CN110523248A - A kind of constant temperature, multistage exhaust treatment system - Google Patents

A kind of constant temperature, multistage exhaust treatment system Download PDF

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Publication number
CN110523248A
CN110523248A CN201910741106.XA CN201910741106A CN110523248A CN 110523248 A CN110523248 A CN 110523248A CN 201910741106 A CN201910741106 A CN 201910741106A CN 110523248 A CN110523248 A CN 110523248A
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China
Prior art keywords
case
constant temperature
treatment system
exhaust treatment
scrubbing tower
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Pending
Application number
CN201910741106.XA
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Chinese (zh)
Inventor
赵云
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Jiangsu Xinjiuyang Environmental Protection Equipment Technology Co Ltd
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Jiangsu Xinjiuyang Environmental Protection Equipment Technology Co Ltd
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Priority to CN201910741106.XA priority Critical patent/CN110523248A/en
Publication of CN110523248A publication Critical patent/CN110523248A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/30Controlling by gas-analysis apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/40Acidic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/52Hydrogen sulfide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/90Odorous compounds not provided for in groups B01D2257/00 - B01D2257/708
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of constant temperature, multistage exhaust treatment system, including greenhouse and it is set to sequentially connected raw-gas pipeline in greenhouse, scrubbing tower, biological case, knockout drum, centrifugal blower and several heaters are additionally provided in greenhouse, centrifugal blower is for driving gas processed to recycle in system, the conducting of activated carbon adsorption case is equipped in outside air, scrubbing tower for driving the NaOH solution circulating pump that lye recycles in scrubbing tower.Heater of the invention is to guarantee the normal work of links in the present embodiment present system provides suitable temperature environment, especially ensure that microorganism is in suitable environment, provide advantageous external condition for its biological decomposition.The present embodiment successively passes through washing stage, bioanalysis degradation, absorption phase to exhaust gas.Wherein the washing stage has pH value monitoring point, it is ensured that rear stage microorganism is reliable, stable operation, and exhaust gas is relatively long in the residence time in biological stage, and absorption phase ensure that the qualified discharge of gas.

