CN110527250A - A kind of epoxy resin cellar well lid and preparation method thereof using post-consumer glass fiber - Google Patents
A kind of epoxy resin cellar well lid and preparation method thereof using post-consumer glass fiber Download PDFInfo
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- CN110527250A CN110527250A CN201910675014.6A CN201910675014A CN110527250A CN 110527250 A CN110527250 A CN 110527250A CN 201910675014 A CN201910675014 A CN 201910675014A CN 110527250 A CN110527250 A CN 110527250A
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- Prior art keywords
- epoxy resin
- glass fabric
- well lid
- glass
- mass percentage
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D29/00—Independent underground or underwater structures; Retaining walls
- E02D29/12—Manhole shafts; Other inspection or access chambers; Accessories therefor
- E02D29/14—Covers for manholes or the like; Frames for covers
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D29/00—Independent underground or underwater structures; Retaining walls
- E02D29/12—Manhole shafts; Other inspection or access chambers; Accessories therefor
- E02D29/14—Covers for manholes or the like; Frames for covers
- E02D29/1472—Cover entirely made of synthetic material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Mining & Mineral Resources (AREA)
- Paleontology (AREA)
- Civil Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of epoxy resin cellar well lids and preparation method thereof using post-consumer glass fiber, component including mass percentage, glass fabric of epoxy resin 86-92.5%, calcium activated 6-12%, curing agent 1.5-2.8%, the glass fabric of epoxy resin include mass percentage glass fabric 60-80% and coating in the epoxy resin 20-40% on glass fabric.Cellar well lid of the invention and preparation method, component including mass percentage, glass fabric of epoxy resin 86-92.5%, calcium activated 6-12%, curing agent 1.5-2.8%, it avoids directly using formaldehyde, compared with prior art, the beneficial effect is that, it is recycled using the waste recovery of glass fibre, turn waste into wealth, improve the usage amount of post-consumer glass fiber, reduces the usage amount of epoxy resin.To reduce industrial cost, cellar well lid intensity height, wear-resisting acid-fast alkali-proof, fire-retardant, insulation, the comprehensive mechanical property produced are good, long service life.More importantly formaldehyde is not used, it is environmentally protective.
Description
Technical field
The present invention relates to a kind of epoxy resin cellar well lids and preparation method thereof using post-consumer glass fiber.
Background technique
Glass fibre is first is that being raw material through works such as high temperature melting, wire drawing, doff, woven fabrics using glass marble or post-consumer glass
Skill.Various product is eventually formed, the diameter of glass fiber single filament is equivalent to a head from several microns to twenties meters microns
The 1/20-1/5 of hair, every bundle fiber precursor is made of hundreds of even thousands of monofilament, usually as the increasing in multiple material
Strong material, electrically insulating material and heat-insulating material, circuit substrate etc. are widely used in national economy every field.
Epocel cloth is to be soaked with glass fabric using epoxy resin as ground, is formed through hot pressing.Epoxy resin mainly at
Part is phenolic resin；Phenolic resin be phenol and formaldehyde under catalysts conditions polycondensation, it is neutralized, washing and made of tree
Rouge, wherein being most important with phenol and formaldehyde resin.It is also the still critically important high score so far in the world earliest by artificial synthesized
Sub- material can be divided into two class of thermosetting property and thermoplasticity because selecting the difference of catalyst.Phenolic resin has good acid resistance
Energy, mechanical property, heat resistance are widely used in the industries such as anticorrosion engineering, adhesive, fire proofing, grinding wheel manufacture.
And the leftover pieces and dust that cellar well lid currently produced on the market generates in process of production are excessive, both produce dirt
Dye, and the health of worker is compromised, while intensity is lower, wear-resisting acid-fast alkali-proof is weaker, and service life is short, anti-flammability and insulation
Property is low, and comprehensive mechanical property is weaker.
A kind of glass-epoxy cellar well lid of earlier application and preparation method thereof, needs using excessive formaldehyde,
Harm can be generated to environment, so its production and using will be greatly limited.
Summary of the invention
The technical problem to be solved in the present invention is to provide one kind can be high using waste material production, intensity, and wear-resisting acid-fast alkali-proof makes
Long with the service life, anti-flammability and insulating properties are high, comprehensive mechanical property is strong, environment friendly and pollution-free glass-epoxy cellar well lid and
Preparation method.
The present invention is to solve the above problems, the technical solution provided, a kind of epoxy resin cellar using post-consumer glass fiber
Glass fabric of epoxy resin 86-92.5%, well lid calcium activated 6-12%, is consolidated as an improvement, including the component of mass percentage
Agent 1.5-2.8%, the glass fabric of epoxy resin include mass percentage glass fabric 60-80% and coating in glass
Epoxy resin 20-40% in glass fiber cloth.
