CN110526632A - Foamslag based geopolymer material and preparation method thereof - Google Patents
Foamslag based geopolymer material and preparation method thereof Download PDFInfo
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- CN110526632A CN110526632A CN201910878901.3A CN201910878901A CN110526632A CN 110526632 A CN110526632 A CN 110526632A CN 201910878901 A CN201910878901 A CN 201910878901A CN 110526632 A CN110526632 A CN 110526632A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/006—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/10—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/10—Mortars, concrete or artificial stone characterised by specific physical values for the viscosity
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Abstract
The present invention relates to a kind of foamslag based geopolymer materials and preparation method thereof, and in terms of mass fraction, the raw material for preparing the foamslag based geopolymer material include: compound alkali-activator 15-30 parts, 30-40 parts of slag, 7-9 parts of the metakaolin of Calcination: Calcination, 4-6 parts of rice hull ash, 6-8 parts of portland cement, 15-20 parts of water, 0.1-0.3 parts of water-reducing agent, 0.5-0.6 parts of foaming agent, 0.2-0.4 parts of foam stabilizer, 1-3 parts of silane coupling agent, 0.1-0.4 parts of fluxing agent.Foamslag geopolymer of the invention is compared with traditional thermal insulation cement sill: foamslag geopolymer has intensity high, heat insulation property is good, density is smaller, durability is good and lower-price characteristic, the heat insulating coefficient for the foamslag based geopolymer material that the present invention invents are less than 0.05Wm‑1·K‑1, the 0.07Wm of far smaller than national standard GB/T26565-2011 " cement base insulation dry blend " requirement‑1·K‑1。
Description
Technical field
The present invention relates to geopolymer sill technical field more particularly to a kind of foamslag based geopolymer material and
Preparation method
Background technique
With energy sustainable development proposing, energy conservation project rapidly becomes focus concerned by people, according to incompletely statistics,
In total energy consumption all over the world there are about 30% be building energy consumption, it is even more.Building energy conservation refers in the base for meeting primary demand
It on plinth, in Building Design, builds, using effective measures come reasonable sharp resource in use process, and reduces energy consumption.For building
It builds for energy conservation, insulation product has become the hot spot of people's research, and it is heat-insulated that organic heat-insulating is mainly made in people at present
Material and inorganic heat preserving and heat insulation material two major classes.Its raw material of organic insulation material are the nonrenewable resources such as petroleum, need to close
Reason uses, and should not consume excessively, and keeps the temperature problem and do not obtain essence solution, and it is short that there are service lifes, stability difference and table
Face the features such as separately splitting and fall off, and inorganic heat preserving and heat insulation material has thermal coefficient larger, after water suction tool will affect its every
The features such as thermal effect and service life, energy-saving efficiency is lower, also significantly limits its application.Geopolymer is by aluminium silicon salt work
Industry waste or activated aluminosilicate mineral pass through depolymerization, one kind that polycondensation and gel network process are formed in strong base solution
The three-dimensional network gel rubber material connected by oxygen-octahedron and aluminum-oxygen tetrahedron by bridging oxygen has high temperature resistant, corrosion-resistant, resistance to
The advantages that freeze thawing, is widely used in airfield runway, communications service, and road and bridge is built and the fields such as reparation, therefore carries out one kind
It is extremely urgent that organic and inorganic keeps the temperature geopolymer.
Summary of the invention
In view of the deficiencies of the prior art, the object of the present invention is to provide a kind of foamslag based geopolymer material and its systems
Preparation Method, the material have the advantages that good heat insulating, hole is high, and intensity is high.
In order to achieve the above objectives, one aspect of the present invention provides a kind foamslag based geopolymer material, feature
It is: includes following component in terms of mass fraction: compound alkali-activator 15-30 parts, 30-40 parts of slag, the metakaolin of calcining
7-9 parts, 4-6 parts of rice hull ash, 6-8 parts of portland cement, 15-20 parts of water, 0.1-0.3 parts of water-reducing agent, 0.5-0.6 parts of foaming agent,
0.2-0.4 parts of foam stabilizer, 1-3 parts of silane coupling agent, 0.1-0.4 parts of fluxing agent.