Description

A kind of constant temperature, multistage exhaust treatment system
Technical field
The present invention relates to exhaust gas, washing, biology, absorption, petrochemical industry, environment protection field fields, and in particular to a kind of constant temperature, multistage Section exhaust treatment system.
Background technique
Current major petrochemical plant, refinery factory, coke-oven plant, storage tank farm Deng Junyou sewage treatment plant, sewage treatment plant's surge tank, Between inclined plate oil removing, between air bearing, coagulating basin, flocculation basin, newly-built flotation tank, the pond A/O, sludge treatment facilities etc. foul waste gas need Carry out after closed collection through emission-control equipment handle could qualified discharge, such practical non-methane total hydrocarbons concentration of foul waste gas Lower, main component has: sulfide, benzene homologues, Ammonia etc., and common treatment process has incineration method, washing method, plasma, light to urge Change, absorption method, bioanalysis etc..In this context, such foul waste gas is passed through the above single technique by more enterprise customer's selection Processing, treatment effect, which exists, is unable to that longtime running is up to standard or operating cost is high, cannot especially open in environment temperature lower than -10 DEG C The extreme phenomenon of machine.
Northern Part of China is low in autumn and winter environment temperature, reachable -40 DEG C of limit low temperature hereinafter, more treatment process herein Normal boot-strap operation is unable under environment, as washing system freezes, microorganism cannot survive at low temperature.
Summary of the invention
To solve deficiency in the prior art, the present invention provides a kind of constant temperature, multistage exhaust treatment system, solves existing There is waste treatment system poor processing effect in technology, it can not be the technical issues of low temperature environment works normally.
In order to achieve the above objectives, the present invention adopts the following technical scheme:
A kind of constant temperature, multistage exhaust treatment system, it is characterised in that: including greenhouse and be set to sequentially connected original in greenhouse Gas pipeline, scrubbing tower, biological case, knockout drum, are additionally provided with centrifugal blower and several heaters in the greenhouse, it is described from Heart blower is for driving gas processed to recycle in system, and the activated carbon adsorption case conducting is in outside air, the washing Tower is equipped with for driving the NaOH solution circulating pump that lye recycles in scrubbing tower.
It is preferred that a kind of constant temperature above-mentioned, multistage exhaust treatment system, it is characterised in that: the biology case is additionally provided with battalion Nutrient solution circulating pump, the nutrient solution circulating pump is for driving nutrient solution to recycle in biological case.
It is preferred that a kind of constant temperature above-mentioned, multistage exhaust treatment system, it is characterised in that: the biology case is also connected with life Object case pH value monitor, the biology case pH value monitor connect ratio of nutrient solution tank by nutrient solution delivery pump.
It is preferred that a kind of constant temperature above-mentioned, multistage exhaust treatment system, it is characterised in that: the scrubbing tower, which is additionally provided with, to be washed Tower pH value monitor is washed, the scrubbing tower pH value monitor connects lye delivery pump, and the lye delivery pump is for matching lye Scrubbing tower is delivered to than the lye in tank.
It is preferred that a kind of constant temperature above-mentioned, multistage exhaust treatment system, it is characterised in that: it further include activated carbon adsorption case, The outlet side of the activated carbon adsorption case connection knockout drum;Activated carbon adsorption case automatic transfer valve also in parallel, it is described Automatic transfer valve is also connected with in-line analyzer, and the in-line analyzer connects system gas outlet.
It is preferred that a kind of constant temperature above-mentioned, multistage exhaust treatment system, it is characterised in that: the centrifugal blower is connected to The outlet side of activated carbon adsorption case.
It is preferred that a kind of constant temperature above-mentioned, multistage exhaust treatment system, it is characterised in that: it further include evacuated tube, the row Empty coupling systems for tubes gas outlet, the evacuated tube are set to outside greenhouse.
It is preferred that a kind of constant temperature above-mentioned, multistage exhaust treatment system, it is characterised in that: the biology case is that second level is raw Object case.
It is preferred that a kind of constant temperature above-mentioned, multistage exhaust treatment system, it is characterised in that: the nutrient solution delivery pump is Metering pump.
It is preferred that a kind of constant temperature above-mentioned, multistage exhaust treatment system, it is characterised in that: the lye delivery pump is meter Amount pump.
Advantageous effects of the invention:
Heater of the invention is to guarantee the normal work of links in the present embodiment present system provides suitable temperature environment Make, especially ensure that microorganism is in suitable environment, provide advantageous external condition for its biological decomposition.
The present embodiment successively passes through washing stage, bioanalysis degradation, absorption phase to exhaust gas.Wherein the washing stage has PH It is worth monitoring point, monitors exhaust gas pH value concentration in real time, it is ensured that rear stage microorganism is reliable, stable operation.
Bioanalysis degradation period is different from traditional biological technique, and bioanalysis degradation uses two stage biological degradation technique, exhaust gas Longer in the residence time in biological stage, treatment effect is more thorough, and by nutrient solution circulating pump, is used in micro- life of degradation Object can come into full contact with nutrient solution.
Absorption phase and the chain work of on-line monitoring instrument are switched to when discharge value is higher than setting value and arrange by absorption It puts, passes the gas through the purification of activated carbon adsorption case further progress, more effectively solve emission problem.
Detailed description of the invention
Fig. 1 is overall structure schematic diagram of the present invention;
The meaning of appended drawing reference: 1- lye proportioning tank;2- raw-gas pipeline;3- ratio of nutrient solution tank;4- lye delivery pump;5- is washed Wash tower;6- scrubbing tower pH value monitor;7- NaOH solution circulating pump;8- biology case;9- biology case pH value monitor;10- nutrient solution follows Ring pump;11- nutrient solution delivery pump;12- knockout drum;13- activated carbon adsorption case;14- automatic transfer valve;15- centrifugal blower; 16- in-line analyzer;17- evacuated tube;18- greenhouse;19- heater.