The invention also discloses a kind of preparation methods for storing well lid, and steps are as follows,
Step 1, by the glass fabric of epoxy resin waste material dissection of mass percentage 86-92.5% at the fragment of 5-10cm,
It is put into blender and stirred, the curing agent of calcium activated, 1.5-2.8% that 6-12% is added is thoroughly mixed, the asphalt mixtures modified by epoxy resin
Rouge glass cloth includes mass percentage glass fabric 60-80% and coating in the epoxy resin 20- on glass fabric
40%.
Step 2, the mixture after step 1 is sufficiently stirred are put into hot pressing in corresponding well lid mold.
It is cooling to be put into upper and lower press mold by step 3 for molding cellar well lid after step 2 depanning.
As a further improvement, above-mentioned cellar well lid and preparation method, including mass percentage, glass fabric of epoxy resin
86-92.5%, calcium activated 6-12%, curing agent 1.5-2.8% and pigment powder 2.5-4.5%.
As a further improvement, above-mentioned cellar well lid and preparation method, including mass percentage, glass fabric of epoxy resin
90%, the pigment powder of calcium activated 8%, curing agent 1.8% and surplus.
As a further improvement, above-mentioned cellar well lid and preparation method, the glass fabric of epoxy resin includes quality hundred
Divide content glass fabric 60% and coating in the epoxy resin 40% on glass fabric.
As a further improvement, above-mentioned cellar well lid and preparation method, the glass fabric of epoxy resin includes quality hundred
Divide content glass fabric 70% and coating in the epoxy resin 30% on glass fabric.
As a further improvement, keeping temperature filler heat in the step two, after mold is first preheated 160-240 DEG C
Pressure；
As a further improvement, step 2 further includes, to filler is continued in the mold after hot pressing in step 2, step is inserted
The hot pressing depanning to after forming again of one mixture.
As a further improvement, hot pressing 10-20s in the step two, temperature heat is kept after filler again in step 3
Depanning is formed after pressure 10-15min.
As a further improvement, hot pressing pressure is 315-1000 tons in the step two.
As a further improvement, the upper and lower pressing mold is the plate with cellar well lid molding cooperation in the step three
Press mold.
As a further improvement, the upper and lower pressing mold is water cooling press mold.
Cellar well lid of the invention and preparation method, the component including mass percentage, glass fabric of epoxy resin 86-
92.5%, calcium activated 6-12%, curing agent 1.5-2.8%, avoid directly is had using formaldehyde compared with prior art
Beneficial effect is to be recycled using the waste recovery of glass fibre, turn waste into wealth, improve the usage amount of post-consumer glass fiber, dropped
The low usage amount of epoxy resin.To reducing industrial cost, the cellar well lid intensity produced is high, wear-resisting acid-fast alkali-proof,
Fire-retardant, insulation, comprehensive mechanical property are good, long service life.More importantly formaldehyde is not used, it is environmentally protective.
Following is present invention cellar well lid using the corresponding detection data of any component solutions test in summary of the invention.RJG-
1-Z-700 (thickness 5cm)
Test specification specification 1200*500*50mm (C250) co=500mm
Test specification 1000*500*50mm (C250) co=500mm
600*600*50mm (C250) co=600mm
Specific embodiment
Case study on implementation 1, a kind of epoxy resin cellar well lid using post-consumer glass fiber, the group including mass percentage
Point, glass fabric of epoxy resin 86-92.5%, calcium activated 6-12%, curing agent 1.5-2.8%, the glass fabric of epoxy resin
Including mass percentage glass fabric 60-80% and coating in the epoxy resin 20-40% on glass fabric.
Case study on implementation 2, the component including mass percentage, glass fabric of epoxy resin 86-92.5%, calcium activated 6-
12%, curing agent 1.5-2.8% further includes the pigment powder of surplus, and the component of pigment powder mass percentage is preferably 2.5-
4.5%, wherein glass fabric of epoxy resin includes mass percentage glass fabric 60-80% and coating in glass fabric
On epoxy resin 20-40%.
Case study on implementation 3, the component including mass percentage, glass fabric of epoxy resin 86%, calcium activated 12%, curing agent
2%, wherein glass fabric of epoxy resin includes mass percentage glass fabric 60% and coating in the ring on glass fabric
Oxygen resin 40%.
Case study on implementation 4, the component including mass percentage, glass fabric of epoxy resin 88%, calcium activated 10%, curing agent
2%, wherein glass fabric of epoxy resin includes mass percentage glass fabric 60% and coating in the ring on glass fabric
Oxygen resin 40%.