Preferably, the slag is using sieve method by ball ball mill ball milling 24-48 hours, so that average grain diameter
For 0.096-0.105mm；
The preparation process of the metakaolin of the calcining is as follows: the temperature lower calcination 15- by kaolinite at 750 DEG C -850 DEG C
Then 20h is ground, screening makes its partial size 150-200nm；
The preparation process of the rice hull ash is as follows: the temperature lower calcination 6-8h by rice husk at 700 DEG C -800 DEG C, the rice husk
The partial size of ash is 100-200nm；
The compound alkali-activator is the compound alkali-activator of salt-alkali using sodium sulphate and sodium metasilicate, sodium sulphate and silicic acid
The weight mass ratio of sodium is 0.11-0.15:1；
The foaming agent is lauryl sodium sulfate, and solid content is 20~24%；
The foam stabilizer is the mixture using neopelex and triethanolamine, neopelex
Mass ratio with triethanolamine is 0.55-0.36:1；
The fluxing agent is the agar hydrosol, and solid content is 80-90%；
The ordinary portland cement is 42.5R ordinary portland cement；
The water-reducing agent is polycarboxylic acids dehydragent, the 0.6-1.0 of mass parts gross weight；
The silane coupling agent is NH2CH2CH2CH2Si(OC2H5)3Or/and CH2-CH(OCH2-O(CH2)3Si(OCH3)3。
Two aspect of the present invention provides a kind of preparation method for preparing above-mentioned foamslag based geopolymer material, feature
It is: includes the following steps:
(1) compound alkali-activator 15-30 parts are weighed in terms of mass fraction, 30-40 parts of slag, the metakaolin 7-9 of calcining
Part, 4-6 parts of rice hull ash, 6-8 parts of portland cement, 15-20 parts of water, 0.1-0.3 parts of water-reducing agent, 0.5-0.6 parts of foaming agent, foam stabilizing
0.2-0.4 parts of agent, 1-3 parts of silane coupling agent, 0.1-0.4 parts of fluxing agent；
(2) above-mentioned slag, the metakaolin of calcining, rice hull ash, foam stabilizer, water-reducing agent and portland cement are put into casserole
Interior ball milling, Ball-milling Time 25-30h, obtains premix；The premix and silane coupling agent, compound alkali-activator, water are mixed
It closes uniformly, mixing time 2-4min；
(3) foaming agent is added into above-mentioned slurry, mechanical stirring makes it completely dissolved, and then quickly stirs and obtains a large amount of
Foam, persistently stir 3-5min, foam slurry, i.e. foamslag based geopolymer material obtained after stablizing.
Foamslag based geopolymer material of the invention and traditional curing materials, have the advantage that
(1) foamslag based geopolymer material of the invention is using industrial slag, the wastes such as flyash and rice
The agricultural wastes such as shell ash, not only can solve trade waste and agricultural wastes concentrate the problem of stacking, and can also exempt
" two mills one are burnt " technique, energy-saving and emission-reduction in cement production process.
(2) foamslag based geopolymer of the invention can reduce cost, and solid waste is made to get utilization,
Obtain good economic benefit.
(3) foamslag based geopolymer material of the invention has good heat insulating, and porosity is high, and intensity is high, durable
The advantages that performance is good.
(4) preparation method of foamslag based geopolymer material of the invention is simple, easy to spread.
Other features and advantages of the present invention will then part of the detailed description can be specified.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
In following case study on implementation, the dosage number of foamslag based geopolymer material each component is mass parts: with
Mass fraction meter, compound alkali-activator 15-30 parts, 30-40 parts of slag, 7-9 parts of the metakaolin of calcining, 4-6 parts of rice hull ash, silicon
6-8 parts of acid salt cement, 15-20 parts of water, 0.1-0.3 parts of water-reducing agent, 0.5-0.6 parts of foaming agent, 0.2-0.4 parts of foam stabilizer, silane
1-3 parts of coupling agent, 0.1-0.4 parts of fluxing agent.
Compound alkali-activator used in following embodiment by sodium sulphate and sodium metasilicate the compound alkali-activator group of salt-alkali
At mass ratio 0.11-0.15:1；The partial size of rice hull ash is 100-200nm；The average grain diameter of slag is in 0.096-0.105mm
Between；The average grain diameter of the metakaolin of calcining is 150-200nm；The solid content of lauryl sodium sulfate is 20%~24%；
The mass ratio of neopelex and triethanolamine is 0.55-0.36:1；Portland cement is 42.5R normal silicate
Cement；The solid content of the agar hydrosol is 80-90%；Polycarboxylic acids dehydragent, the 0.6-1.0 of mass parts gross weight, silane are even
Connection agent is NH2CH2CH2CH2Si(OC2H5)3And CH2-CH(OCH2-O(CH2)3Si(OCH3)3Or mixtures thereof one kind.