Specific embodiment
The invention will be further described below in conjunction with the accompanying drawings.Following embodiment is only used for clearly illustrating the present invention Technical solution, and not intended to limit the protection scope of the present invention.
Present embodiment discloses a kind of constant temperature, multistage exhaust treatment system as shown in Figure 1:: including greenhouse 18 and setting In be additionally provided in raw-gas pipeline 2 sequentially connected in greenhouse 18, scrubbing tower 5, biological case 8, knockout drum 12, greenhouse 18 from Heart blower 15 and several heaters 19, centrifugal blower 15 is for driving gas processed to recycle in system, activated carbon adsorption case 13 conductings are equipped in outside air, scrubbing tower 5 for driving the NaOH solution circulating pump 7 that lye recycles in scrubbing tower 5.
In order to promote the effect of biological decomposition, the preferred two stage biological case of biological case 8 of the present embodiment.Biological case 8 is also connected with Biological case pH value monitor 9, the pH value in biological 9 real-time monitoring biology case 8 of case pH value monitor, when its internal pH value is abnormal When, just influence whether the living environment of internal microorganism, biological case pH value monitor 9 is connected by nutrient solution delivery pump 11 at this time Ratio of nutrient solution tank 13, by the interior nutrient delivery of ratio of nutrient solution tank 13 to biological case 8.
Scrubbing tower 5 is additionally provided with scrubbing tower pH value monitor 6, and scrubbing tower pH value monitor 6 connects lye delivery pump 4, lye Delivery pump 4 is used to the lye in lye proportioning tank 1 being delivered to scrubbing tower 5.
The present embodiment further includes activated carbon adsorption case 13, and activated carbon adsorption case 13 connects the outlet side of knockout drum 12, Security measures of the activated carbon adsorption case 13 as terminal exhaust-gas treatment are equivalent to last one of safety measures, for further inhaling Organic principle in attached exhaust gas.The automatic transfer valve 14 also in parallel of activated carbon adsorption case 13, the control terminal of automatic transfer valve 14 are also connected with In-line analyzer 16, in-line analyzer 16 connect system gas outlet, and system gas outlet here refers to exhaust gas by all net Airflow channel after change processing, the effect of in-line analyzer 16 are exactly to detect to the gas after processing, are detected whether Compound discharge standard is just mounted at the air outlet of centrifugal blower 15 specific to the present embodiment.
Automatic transfer valve 14 is on state under normal circumstances, when its conducting, is formed to activated carbon adsorption case 13 short Road, causes gas without activated carbon adsorption case 13, and gas after in-line analyzer 16 detects processing does not meet discharge When standard, automatic transfer valve 14 is closed, passes the gas through the purification of 13 further progress of activated carbon adsorption case.
The centrifugal blower 15 of the present embodiment is preferably attached to the outlet side of activated carbon adsorption case 13, and centrifugal blower 15 is to whole A offer power, centrifugal blower 15 can overcome all resistance drops of this system when working, while system is formed tiny structure, make whole A system No leakage operation, it is ensured that system operational safety.
The present embodiment further includes evacuated tube 17, and evacuated tube 17 connects system gas outlet, and evacuated tube 17 is set to outside greenhouse 18 Portion.
When work, foul waste gas enters to scrubbing tower 5 from raw-gas pipeline 2, and the bottom of scrubbing tower 5 is equipped with lye pond, leads to The ringing for crossing NaOH solution circulating pump 7 sprays gas by lye, the sour gas such as hydrogen sulfide in washing absorption exhaust gas Body, while increasing the humidity in exhaust gas, when the alkalinity decline in lye pond, lye delivery pump 4 works, new lye is supplemented, Lye delivery pump 4 is metering pump, with the chain work of pH value alarm 6, the component of the lye of accurate statistics discharge, it is ensured that lye pond Interior lye is moderate.
Furthermore the PH of gas is discharged in scrubbing tower pH value monitor 6 and lye delivery pump 4 also strict control from scrubbing tower 5 Value, this is because pH value directly influences the living environment of microorganism (in biological case 8).
During exhaust gas passes through second level deodoration system biologic packing material in biological case 8, odor molecules therein are diffused into On the biomembrane that biologic packing material surface is formed, microorganism is odor molecules oxygenolysis, to eliminate odor pollution;Nutrient input Sending pump 11 is metering pump, and running parameter (flow velocity, flow) is controlled by biological case pH value monitor 9.Gas is discharged through biological case 8 It enters to knockout drum 12 later, reduces the steam in discharge exhaust gas, subsequently into cutting to activated carbon adsorption case 13 or automatically Valve 14 is changed, is discharged through centrifugal blower 15.
The preferred hot-water heater of heater 19 of the present embodiment, heater 19 are that present system provides suitable temperature rings Border guarantees the normal work of links in the present embodiment, especially ensure that microorganism is in suitable environment, be Its biological decomposition provides advantageous external condition.
The present embodiment successively passes through washing stage, bioanalysis degradation, absorption phase to exhaust gas.Wherein the washing stage has PH It is worth monitoring point (scrubbing tower pH value monitor 6), monitors exhaust gas pH value concentration in real time, it is ensured that rear stage microorganism is reliable, stablizes fortune Row.
Bioanalysis degradation period is different from traditional biological technique, and bioanalysis degradation uses two stage biological degradation technique, exhaust gas Longer in the residence time in biological stage, treatment effect is more thorough, and by nutrient solution circulating pump 10, is used in the micro- of degradation Biology can come into full contact with nutrient solution.
Absorption phase and on-line monitoring instrument (in-line analyzer 16) chain work switch when discharge value is higher than setting value To by absorption (activated carbon adsorption case 13) discharge, the purification of 13 further progress of activated carbon adsorption case is passed the gas through.More effectively Ground solves emission problem.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, several improvement and deformations can also be made, these improvement and deformations Also it should be regarded as protection scope of the present invention.