Case study on implementation 5, the component including mass percentage, glass fabric of epoxy resin 86%, calcium activated 11.2%, solidification
Agent 2.8%, wherein glass fabric of epoxy resin includes mass percentage glass fabric 60% and coating on glass fabric
Epoxy resin 40%.
Case study on implementation 6, the component including mass percentage, glass fabric of epoxy resin 92.5%, calcium activated 6%, solidification
Agent 1.5%, wherein glass fabric of epoxy resin includes mass percentage glass fabric 60% and coating on glass fabric
Epoxy resin 40%.
Case study on implementation 7, the component including mass percentage, glass fabric of epoxy resin 90.5%, are consolidated calcium activated 7.5%
Agent 2%, wherein glass fabric of epoxy resin includes mass percentage glass fabric 60% and coating on glass fabric
Epoxy resin 40%.
Case study on implementation 8, the component including mass percentage, glass fabric of epoxy resin 90.5%, calcium activated 8%, solidification
The pigment powder of agent 1.5% and surplus, wherein glass fabric of epoxy resin includes mass percentage glass fabric 60% and applies
Layer is in the epoxy resin 40% on glass fabric.
Case study on implementation 9, the component including mass percentage, glass fabric of epoxy resin 88%, calcium activated 6%, curing agent
1.5%, pigment powder 4.5%, wherein glass fabric of epoxy resin includes mass percentage glass fabric 60% and coating in glass
Epoxy resin 40% in glass fiber cloth.
Case study on implementation 10, the component including mass percentage: glass fabric of epoxy resin 90%, calcium activated 8%, curing agent
1.8% and surplus pigment powder.
Case study on implementation 11, on the basis of any one case of case study on implementation 2 or 10, wherein glass fabric of epoxy resin includes
Mass percentage glass fabric 70% and coating are in the epoxy resin 30% on glass fabric.
Case study on implementation 12, on the basis of any one case of case study on implementation 2 or 10, wherein glass fabric of epoxy resin includes
Mass percentage glass fabric 80% and coating are in the epoxy resin 20% on glass fabric.
Case study on implementation 13, on the basis of any one case of case study on implementation 2 or 10, wherein glass fabric of epoxy resin includes
Mass percentage glass fabric 70% and coating are in the epoxy resin 30% on glass fabric.The invention also discloses one
The preparation method of kind cellar well lid, steps are as follows,
Step 1, by the glass fabric of epoxy resin waste material dissection of mass percentage 86-92.5% at the fragment of 5-10cm,
It is put into blender and stirred, the curing agent of calcium activated, 1.5-2.8% that 6-12% is added is thoroughly mixed, the asphalt mixtures modified by epoxy resin
Rouge glass cloth includes mass percentage glass fabric 60-80% and coating in the epoxy resin 20- on glass fabric
40%.
Step 2, the mixture after step 1 is sufficiently stirred are put into hot pressing in corresponding well lid mold.
It is cooling to be put into upper and lower press mold by step 3 for molding cellar well lid after step 2 depanning.
Wherein, in the step two, the hot pressing of temperature filler is kept after mold is first preheated 160-240 DEG C.Step 2 is also
Including inserting mixture hot pressing depanning to after forming again of step 1 to filler is continued in the mold after hot pressing in step 2.
It can a hot pressing 10-15min molding depanning if it is well lid.It can continue filler hot pressing twice if it is pedestal.In step 2 just
Secondary hot pressing 10-20s, again after filler in keep temperature hot pressing 10-15min after filler again after form depanning.
Wherein, hot pressing pressure is 315-1000 tons in the step two.
Wherein, in the step three, the upper and lower pressing mold is the plate press mold with cellar well lid molding cooperation.Step
In three, the cellar well lid after depanning forms between the upper and lower pressing mold of plate, is further pressed cooling moulding.Upper and lower pressing mold is water
It is cold-pressed film and accelerates cooling speed especially by lasting circulating water flow through upper and lower press mold.
In the preparation method step 1 for storing well lid, glass fabric of epoxy resin, calcium activated, curing agent, surplus pigment powder
The glass fabric and coating that mass percentage and glass fabric of epoxy resin include mass percentage are on glass fabric
Epoxy resin scheme, can be used case study on implementation 1-13 any one scheme.
Claims (10)
1. a kind of epoxy resin using post-consumer glass fiber stores well lid, it is characterised in that: the component including mass percentage,
Glass fabric of epoxy resin 86-92.5%, calcium activated 6-12%, curing agent 1.5-2.8%, the glass fabric of epoxy resin include
Mass percentage glass fabric 60-80% and coating are in the epoxy resin 20-40% on glass fabric.