Embodiment 1
The present embodiment provides a kind of foamslag based geopolymer materials, specifically the preparation method comprises the following steps: by 35 parts of slags, 8
The metakaolin of part calcining, 5 parts of rice hull ash, 0.3 portion of foam stabilizer, 0.2 part of water-reducing agent, 7 parts of portland cements are put into ball in casserole
Mill, Ball-milling Time 25-30h obtains premix, spare, by the premix pour into cement plaster blender and with 2 parts of silicon
Alkane coupling agent, 25 parts of compound alkali-activators, 18 parts of water are uniformly mixed, mixing time 3min；0.5 part is added into above-mentioned slurry
Foaming agent, mechanical stirring make it completely dissolved, and then quickly stir and obtain a large amount of foam, 4min is persistently stirred, wait stablize
After obtain foam slurry.
Embodiment 2
The present embodiment provides a kind of foamslag based geopolymer materials, specifically the preparation method comprises the following steps: by 35 parts of slags, 8
The metakaolin of part calcining, 5 parts of rice hull ash, 0.3 portion of foam stabilizer, 0.2 part of water-reducing agent, 7 parts of portland cements are put into ball in casserole
Mill, Ball-milling Time 25-30h obtains premix, spare, by the premix pour into cement plaster blender and with 2 parts of silicon
Alkane coupling agent, 25 parts of compound alkali-activators, 18 parts of water are uniformly mixed, mixing time 3min；0.5 part is added into above-mentioned slurry
Foaming agent, mechanical stirring make it completely dissolved, and then quickly stir and obtain a large amount of foam, 3min is persistently stirred, wait stablize
After obtain foam slurry.
Embodiment 3
The present embodiment provides a kind of foamslag based geopolymer materials, specifically the preparation method comprises the following steps: by 35 parts of slags, 8
The metakaolin of part calcining, 5 parts of rice hull ash, 0.3 portion of foam stabilizer, 0.2 part of water-reducing agent, 7 parts of portland cements are put into ball in casserole
Mill, Ball-milling Time 25-30h obtains premix, spare, by the premix pour into cement plaster blender and with 2 parts of silicon
Alkane coupling agent, 25 parts of compound alkali-activators, 18 parts of water are uniformly mixed, mixing time 3min；0.5 part is added into above-mentioned slurry
Foaming agent, mechanical stirring make it completely dissolved, and then quickly stir and obtain a large amount of foam, 5min is persistently stirred, wait stablize
After obtain foam slurry.
Embodiment 4
The present embodiment provides a kind of foamslag based geopolymer materials, specifically the preparation method comprises the following steps: by 35 parts of slags, 8
The metakaolin of part calcining, 5 parts of rice hull ash, 0.3 portion of foam stabilizer, 0.2 part of water-reducing agent, 7 parts of portland cements are put into ball in casserole
Mill, Ball-milling Time 25-30h obtains premix, spare, by the premix pour into cement plaster blender and with 2 parts of silicon
Alkane coupling agent, 25 parts of compound alkali-activators, 18 parts of water are uniformly mixed, mixing time 3min；0.5 part is added into above-mentioned slurry
Foaming agent, mechanical stirring make it completely dissolved, and then quickly stir and obtain a large amount of foam, 5min is persistently stirred, wait stablize
After obtain foam slurry.
Embodiment 5
The present embodiment provides a kind of foamslag based geopolymer materials, specifically the preparation method comprises the following steps: by 35 parts of slags, 8
The metakaolin of part calcining, 5 parts of rice hull ash, 0.3 portion of foam stabilizer, 0.2 part of water-reducing agent, 7 parts of portland cements are put into ball in casserole
Mill, Ball-milling Time 25-30h obtains premix, spare, by the premix pour into cement plaster blender and with 2 parts of silicon
Alkane coupling agent, 25 parts of compound alkali-activators, 18 parts of water are uniformly mixed, mixing time 3min；0.5 part is added into above-mentioned slurry
Foaming agent, mechanical stirring make it completely dissolved, and then quickly stir and obtain a large amount of foam, 4min is persistently stirred, wait stablize
After obtain foam slurry.