Claims (10)

1. a kind of constant temperature, multistage exhaust treatment system, it is characterised in that: including greenhouse (18) and be set to suitable in greenhouse (18) The raw-gas pipeline (2) of secondary connection, scrubbing tower (5), biological case (8), knockout drum (12), the greenhouse (18) is interior to be additionally provided with Centrifugal blower (15) and several heaters (19), the centrifugal blower (15) are used to that gas processed to be driven to recycle in system, In outside air, the scrubbing tower (5) is equipped with for driving scrubbing tower (5) interior lye to follow for activated carbon adsorption case (13) conducting The NaOH solution circulating pump (7) of ring.
2. a kind of constant temperature according to claim 1, multistage exhaust treatment system, it is characterised in that: the biology case (8) It is additionally provided with nutrient solution circulating pump (10), the nutrient solution circulating pump (10) is for driving nutrient solution circulation in biological case (8).
3. a kind of constant temperature according to claim 1 or 2, multistage exhaust treatment system, it is characterised in that: the biology case (8) it is also connected with biological case pH value monitor (9), the biology case pH value monitor (9) is connected by nutrient solution delivery pump (11) Ratio of nutrient solution tank (13).
4. a kind of constant temperature according to claim 1, multistage exhaust treatment system, it is characterised in that: the scrubbing tower (5) It is additionally provided with scrubbing tower pH value monitor (6), the scrubbing tower pH value monitor (6) connects lye delivery pump (4), and the lye is defeated Send pump (4) for the lye in lye proportioning tank (1) to be delivered to scrubbing tower (5).
5. a kind of constant temperature according to claim 1, multistage exhaust treatment system, it is characterised in that: further include active carbon Adsorption box (13), the outlet side of activated carbon adsorption case (13) connection knockout drum (12);The activated carbon adsorption case (13) automatic transfer valve (14) also in parallel, the automatic transfer valve (14) are also connected with in-line analyzer (16), the on-line analysis Instrument (16) connects system gas outlet.
6. a kind of constant temperature according to claim 5, multistage exhaust treatment system, it is characterised in that: the centrifugal blower (15) it is connected to the outlet side of activated carbon adsorption case (13).
7. a kind of constant temperature according to claim 1, multistage exhaust treatment system, it is characterised in that: further include evacuated tube (17), the evacuated tube (17) connects system gas outlet, and it is external that the evacuated tube (17) is set to greenhouse (18).
8. a kind of constant temperature according to claim 1 or 2, multistage exhaust treatment system, it is characterised in that: the biology case It (8) is two stage biological case.
9. a kind of constant temperature according to claim 3, multistage exhaust treatment system, it is characterised in that: the nutrient input Sending pump (11) is metering pump.
10. a kind of constant temperature according to claim 4, multistage exhaust treatment system, it is characterised in that: the lye conveying Pumping (4) is metering pump.
CN201910741106.XA 2019-08-12 2019-08-12 A kind of constant temperature, multistage exhaust treatment system Pending CN110523248A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013027817A (en) * 2011-07-28 2013-02-07 National Agriculture & Food Research Organization Method and apparatus for leveling odor quantity
KR20140096806A (en) * 2013-01-29 2014-08-06 (주)파인텍 The separation and recycling system for a perfluoro compounds that have a separation fillter heating equipment
CN106345253A (en) * 2016-11-18 2017-01-25 广西金邦泰科技有限公司 Waste gas treatment device
CN107349769A (en) * 2017-08-18 2017-11-17 安徽省科林环境生物技术有限公司 A kind of beer waste water foul smell puies forward mark processing system and technique
CN207153433U (en) * 2017-07-05 2018-03-30 周艳 One kind is applied to processing high-concentration waste Flash Gas Compression Skid System
CN108854355A (en) * 2018-08-28 2018-11-23 湖北君集水处理有限公司 A kind of system and method for sewage treatment plant's foul smell Collecting and dealing

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Publication number Priority date Publication date Assignee Title
JP2013027817A (en) * 2011-07-28 2013-02-07 National Agriculture & Food Research Organization Method and apparatus for leveling odor quantity
KR20140096806A (en) * 2013-01-29 2014-08-06 (주)파인텍 The separation and recycling system for a perfluoro compounds that have a separation fillter heating equipment
CN106345253A (en) * 2016-11-18 2017-01-25 广西金邦泰科技有限公司 Waste gas treatment device
CN207153433U (en) * 2017-07-05 2018-03-30 周艳 One kind is applied to processing high-concentration waste Flash Gas Compression Skid System
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Application publication date: 20191203