2. storing well lid using the epoxy resin of post-consumer glass fiber as described in claim 1, it is characterised in that: including quality hundred
Divide the component of content, glass fabric of epoxy resin 86-92.5%, calcium activated 6-12%, curing agent 1.5-2.8%, pigment powder 2.5-
4.5%.
3. storing well lid using the epoxy resin of post-consumer glass fiber as claimed in claim 1 or 2, it is characterised in that: including matter
Measure the component of percentage composition: glass fabric of epoxy resin 90%, calcium activated 8%, curing agent 1.8% and surplus pigment powder.
4. storing well lid using the epoxy resin of post-consumer glass fiber as described in claim 1, it is characterised in that: the epoxy
Plexiglas cloth includes mass percentage glass fabric 60% and coating in the epoxy resin 40% on glass fabric.
5. storing well lid using the epoxy resin of post-consumer glass fiber as described in claim 1, it is characterised in that: the epoxy
Plexiglas cloth includes mass percentage glass fabric 70% and coating in the epoxy resin 30% on glass fabric.
6. a kind of preparation method for storing well lid, it is characterised in that: steps are as follows,
Step 1 is put by the glass fabric of epoxy resin waste material dissection of mass percentage 86-92.5% at the fragment of 5-10cm
Blender stirring, the curing agent of calcium activated, 1.5-2.8% that 6-12% is added are thoroughly mixed, the epoxy resin glass
Glass cloth includes mass percentage glass fabric 60-80% and coating in the epoxy resin 20-40% on glass fabric；
Step 2, the mixture after step 1 is sufficiently stirred are put into hot pressing in corresponding well lid mold；
It is cooling to be put into upper and lower press mold by step 3 for molding cellar well lid after step 2 depanning.
7. the preparation method of cellar well lid as claimed in claim 6, it is characterised in that: in the step one, including quality hundred
Point content: glass fabric of epoxy resin 90%, calcium activated 8%, curing agent 1.8% and surplus pigment powder.
8. the preparation method of cellar well lid as claimed in claim 6, it is characterised in that: first preheat mold in the step two
The hot pressing of temperature filler is kept after 160-240 DEG C；Step 2 further includes, to filler is continued in the mold after hot pressing in step 2, filling out
Enter mixture hot pressing depanning to after forming again of step 1；First hot pressing 10-20s in the step two, again after filler
Depanning is formed after keeping temperature hot pressing 10-15min.
9. the preparation method of cellar well lid as claimed in claim 8, it is characterised in that: hot pressing pressure is in the step two
315-1000 tons.
10. the preparation method of cellar well lid as claimed in claim 4, it is characterised in that: in the step three, it is described it is upper,
Lower die is the plate press mold with cellar well lid molding cooperation；The upper and lower pressing mold is water cooling press mold.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910675014.6A CN110527250A (en) | 2019-07-25 | 2019-07-25 | A kind of epoxy resin cellar well lid and preparation method thereof using post-consumer glass fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910675014.6A CN110527250A (en) | 2019-07-25 | 2019-07-25 | A kind of epoxy resin cellar well lid and preparation method thereof using post-consumer glass fiber |
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| Publication Number | Publication Date |
|---|---|
| CN110527250A true CN110527250A (en) | 2019-12-03 |
Family
ID=68661947
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910675014.6A Pending CN110527250A (en) | 2019-07-25 | 2019-07-25 | A kind of epoxy resin cellar well lid and preparation method thereof using post-consumer glass fiber |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112708243A (en) * | 2020-12-25 | 2021-04-27 | 陈志良 | Environment-friendly epoxy resin manhole cover and preparation method thereof |
| CN112726795A (en) * | 2020-12-25 | 2021-04-30 | 陈志良 | Wear-resistant and compression-resistant light cellar well lid and preparation method thereof |
| CN113696365A (en) * | 2021-05-15 | 2021-11-26 | 吴家谅 | Method for manufacturing well cover grate by using cutting piece waste and phenolic resin |
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2019
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| US6070375A (en) * | 1996-09-20 | 2000-06-06 | Anderson; Justin J. | Frame for a wall opening and methods of assembly and use |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112708243A (en) * | 2020-12-25 | 2021-04-27 | 陈志良 | Environment-friendly epoxy resin manhole cover and preparation method thereof |
| CN112726795A (en) * | 2020-12-25 | 2021-04-30 | 陈志良 | Wear-resistant and compression-resistant light cellar well lid and preparation method thereof |
| CN113696365A (en) * | 2021-05-15 | 2021-11-26 | 吴家谅 | Method for manufacturing well cover grate by using cutting piece waste and phenolic resin |
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