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20090113513A (en) * | 2008-04-28 | 2009-11-02 | 주식회사 이파엘지종합특수방수 | A paint composition for repairing the outer wall and repair method by using of it |
| CN105086742A (en) * | 2015-07-31 | 2015-11-25 | 安徽和润特种玻璃有限公司 | High-tenacity wear-resisting coating film for mouse touch tablet glass |
| CN105462458A (en) * | 2015-12-02 | 2016-04-06 | 铜陵市肆得科技有限责任公司 | Special powder coating added with silica powder and applied to pump valve |
| CN107400397A (en) * | 2016-05-20 | 2017-11-28 | 立邦涂料（中国）有限公司 | A kind of new stain resistant water-based paint compositions and its preparation method and application |
| CN107760065A (en) * | 2017-09-22 | 2018-03-06 | 国网山东省电力公司电力科学研究院 | A kind of method of modifying of super-hydrophobic filler grain for antifouling flush paint and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106147441B (en) | Resistance to soiling water-based paint compositions | |
| CA2792151C (en) | Hybrid organic-inorganic nanocomposites | |
| CN104893242B (en) | Water base organic zinc rich paint composition forms the method and multilayer film of anti-rust coating | |
| CN102020905A (en) | One-component water-based semi-gloss varnish and preparation method thereof | |
| WO2007077879A1 (en) | Coating agent | |
| CN107849385A (en) | Strippable coating composition and its manufacture method | |
| CN107400397A (en) | A kind of new stain resistant water-based paint compositions and its preparation method and application | |
| CN103965669B (en) | A kind of aqueous fluorine-carbon paint | |
| CN103113796A (en) | Elastic antifouling aqueous fluorocarbon exterior wall paint | |
| CN108047839A (en) | A kind of aqueous inorganic environmental protection coating material and preparation method thereof | |
| AU2014237704B2 (en) | Superhydrophilic coating composition | |
| CN106978014A (en) | TiO 2 pigment grinding distribution body and paint | |
| CN107001844A (en) | Water-based paint compositions and its obtained method | |
| CN103965716A (en) | Water-based quick-drying acrylic acid protective coating and preparation method thereof | |
| CN102212298A (en) | Aqueous inner wall paint composition | |
| CN107001846A (en) | Water-based paint compositions and its method | |
| CN106833333B (en) | A kind of aqueous anti-doodling paint and preparation method thereof | |
| JP2010111793A (en) | Aqueous low stain coating | |
| CN103666155A (en) | Nano modified high-stain-resistance elastic paint | |
| CN110358391A (en) | A kind of quick-dry type water soluble acrylic acid container case mark paint and preparation method thereof | |
| CN104559593A (en) | Dustproof paint for inner wall of shell of dust collector | |
| CN108948832A (en) | A kind of graphene-antifouling fluorocarbon coating of silver antibacterial and its preparation method and application | |
| CN103740197A (en) | Modified acrylic acid high-efficient waterproof elastic coating | |
| KR102426609B1 (en) | High-performance paint or finishing material composition for interior construction with excellent harmful substances reduction and antibacterial performance by forming nano-sized micelles with ultrafine nano silica and acrylic resin, and its construction method | |
| JP2024028732A (en) | Air purification coating system and its production method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20210609 Address after: 287 Chuangye Road, South District, Jinqiao Export Processing Zone, Pudong New Area, Shanghai 201201 Applicant after: NIPPON PAINT (CHINA) Co.,Ltd. Applicant after: Nippon coatings (Hubei) Co.,Ltd. Address before: 287 Chuangye Road, South District, Jinqiao Export Processing Zone, Pudong New Area, Shanghai 201201 Applicant before: NIPPON PAINT (CHINA) Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191203 |
|
| RJ01 | Rejection of invention patent application after publication |