Embodiment 6
The present embodiment provides a kind of foamslag based geopolymer materials, specifically the preparation method comprises the following steps: by 35 parts of slags, 8
The metakaolin of part calcining, 5 parts of rice hull ash, 0.3 portion of foam stabilizer, 0.2 part of water-reducing agent, 7 parts of portland cements are put into ball in casserole
Mill, Ball-milling Time 25-30h obtains premix, spare, by the premix pour into cement plaster blender and with 2 parts of silicon
Alkane coupling agent, 25 parts of compound alkali-activators, 18 parts of water are uniformly mixed, mixing time 3min；0.5 part is added into above-mentioned slurry
Foaming agent, mechanical stirring make it completely dissolved, and then quickly stir and obtain a large amount of foam, 3min is persistently stirred, wait stablize
After obtain foam slurry.
Test case
Using cement concrete/mortar country " GB/T26565-2011, GB/T1966-1996, GB/T50081-2002
And GB/T10247-2008 " standard, foamslag based geopolymer material prepared by embodiment 1-6 is tested for the property,
Its test result such as table 1, thermal coefficient is tested according to GB/T26565-2011, and porosity and bulk density are according to GB/T1966-
1996 are tested, and compression strength is tested according to GB/T50081-2002, and viscosity is surveyed according to GB/T10247-2008
Examination.
Table 1 is the performance test results of foamslag based geopolymer
Various embodiments of the present invention are described above, above description is exemplary, and more exhaustive, and
It is not limited to each embodiment of institute's careless mistake.Without departing from the scope and spirit of illustrated each embodiment, for this skill
Many modifications and changes are obvious for the those of ordinary skill in art field.
Claims (3)
1. a kind of foamslag based geopolymer material, it is characterised in that: include following component: compound alkali in terms of mass fraction
15-30 parts of exciting agent, 30-40 parts of slag, 7-9 parts of the metakaolin of calcining, 4-6 parts of rice hull ash, 6-8 parts of portland cement, water
It is 15-20 parts, 0.1-0.3 parts of water-reducing agent, 0.5-0.6 parts of foaming agent, 0.2-0.4 parts of foam stabilizer, 1-3 parts of silane coupling agent, fluxing
0.1-0.4 parts of agent.
2. foamslag based geopolymer material according to claim 1, it is characterised in that: the slag is using screening
Method was by ball ball mill ball milling 24-48 hours, so that average grain diameter is 0.096-0.105mm；
The preparation process of the metakaolin of the calcining is as follows: the temperature lower calcination 15-20h by kaolinite at 750 DEG C -850 DEG C,
Then it grinds, sieves, make its partial size 150-200nm；
The preparation process of the rice hull ash is as follows: the temperature lower calcination 6-8h by rice husk at 700 DEG C -800 DEG C, the rice hull ash
Partial size is 100-200nm；
The compound alkali-activator is the compound alkali-activator of salt-alkali using sodium sulphate and sodium metasilicate, sodium sulphate and sodium metasilicate
Weight mass ratio is 0.11-0.15:1；
The foaming agent is lauryl sodium sulfate, and solid content is 20~24%；
The foam stabilizer is the mixture using neopelex and triethanolamine, neopelex and three
The mass ratio of ethanol amine is 0.55-0.36:1；
The fluxing agent is the agar hydrosol, and solid content is 80-90%；
The ordinary portland cement is 42.5R ordinary portland cement；
The water-reducing agent is polycarboxylic acids dehydragent, the 0.6-1.0 of mass parts gross weight；
The silane coupling agent is NH2CH2CH2CH2Si(OC2H5)3Or/and CH2-CH(OCH2-O(CH2)3Si(OCH3)3。
3. a kind of preparation method for preparing foamslag based geopolymer material as claimed in claim 1 or 2, feature exist
In: include the following steps:
(1) compound alkali-activator 15-30 parts are weighed in terms of mass fraction, 30-40 parts of slag, 7-9 parts of the metakaolin of calcining,
4-6 parts of rice hull ash, 6-8 parts of portland cement, 15-20 parts of water, 0.1-0.3 parts of water-reducing agent, 0.5-0.6 parts of foaming agent, foam stabilizer
0.2-0.4 parts, 1-3 parts of silane coupling agent, 0.1-0.4 parts of fluxing agent；
(2) above-mentioned slag, the metakaolin of calcining, rice hull ash, foam stabilizer, water-reducing agent and portland cement are put into ball in casserole
Mill, Ball-milling Time 25-30h obtain premix；The premix and silane coupling agent, compound alkali-activator, water are mixed equal
It is even, mixing time 2-4min；
(3) foaming agent is added into above-mentioned slurry, mechanical stirring makes it completely dissolved, and then quickly stirs and obtains a large amount of bubble
Foam persistently stirs 3-5min, and foam slurry, i.e. foamslag based geopolymer material are obtained after stablizing.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112723801A (en) * | 2021-01-13 | 2021-04-30 | 武汉大学 | Cement concrete pavement rapid repairing material and preparation method thereof |
| CN115403298A (en) * | 2022-09-28 | 2022-11-29 | 北京工业大学 | Oleophobic base polymer composite foaming agent and preparation method thereof |
| CN115925334A (en) * | 2022-11-22 | 2023-04-07 | 西南石油大学 | High-titanium slag-based foamed geopolymer electromagnetic absorption material and preparation method thereof |
| EP4269370A1 (en) * | 2022-04-28 | 2023-11-01 | Giovanbattista Salzano | Process for the production of alkali-activated materials (aams), products obtainable with said process and heat insulating materials comprising said aam products |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102320782A (en) * | 2011-05-31 | 2012-01-18 | 华南理工大学 | Rice hull ash and metakaolin based polymer composite fireproof paint and preparation method thereof |
| CN102701656A (en) * | 2012-06-21 | 2012-10-03 | 重庆大学 | Metakaolin-based polymer foam concrete and preparation method thereof |
| CN103771822A (en) * | 2014-01-27 | 2014-05-07 | 同济大学 | Waterproof heat preservation material and preparation method thereof |
| CN108030961A (en) * | 2017-12-04 | 2018-05-15 | 上海富吉医疗器械有限公司 | Medical injection material and its preparation method and application |
| CN108424087A (en) * | 2018-05-29 | 2018-08-21 | 武汉轻工大学 | A kind of geopolymer base cement pavement crack fast repairing material and its preparation method and application |
-
2019
- 2019-09-18 CN CN201910878901.3A patent/CN110526632B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102320782A (en) * | 2011-05-31 | 2012-01-18 | 华南理工大学 | Rice hull ash and metakaolin based polymer composite fireproof paint and preparation method thereof |
| CN102701656A (en) * | 2012-06-21 | 2012-10-03 | 重庆大学 | Metakaolin-based polymer foam concrete and preparation method thereof |
| CN103771822A (en) * | 2014-01-27 | 2014-05-07 | 同济大学 | Waterproof heat preservation material and preparation method thereof |
| CN108030961A (en) * | 2017-12-04 | 2018-05-15 | 上海富吉医疗器械有限公司 | Medical injection material and its preparation method and application |
| CN108424087A (en) * | 2018-05-29 | 2018-08-21 | 武汉轻工大学 | A kind of geopolymer base cement pavement crack fast repairing material and its preparation method and application |
Non-Patent Citations (2)
| Title |
|---|
| 王晴等: "地聚物基泡沫混凝土制备与性能研究", 《混凝土》 * |
| 黄竞霖等: "吸水性地质聚合物多孔材料的制备与研究", 《陶瓷学报》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112723801A (en) * | 2021-01-13 | 2021-04-30 | 武汉大学 | Cement concrete pavement rapid repairing material and preparation method thereof |
| CN112723801B (en) * | 2021-01-13 | 2022-06-03 | 武汉大学 | Cement concrete pavement rapid repairing material and preparation method thereof |
| EP4269370A1 (en) * | 2022-04-28 | 2023-11-01 | Giovanbattista Salzano | Process for the production of alkali-activated materials (aams), products obtainable with said process and heat insulating materials comprising said aam products |
| CN115403298A (en) * | 2022-09-28 | 2022-11-29 | 北京工业大学 | Oleophobic base polymer composite foaming agent and preparation method thereof |
| CN115925334A (en) * | 2022-11-22 | 2023-04-07 | 西南石油大学 | High-titanium slag-based foamed geopolymer electromagnetic absorption material and preparation method thereof |
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